A review on spatial self-phase modulation of two-dimensional materials

Self-diffraction appears when the strong laser goes through two-dimensional material suspension,and this spatial self-phase modulation(SPPM)phenomenon can be used to measure nonlinear optical parameters and achieve optical switch.At present,the mechanism of SPPM is still ambiguous.The debate mainly focuses on whether the phenomenon is caused by the nonlinear refractive index of the two-dimensional material or the thermal effect of the laser.The lack of theory limits the dimension of the phase modulation to the radius of the diffraction ring and the vertical imbalance.Therefore,it is urgent to establish a unified and universal SSPM theoretical system of two-dimensional material.

Pulse Propagation with Self-Phase Modulation in Nonlinear Chiral Fiber and Its Applications

From Maxwell＇s equations and Post＇s formalism, a generalized chiral nonlinear Schr6dinger equation （CNLSE） is obtained for the nonlinear chiral fiber. This equation governs light transmission through a dispersive nonlinear chiral fiber with joint action of chirality in linear and nonlinear ways. The generalized CNLSE shows a modu- lation of chirality to the effect of attenuation and nonlinearity compared with the case for a conventional fiber. Simulations based on the split-step beam propagation method reveal the role of nonlinearity with cooperation to chirality playing in the pulse evolution. By adjusting its strength the role of chirality in forming solitons is demonstrated for a given circularly polarized component. The application of nonlinear optical rotation is also discussed in an all-optical switch.

350-2500 nm supercontinuum white laser enabled by synergic high-harmonic generation and self-phase modulation

Supercontinuum white laser with large bandwidth and high pulse energy would offer incredible versatility and opportunities for basic science and high technology applications. Here, we report the generation of high-efficiency 2.8-octave-spanning ultraviolet- visible-infrared (UV-Vis-IR) (with 350-2500 nm 25 dB bandwidth) supercontinuum white laser from a single chirped periodically poled lithium niobate (CPPLN) nonlinear crystal via synergic high-harmonic generation (HHG) and self-phase modulation (SPM). The CPPLN exhibits multiple controllable reciprocal-lattice bands to simultaneously support the quasi-phase matching (QPM) for simultaneous broadband 2nd-10th HHG via cascaded three-wave mixing against a broadband fundamental pump laser. Due to the efficient second-order nonlinearity (2nd-NL) up-conversion and significant 3rd-NL SPM effect both in the pump and HHG laser pulses, 350-2500 nm supercontinuum white laser is eventually obtained with 17 μJ per pulse under pump of 45 μJ per pulse mid-infrared femtosecond laser corresponding to an average high conversion efficiency of 37%. Our work opens up a route towards creating UV-Vis-IR all-spectrum white lasers through engineering the synergic action of HHG and SPM effects in nonlinear crystals for applications in ultrafast spectroscopy, single-shot remote sensing, biological imaging, and so on.

Highly efficient transient stimulated Raman scattering on secondary vibrational mode of BaWO_(4) crystal due to its constructive interference with self-phase modulation

An exceptionally high stimulated Raman scattering[SRS]conversion efficiency to the first Stokes component associated with the secondary[low-frequency and low intensity]vibrational mode v2[~330 cm^[-1]]was observed in a BaWO4 crystal in a highly transient regime of interaction.The effect takes place in the range of pump pulse energy from~0.1 to~0.5μJ with maximum energy conversion efficiency up to 35%at 0.2μJ.The nature of the observed effects is explained by interference of SRS and self-phase modulation,where the latter is related to a noninstantaneous orientational Kerr nonlinearity in the BaWO4 crystal.

High-Quality Ultrashort Pulse Generation Utilizing a Self-Phase Modulation-Based Reshaper

An ultrashort 10-GHz pulse generation scheme was successfully demonstrated using a bulk material InGaAsP electroabsorption modulator to generate the seed pulse. A self-phase modulation-based reshaper was used after the adiabatic soliton compression in a comb-like dispersion profiled fiber. Experiments and simulations confirm that the reshaper effectively removes the pulse pedestal and improves the pulse extinction ratio. As a result, the 10-GHz pulse had no pedestal, a high extinction ratio, and a pulse width of only 1.4 ps.

Effect of concentration on the formation time of diffraction rings in spatial self-phase modulation

A new unsaturated wind-chime model is proposed for calculating the formation time of the diffraction rings induced by spatial self-phase modulation(SSPM) in molybdenum disulfide suspension.To optimize the traditional wind-chime model,the concentration variable of 2 D materials was introduced.The results of the unsaturated wind-chime model match quite well with the SSPM experimental results of molybdenum disulfide.Based on this model,the shortest formation time of diffraction rings and their corresponding concentration and light intensity can be predicted using limited data.Theoretically,by increasing the viscosity coefficient of the solution,the response time of the diffraction ring,to reach the maximum value,can be significantly reduced.It has advanced significance in shortening the response time of photonic diodes.

Defect Engineering with Rational Dopants Modulation for High‑Temperature Energy Harvesting in Lead‑Free Piezoceramics

High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.

Increase in the variability of terrestrial carbon uptake in response to enhanced future ENSO modulation

El Niño-Southern Oscillation(ENSO)is a major driver of climate change in middle and low latitudes and thus strongly influences the terrestrial carbon cycle through land-air interaction.Both the ENSO modulation and carbon flux variability are projected to increase in the future,but their connection still needs further investigation.To investigate the impact of future ENSO modulation on carbon flux variability,this study used 10 CMIP6 earth system models to analyze ENSO modulation and carbon flux variability in middle and low latitudes,and their relationship,under different scenarios simulated by CMIP6 models.The results show a high consistency in the simulations,with both ENSO modulation and carbon flux variability showing an increasing trend in the future.The higher the emissions scenario,especially SSP5-8.5 compared to SSP2-4.5,the greater the increase in variability.Carbon flux variability in the middle and low latitudes under SSP2-4.5 increases by 30.9%compared to historical levels during 1951-2000,while under SSP5-8.5 it increases by 58.2%.Further analysis suggests that ENSO influences mid-and low-latitude carbon flux variability primarily through temperature.This occurrence may potentially be attributed to the increased responsiveness of gross primary productivity towards regional temperature fluctuations,combined with the intensified influence of ENSO on land surface temperatures.

Crystallization Modulation and Holistic Passivation Enables Efficient Two‑Terminal Perovskite/CuIn(Ga)Se_(2)Tandem Solar Cells

Two-terminal(2-T)perovskite(PVK)/CuIn(Ga)Se_(2)(CIGS)tandem solar cells(TSCs)have been considered as an ideal tandem cell because of their best bandgap matching regarding to Shockley–Queisser(S–Q)limits.However,the nature of the irregular rough morphology of commercial CIGS prevents people from improving tandem device performances.In this paper,D-homoserine lactone hydrochloride is proven to improve coverage of PVK materials on irregular rough CIGS surfaces and also passivate bulk defects by modulating the growth of PVK crystals.In addition,the minority carriers near the PVK/C60 interface and the incompletely passivated trap states caused interface recombination.A surface reconstruction with 2-thiopheneethylammonium iodide and N,N-dimethylformamide assisted passivates the defect sites located at the surface and grain boundaries.Meanwhile,LiF is used to create this field effect,repelling hole carriers away from the PVK and C60 interface and thus reducing recombination.As a result,a 2-T PVK/CIGS tandem yielded a power conversion efficiency of 24.6%(0.16 cm^(2)),one of the highest results for 2-T PVK/CIGS TSCs to our knowledge.This validation underscores the potential of our methodology in achieving superior performance in PVK/CIGS tandem solar cells.

Enhancement of chaotic carrier bandwidth in a semiconductor laser transmitter using self-phase modulation in an optical fiber external round cavity

A novel method to enhance the bandwidth of a chaotic carrier from a delayed feedback semiconductor laser transmitter is pre- sented using self-phase modulation (SPM) in an optical fiber external round cavity. A physical model of the laser dynamics is established under the condition of optical feedback light with the SPM effect in the fiber path. A formula for frequency detuning of the optical dual-feedback under SPM is theoretically deduced. The results show that the nonlinear phase shift caused by SPM has an impact on the gain and bandwidth enhancement factor of the laser. The second-order nonlinear effect of the fiber enriches the variety of the amplitudes and phases of the laser while the nonlinear phase shift produces a number of new frequencies, which can spread the bandwidth. Numerical results reveal that with the SPM effect, the bandwidth can be enhanced 4 times more than the bandwidth without it, and the relaxation oscillation frequency of the chaotic laser is increased to 2.56 times more than that of the laser without the fiber path. The enhancement of the chaotic bandwidth can be extended by increasing the optical fiber length, the coupling-feedback ratio, the mirror reflectance and the second order nonlinear coefficient affect.

Self-phase modulation via similariton solutions of the perturbed NLSE Modulation instability and induced self-steepening

The perturbed nonlinear Schrodinger equation(PNLSE)describes the pulse propagation in optical fibers,which results from the interaction of the higher-order dispersion effect,self-steepening(SS)and self-phase modulation(SPM).The challenge between these aforementioned phenomena may lead to a dominant one among them.It is worth noticing that the study of modulation instability(MI)leads to the inspection of dominant phenomena(DPh).Indeed,the MI triggers when the coefficient of DPh exceeds a critical value and it may occur that the interaction leads to wave compression.The PNLSE is currently studied in the literature,mainly on finding traveling wave solutions.Here,we are concerned with analyzing the similarity solutions of the PNLSE.The exact solutions are obtained via introducing similarity transformations and by using the extended unified method.The solutions are evaluated numerically and they are shown graphically.It is observed that the intensity of the pulses exhibits self steepening which progresses to shock soliton in ultrashort time(or near t=0).Also,it is found that the real part of the solution exhibits self-phase modulation in time.The study of(MI)determines the critical value for the coefficients of SS,SPM,or high dispersivity to occur.

High photoelectric conversion efficiency and fast relaxation time of FA_(0.4)MA_(0.6)PbI_(3) applied in ultrafast modulation of terahertz waves

Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufacturing process,has emerged as a promising candidate for optoelectronic applications.However,the exploration of perovskites in optically controlled THz modulators is still limited.In this work,the photoelectric properties and carrier dynamics of FA_(0.4)MA_(0.6)PbI_(3)perovskite films were investigated by optical pumped terahertz probe(OPTP)system.The ultrafast carrier dynamics reveal that FA_(0.4)MA_(0.6)PbI_(3)thin film exhibits rapid switching and relaxation time within picosecond level,suggesting that FA_(0.4)MA_(0.6)PbI_(3)is an ideal candidate for active THz devices with ultrafast response.Furthermore,as a proof of concept,a FA_(0.4)MA_(0.6)PbI_(3)-based metadevice with integrating plasma-induced transparency(PIT)effect was fabricated to achieve ultrafast modulation of THz wave.The experimental results demonstrated that the switching time of FA_(0.4)MA_(0.6)PbI_(3)-based THz modulator is near to 3.5 ps,and the threshold of optical pump is as low as 12.7μJ cm^(-2).The simulation results attribute the mechanism of ultrafast THz modulation to photo-induced free carriers in the FA_(0.4)MA_(0.6)PbI_(3)layer,which progressively shorten the capacitive gap of PIT resonator.This study not only illuminates the potential of FA_(0.4)MA_(0.6)PbI_(3)in THz modulation,but also contributes to the field of ultrafast photonic devices.

Design of Protograph LDPC-Coded MIMO-VLC Systems with Generalized Spatial Modulation

This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID scheme, the information bits conveyed by the signal-domain(SiD) symbols and the spatial-domain(SpD) light emitting diode(LED)-index patterns are coded by a protograph low-density parity-check(P-LDPC) code. Specifically, we propose a signal-domain symbol expanding and re-allocating(SSER) method for constructing a type of novel generalized spatial modulation(GSM) constellations, referred to as SSERGSM constellations, so as to boost the performance of the BICGSM-ID MIMO-VLC systems.Moreover, by applying a modified PEXIT(MPEXIT) algorithm, we further design a family of rate-compatible P-LDPC codes, referred to as enhanced accumulate-repeat-accumulate(EARA) codes,which possess both excellent decoding thresholds and linear-minimum-distance-growth property. Both analysis and simulation results illustrate that the proposed SSERGSM constellations and P-LDPC codes can remarkably improve the convergence and decoding performance of MIMO-VLC systems. Therefore, the proposed P-LDPC-coded SSERGSM-mapped BICGSMID configuration is envisioned as a promising transmission solution to satisfy the high-throughput requirement of MIMO-VLC applications.

From VIB‑to VB‑Group Transition Metal Disulfides:Structure Engineering Modulation for Superior Electromagnetic Wave Absorption

The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance.

Systemic modulation of skeletal mineralization by magnesium implant promoting fracture healing: Radiological exploration enhanced with PCA-based machine learning in a rat femoral model

The clinical application of magnesium(Mg)and its alloys for bone fractures has been well supported by in vitro and in vivo trials.However,there were studies indicating negative effects of high dose Mg intake and sustained local release of Mg ions on bone metabolism or repair,which should not be ignored when developing Mg-based implants.Thus,it remains necessary to assess the biological effects of Mg implants in animal models relevant to clinical treatment modalities.The primary purpose of this study was to validate the beneficial effects of intramedullary Mg implants on the healing outcome of femoral fractures in a modified rat model.In addition,the mineralization parameters at multiple anatomical sites were evaluated,to investigate their association with healing outcome and potential clinical applications.Compared to the control group without Mg implantation,postoperative imaging at week 12 demonstrated better healing outcomes in the Mg group,with more stable unions in 3D analysis and high-mineralized bridging in 2D evaluation.The bone tissue mineral density(TMD)was higher in the Mg group at the non-operated femur and lumbar vertebra,while no differences between groups were identified regarding the bone tissue volume(TV),TMD and bone mineral content(BMC)in humerus.In the surgical femur,the Mg group presented higher TMD,but lower TV and BMC in the distal metaphyseal region,as well as reduced BMC at the osteotomy site.Principal component analysis(PCA)-based machine learning revealed that by selecting clinically relevant parameters,radiological markers could be constructed for differentiation of healing outcomes,with better performance than 2D scoring.The study provides insights and preclinical evidence for the rational investigation of bioactive materials,the identification of potential adverse effects,and the promotion of diagnostic capabilities for fracture healing.

Nano-Au-decorated hierarchical porous cobalt sulfide derived from ZIF-67 toward optimized oxygen evolution catalysis:Important roles of microstructures and electronic modulation

Enhancing both the number of active sites available and the intrinsic activity of Co-based electrocatalysts simultaneously is a desirable goal.Herein,a ZIF-67-derived hierarchical porous cobalt sulfide decorated by Au nanoparticles(NPs)(denoted as HP-Au@CoxSy@ZIF-67)hybrid is synthesized by low-temperature sulfuration treatment.The well-defined macroporous-mesoporous-microporous structure is obtained based on the combination of polystyrene spheres,as-formed CoxSy nanosheets,and ZIF-67 frameworks.This novel three-dimensional hierarchical structure significantly enlarges the three-phase interfaces,accelerating the mass transfer and exposing the active centers for oxygen evolution reaction.The electronic structure of Co is modulated by Au through charge transfer,and a series of experiments,together with theoretical analysis,is performed to ascertain the electronic modulation of Co by Au.Meanwhile,HP-Au@CoxSy@ZIF-67 catalysts with different amounts of Au were synthesized,wherein Au and NaBH4 reductant result in an interesting“competition effect”to regulate the relative ratio of Co^(2+)/Co^(3+),and moderate Au assists the electrochemical performance to reach the highest value.Consequently,the optimized HP-Au@CoxSy@ZIF-67 exhibits a low overpotential of 340 mV at 10 mA cm^(-2)and a Tafel slope of 42 mV dec-1 for OER in 0.1 M aqueous KOH,enabling efficient water splitting and Zn-air battery performance.The work here highlights the pivotal roles of both microstructural and electronic modulation in enhancing electrocatalytic activity and presents a feasible strategy for designing and optimizing advanced electrocatalysts.

Automatic modulation recognition of radio fuzes using a DR2D-based adaptive denoising method and textural feature extraction

The identification of intercepted radio fuze modulation types is a prerequisite for decision-making in interference systems.However,the electromagnetic environment of modern battlefields is complex,and the signal-to-noise ratio(SNR)of such environments is usually low,which makes it difficult to implement accurate recognition of radio fuzes.To solve the above problem,a radio fuze automatic modulation recognition(AMR)method for low-SNR environments is proposed.First,an adaptive denoising algorithm based on data rearrangement and the two-dimensional(2D)fast Fourier transform(FFT)(DR2D)is used to reduce the noise of the intercepted radio fuze intermediate frequency(IF)signal.Then,the textural features of the denoised IF signal rearranged data matrix are extracted from the statistical indicator vectors of gray-level cooccurrence matrices(GLCMs),and support vector machines(SVMs)are used for classification.The DR2D-based adaptive denoising algorithm achieves an average correlation coefficient of more than 0.76 for ten fuze types under SNRs of-10 d B and above,which is higher than that of other typical algorithms.The trained SVM classification model achieves an average recognition accuracy of more than 96%on seven modulation types and recognition accuracies of more than 94%on each modulation type under SNRs of-12 d B and above,which represents a good AMR performance of radio fuzes under low SNRs.

High-speed autopolarization synchronization modulation three-dimensional structured illumination microscopy

In recent years,notable progress has been achieved in both the hardware and algorithms of structured illumination microscopy(SIM).Nevertheless,the advancement of three-dimensional structured illumination microscopy(3DSIM)has been impeded by challenges arising from the speed and intricacy of polarization modulation.We introduce a high-speed modulation 3DSIM system,leveraging the polarizationmaintaining and modulation capabilities of a digital micromirror device(DMD)in conjunction with an electrooptic modulator.The DMD-3DSIM system yields a twofold enhancement in both lateral(133 nm)and axial(300 nm)resolution compared to wide-field imaging and can acquire a data set comprising 29 sections of 1024 pixels×1024 pixels,with 15 ms exposure time and 6.75 s per volume.The versatility of the DMD-3DSIM approach was exemplified through the imaging of various specimens,including fluorescent beads,nuclear pores,microtubules,actin filaments,and mitochondria within cells,as well as plant and animal tissues.Notably,polarized 3DSIM elucidated the orientation of actin filaments.Furthermore,the implementation of diverse deconvolution algorithms further enhances 3D resolution.The DMD-based 3DSIM system presents a rapid and reliable methodology for investigating biomedical phenomena,boasting capabilities encompassing 3D superresolution,fast temporal resolution,and polarization imaging.

Parallel generation of low-correlation wideband complex chaotic signals using CW laser and external-cavity laser with self-phase-modulated injection

A novel scheme for generating optical chaos is proposed and experimentally demonstrated,which supports to simultaneously produce two low-correlation chaotic signals with wideband spectrum and suppressed time-delay-signature(TDS).In the proposed scheme,we use the output of an external-cavity semiconductor laser(ECSL)as the driving signal of a phase modulator to modulate the output of a CW laser.Then the phase-modulated continuous-wave(CW)light is split into two parts,one is injected back into the ECSL that outputs one chaotic signal,while the other part is passed through a dispersion module for generating another chaotic signal simultaneously.The experimental results prove that the proposed scheme has three merits.Firstly,it can improve the bandwidth of ECSL-based chaos by several times,and simultaneously generate another wideband flat-spectrum chaotic signal.Secondly,the undesired TDS characteristics of the simultaneously-generated chaotic signals can be efficiently suppressed to an indistinguishable level within a wide parameter range,as such the complexities of the chaotic signals are considerably high.Thirdly,the correlation coefficient between these two simultaneously-generated chaotic signals is smaller than 0.1.The proposed scheme provides an attractive solution for parallel multiple chaos generation,and shows great potential for multiple channel chaos communications and multiple random bit generations.

Interference-induced suppression of particle emission from a Bose-Einstein condensate in lattice with time-periodic modulations

Emission of matter-wave jets from a parametrically driven condensate has attracted significant experimental and theoretical attention due to the appealing visual effects and potential metrological applications.In this work,we investigate the collective particle emission from a Bose-Einstein condensate confined in a one-dimensional lattice with periodically modulated interparticle interactions.We give the regimes for discrete modes,and find that the emission can be distinctly suppressed.The configuration induces a broad band,but few particles are ejected due to the interference of the matter waves.We further qualitatively model the emission process and demonstrate the short-time behaviors.This engineering provides a way to manipulate the propagation of particles and the corresponding dynamics of condensates in lattices,and may find application in the dynamical excitation control of other nonequilibrium problems with time-periodic driving.