Properties of Self-recoverable Mechanoluminescence Phosphor Ca_(5)Ga_(6)O_(14)∶Eu^(3+) and Its Information Encryption Application

A novel self-recoverable mechanoluminescent phosphor Ca_(5)Ga_(6)O_(14)∶Eu^(3+) was developed by the high-tem-perature solid-state reaction method,and its luminescence properties were investigated.Ca_(5)Ga_(6)O_(14)∶Eu^(3+)can produce red mechanoluminescence,and importantly,it shows good repeatability.The mechanoluminescence of Ca_(5)Ga_(6)O_(14)∶Eu^(3+) results from the piezoelectric field generated inside the material under stress,rather than the charge carriers stored in the traps,which can be confirmed by the multiple cycles of mechanoluminescence tests and heat treatment tests.The mechanoluminescence color can be turned from red to green by co-doping varied concentrations of Tb^(3+),which may be meaningful for encrypted letter writing.The encryption scheme for secure communication was devised by harnessing mechanoluminescence patterns in diverse shapes and ASCII codes,which shows good encryption performance.The results suggest that the mechanoluminescence phosphor Ca_(5)Ga_(6)O_(14)∶Eu^(3+),Tb^(3+)may be applied to the optical information encryption.

Design of Novel and Low Cost Triple-node Upset Self-recoverable Latch

With the development of semiconductor technology,the size of transistors continues to shrink.In complex radiation environments in aerospace and other fields,small-sized circuits are more prone to soft error(SE).Currently,single-node upset(SNU),double-node upset(DNU)and triple-node upset(TNU)caused by SE are relatively common.TNU’s solution is not yet fully mature.A novel and low-cost TNU self-recoverable latch(named NLCTNURL)was designed which is resistant to harsh radiation effects.When analyzing circuit resiliency,a double-exponential current source is used to simulate the flipping behavior of a node’s stored value when an error occurs.Simulation results show that the latch has full TNU self-recovery.A comparative analysis was conducted on seven latches related to TNU.Besides,a comprehensive index combining delay,power,area and self-recovery—DPAN index was proposed,and all eight types of latches from the perspectives of delay,power,area,and DPAN index were analyzed and compared.The simulation results show that compared with the latches LCTNURL and TNURL which can also achieve TNU self-recoverable,NLCTNURL is reduced by 68.23%and 57.46%respectively from the perspective of delay.From the perspective of power,NLCTNURL is reduced by 72.84%and 74.19%,respectively.From the area perspective,NLCTNURL is reduced by about 28.57%and 53.13%,respectively.From the DPAN index perspective,NLCTNURL is reduced by about 93.12%and 97.31%.The simulation results show that the delay and power stability of the circuit are very high no matter in different temperatures or operating voltages.

Self-recoverable NIR mechanoluminescence from Cr^(3+) doped perovskite type aluminate

Mechanoluminescent(ML)materials,which have the ability to convert mechanical energy to optical energy,have found huge promising applications such as in stress imaging and anti-counterfeiting.However,the main reported ML phosphors are based on trap-related ones,thus hindering the practical applications due to the requirement of complex light pre-irradiation process.Here,a self-recoverable near infrared(NIR)ML material of Lali-xO:xCr^(3+)(x=0.2%,0.4%,0.6%,0.8%,1.0%,and 1.2%)has been developed.Based on the preheating method and corresponding ML performance analysis,the influences of residual carriers are eliminated and the detailed dynamic luminescence process analysis is realized.Systematic experiments are conducted to reveal the origin of the ML emissions,demonstrating that ML is dictated more by the non-centrosymmetric piezoelectric crystal characteristic.In general,this work has provided significant references for exploring more efficient NIR ML materials,which may provide potential applications in anti-counterfeiting and bio-stress sensing.

Ultra-robust Metallosupramolecular Hydrogels with Unprecedented Self-recoverability using Asymmetrically Distributed Carboxyl-Fe3+Coordination Interactions

Recently,numerous mechanically robust synthetic hydrogels have been created.However,unlike natural loading-bearing materials such as cartilages and muscles,most hydrogels have inherently contradictory requirements,obstructing the design of hydrogels with characteristics of robustness and rapid self-recoverability.Herein,we present a facile strategy for constructing mechanically robust and rapidly self-recoverable hydrogels.The linear poly(acrylamide-co-itaconic acid)chains crosslink via coordination bonds and minimal chemical crosslinkers to form the hydrogel network.Such design endows the coordination interactions to be asymmetrically distributed.Under deformation,the coordination interactions exhibit a reversible dissociation-and-reorganization property,demonstrating a new mechanism for energy dissipation and stress redistribution.Thus,the hydrogels possess tensile strength up to 12.5 MPa and toughness up to 28.2 MJ/m3.Moreover,the inherent dynamic nature of the coordination bonds imparts these hydrogels with stretch rate-and temperature-dependent mechanical behavior as well as excellent self-recovery performance.The method employed in this study is universal and is applicable to other polymers with load-bearing yet rapid recovery conditions.This study will facilitate diverse applications of most metallosupramolecular hydrogels.