Improving the activity of Iron Ore Tailings(IOTs)to utilize them as a mineral admixture in cement-based minerals is still challenging.In this paper,the wet grinding technology was employed to stimulate the activity of...Improving the activity of Iron Ore Tailings(IOTs)to utilize them as a mineral admixture in cement-based minerals is still challenging.In this paper,the wet grinding technology was employed to stimulate the activity of IOTs,and the traditional dry grinding method was used as a reference.The effect of wet grinding on the activation of IOTs was evaluated through ion leaching from an alkaline solution and the reactivity index.Additionally,a detailed comparison between Dry-grinding Iron Ore Tailings(DIOTs)and Wet-grinding Iron Ore Tailings(WIOTs)was made.This comparison was based on particle characteristics,crystal structures,chemical structure,and surface properties.The results showed that the particle size of IOTs reduced rapidly during wet grinding.In addition,WIOTs had a higher activity index compared to DIOTs.The storage of lattice distortions in the quartz crystal structure was also more significant during the wet grinding process than during the dry grinding process.Moreover,both prolonged dry and wet grinding could destabilize the Si-O bond and decrease the surface binding energy.展开更多
Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types...Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types of regional municipal sludge(sludge) in an orthogonal experiment. The sludge type,sludge mixing proportion, dosage of dispersant, and grinding time were tested in this study. The results show that water content and its occurrence characteristics in the sludge have primary hindering influences on slurry ability. The range of fixed-viscosity concentrations with raw wet sludge is from 50.78%to 44.40%(by weight), while the range is from 53.35% to 51.51%(by weight) with dry sludge. All of the CSSs exhibit shear-thinning behaviors with different variation trends, especially the CSSs with more than 15%(by weight) raw wet sludge in it. Adding the same proportion of raw wet sludge increases the thixotropic properties of CSSs and the highest area of thixotropy loop is 3065 Pa/s, while the highest value of dry sludge is 1798 Pa/s. Hydrophilic group plays an important role in adsorbing water and building three-dimension networks with other particles, which is the main reason for CSS properties.Therefore, the mechanism can be used to find the way for making high quality CSS.展开更多
Rest potentials for the steel ball electrode and the pyrite electrode as well as the combination potentials and the galvanic currents developed in the pyrite steel ball couple were measured. The data demonstrate that ...Rest potentials for the steel ball electrode and the pyrite electrode as well as the combination potentials and the galvanic currents developed in the pyrite steel ball couple were measured. The data demonstrate that the galvanic couples are going to form between the pyrite particles and the steel balls when they contact with each other. The initial combination potential and the initial galvanic current of the pyrite ball couple while bubbling with oxygen are greater than those in aeration of air. The combination potential and the galvanic current decrease more quickly with time while bubbling with oxygen than they do in aeration of air. In an experiment of simulating wear differences, a galvanic current, which is smaller than that developed in the pyrite ball couple, exists between two different ball electrodes in wear degree on the surface of them. Under different grinding time conditions, the equivalent corrosion current density calculated from marked ball wear data by applying Faraday’s law correlates well with those estimated from polarization curves of pyrite and ball electrodes, and the former is always greater than the latter.展开更多
基金This work was supported by University Natural Science Research Project of Anhui Province(KJ2019A0171).
文摘Improving the activity of Iron Ore Tailings(IOTs)to utilize them as a mineral admixture in cement-based minerals is still challenging.In this paper,the wet grinding technology was employed to stimulate the activity of IOTs,and the traditional dry grinding method was used as a reference.The effect of wet grinding on the activation of IOTs was evaluated through ion leaching from an alkaline solution and the reactivity index.Additionally,a detailed comparison between Dry-grinding Iron Ore Tailings(DIOTs)and Wet-grinding Iron Ore Tailings(WIOTs)was made.This comparison was based on particle characteristics,crystal structures,chemical structure,and surface properties.The results showed that the particle size of IOTs reduced rapidly during wet grinding.In addition,WIOTs had a higher activity index compared to DIOTs.The storage of lattice distortions in the quartz crystal structure was also more significant during the wet grinding process than during the dry grinding process.Moreover,both prolonged dry and wet grinding could destabilize the Si-O bond and decrease the surface binding energy.
基金supported by the National Natural Science Foundation of China (Nos. 51204179, 51204182)the Natural Science Foundation of Jiangsu Province of China (No. BK20141242)the Fundamental Research Funds for the Central Universities of China (No. 2014XT05)
文摘Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types of regional municipal sludge(sludge) in an orthogonal experiment. The sludge type,sludge mixing proportion, dosage of dispersant, and grinding time were tested in this study. The results show that water content and its occurrence characteristics in the sludge have primary hindering influences on slurry ability. The range of fixed-viscosity concentrations with raw wet sludge is from 50.78%to 44.40%(by weight), while the range is from 53.35% to 51.51%(by weight) with dry sludge. All of the CSSs exhibit shear-thinning behaviors with different variation trends, especially the CSSs with more than 15%(by weight) raw wet sludge in it. Adding the same proportion of raw wet sludge increases the thixotropic properties of CSSs and the highest area of thixotropy loop is 3065 Pa/s, while the highest value of dry sludge is 1798 Pa/s. Hydrophilic group plays an important role in adsorbing water and building three-dimension networks with other particles, which is the main reason for CSS properties.Therefore, the mechanism can be used to find the way for making high quality CSS.
文摘Rest potentials for the steel ball electrode and the pyrite electrode as well as the combination potentials and the galvanic currents developed in the pyrite steel ball couple were measured. The data demonstrate that the galvanic couples are going to form between the pyrite particles and the steel balls when they contact with each other. The initial combination potential and the initial galvanic current of the pyrite ball couple while bubbling with oxygen are greater than those in aeration of air. The combination potential and the galvanic current decrease more quickly with time while bubbling with oxygen than they do in aeration of air. In an experiment of simulating wear differences, a galvanic current, which is smaller than that developed in the pyrite ball couple, exists between two different ball electrodes in wear degree on the surface of them. Under different grinding time conditions, the equivalent corrosion current density calculated from marked ball wear data by applying Faraday’s law correlates well with those estimated from polarization curves of pyrite and ball electrodes, and the former is always greater than the latter.
