Response of environmental sensitive grain size group in Core FJ04 from mud area in the north of East China Sea to East Asian winter monsoon evolvement

AMS14C dating and grain-size analysis for Core FJ04, located at mud area in the North of East China Sea provide us a high-resolution grain-size distribution curve varying with depth and time. This paper got environmental sensitive grain-size group by using standard deviation method, and proved that the selected sensitive grain-size group is an important proxy which can be used to reconstruct intensity of East Asian Winter Monsoon （EAWM）. Then we got reconstruction of EAWM evolvement since 3 ka B.P., which revealed two main phases： （1） 3 - 1.15ka B.P., relative weak EAWM with middle frequency fluctuation; （2） 1.15 - 0ka B.P., really strong EAWM with high frequency fluctuation. And 1.15 ka B.P. is a distinct turning point. During the whole period, 11 intense events of EAWM were recorded and correlated well with other climate records, but the response extent was different, which showed consistency of climate change and particularity of region response.

Board-invited review: Sensitivity and responses of functional groups to feed processing methods on a molecular basis

In complex feed structures, there exist main chemical functional groups which are associated with nutrient utilization and availability and functionality. Each functional group has unique molecular structure therefore produce unique molecular vibration spectral profile. Feed processing has been used to improve nutrient utilization for many years. However, to date, there was little study on processing-induced changes of feed intrinsic structure and functional groups on a molecular basis within intact tissue. This is because limited research technique is available to study inherent structure on a molecular basis. Recently bioanalytical techniques： such as Synchrotron Infrared Microspectroscopy as well as Diffuse Reflectance Infrared Fourier Transform molecular spectroscopy have been developed. These techniques enable to detect molecular structure change within intact tissues. These techniques can prevent destruction or alteration of the intrinsic protein structures during processing for analysis. However, these techniques have not been used in animal feed and nutrition research. The objective of this review was show that with the advanced technique, sensitivity and responses of functional groups to feed processing on a molecular basis could be detected in my research team. These functional groups are highly associated with nutrient utilization in animals.

Theoretical Calculation about the High Energy Density Molecules of Nitrate Ester Substitution Derivatives of Prismane

The nitrate ester substitution derivatives of prismane were studied at the B3LYP/6-311G＊＊ level. The sublimation enthalpies and heats of formation in gas phase and solid state were calculated. The detonation performances were also predicted by using the famous Kamlet-Jacbos equation. Our calculated results show that introducing nitrate ester group into prismane is helpful to enhance its detonation properties. Stabilities were evaluated through the bond dissociation energies, bond order, characteristic heights（H50） and band gap calculations. The trigger bonds in the pyrolysis process of prismane derivatives were confirmed as O–ON2 bond. The BDEs of all compounds were large, so these prismane derivatives have excellent stability consistent with the results of H50 and band gap.

New tetrazole-based organic dyes for dye-sensitized solar cells

A series of new metal-free organic dyes that contain donors with triphenylamine or its derivatives and tetrazole-based acceptors were synthesized and characterized by photophysical, electrochemical, and the- oretical computational methods. They were applied in nanocrystalline TiO2 solar cells （DSSCs）. It is found that the introduction of diphenylamine units as antennas in the as-synthesized dyes could improve photo- voltaic performance compared with phenothiazine and carbazole units as antennas in DSSCs. The dye with （2H-tetrazol-5-yl） acrylonitrile electron acceptor also displayed the highest solar-to-electrical energy conver- sion efficiency.