Properties of Sensitive Materials Mainly Composed of ZnO

Sensitive materials mainly composed of ZnO and their multi-functional properties were investigated. The temperature extent of linear resistance, non-linear deviation and endurance ability of surge energy were further discussed. The effect of Mg^2+, AI^3+ and Si^4+, which could be solid solutioned in ZnO grain and the function of Y^3+ ion segregated out in grain boundary were studied as well. The function of Ti was analyzed emphatically.

Studies on Gas Sensitive Materials of γ-Fe_2O_3 Doped with Rare Earth Oxides

Fine powders of γ-Fe_2O_3,doped with Y_2O_3,CeO_2,Eu_2O_3 or Tb_2O_3 have been prepared by the chemical co-precipitation method.The sensitivity of gas sensation has been measured with respect to the relative resist- ance change in the ceramic matrix upon introduction of inflammable gases.The structure of the materials has been studied with X-ray diffraction spectroscopy(XRD),electron diffraction spectroscopy( ED) and transmis- sion electron microscopy(TEM).The addition of rare earth oxides,which improves ceramic microstructure of γ-Fe_2O_3,improves gas sensitivity of γ-Fe_2O_3.The stability can be increased because of the increase of phase transition temperature.In addition,the selectivity of gas sensation of γ-Fe_2O_3 can be improved because of the variation of rare earth oxides.

Surface Photovoltage Studies of Moisture Sensitive Characteristic of Copper Tetrasulfonato-Phthalocyanine

The surface photovoltaic characteristic of copper tetrasulfonato- phthalocyanine (CuTsPc) in water vapor was studied by surface photovoltage spectroscopy (SPS). It was found that the adsorption of water vapor caused some marvelous changes of the photovoltaic response, that is, the SPS signal diminished rapidly and even reversed; the bands were widened and displayed a bathochromic shift. The dependence of surface photovoltage on the vapor pressure indicates that the reversed signal reaches to a maximum when the vapor pressure is 4.7×102 Pa. The time response velocity, reversibility, selectivity and reproducibili-ty were examined as well. All results obtained show that CuTsPc is of great significance in the manufacture of moisture sensitive devices. In addition, the mechanism of moisture sensitivity is discussed.

Strain-rate Sensitivity of Aluminum 2024-T6/TiB_2 Composites and Aluminum 2024-T6

Strain-rate sensitivities of 55vol%-65vol% aluminum 2024-T6/TiB2 composites and the corresponding aluminum 2024-T6 matrix were investigated using split Hopkinson pressure bar method. The experimental results showed that 55vol%-65vol% aluminum 2024-T6/TiB2 composites exhibited significant strain-rate sensitivities, which were three times higher than the strain-rate sensitivity of the aluminum 2024-T6 matrix. The strain-rate sensitivity of the aluminum 2024-T6 matrix composites rose obviously with increasing reinforcement content（up to 60%）, which agreed with that from the previous researches. But it decreased as the ceramic reinforcement content reached 65%. After high strain rates compression, a large number of dislocations and micro-cracks were found inside the matrix and the Ti B2 particles, respectively. These micro-cracks can accelerate the brittle fracture of the composites. The aluminum 2024-T6/Ti B2 composites showed various fracture characteristics and shear instability was the predominant failure mechanism under dynamic loading.

Nonvolatile holographic storage in triply doped LiNbO_3:Hf,Fe,Mn crystals

It has been suggested to use LiNbO3：Fe,Mn crystal for solving the problem of information volatility during the read-out process with all-optical facilities,but the minute order response time is far from the requirements for the real-time information processing.We present the nonvolatile holographic storage properties of LiNbO3：Hf,Fe,Mn.The response time is shortened to 5.0 s,and the sensitivity S is enhanced to 0.22 cm/J in this triply doped crystal.The experimental results show that the HfO2 doping threshold is 5.0 mol.%.Thus it seems that we have found a useful tetravalent dopant for LiNbO3：Fe,Mn that can obviously improve the nonvolatile holographic recording sensitivity.

High-sensitivity temperature sensor based on Bragg grating in BDK-doped photosensitive polymer optical fiber

A single-mode polymer optical fiber （POF） with highly photosensitive core doped with benzil dimethyl ketal （BDK） is fabricated and used for writing Bragg grating through the two-beam interference method. The Bragg wavelength of the grating is about 1570 nm, while the full-width at half-maximum （FWHM） of the reflection peak is 0.3 nm. The temperature response of POF Bragg grating is theoretically analyzed and experimentally measured in contrast to silica optical fiber Bragg grating （FBG）. The result shows that the temperature character of POF Bragg grating is negative, which is opposite to the silica optical FBG. The absolute value of the temperature response of POF Bragg grating is one order of magnitude higher than that of the silica optical FBG, making POF Bragg grating appear to be very attractive for constructing temperature sensors with high resolution.

KrF excimer laser-fabricated Bragg grating in optical microfiber made from pre-etched conventional photosensitive fiber

A method to fabricate fiber Bragg grating （FBG） in an optical microfiber （OM） from a conventional photosensitive fiber is proposed in this letter. The cladding of a conventional photosensitive fiber is etched to 17 pro. The etched fiber is drawn to an OM 6μm in diameter. The photosensitivity of the fabricated OM is effectively reserved. A FBG in the OM （MFBG） is successfully fabricated using a KrF excimer laser at a fluence of 400 mJ/cm2 through a phase mask with a pitch of 1 089.3 nm. The reflectivity of the FBG is approximately 10%, and the 3-dB spectrum bandwidth is 0.13 nm. The concentration of brine is measured by immersing the MFBG in the liquid, and the minimum detectable refractive index variation can reach 7.2×10^-5 at a refractive index value of 1.33.

Low birefringence depressed cladding photosensitive fiber

The highly Ge-doped photosensitive fiber （PSF） has been widely used in the fabrication of fiber Bragg gratings （FBGs）. Its birefringence and cladding mode coupling characteristics greatly influence FBG＇s transmission feature in communication application areas. In this work, a new concept of the PSF is introduced which, along with an optimized birefringence design, a precisely controlled fabrication process, and a cladding mode depressed design, results in a written FBG with -25-dB clad mode-depressed ratio and a polarization mode dispersion value less than 0.045 ps.

Fiber structures and material science in optical fiber magnetic field sensors

Magnetic feld sensing plays an important role in many felds of scientifc research and engineering applications.Benefting from the advantages of optical fbers,the optical fber-based magnetic feld sensors demonstrate characteristics of light weight,small size,remote controllability,reliable security,and wide dynamic ranges.This paper provides an overview of the basic principles,development,and applications of optical fber magnetic feld sensors.The sensing mechanisms of fber grating,interferometric and evanescent feld fber are discussed in detail.Magnetic fuid materials,magneto-strictive materials,and magneto-optical materials used in optical fber sensing systems are also introduced.The applications of optical fber magnetic feld sensors as current sensors,geomagnetic monitoring,and quasi-distributed magnetic sensors are presented.In addition,challenges and future development directions are analyzed.

Drying of suspensions and solutions on inert particle surface in mechanically spouted bed dryer

To eliminate some disadvantages of the conventional spouted bed dryers the mechanically spouted bed （MSB） system was developed. This dryer type is convenient to use inert particles providing an increased surface area for drying of materials of high-moisture content and heat sensitive materials. On three different drying tasks are demonstrated the experimental optimization of process parameters to obtain products of demanded quality. The main object was at drying of AIO（OH） suspension to preserve the particle size under 2.5μm and to obtain product with a moisture content of about 0.05 kg/kg （d.b.）. For this reason a very thin particle coating and intensive abrasion had to be assured. At drying of tomato concentrates the thermoplasticity makes the process very difficult. To jump over the deliquescent and sticky state developed at the critical temperature-moisture content values a very short drying time （8-10 s） must be provided. The third task was to form powder-like product from bovine serum albumin （BSA） solution having very low solid content （2-4%）. The selected process parameters given in this paper resulted in a mean particle size of less than 20 μm while the soluble oreserved orotein content was higher than 90%.

Photosensitivity and photoluminescence of Sn/Yb codoped silica optical fiber preform

Sn/Yb codoped silica optical fiber preform is prepared by the modified chemical vapor deposition （MCVD） followed by the solution-doping method. Ultraviolet （UV） optical absorption, photoluminescence （PL） spectra under 978-nm laser diode （LD） pumping, and refractive index change after exposure to 266-nm laser pulses are obtained. There is only a little change in the PL spectra while a positive refractive index change up to 2×10^-4 is observed after 30-min exposure to 266-nm laser pulses. The results show that both of the peculiar photosensitivity of Smdoped silica and the gain property of Yb-doped silica fiber are preserved in the Sn/Yb codoped silica optical fiber preform. The experimental data suggest that the photosensitivity of the fiber preform under high energy density laser irradiation should be mainly due to the bond-breaking of oxygen deficient defects, while under relatively low energy density laser irradiation, the refractive index change probably originates from the photoconversion of optically active defects.