Insight into structure evolution of carbon nitrides and its energy conversion as luminescence

A series of carbon nitride(CN)materials represented by graphitic carbon nitride(g-C_(3)N_(4))have been widely used in bioimaging,biosensing,and other fields in recent years due to their nontoxicity,low cost,and high luminescent quantum efficiency.What is more attractive is that the luminescent properties such as wavelength and intensity can be regulated by controlling the structure at the molecular level.Hence,it is time to summarize the related research on CN structural evolution and make a prospect on future developments.In this review,we first summarize the research history and multiple structural evolution of CN.Then,the progress of improving the luminescence performance of CN through structural evolution was discussed.Significantly,the relationship between CN structure evolution and energy conversion in the forms of photoluminescence,chemiluminescence,and electrochemiluminescence was reviewed.Finally,key challenges and opportunities such as nanoscale dispersion strategy,luminous efficiency improving methods,standardization evaluation,and macroscopic preparation of CN are highlighted.

Quasi-40-Day Oscillation and Its Teleconnection Structure together with the Possible Dependence on Conversion of Barotropic Unstable Energy of Temporal Mean Flow

A study is made of the distribution of the diagnostic quantity vector E and the teleconnection structure of 30-50 (quasi-40) day oscillation, together with the dependence on the conversion of barotropic unstable energy of mean flow in terms of ECWMF daily 500 hPa grid data in winter, indicating that the energy transportation is closely associated with the westerly jet position, with zonal (meridional) propagation in the strong (weak) wind region, that considerable conversion of barotropic energy occurs at the jet exit region where low-frequency oscillation gains energy from the mean flow, leading to maximum kinetic energy for the oscillation observed there, which is marked by evident barotropy in striking contrast to the baroclinicity at low latitudes and that the teleconnection core is related to the center of action in the atmosphere and bound up with the pattern of the west wind.

Impact of Two-Way FDI on the Industrial Structure in Shandong Province Under the Background of “New and Old Kinetic Energy Conversion”

This paper uses the panel data of 17 cities in Shandong Province from 2003 to 2018 to construct a panel model to empirically study the impact of foreign direct investment(FDI)on the industrial structure.The results show that two-way investment,financial industry development,and policy variables have significant roles in promoting the advancement of the industrial structure in the province.In the future implementation of the“Going Global”strategy in Shandong Province,the cooperation between two-way investment and the financial industry should be strengthened,the level of regional financial development should be improved,and the impact of two-way investment on the optimization and upgrading of the industrial structure should be reinforced.

Evidence for the Hierarchical Structure of Sentences Revisited

To reveal invariant properties of human languages is one of the central goals of modern generative grammar.Hierarchical feature of sentence construction, one of the key notions in this regard, reflects one of the most widely accepted invariant properties of human languages. However,researchers also challenge this point and argue that languages differ fundamentally from one another so that it is very hard to find any single structural property which they share. This paper revisits the evidence for the hierarchical structure of sentences from the principle of structure dependence in first and second language acquisition and argues that the recognition of hierarchical structure of sentences is essential to any linguistic exploration.

Simplification of English Sentence Pattern Structure in the Teaching of Translation and Grammar

In the teaching of translation and grammar,it is essential that the English sentence structure is analyzed and transformation of sentence structures both in English and Chinese in class and after class. However,many kinds of English sentences structures prevent the students who study English from getting the basic idea and concept of a sentence in translation or grammatical analysis. In this paper,the author submitted the basic mould of simplification of English sentence structure,and the students can learn and master the translating technique through the simplified English sentence structure. Thus it helps to improve students' competence of translation.

Synthesis and Crystal Structure of a New Quinazolinone Compound 2,3-Dihydro-2-(2-hydroxyphenyl)-3-phenyl-quinazolin-4(1H)-one

A new quinazolinone compound 2,3-dihydro-2-(2-hydroxyphenyl)-3-phenyl- quinazolin-4(1H)-one 3 ([C20H16O2N2]?C2H5OH, Mr = 362.42) and compound 2-(2-hydroxy- benzylidene-amino)-N-phenyl-benzamide 2 (C20H16O2N2, Mr = 316.34) were prepared from a precursor of 2-amino-N-phenyl-benzamide 1 (C13H12ON2, Mr = 212.25). Compound 3 was characterized by single-crystal X-ray diffraction analysis. The crystal belongs to orthorhombic, space group Pbca with a = 1.2889(11), b = 1.6170(14), c = 1.7729(15) nm, V = 3.695(6) nm3, Z = 8, F(000) = 1536, Mr = 362.42, Dc = 1.303 g/cm3, μ(MoKα) = 0.087 mm-1, R = 0.0447 and wR = 0.0879. The crystal structure analysis indicates that the title compound has a two-dimensional network structure formed by hydrogen bonds and electrostatic interactions.

Hollow structured Cu@ZrO_(2) derived from Zr-MOF for selective hydrogenation of CO_(2) to methanol

The development of a highly efficient catalyst for CO_(2) activation and selective conversion to methanol is critical to address the issues associated with the high thermal stability of CO_(2) and controllable synthesis of methanol.Cu-based catalysts have been widely studied because of the low cost and excellent performance in mild conditions.However,the improvement of catalytic activity and selectivity remains challenging.Herein,we prepared hollow Cu@ZrO_(2) catalysts through pyrolysis of Cu-loaded Zr-MOF for CO_(2) hydrogenation to methanol.Low-temperature pyrolysis generated highly dispersed Cu nanoparticles with balanced Cu^(0)/Cu^(+)sites,larger amounts of surface basic sites and abundant Cu-ZrO_(2) interface in the hollow structure,contributing to enhanced catalytic capacity for adsorption/activation of CO_(2) and selective hydrogenation to methanol.In situ Fourier Transform Infrared Spectroscopy revealed the methanol formation followed the formate-intermediated pathway.This work would provide a guideline for the design of high-performance catalysts and the understanding of the mechanism and active sites for CO_(2) hydrogenation to methanol.

Chinese Conversation Structure

This paper aims to describe the features of Chinese conversation structure. Specifically speaking, the structure will be analyzed from the following four aspects: openings and pre-sequence, adjacency pairs, pre-closing and closing. Generally speaking, Chinese conversation structure is similar to English conversation structure. But still a lot of differences are found due to cultural factors.

The method of design for seismic data database system based on tree structure

With the massive growth of the seismic data, it is required a new method to manage them. In this paper, the design method will be reported about relational database based on tree structure. Comparing with other designs, it is not only simpler and easier to organize data, but also can simplify the design process of the database. This method has been used to design database of the earthquake monitor center station of the earthquake monitoring system for the Yangtze River Three Gorges Project and has shown good results.

基于Tekla Structure与Ansys Workbench联合应用的有限元分析

利用加工设计常用的Tekla Structure软件建立三维模型,经模型转换后,导入到Ansys Workbench中进行结构静力学有限元分析,分析的结果可为吊装、运输和辅助工装设计等提供理论参考依据。通过具体实例,说明通过Tekla Structure建模和Ansys Workbench分析有效结合,能够有效提高工作效率,操作和修改优化更加简单。为类似工程实际提供参考。

Nonlinear optics with structured light

The interest in tailoring light in all its degrees of freedom is steadily gaining traction,driven by the tremendous developments in the toolkit for the creation,control and detection of what is now called structured light.Because the complexity of these optical fields is generally understood in terms of interference,the tools have historically been linear optical elements that create the desired superpositions.For this reason,despite the long and impressive history of nonlinear optics,only recently has the spatial structure of light in nonlinear processes come to the fore.In this review we provide a concise theoretical framework for understanding nonlinear optics in the context of structured light,offering an overview and perspective on the progress made,and the challenges that remain.

Revit Structure转盈建科软件的数据分析与研究

本文主要研究在Revit Structure中建立结构模型,然后采用YJK计算软件的接口程序将Revit模型转换为YJK计算模型用于设计分析。同时对YJK模型与PKPM模型进行比较,验证转换程序的正确性。

Reflections on Chinese Culture from the Perspective of Chinese Conversation Structure

Though Chinese conversation structure has some overlap with the English conversation structure, it has many differences in the details because of the in? uence of unique Chinese culture. This thesis analyses every part of the Chinese conversation structure by listing many concrete examples which reflects how Chinese culture in? uence the Chinese conversation structure.

Nanocrystal formation and structure in oxyfluoride glass ceramics

The up-conversion luminescent property of the oxyfluoride glass ceramics 30SiO2·15Al2O3· （50-x）PbF2·xCdF2 doped with 4ErF3·1YbF3 has been investigated. Up-conversion luminescent intensity of Er^3＋ ions increased obviously after heat-treatment due to co-doping with CdF2. The structure model of nanocrystals PbxCdl-xF2 was determined and the effect of CdF2 in oxyfluoride glass ceramics was explained by the analysis of x-ray diffraction data. Different nucleation temperatures of samples with different compositions were obtained by differential thermal analysis curves and the results showed the growth process of different nanocrystals in glass ceramics.

On Chinese Conversation Structure

With the aim of introducing Chinese conversational communication characteristics in Chinese cultural,this paper lists the Chinese conversation structure and describes the characteristics of its components "setting up","pragmatic acts","uptakes" and "pre-closing".By giving some specific examples,the paper also explains how the components work according to Chinese social conventions in Chinese society.

Triazine-based multicomponent metallacages with tunable structures for SO_(2) selective capture and conversion

The design of novel materials for sulfur dioxide(SO_(2))capture and conversion with considerable efficiency under mild conditions is of great significance for human health and environmental protection yet highly challenging.Herein,we report a series of triazine-based multicomponent metallacages via coordination-driven self-assembly of 2,4,6-tri(4-pyridyl)-1,3,5-triazine,cis-Pt(PEt3)2(OTf)2 and different tetracarboxylic ligands.As the increase of the length of the tetracarboxylates,the structures of the metallacages change from pyramids to extended octahedrons.Owing to their N-rich structure,these metallacages are further used for selective SO_(2)capture,showing good adsorption capacity and remarkable SO_(2)/CO_(2)selectivity in ambient conditions,suggesting their potential applications toward real flue gas desulfurization.The metallacages are further employed for the conversion of SO_(2)into value-added compounds,showing exceptional efficiency even dilute SO_(2)is used as the reactant.This study represents a type of structure-tunable triazinebased metallacages for SO_(2)capture and conversion,which will pave the way on the applications of metal-organic complexes for gas adsorption.

Design of ZnSe-CoSe heterostructure decorated in hollow N-doped carbon nanocage with generous adsorption and catalysis sites for the reversibly fast kinetics of polysulfide conversion

Although lithium-sulfur batteries(Li SBs)are regarded as one of the most promising candidates for the next-generation energy storage system,the actual industrial application is hindered by the sluggish solid–liquid phase conversion kinetics,severe shuttle effect,and low sulfur loadings.Herein,a zeolitic imidazolate framework(ZIF)derived heterogeneous ZnSe-CoSe nanoparticles encapsulated in hollow N-doped carbon nanocage(ZnSe-CoSe-HNC)was designed by etching with tannic acid as a multifunctional electrocatalyst to boost the polysulfide conversion kinetics in LiSBs.The hollow structure in ZIF ensures large inner voids for sulfur and buffering volume expansions.Abundant exposed ZnSe-CoSe heterogeneous interfaces serve as bifunctional adsorption-catalytic centers to accelerate the conversion kinetics and alleviate the shuttle effect.Together with the highly conductive framework,the ZnSe-CoSeHNC/S cathode exhibits a high initial reversible capacity of 1305.3 m A h g-1at 0.2 C,high-rate capability,and reliable cycling stability under high sulfur loading and lean electrolyte(maintaining at 745 m A h g-1after 200 cycles with a high sulfur loading of 6.4 mg cm-2and a low electrolyte/sulfur ratio of 6μL mg^(-1)).Theoretical calculations have demonstrated the heterostructures of ZnSe-CoSe offer higher binding energy to lithium polysulfides than that of ZnSe or CoSe,facilitating the electron transfer to lithium polysulfides.This work provides a novel heterostructure with superior catalytic ability and hollow conductive architecture,paving the way for the practical application of functional sulfur electrodes.

Voice conversion using structured Gaussian mixture model in cepstrum eigenspace

A new methodology of voice conversion in cepstrum eigenspace based on structured Gaussian mixture model is proposed for non-parallel corpora without joint training. For each speaker, the cepstrum features of speech are extracted, and mapped to the eigenspace which is formed by eigenvectors of its scatter matrix, thereby the Structured Gaussian Mixture Model in the EigenSpace （SGMM-ES） is trained. The source and target speaker＇s SGMM-ES are matched based on Acoustic Universal Structure （AUS） principle to achieve spectrum transform function. Experimental results show the speaker identification rate of conversion speech achieves 95.25%, and the value of average cepstrum distortion is 1.25 which is 0.8% and 7.3% higher than the performance of SGMM method respectively. ABX and MOS evaluations indicate the conversion performance is quite close to the traditional method under the parallel corpora condition. The results show the eigenspace based structured Gaussian mixture model for voice conversion under the non-parallel corpora is effective.

Luminescence properties of composite material Sr_(2)MgSi_(2)O_(7):Eu^(2+),Dy^(3+)/light conversion agent with multilayer structure

In order to improve the red luminescent properties,Sr_(2)MgSi_(2)O_(7):Eu^(2+),Dy^(3+)was selected as a blue persistent luminescent donor phosphor,while light conversion agent was utilized to tune the persistent luminescent spectra from blue to red.Composite red luminescent material Sr_(2)MgSi_(2)O_(7):Eu^(2+),Dy^(3+)/light conversion agent(SMED/LCA)was fabricated with light conversion agent and Sr_(2)MgSi_(2)O_(7):Eu^(2+),Dy^(3+)at a certain mass ratio.SiO_(2)(Al2 O_(3) or MgF2)were coated on the surface of SMED/LCA through heterogeneous deposition method.The structural and optical characteristics of the resulting samples were launched in terms of X-ray diffraction and emission spectrum as well as afterglow brightness.The results demonstrate that the emission spectrum exhibits two emission bands,and the peaks are located at around 470 and 615 nm.SiO_(2),Al_(2)O_(3) and MgF_(2) are coated on the surface of SMED/LCA like a protective shell to maintain its stability and luminescent properties,the afterglow initial brightness is still up to 0.37 cd/m^(2) and the afterglow color purity calculated from CIE color coordinates is basically unchanged.

Structure Types and Discourse Function of N＋N Nominal Sentence in Mandarin Chinese

N＋N nominal sentence is an important structure type of nominal sentences in Mandarin Chinese. Attributive-center, combination, apposition and subject-predicate are its main structure types. In main literary genres, the distribution of N＋N nominal sentence shows a certain trend of dominant hierarchy： poem﹥drama﹥novel﹥prose. No matter what kind of literary genres, attributive-center structure is the type with maximum quantity, while appositive structure is the type with minimum quantity. Statistical result indicates that most of N＋N nominal sentence is nominal and its use is limited by genres. Function of N＋N nominal sentence is textual. When it comes to discourse, it can be used as theme, rheme and dual identity of theme and rheme based on the theory of Theme-Rheme （T-R） structure pattern. It does not only construct the information structure to deliver textual information, but also its a vital means of discourse cohesion and coherence.