High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising,which also is the determining short slab in volatile organic compounds(VOCs)adsorption application...High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising,which also is the determining short slab in volatile organic compounds(VOCs)adsorption applications.Herein,we develop the outstanding engineering carbon adsorbents from waste shaddock peel which affords greatly-enhanced thermal-stability and super structural property(S_(Lang)=4962.6 m2·g^(-1),Vmicro=1.67 cm^(3)·g^(-1)).Such character endows the obtained adsorbent with ultrahigh adsorption capture performance of VOCs specific to benzene(16.58 mmol·g^(-1))and toluene(15.50 mmol·g^(-1),far beyond traditional zeolite and activated carbon even MOFs materials.The structural expression characters were accurately correlated with excellent adsorption efficiency of VOCs by studying synthetic factor-controlling comparative samples.Ulteriorly,adsorption selectivity prediction at different relative humidity was demonstrated through DIH(difference of the isosteric heats),exceedingly highlighting great superiority(nearly sixfold)in selective adsorption of toluene compared to volatile benzene.Our findings provide the possibility for practical industrial application and fabrication of waste biomass-derived outstanding biochar adsorbent in the environmental treatment of threatening VOCs pollutants.展开更多
[Objective] The precipitation conditions of salting out method for extracting shaddock peel pectin were studied.[Method] Taking shaddock peel as the raw material, the optimal technological conditions for pectin precip...[Objective] The precipitation conditions of salting out method for extracting shaddock peel pectin were studied.[Method] Taking shaddock peel as the raw material, the optimal technological conditions for pectin precipitation were obtained by precipitating shaddock peel under dif-ferent salting-out conditions.[Result] The optimal conditions of salting out method for precipitating shaddock peel pectin were as follows: aluminum sulfate saturated solution: pectin extract 1∶1, salting out time 60 min, salting out temperature 60℃, salting out pH 4, and the extraction rate reached 6.8%.[Conclusion] Precipitation of pectin through salting out method reduced the consumption of ethanol, energy consumption and production cost.展开更多
基金financially supported by National Natural Science Foundation of China (21908085)Natural Science Foundation of Jiangsu Province, China (BK20190961)+2 种基金Postdoctoral Research Foundation of Jiangsu Province (2020Z291)Foundation from Marine Equipment and Technology Institute for Jiangsu University of Science and Technology, China (HZ20190004)High-tech Ship Research Project of the Ministry of Industry and Information Technology, China (No. [2017] 614)
文摘High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising,which also is the determining short slab in volatile organic compounds(VOCs)adsorption applications.Herein,we develop the outstanding engineering carbon adsorbents from waste shaddock peel which affords greatly-enhanced thermal-stability and super structural property(S_(Lang)=4962.6 m2·g^(-1),Vmicro=1.67 cm^(3)·g^(-1)).Such character endows the obtained adsorbent with ultrahigh adsorption capture performance of VOCs specific to benzene(16.58 mmol·g^(-1))and toluene(15.50 mmol·g^(-1),far beyond traditional zeolite and activated carbon even MOFs materials.The structural expression characters were accurately correlated with excellent adsorption efficiency of VOCs by studying synthetic factor-controlling comparative samples.Ulteriorly,adsorption selectivity prediction at different relative humidity was demonstrated through DIH(difference of the isosteric heats),exceedingly highlighting great superiority(nearly sixfold)in selective adsorption of toluene compared to volatile benzene.Our findings provide the possibility for practical industrial application and fabrication of waste biomass-derived outstanding biochar adsorbent in the environmental treatment of threatening VOCs pollutants.
基金Supported by Guangxi Scientific Research and Technology Development Plan "Construction of Science and Technology Service Platform of Hezhou Agricultural Science and Technology Park"(GKN14258003)Research Project of Hezhou University(HZUJS201617)
文摘[Objective] The precipitation conditions of salting out method for extracting shaddock peel pectin were studied.[Method] Taking shaddock peel as the raw material, the optimal technological conditions for pectin precipitation were obtained by precipitating shaddock peel under dif-ferent salting-out conditions.[Result] The optimal conditions of salting out method for precipitating shaddock peel pectin were as follows: aluminum sulfate saturated solution: pectin extract 1∶1, salting out time 60 min, salting out temperature 60℃, salting out pH 4, and the extraction rate reached 6.8%.[Conclusion] Precipitation of pectin through salting out method reduced the consumption of ethanol, energy consumption and production cost.
