The late Quaternary shallow-water carbonates have been altered by a variety of diagenetic processes,and further influenced by high-amplitude global and regional sea level changes.This study utilizes a new borehole dri...The late Quaternary shallow-water carbonates have been altered by a variety of diagenetic processes,and further influenced by high-amplitude global and regional sea level changes.This study utilizes a new borehole drilled on the Yongxing Island,Xisha Islands to investigate meteoric diagenetic alteration in the late Quaternary shallowwater carbonates.Petrographic,mineralogical,stable isotopic and elemental data provide new insights into the meteoric diagenetic processes of the reef limestone.The results show the variation in the distribution of aragonite,high-Mg calcite(HMC)and low-Mg calcite(LMC)divides the shallow-water carbonates in Core SSZK1 into three intervals,which are UnitⅠ(31.20-55.92 m,LMC),UnitⅡ(18.39-31.20 m,aragonite and LMC)and UnitⅢ(upper 18.39 m of core,aragonite,LMC and HMC).Various degrees of meteoric diagenesis exist in the identified three units.The lowermost UnitⅠhas suffered almost complete freshwater diagenesis,whereas the overlying UnitsⅡandⅢhave undergone incompletely meteoric diagenesis.The amount of time that limestone has been in the freshwater diagenetic environment has the largest impact on the degree of meteoric diagenesis.Approximately four intact facies/water depth cycles are recognized.The cumulative depletion of elements such as strontium(Sr),sodium(Na)and sulphur(S)caused by duplicated meteoric diagenesis in the older reef sequences are distinguished from the younger reef sequences.This study provides a new record of meteoric diagenesis,which is well reflected by whole-rock mineralogy and geochemistry.展开更多
基金The National Natural Science Foundation of China-Guangdong Joint Foundation under contract No.U1701245the Hainan Provincial Natural Science Foundation of China under contract No.418QN306+2 种基金the Land and Georesource Bureau of Hainan Province under contract No.SQ2016KJHZ0027the Pioneer Hundred Talents Program under contract No.Y910091001the Guangzhou Marine Geological Survey Project under contract No.GZH201400210.
文摘The late Quaternary shallow-water carbonates have been altered by a variety of diagenetic processes,and further influenced by high-amplitude global and regional sea level changes.This study utilizes a new borehole drilled on the Yongxing Island,Xisha Islands to investigate meteoric diagenetic alteration in the late Quaternary shallowwater carbonates.Petrographic,mineralogical,stable isotopic and elemental data provide new insights into the meteoric diagenetic processes of the reef limestone.The results show the variation in the distribution of aragonite,high-Mg calcite(HMC)and low-Mg calcite(LMC)divides the shallow-water carbonates in Core SSZK1 into three intervals,which are UnitⅠ(31.20-55.92 m,LMC),UnitⅡ(18.39-31.20 m,aragonite and LMC)and UnitⅢ(upper 18.39 m of core,aragonite,LMC and HMC).Various degrees of meteoric diagenesis exist in the identified three units.The lowermost UnitⅠhas suffered almost complete freshwater diagenesis,whereas the overlying UnitsⅡandⅢhave undergone incompletely meteoric diagenesis.The amount of time that limestone has been in the freshwater diagenetic environment has the largest impact on the degree of meteoric diagenesis.Approximately four intact facies/water depth cycles are recognized.The cumulative depletion of elements such as strontium(Sr),sodium(Na)and sulphur(S)caused by duplicated meteoric diagenesis in the older reef sequences are distinguished from the younger reef sequences.This study provides a new record of meteoric diagenesis,which is well reflected by whole-rock mineralogy and geochemistry.