Isotropic sintering shrinkage of 3D glass-ceramic nanolattices:backbone preforming and mechanical enhancement

There is a perpetual pursuit for free-form glasses and ceramics featuring outstanding mechanical properties as well as chemical and thermal resistance.It is a promising idea to shape inorganic materials in three-dimensional(3D)forms to reduce their weight while maintaining high mechanical properties.A popular strategy for the preparation of 3D inorganic materials is to mold the organic–inorganic hybrid photoresists into 3D micro-and nano-structures and remove the organic components by subsequent sintering.However,due to the discrete arrangement of inorganic components in the organic-inorganic hybrid photoresists,it remains a huge challenge to attain isotropic shrinkage during sintering.Herein,we demonstrate the isotropic sintering shrinkage by forming the consecutive–Si–O–Si–O–Zr–O–inorganic backbone in photoresists and fabricating 3D glass–ceramic nanolattices with enhanced mechanical properties.The femtosecond(fs)laser is used in two-photon polymerization(TPP)to fabricate 3D green body structures.After subsequent sintering at 1000℃,high-quality 3D glass–ceramic microstructures can be obtained with perfectly intact and smooth morphology.In-suit compression experiments and finite-element simulations reveal that octahedral-truss(oct-truss)lattices possess remarkable adeptness in bearing stress concentration and maintain the structural integrity to resist rod bending,indicating that this structure is a candidate for preparing lightweight and high stiffness glass–ceramic nanolattices.3D printing of such glasses and ceramics has significant implications in a number of industrial applications,including metamaterials,microelectromechanical systems,photonic crystals,and damage-tolerant lightweight materials.

Effect of Shrinkage Reducing Agent and Steel Fiber on the Fluidity and Cracking Performance of Ultra-High Performance Concrete

Due to the low water-cement ratio of ultra-high-performance concrete(UHPC),fluidity and shrinkage cracking are key aspects determining the performance and durability of this type of concrete.In this study,the effects of different types of cementitious materials,chemical shrinkage-reducing agents(SRA)and steel fiber(SF)were assessed.Compared with M2-UHPC and M3-UHPC,M1-UHPC was found to have better fluidity and shrinkage cracking performance.Moreover,different SRA incorporation methods,dosage and different SF types and aspect ratios were implemented.The incorporation of SRA and SF led to a decrease in the fluidity of UHPC.SRA internal content of 1%(NSRA-1%),SRA external content of 1%(WSRA-1%),STS-0.22 and STE-0.7 decreased the fluidity of UHPC by 3.3%,8.3%,9.2%and 25%,respectively.However,SRA and SF improved the UHPC shrinkage cracking performance.NSRA-1%and STE-0.7 reduced the shrinkage value of UHPC by 40%and 60%,respectively,and increased the crack resistance by 338%and 175%,respectively.In addition,the addition of SF was observed to make the microstructure of UHPC more compact,and the compressive strength and flexural strength of 28 d were increased by 26.9%and 19.9%,respectively.

Effect of Lightweight Aggregates Incorporation on the Mechanical Properties and Shrinkage Compensation of a Cement-Ground Granulated Blast Furnace Slag-Phosphogypsum Ternary System

Shrinkage-induced cracking is a common issue in concrete structures,where the formation of cracks not only affects the aesthetic appearance of concrete but also potentially reduces its durability and strength.In this study,the effect of ceramsite sand addition on the properties of a ternary system of cement-ground granulated blast furnace slag(GGBFS)-phosphogypsum(PG)is investigated.In particular,the fluidity,rheology,hydration heat,compressive strength,autogenous shrinkage,and drying shrinkage of the considered mortar specimens are analyzed.The results indicate that an increase in PG content leads to a decrease in fluidity,higher viscosity,lower exothermic peak,and lower compressive strength.However,the shrinkage of the mortar specimens is effectively compensated.The incorporation of internal curing water from ceramsite sand improves fluidity,decreases both yield stress and viscosity,enhances the degree of hydration,and induces mortar expansion.However,the inferior mechanical properties of the ceramsite sand generally produce a decrease in the compressive strength.

Attention-Based Residual Dense Shrinkage Network for ECG Denoising

Electrocardiogram(ECG)signal is one of the noninvasive physiological measurement techniques commonly usedin cardiac diagnosis.However,in real scenarios,the ECGsignal is susceptible to various noise erosion,which affectsthe subsequent pathological analysis.Therefore,the effective removal of the noise from ECG signals has becomea top priority in cardiac diagnostic research.Aiming at the problem of incomplete signal shape retention andlow signal-to-noise ratio(SNR)after denoising,a novel ECG denoising network,named attention-based residualdense shrinkage network(ARDSN),is proposed in this paper.Firstly,the shallow ECG characteristics are extractedby a shallow feature extraction network(SFEN).Then,the residual dense shrinkage attention block(RDSAB)isused for adaptive noise suppression.Finally,feature fusion representation(FFR)is performed on the hierarchicalfeatures extracted by a series of RDSABs to reconstruct the de-noised ECG signal.Experiments on the MIT-BIHarrhythmia database and MIT-BIH noise stress test database indicate that the proposed scheme can effectively resistthe interference of different sources of noise on the ECG signal.

How Does Urban Shrinkage Affect Land Use Efficiency?A Case Study of Shrinking Cities in Northeast China

The effect of urban shrinkage has gradually become a new topic.Theoretically,urban shrinkage may exert great influence on land use efficiency(LUE)through various urban subsystems,but there is currently limited research examining these pathways.Using the Super-SBM-Undesirable model and the Structural Equation Model(SEM),this study calculates the LUE of shrinking cities in Northeast China and simulates the process of urban shrinkage affecting LUE.To quantify the process of urban shrinkage affecting LUE,three mediation variables,namely the economy,public services,and innovation,are used as latent variables to apply SEM.The results show that urban shrinkage will affect LUE through a direct path and indirect paths.In the direct path,urban shrinkage leads to an improvement in LUE.In the indirect paths,the economy and innovation will transmit the negative effect of urban shrinkage on LUE,while public services will reverse this effect.An important contribution of this study is that it quantifies the paths of urban shrinkage affecting LUE,thereby expanding the understanding of urban shrinkage effect and laying a foundation for the sustainable development of shrinking cities.

Analysis and Prediction Model Reinforced UHPC Shrinkage Property

This paper explores the shrinkage of reinforced UHPC under high-temperature steam curing and natural curing conditions.The results are compared with the existing shrinkage prediction models.The results show that the maximum shrinkage strain of reinforced UHPC after steam curing is 164μεand gradually becomes zero.As for natural curing,the maximum shrinkage strain is 173μεand the value stabilizes on the 10th day after pouring.This indicated that steam curing can significantly reduce shrinkage time.Compared with the plain UHPC tested in the previous literature,the structural reinforcement can significantly inhibit the UHPC shrinkage and greatly reduce the risk of cracking due to shrinkage.By comparing the results in this paper with the existing models for predicting the shrinkage strain development,it is found that the formula recommended in the French UHPC structural and technical specification is suitable for the shrinkage curve in the present paper.

基于截断p-shrinkage范数的航空发动机数据重构

针对航空发动机传感器的数据缺失问题,提出基于张量奇异值阈值(TSVT)的张量重构模型LRTC-PTNN,对航空发动机的传感器数据进行重构。LRTC-PTNN模型运用截断pshrinkage范数的方式代替原始张量迹范数作为张量秩的凸包络,并根据TSVT的特性,计算了传感器之间的相关性,选取传感器截面作为重构精度最佳的数据输入方向,使用交替乘子法实现LRTCPTNN算法。选取NASA提供的PHM2008数据集进行实验,对数据集进行标准化,并在重构后进行恢复,将多个时间序列个数相近的发动机传感器数据构建为高维张量的形式,设置2种传感器的数据缺失场景进行实验,结果表明:重构后数据的均方根误差和平均绝对百分比误差范围分别为2.10~13.13和0.32~1.49,LRTC-PTNN模型优于现有的基线模型,且在极端情况下有较强的鲁棒性。

Numerical simulation of concrete shrinkage based on heat and moisture transfer in porous medium

To simulate the concrete shrinkage in varying temperature and moisture environments, a simulate procedure comprising an analytical process and a finite element analysis is proposed based on the coupled partial differential equations describing heat and moisture transfer in a porous medium. Using the Laplace transformation method and transfer function to simplify and solve the coupled equations in Laplace domain, the moisture and temperature distribution in time domain are obtained by inverse Laplace transformation. The shrinkage deformations of concrete are numerically simulated by the finite element method （FEM） based on the obtained temperature and moisture distribution. This approach avoids the complex eigenvalues, coupling difficulty and low accuracy found in other solving methods, and also effectively calculates the moisture induced shrinkage which is almost impossible using familiar FEM software. The validity of the simulation procedure is verified by Hundt＇s test data. The results reveal that the proposed approach can be considered a reliable and efficient method to simulate the coupling moisture and temperature shrinkage of concrete.

Experimental study on shrinkage and rehydration of seed during drying process

Biomaterial will shrink during the drying process. The characteristics of shrinkage and rehydration of fresh peas were studied. Drying curves, shrinkage and rehydration curves of peas without seed coats and whole peas were compared. In addition, different volumetric shrinkage coefficients were obtained and discussed. The results show that seed coats resist moisture movement not only from inside to outside but also from outside to inside during different drying conditions. During a seed’s drying process, the drying curve is similar to the shrinkage curve. The higher the heat flux is, the less drying time is needed, and in the meantime, volume would shrink more and more intensively. Dried media will break easily at high heat flux. When we create a drying regime, both drying speed and the quality of dried media should be considered.

Surface Modification of Fly Ashes with Carbide Slag and Its Effect on Compressive Strength and Autogenous Shrinkage of Blended Cement Pastes

Surfaces of grade III fly ashes were modified through mixing with carbide slag and calcining at 850 ℃ for 1 h. Mineralogical compositions and surface morphology of fly ashes before and after modification were characterized by X-ray diffraction （XRD） and scanning electron microscopy （SEM）, respectively. Effect of surface-modified fly ashes on compressive strength and autogenous shrinkage of blended cement pastes was investigated. Microstructures of cement pastes were examined by backscattered electron （BSE） imaging and mercury intrusion porosimetry （MIP）. The experimental results showed that β-C2S was formed on the surfaces of fly ashes after modification. Hydration ofβ-C2S on the surface-modified fly ashes densified interface zone and enhanced bond strength between particles of fly ashes and hydrated clinkers. In addition, surface modification of fly ashes tended to decrease total porosity and 10-50 nm pores of cement pastes. Surface modification of fly ashes increased compressive strength and reduced autogenous shrinkage of cement pastes.

Factors affecting the shrinkage of fly ash geopolymers

The shrinkage of fly ash geopolymers was studied in the present study.Fly ash was used as the source material for making the geopolymers.The effects of the concentration of NaOH,sodium silicate-to-NaOH ratio,liquid-to-ash ratio,curing temperature,and curing time on shrinkage were investigated.The geopolymers were cured at 25,40,and 60℃,respectively.The results indicate that the shrinkage of geopolymers is strongly dependent on curing temperature and liquid-to-ash ratio.The increase in shrinkage is associated with the low strength development of geopolymers.It is also found that NaOH concentration and sodium silicate-to-NaOH ratio also affect the shrinkage of geopolymers but to a lesser extent.

Population Shrinkage in Resource-dependent Cities in China: Processes, Patterns and Drivers

Resource-dependent cities(RCs)are a vulnerable group of urban settlements that often face population shrinkage;however,population changes in RCs in China are not well understood.This study offers new insight into this matter through a robust analysis that features a longer time scale,a larger sample of RCs,and a finer unit of analysis.It finds new evidence that problems of population shrinkage in RCs are more serious than previous literature has suggested.Approximately 30%of the studied units have experienced either long-term or short-term population shrinkage,and many more are experiencing a slowing down of population growth.Problems are especially common among three types of RCs:the resource-depleted RCs,the forestry-based RCs,and RCs in Northeast China.These results underscore transition policy inadequacies in addressing population loss,and call for a more comprehensive and diversified population policy that tackles the multifaceted factors that contribute to population shrinkage,including lack of industrial support,maladjustment to market oriented reformation,poor urban environment and natural population decline.

Effects of climate change and human activity on lake shrinkage in Gonghe Basin of northeastern Tibetan Plateau during the past 60 years

Changes in the status of freshwater resources are a topic of major global, regional and local concern. This is especially so in the arid and semi-arid regions of China, where shortage of water resources plays a crucial role in limiting sustainable socioeconomic development, as well as in sustaining natural ecosystems. Recent climate change, as well as the effects of localized human activity, such as the use of water for irrigation agriculture, may have significant effects on the status of the water resources in the region. Here, we report the results of a study of changes in the areas of lakes in Gonghe Basin, northeastern Tibetan Plateau of China, over the last 60 years. The data were acquired from optical satellite images and demonstrate that the total water area of lakes in Gonghe Basin decreased significantly from the 1950s to 1980s. The cause is ascribed mainly to human activity including exploitation of farmland, against a background of increasing population; in addition, climatic data for the region demonstrate a minor drying trend during this period as the temperature increased slightly. After the construction of several reservoirs, significant amounts of water were redistributed to promote irrigation agriculture and we conclude that this caused a significant shrinkage of the natural lakes. However, both the area of farmland and the population size remained approximately constant after 1990. We conclude that the variation of the total area of lakes during the second period was mainly controlled by climatic factors （precipitation and temperature）. As the regional temperature reached a new high, the area of some of the lakes decreased sharply before finally maintaining a relatively steady state. We emphasize that anthropogenic climate change and human activity have both significantly influenced the status of water resources in the arid and semi-arid regions of China.

Effects of Manufactured-sand on Dry Shrinkage and Crccp of High-strength Concrete

The influences of natural sand, manufactured-sand （MS） and stone-dust （SD） in the manufactured-sand on workability, compressive strength, elastic modulus, drying shrinkage and creep properties of high-strength concrete （HSC） were tested and compared. The results show that the reasonable content （7%-10.5%） of SD in MS will not deteriorate the workability of MS-HSC. It could even improve the workability. Moreover, the compressive strength increases gradually with the increasing SD content,and the MS- HSC with low SD content （smaller than 7%） has the elastic modulus which approaches that of the natural sand HSC, but the elastic modulus reduces when the SD content is high. The influence of the SD content on drying shrinkage performance of MS-HSC is closely related to the hydration age. The shrinkage rate of MS-HSC in the former 7 d age is higher than that of the natural sand HSC, but the difference of the shrinkage rate in the late age is not marked. Meanwhile the shrinkage rate reduces as the fly ash is added; the specific creep and creep coefficient of MS-HSC with 7% SD are close to those of the natural sand HSC.

Influence of shrinkage-reducing admixture on drying shrinkage and mechanical properties of high-performance concrete

High-performance concrete （HPC） has specific performance advantages over conventional concrete in strength and durability. HPC mixtures are usually produced with water/binder mass ratios （mW/mB） in the range of 0.2-0.4, so volume changes of concrete as a result of drying, chemical reactions, and temperature change cannot be avoided. For these reasons, shrinkage and cracking are frequent phenomena. It is necessary to add some types of admixture for reduction of shrinkage and cracking of HPC. This study used a shrinkage-reducing admixture （SRA） for that purpose. Concrete was prepared with two different mW/mB （0.22 and 0.40） and four different mass fractions of SRA to binder （w（SRA） = 0%, 1%, 2%, and 4%）. The mineral admixtures used for concrete mixes were： 25% fly ash （FA） and 25% slag by mass of binder for the mixture with mW/mB = 0.40, and 15% silica fume （SF） and 25% FA for the mixture with mW/mB = 0.22. Tests were conducted on 24 prismatic specimens, and shrinkage strains were measured through 120 days of drying. Compressive strength, splitting strength, and static modulus of elasticity were also determined. The results show that the SRA effectively reduces some mechanical properties of HPC. The reductions in compressive strength, splitting tensile strength, and elastic modulus of the concrete were 7%-24%, 9%-19%, and 5%-12%, respectively, after 90 days, compared to concrete mixtures without SRA. SRA can also help reduce drying shrinkage of concrete. The shrinkage strains of HPC with SRA were only as high as 41% of the average free shrinkage of concrete without SRA after 120 days of drying.

Pre-reinforcement grout in fractured rock masses and numerical simulation for optimizing shrinkage stoping configuration

Proper room and pillar sizes are both critical factors for safe mining and high ore recovery rate in shrinkage stoping mining of underground metal mines. The rock masses of Tangdan copper mine of China are fractured, which needs much reinforcement and support prior to mining. Cement-sodium silicate grout technology was selected, then its related parameters such as grout pressure, diffusion radius and time were calculated and proposed. In order to test the effect of the pressured grout in the fractured No.4 ore block, field experiments were conducted. To optimize stoping configuration, three-dimensional numerical simulation with ANSYS and FLAC 3 D softwares was proposed. The results show that the drilling porosity and mechanical properties of the rock masses are increased obviously. After grout, ore recovery rate is increased by 10.2 % employing the newly designed stoping configuration compared with the previous. Last, analyzed from the surface movements, roof subsidence and the maximum principal stress of the pillars, the mining safety is probable of being ensured.

Numerical Simulation of Shrinkage Cavity Formation in Spheroidal Graphite Iron Castings Based on Micro Modeling

A micro-modeling method (MM) for the quantitative prediction of the shrinkage cavity formation in SGiron castings is proposed. The mathematical models describing the volume changes during the solidification ofspheroidal graphite cast iron are established based on the models of solidification kinetics. The shrinkage cavityformation of T-shaped SG iron castings is calculated with MM method. The calculated results are compared with theexperimental results. It is shown that the predicted size, shape and distribution of shrinkage cavity by MM methodare in good agreement with the measured results.

Influence of MB-value of Manufactured Sand on the Shrinkage and Cracking of High Strength Concrete

The relation between methylene blue （MB） value of MS and its limestone dust content and clay content was investigated. The effects of MB value ranging from 0.35 to 2.5 on the workability of fresh concrete and crack propagation characteristics at the age of 24 hours, and effects on the mechanical properties, dry shrinkage of the harden concrete were tested. The experimental results show that the MB value is not related with the limestone dust content of MS, but in direct proportion to clay content. With the increase of MB value, the concrete workability decreases, and the flexural strength and 7 d compressive strength reduce markedly, whearas the 28 d compressive strength is not affected. When the MB-value is less than or equal to 1.35, the change of the MB-value has a little influence on early plastic cracking and dry shrinkage property of concrete, but when the MB-value is more than 1.35, the tendency of plastic cracking and dry shrinkage is remarkable.

Effects of Specimen Shape and Size on Water Loss and Drying Shrinkage of Cement-based Materials

The effects of specimen size and shape on development of water loss and shrinkage of mortar and concrete respectively were investigated. The experimental results showed that the effects of specimen size and shape on water loss ratio were consistent with those on drying shrinkage strain. It is also indicated that drying shrinkage strain has obvious linear correlation with water loss ratios independent of specimen size and shape. The effects of specimen size and shape on the water loss ratio were embodied in established model of averaged relative humidity improved by considering effects of sequential hydration and calculated by finite difference method. Furthermore, the effects of specimen size and shape on drying shrinkage strain of concrete were experimentally deduced and applied to modify criterion EB-FIP1990. The comparison between experimental and calculated results shows that the modified EB-FIP1990 can be adopted to predict drying shrinkage strain of concrete with reasonable accuracy.

Surface modification of polyolefin separators for lithium ion batteries to reduce thermal shrinkage without thickness increase

Surface chemical modification of polyolefin separators for lithium ion batteries is attempted to reduce the thermal shrinkage, which is im- portant for the battery energy density. In this study, we grafted organic/inorganic hybrid crosslinked networks on the separators, simply by grafting polymerization and condensation reaction. The considerable silicon-oxygen crosslinked heat-resistance networks are responsible for the reduced thermal shrinkage. The strong chemical bonds between networks and separators promise enough mechanical support even at high temperature. The shrinkage at 150 ℃ for 30 min in the mechanical direction was 38.6% and 4.6% for the pristine and present graft-modified separators, respectively. Meanwhile, the grafting organic-inorganic hybrid crosslink networks mainly occupied part of void in the internal pores of the separators, so the thicknesses of the graft-modified separators were similar with the pristine one. The half cells prepared with the modified separators exhibited almost identical electrochemical properties to those with the commercial separators, thus proving that, in order to enhance the thermal stability of lithium ion battery, this kind of grafting-modified separators may be a better alternative to conventional silica nanoparticle layers-coated polyolefin separators.