The study of inter-system bias(ISB)is important for multi-system fusion and the performance of different signal compatibility.In this paper,the stability of ISB at the BDS3/BDS2 receiver end is calculated and analyzed...The study of inter-system bias(ISB)is important for multi-system fusion and the performance of different signal compatibility.In this paper,the stability of ISB at the BDS3/BDS2 receiver end is calculated and analyzed for different time spans(DOY 060~090 in 2021)from a total of 31 MGEX and iGMAS stations.We adopted two estimation strategies,random walk and constant approach,using the precision products of orbit and clock bias provided by WUM,the influence of which on ISB was also analyzed.Our results showed that the ISB value varied little within a day,and the mean of daily ISB standard deviation was only 0.037 m when the observation condition was good.The signal reception was continuous,indicating a high ISB stability for one day.If extending the time series to one month,however,the ISB standard deviation calculated by constant approach,in which a constant ISB is estimated on a daily basis was about 0.1 m,and the results of adjacent days were not continuous,with no apparent pattern.Concerning the random walk approach,the obtained ISB time series also had a jump,and the conclusion was the same as that of the constant strategy.Besides,receiver types showed a strong regularity in ISB numerical situation,and the distribution of ISB values corresponding to the same receiver type was relatively close.Therefore,we conclude that the ISB parameters remain stable in the short term(one day)and less stable in the long-term period.It is recommended that the ISB term should be set as a constant estimate every day in BDS3/BDS2 solutions,regardless of receiver type consistency.展开更多
The numerical simulation and slope stability prediction are the focus of slope disaster research.Recently,machine learning models are commonly used in the slope stability prediction.However,these machine learning mode...The numerical simulation and slope stability prediction are the focus of slope disaster research.Recently,machine learning models are commonly used in the slope stability prediction.However,these machine learning models have some problems,such as poor nonlinear performance,local optimum and incomplete factors feature extraction.These issues can affect the accuracy of slope stability prediction.Therefore,a deep learning algorithm called Long short-term memory(LSTM)has been innovatively proposed to predict slope stability.Taking the Ganzhou City in China as the study area,the landslide inventory and their characteristics of geotechnical parameters,slope height and slope angle are analyzed.Based on these characteristics,typical soil slopes are constructed using the Geo-Studio software.Five control factors affecting slope stability,including slope height,slope angle,internal friction angle,cohesion and volumetric weight,are selected to form different slope and construct model input variables.Then,the limit equilibrium method is used to calculate the stability coefficients of these typical soil slopes under different control factors.Each slope stability coefficient and its corresponding control factors is a slope sample.As a result,a total of 2160 training samples and 450 testing samples are constructed.These sample sets are imported into LSTM for modelling and compared with the support vector machine(SVM),random forest(RF)and convo-lutional neural network(CNN).The results show that the LSTM overcomes the problem that the commonly used machine learning models have difficulty extracting global features.Furthermore,LSTM has a better prediction performance for slope stability compared to SVM,RF and CNN models.展开更多
Perovskite solar cells(PSCs)have become the represent-atives of next generation of photovoltaics;nevertheless,their stability is insufficient for large scale deployment,particularly the reverse bias stability.Here,we ...Perovskite solar cells(PSCs)have become the represent-atives of next generation of photovoltaics;nevertheless,their stability is insufficient for large scale deployment,particularly the reverse bias stability.Here,we propose a transparent conducting oxide(TCO)and low-cost metal composite electrode to improve the stability of PSCs without sacrificing the efficiency.The TCO can block ion migrations and chemical reactions between the metal and perovskite,while the metal greatly enhances the conductivity of the composite electrode.As a result,composite electrode-PSCs achieved a power conversion efficiency(PCE)of 23.7%(certified 23.2%)and exhibited excellent stability,maintaining 95%of the initial PCE when applying a reverse bias of 4.0 V for 60 s and over 92%of the initial PCE after 1000 h continuous light soaking.This composite electrode strategy can be extended to different combinations of TCOs and metals.It opens a new avenue for improving the stability of PSCs.展开更多
The effect of oxygen partial pressure (Po2) during the channel layer deposition on bias stability of amorphous indium-gallium-zinc oxide (a-IGZO) thin film transistors (TFTs) is investigated. As Po2 increases fr...The effect of oxygen partial pressure (Po2) during the channel layer deposition on bias stability of amorphous indium-gallium-zinc oxide (a-IGZO) thin film transistors (TFTs) is investigated. As Po2 increases from 10% to 30%, it is found that the device shows enhanced bias stress stability with significantly reduced threshold voltage drift under positive gate bias stress. Based on the x-ray photoelectron spectroscopy measurement, the concentration of oxygen vacancies (Or) within the a-IGZO layer is suppressed by increasing Po2. Meanwhile, the low-frequency noise analysis indicates that the average trap density near the channel/dielectric interface continuously drops with increasing Po2. Therefore, the improved interface quality with increasing Po2 during the channel layer deposition can be attributed to the reduction of interface Ov-related defects, which agrees with the enhanced bias stress stability of the a-IGZO TFTs.展开更多
To improve the signal to noise ratio(SNR)and the short-term stability of cesium atomic fountain clocks,the work of two-laser optical pumping is presented theoretically and experimentally.The short-term stability of th...To improve the signal to noise ratio(SNR)and the short-term stability of cesium atomic fountain clocks,the work of two-laser optical pumping is presented theoretically and experimentally.The short-term stability of the NIM6 fountain clock has been improved by preparing more cold atoms in the|F=4,m_(F)=0>clock state with a shortened cycle time.Two π-polarized laser beams overlapped in the horizontal plane have been applied after launching,one is resonant with|F=4>→|F′=4>transition and the other is resonant with|F=3>→|F′=4>transition.With optical pumping,the population accumulated in the|m_(F)=0>clock state is improved from 11%to 63%,and the detection signal is increased by a factor of 4.2,the SNR of the clock transition probability and the short-term stability are also improved accordingly.展开更多
The recently proposed ambient signal-based load modeling approach offers an important and effective idea to study the time-varying and distributed characteristics of power loads.Meanwhile,it also brings new problems.S...The recently proposed ambient signal-based load modeling approach offers an important and effective idea to study the time-varying and distributed characteristics of power loads.Meanwhile,it also brings new problems.Since the load model parameters of power loads can be obtained in real-time for each load bus,the numerous identified parameters make parameter application difficult.In order to obtain the parameters suitable for off-line applications,load model parameter selection(LMPS)is first introduced in this paper.Meanwhile,the convolution neural network(CNN)is adopted to achieve the selection purpose from the perspective of short-term voltage stability.To begin with,the field phasor measurement unit(PMU)data from China Southern Power Grid are obtained for load model parameter identification,and the identification results of different substations during different times indicate the necessity of LMPS.Meanwhile,the simulation case of Guangdong Power Grid shows the process of LMPS,and the results from the CNNbased LMPS confirm its effectiveness.展开更多
We describe the long-term stability and mean climatology of oceanic circulations simulated by version 2 of the Flexible Global Ocean-Atmosphere-Land System model (FGOALS-s2). Driven by pre-industrial forcing, the in...We describe the long-term stability and mean climatology of oceanic circulations simulated by version 2 of the Flexible Global Ocean-Atmosphere-Land System model (FGOALS-s2). Driven by pre-industrial forcing, the integration of FGOALS-s2 was found to have remained stable, with no obvious climate drift over 600 model years. The linear trends of sea SST and sea surface salinity (SSS) were -0.04℃ (100 yr)-1 and 0.01 psu (100 yr)-1, respectively. The simulations of oceanic temperatures, wind-driven circulation and thermohaline circulation in FGOALS-s2 were found to be comparable with observations, and have been substantially improved over previous FGOALS-s versions (1.0 and 1.1). However, significant SST biases (exceeding 3℃) were found around strong western boundary currents, in the East China Sea, the Sea of Japan and the Barents Sea. Along the eastern coasts in the Pacific and Atlantic Ocean, a warm bias (〉3℃) was mainly due to overestimation of net surface shortwave radiation and weak oceanic upwelling. The difference of SST biases in the North Atlantic and Pacific was partly due to the errors of meridional heat transport. For SSS, biases exceeding 1.5 psu were located in the Arctic Ocean and around the Gulf Stream. In the tropics, freshwater biases dominated and were mainly caused by the excess of precipitation. Regarding the vertical dimension, the maximal biases of temperature and salinity were located north of 65°N at depths of greater than 600 m, and their values exceeded 4℃ and 2 psu, respectively.展开更多
The short-and long-term stability of multi-component mixtures and intermediate mixtures of analytical standards of veterinary drugs,which can potentially occur in food and feed chains,was examined by an isochronous me...The short-and long-term stability of multi-component mixtures and intermediate mixtures of analytical standards of veterinary drugs,which can potentially occur in food and feed chains,was examined by an isochronous measurement approach.Short-term stability testing of calibrants included storage for 1,2,4,and 7 days at-20℃(as a baseline)4℃,and 23℃(with and without exposure to sunlight),respectively.Long-term stability testing conditions of intermediate mixes were-20℃,4℃,23℃(with and without exposure to sunlight),and control temperature at-80℃while the testing period was 2,4,8,and 12 weeks,respectively.Results indicated that calibration standards should ideally be stored at 4℃for only 1~2 days,without the presence of acid.Neutral storage conditions were acceptable even at room temperature.Storage of intermediate mixtures containingß-lactams and cephalosporins for longer than 1 month under 4℃ and room temperature resulted in a loss of almost 90%.When it comes to the intermediate mixtures with penicillin V and G,acceptable storage conditions were 2 weeks at-20℃,without the presence of acid.Other classes of veterinary drugs were less critical as considers long-term stability.Overall,storage conditions at-20℃were considered optimal for long-term storage of intermediate mixes of veterinary drug standards.展开更多
In the pursuit of advancing imidazolium-based energetic ionic liquids (EILs),the current study is devoted to the synthesis and characterization of 1,3-dibutyl-imidazolium azide ([BBIm][N_(3)]),as a novel member in thi...In the pursuit of advancing imidazolium-based energetic ionic liquids (EILs),the current study is devoted to the synthesis and characterization of 1,3-dibutyl-imidazolium azide ([BBIm][N_(3)]),as a novel member in this ionic liquids class.The chemical structure of this EIL was rigorously characterized and confirmed using FTIR spectroscopy,1D,and 2D-NMR analyses.The thermal behavior assessment was conducted through DSC and TGA experiments.DSC analysis revealed an endothermic glass transition at T_(g)=-61℃,followed by an exothermic degradation event at T_(onset)=311℃.Similarly,TGA thermograms exhibited a one-stage decomposition process resulting in 100% mass loss of the sample.Furthermore,the short-term thermal stability of the azide EIL was investigated by combining the non-isothermal TGA data with the TAS,it-KAS,and VYA/CE isoconversional kinetic approaches.Consequently,the Arrhenius parameters(E_(a)=154 kJ·mol^(-1),Log(A/s^(-1))=11.8) and the most probable reaction model g(a) were determined.The observed high decomposition temperatures and the significantly elevated activation energy affirm the enhanced thermal stability of the modified EIL.These findings revealed that[BBIm][N_(3)]EIL can be a promising candidate for advanced energetic material application.展开更多
In an experimental realization of the sheared cylindrical slab, the level of plasma turbulence is strongly reduced by application of a sufficient bias potential difference in the radial direction. Density fluctuation ...In an experimental realization of the sheared cylindrical slab, the level of plasma turbulence is strongly reduced by application of a sufficient bias potential difference in the radial direction. Density fluctuation levels △nrms/n decrease by more than a factor of five. The ion flow velocity profile is measured spectroscopically from the Doppler shift of an argon ion line. Comparison of the shearing rates with the turbulent amplitudes as a function of bias show no relation between the shearing rate and turbulence reduction, contrary to expectations.展开更多
Multicollinearity in factor analysis has negative effects, including unreliable factor structure, inconsistent loadings, inflated standard errors, reduced discriminant validity, and difficulties in interpreting factor...Multicollinearity in factor analysis has negative effects, including unreliable factor structure, inconsistent loadings, inflated standard errors, reduced discriminant validity, and difficulties in interpreting factors. It also leads to reduced stability, hindered factor replication, misinterpretation of factor importance, increased parameter estimation instability, reduced power to detect the true factor structure, compromised model fit indices, and biased factor loadings. Multicollinearity introduces uncertainty, complexity, and limited generalizability, hampering factor analysis. To address multicollinearity, researchers can examine the correlation matrix to identify variables with high correlation coefficients. The Variance Inflation Factor (VIF) measures the inflation of regression coefficients due to multicollinearity. Tolerance, the reciprocal of VIF, indicates the proportion of variance in a predictor variable not shared with others. Eigenvalues help assess multicollinearity, with values greater than 1 suggesting the retention of factors. Principal Component Analysis (PCA) reduces dimensionality and identifies highly correlated variables. Other diagnostic measures include the condition number and Cook’s distance. Researchers can center or standardize data, perform variable filtering, use PCA instead of factor analysis, employ factor scores, merge correlated variables, or apply clustering techniques for the solution of the multicollinearity problem. Further research is needed to explore different types of multicollinearity, assess method effectiveness, and investigate the relationship with other factor analysis issues.展开更多
The reasons for inducing quadrature error and offset error are analyzed and the expressions of quadrature error and offset error are induced. The open-loop system analysis indicates that, in order to avoid the appeara...The reasons for inducing quadrature error and offset error are analyzed and the expressions of quadrature error and offset error are induced. The open-loop system analysis indicates that, in order to avoid the appearance of harmonic peaks, the frequency difference δf between drive mode and sense mode must be less than 1/(2Qy). In order to eliminate the effects of the quadrature error and the offset error, as well as the inherent non- linearity in the capacitance-type sensors, a closed-loop feedback control circuit with quadrature correction is designed. The experimental results indicate that the quadrature error and offset error are corrected. By comparing with open-loop detection, the closed-loop feedback control circuit with quadrature correction decreases the non-linearity of the scale factor from 16. 02% to 0. 35 %, widens the maximum rate capability from ± 270 (°)/s to ± 370 (°)/s and increases the stability of zero bias from 155. 2 (°)/h to 60. 6 (°)/h.展开更多
为获得用于永磁饱和型故障限流器(permanent-magnet-biased saturation based fault current limiter,PM-FCL)的钕铁硼(Nd-Fe-B)N35永磁体的运行稳定性能,从时间、温度和外磁场影响3方面展开了实验研究。以永磁体随时间的退磁率来表征...为获得用于永磁饱和型故障限流器(permanent-magnet-biased saturation based fault current limiter,PM-FCL)的钕铁硼(Nd-Fe-B)N35永磁体的运行稳定性能,从时间、温度和外磁场影响3方面展开了实验研究。以永磁体随时间的退磁率来表征时间稳定性,以可逆损失率和可逆温度系数来表征温度稳定性,并分析了永磁部件的面积厚度比S/L对温度稳定性的影响。进一步,用通电螺线管模拟220kV变电站的工程磁场环境,通过实验考查了PMFCL永磁体的外磁场稳定性。实验表明,钕铁硼永磁体具有较好的时间稳定性和外磁场稳定性,在温度较高时的退磁效应并不明显,并可通过设计面积厚度比S/L较低的限流拓扑予以抵消。所得研究结果为研制面向工程应用的高压大容量PMFCL提供了基础依据。展开更多
A novel closed-loop control strategy of a silicon microgyroscope (SMG) is proposed. The SMG is sealed in metal can package in drive and sense modes and works under the air pressure of 10 Pa. Its quality factor reach...A novel closed-loop control strategy of a silicon microgyroscope (SMG) is proposed. The SMG is sealed in metal can package in drive and sense modes and works under the air pressure of 10 Pa. Its quality factor reaches greater than l0 000. Self-oscillating and closed-loop methods based on electrostatic force feedback are adopted in both measure and control circuits. Both single side driving and sensing methods are used to simplify the drive circuit. These dual channel decomposition and reconstruction closed loops are applied in sense modes. The testing results demonstrate that useful signals and guadrature signals do not interact with each other because of the decoupling of their phases. Under the condition of a scale factor of 9. 6 mV/((°) .s), in a full measurement range of±300 (°)/s, the zero bias stability reaches 28 (°)/h with a nonlinear coefficient of 400 × 10^-6 and a simulated bandwidth of more than 100 Hz. The overall performance is improved by two orders of magnitude in comparison to that at atmospheric pressure.展开更多
基金the Natural Science Innovation Group Foundation of China under Grants NO.41721003the Science and Technology Support Project of Department of Natural Resources of Hubei Province under Grants NO.ZRZY2022KJ29+1 种基金the Special Fund of Hubei Luojia Laboratory under Grants NO.220100020the National Natural Science Foundation of China under Grants NO.42174030.
文摘The study of inter-system bias(ISB)is important for multi-system fusion and the performance of different signal compatibility.In this paper,the stability of ISB at the BDS3/BDS2 receiver end is calculated and analyzed for different time spans(DOY 060~090 in 2021)from a total of 31 MGEX and iGMAS stations.We adopted two estimation strategies,random walk and constant approach,using the precision products of orbit and clock bias provided by WUM,the influence of which on ISB was also analyzed.Our results showed that the ISB value varied little within a day,and the mean of daily ISB standard deviation was only 0.037 m when the observation condition was good.The signal reception was continuous,indicating a high ISB stability for one day.If extending the time series to one month,however,the ISB standard deviation calculated by constant approach,in which a constant ISB is estimated on a daily basis was about 0.1 m,and the results of adjacent days were not continuous,with no apparent pattern.Concerning the random walk approach,the obtained ISB time series also had a jump,and the conclusion was the same as that of the constant strategy.Besides,receiver types showed a strong regularity in ISB numerical situation,and the distribution of ISB values corresponding to the same receiver type was relatively close.Therefore,we conclude that the ISB parameters remain stable in the short term(one day)and less stable in the long-term period.It is recommended that the ISB term should be set as a constant estimate every day in BDS3/BDS2 solutions,regardless of receiver type consistency.
基金funded by the National Natural Science Foundation of China (41807285)。
文摘The numerical simulation and slope stability prediction are the focus of slope disaster research.Recently,machine learning models are commonly used in the slope stability prediction.However,these machine learning models have some problems,such as poor nonlinear performance,local optimum and incomplete factors feature extraction.These issues can affect the accuracy of slope stability prediction.Therefore,a deep learning algorithm called Long short-term memory(LSTM)has been innovatively proposed to predict slope stability.Taking the Ganzhou City in China as the study area,the landslide inventory and their characteristics of geotechnical parameters,slope height and slope angle are analyzed.Based on these characteristics,typical soil slopes are constructed using the Geo-Studio software.Five control factors affecting slope stability,including slope height,slope angle,internal friction angle,cohesion and volumetric weight,are selected to form different slope and construct model input variables.Then,the limit equilibrium method is used to calculate the stability coefficients of these typical soil slopes under different control factors.Each slope stability coefficient and its corresponding control factors is a slope sample.As a result,a total of 2160 training samples and 450 testing samples are constructed.These sample sets are imported into LSTM for modelling and compared with the support vector machine(SVM),random forest(RF)and convo-lutional neural network(CNN).The results show that the LSTM overcomes the problem that the commonly used machine learning models have difficulty extracting global features.Furthermore,LSTM has a better prediction performance for slope stability compared to SVM,RF and CNN models.
基金supported by National Natural Science Foundation of China(No.21872080)National Key Research and Development Program of China(2022YFB3803304)+2 种基金supported by Tsinghua University Initiative Scientific Research Program(20221080065,20223080044)The State Key Laboratory of Power System and Generation Equipment(Nos.SKLD21Z03 and SKLD20M03)the Chinese Thousand Talents Program for Young Professionals.
文摘Perovskite solar cells(PSCs)have become the represent-atives of next generation of photovoltaics;nevertheless,their stability is insufficient for large scale deployment,particularly the reverse bias stability.Here,we propose a transparent conducting oxide(TCO)and low-cost metal composite electrode to improve the stability of PSCs without sacrificing the efficiency.The TCO can block ion migrations and chemical reactions between the metal and perovskite,while the metal greatly enhances the conductivity of the composite electrode.As a result,composite electrode-PSCs achieved a power conversion efficiency(PCE)of 23.7%(certified 23.2%)and exhibited excellent stability,maintaining 95%of the initial PCE when applying a reverse bias of 4.0 V for 60 s and over 92%of the initial PCE after 1000 h continuous light soaking.This composite electrode strategy can be extended to different combinations of TCOs and metals.It opens a new avenue for improving the stability of PSCs.
基金Supported by the National Basic Research Program of China under Grant Nos 2010CB327504,2011CB922100 and2011CB301900the National Natural Science Foundation of China under Grant Nos 11104130 and 61322112+2 种基金the Natural Science Foundation of Jiangsu Province under Grant Nos BK2011556 and BK2011050the Priority Academic Program Development of Jiangsu Higher Education Institutionsand the NUPTSF Grant Nos NY213069 and NY214028
文摘The effect of oxygen partial pressure (Po2) during the channel layer deposition on bias stability of amorphous indium-gallium-zinc oxide (a-IGZO) thin film transistors (TFTs) is investigated. As Po2 increases from 10% to 30%, it is found that the device shows enhanced bias stress stability with significantly reduced threshold voltage drift under positive gate bias stress. Based on the x-ray photoelectron spectroscopy measurement, the concentration of oxygen vacancies (Or) within the a-IGZO layer is suppressed by increasing Po2. Meanwhile, the low-frequency noise analysis indicates that the average trap density near the channel/dielectric interface continuously drops with increasing Po2. Therefore, the improved interface quality with increasing Po2 during the channel layer deposition can be attributed to the reduction of interface Ov-related defects, which agrees with the enhanced bias stress stability of the a-IGZO TFTs.
基金the National Natural Science Foundation of China(Grant No.11873044).
文摘To improve the signal to noise ratio(SNR)and the short-term stability of cesium atomic fountain clocks,the work of two-laser optical pumping is presented theoretically and experimentally.The short-term stability of the NIM6 fountain clock has been improved by preparing more cold atoms in the|F=4,m_(F)=0>clock state with a shortened cycle time.Two π-polarized laser beams overlapped in the horizontal plane have been applied after launching,one is resonant with|F=4>→|F′=4>transition and the other is resonant with|F=3>→|F′=4>transition.With optical pumping,the population accumulated in the|m_(F)=0>clock state is improved from 11%to 63%,and the detection signal is increased by a factor of 4.2,the SNR of the clock transition probability and the short-term stability are also improved accordingly.
基金supported by the National Natural Science Foundation of China(U2066601,U1766214).
文摘The recently proposed ambient signal-based load modeling approach offers an important and effective idea to study the time-varying and distributed characteristics of power loads.Meanwhile,it also brings new problems.Since the load model parameters of power loads can be obtained in real-time for each load bus,the numerous identified parameters make parameter application difficult.In order to obtain the parameters suitable for off-line applications,load model parameter selection(LMPS)is first introduced in this paper.Meanwhile,the convolution neural network(CNN)is adopted to achieve the selection purpose from the perspective of short-term voltage stability.To begin with,the field phasor measurement unit(PMU)data from China Southern Power Grid are obtained for load model parameter identification,and the identification results of different substations during different times indicate the necessity of LMPS.Meanwhile,the simulation case of Guangdong Power Grid shows the process of LMPS,and the results from the CNNbased LMPS confirm its effectiveness.
基金supported by the National Key Program for Developing Basic Sciences(GrantNos. 2010CB950502)the "Strategic Priority Research Program-Climate Change:Carbon Budget and Related Issues" of the Chinese Academy of Sciences (Grant No.XDA05110302)+1 种基金the National Natural Science Foundation of China(Grant Nos. 40906012 and 41023002)National High Technology Research and Development Program of China(Grant No. 2010AA012303)
文摘We describe the long-term stability and mean climatology of oceanic circulations simulated by version 2 of the Flexible Global Ocean-Atmosphere-Land System model (FGOALS-s2). Driven by pre-industrial forcing, the integration of FGOALS-s2 was found to have remained stable, with no obvious climate drift over 600 model years. The linear trends of sea SST and sea surface salinity (SSS) were -0.04℃ (100 yr)-1 and 0.01 psu (100 yr)-1, respectively. The simulations of oceanic temperatures, wind-driven circulation and thermohaline circulation in FGOALS-s2 were found to be comparable with observations, and have been substantially improved over previous FGOALS-s versions (1.0 and 1.1). However, significant SST biases (exceeding 3℃) were found around strong western boundary currents, in the East China Sea, the Sea of Japan and the Barents Sea. Along the eastern coasts in the Pacific and Atlantic Ocean, a warm bias (〉3℃) was mainly due to overestimation of net surface shortwave radiation and weak oceanic upwelling. The difference of SST biases in the North Atlantic and Pacific was partly due to the errors of meridional heat transport. For SSS, biases exceeding 1.5 psu were located in the Arctic Ocean and around the Gulf Stream. In the tropics, freshwater biases dominated and were mainly caused by the excess of precipitation. Regarding the vertical dimension, the maximal biases of temperature and salinity were located north of 65°N at depths of greater than 600 m, and their values exceeded 4℃ and 2 psu, respectively.
文摘The short-and long-term stability of multi-component mixtures and intermediate mixtures of analytical standards of veterinary drugs,which can potentially occur in food and feed chains,was examined by an isochronous measurement approach.Short-term stability testing of calibrants included storage for 1,2,4,and 7 days at-20℃(as a baseline)4℃,and 23℃(with and without exposure to sunlight),respectively.Long-term stability testing conditions of intermediate mixes were-20℃,4℃,23℃(with and without exposure to sunlight),and control temperature at-80℃while the testing period was 2,4,8,and 12 weeks,respectively.Results indicated that calibration standards should ideally be stored at 4℃for only 1~2 days,without the presence of acid.Neutral storage conditions were acceptable even at room temperature.Storage of intermediate mixtures containingß-lactams and cephalosporins for longer than 1 month under 4℃ and room temperature resulted in a loss of almost 90%.When it comes to the intermediate mixtures with penicillin V and G,acceptable storage conditions were 2 weeks at-20℃,without the presence of acid.Other classes of veterinary drugs were less critical as considers long-term stability.Overall,storage conditions at-20℃were considered optimal for long-term storage of intermediate mixes of veterinary drug standards.
文摘In the pursuit of advancing imidazolium-based energetic ionic liquids (EILs),the current study is devoted to the synthesis and characterization of 1,3-dibutyl-imidazolium azide ([BBIm][N_(3)]),as a novel member in this ionic liquids class.The chemical structure of this EIL was rigorously characterized and confirmed using FTIR spectroscopy,1D,and 2D-NMR analyses.The thermal behavior assessment was conducted through DSC and TGA experiments.DSC analysis revealed an endothermic glass transition at T_(g)=-61℃,followed by an exothermic degradation event at T_(onset)=311℃.Similarly,TGA thermograms exhibited a one-stage decomposition process resulting in 100% mass loss of the sample.Furthermore,the short-term thermal stability of the azide EIL was investigated by combining the non-isothermal TGA data with the TAS,it-KAS,and VYA/CE isoconversional kinetic approaches.Consequently,the Arrhenius parameters(E_(a)=154 kJ·mol^(-1),Log(A/s^(-1))=11.8) and the most probable reaction model g(a) were determined.The observed high decomposition temperatures and the significantly elevated activation energy affirm the enhanced thermal stability of the modified EIL.These findings revealed that[BBIm][N_(3)]EIL can be a promising candidate for advanced energetic material application.
基金supported by the Department of Energy Office of Fusion Energy Sciences DE-FG02-04ER54766
文摘In an experimental realization of the sheared cylindrical slab, the level of plasma turbulence is strongly reduced by application of a sufficient bias potential difference in the radial direction. Density fluctuation levels △nrms/n decrease by more than a factor of five. The ion flow velocity profile is measured spectroscopically from the Doppler shift of an argon ion line. Comparison of the shearing rates with the turbulent amplitudes as a function of bias show no relation between the shearing rate and turbulence reduction, contrary to expectations.
文摘Multicollinearity in factor analysis has negative effects, including unreliable factor structure, inconsistent loadings, inflated standard errors, reduced discriminant validity, and difficulties in interpreting factors. It also leads to reduced stability, hindered factor replication, misinterpretation of factor importance, increased parameter estimation instability, reduced power to detect the true factor structure, compromised model fit indices, and biased factor loadings. Multicollinearity introduces uncertainty, complexity, and limited generalizability, hampering factor analysis. To address multicollinearity, researchers can examine the correlation matrix to identify variables with high correlation coefficients. The Variance Inflation Factor (VIF) measures the inflation of regression coefficients due to multicollinearity. Tolerance, the reciprocal of VIF, indicates the proportion of variance in a predictor variable not shared with others. Eigenvalues help assess multicollinearity, with values greater than 1 suggesting the retention of factors. Principal Component Analysis (PCA) reduces dimensionality and identifies highly correlated variables. Other diagnostic measures include the condition number and Cook’s distance. Researchers can center or standardize data, perform variable filtering, use PCA instead of factor analysis, employ factor scores, merge correlated variables, or apply clustering techniques for the solution of the multicollinearity problem. Further research is needed to explore different types of multicollinearity, assess method effectiveness, and investigate the relationship with other factor analysis issues.
文摘The reasons for inducing quadrature error and offset error are analyzed and the expressions of quadrature error and offset error are induced. The open-loop system analysis indicates that, in order to avoid the appearance of harmonic peaks, the frequency difference δf between drive mode and sense mode must be less than 1/(2Qy). In order to eliminate the effects of the quadrature error and the offset error, as well as the inherent non- linearity in the capacitance-type sensors, a closed-loop feedback control circuit with quadrature correction is designed. The experimental results indicate that the quadrature error and offset error are corrected. By comparing with open-loop detection, the closed-loop feedback control circuit with quadrature correction decreases the non-linearity of the scale factor from 16. 02% to 0. 35 %, widens the maximum rate capability from ± 270 (°)/s to ± 370 (°)/s and increases the stability of zero bias from 155. 2 (°)/h to 60. 6 (°)/h.
文摘为获得用于永磁饱和型故障限流器(permanent-magnet-biased saturation based fault current limiter,PM-FCL)的钕铁硼(Nd-Fe-B)N35永磁体的运行稳定性能,从时间、温度和外磁场影响3方面展开了实验研究。以永磁体随时间的退磁率来表征时间稳定性,以可逆损失率和可逆温度系数来表征温度稳定性,并分析了永磁部件的面积厚度比S/L对温度稳定性的影响。进一步,用通电螺线管模拟220kV变电站的工程磁场环境,通过实验考查了PMFCL永磁体的外磁场稳定性。实验表明,钕铁硼永磁体具有较好的时间稳定性和外磁场稳定性,在温度较高时的退磁效应并不明显,并可通过设计面积厚度比S/L较低的限流拓扑予以抵消。所得研究结果为研制面向工程应用的高压大容量PMFCL提供了基础依据。
基金The National High Technology Research and Development Program of China (863Program)(No.2002AA812038)the National Defense Pre-Research Support Program (No.41308050109)
文摘A novel closed-loop control strategy of a silicon microgyroscope (SMG) is proposed. The SMG is sealed in metal can package in drive and sense modes and works under the air pressure of 10 Pa. Its quality factor reaches greater than l0 000. Self-oscillating and closed-loop methods based on electrostatic force feedback are adopted in both measure and control circuits. Both single side driving and sensing methods are used to simplify the drive circuit. These dual channel decomposition and reconstruction closed loops are applied in sense modes. The testing results demonstrate that useful signals and guadrature signals do not interact with each other because of the decoupling of their phases. Under the condition of a scale factor of 9. 6 mV/((°) .s), in a full measurement range of±300 (°)/s, the zero bias stability reaches 28 (°)/h with a nonlinear coefficient of 400 × 10^-6 and a simulated bandwidth of more than 100 Hz. The overall performance is improved by two orders of magnitude in comparison to that at atmospheric pressure.