The molecular conformation and the microstructure of the slenderized wool fibers have been studied by the Raman spectroscopy. The typical bands analyzed in this paper include the amideⅠand amide Ⅲ regions, the CC sk...The molecular conformation and the microstructure of the slenderized wool fibers have been studied by the Raman spectroscopy. The typical bands analyzed in this paper include the amideⅠand amide Ⅲ regions, the CC skeletal vibration region, and the SS and CS bond vibration regions. The experimental results show that ⅰ) the Raman spectroscopy can reveal the secondary structural transformation from αhelical to βpleated sheet begin at the early stage of stretching; ⅱ) the stretching mechanism of wool fibers can be divided into two different mechanisms, i.e. the secondary structural transformation and the slippage of the polypeptide chain; and ⅲ) the stretching leads to the increasing of the amount of the disordered conformation and the decreasing of the amount of SS bonds.展开更多
Science is the basis of the country’s development and wealth. In particular, it is necessary to effectively use advanced scientific developments and technical achievements in order to strengthen the economy in the pe...Science is the basis of the country’s development and wealth. In particular, it is necessary to effectively use advanced scientific developments and technical achievements in order to strengthen the economy in the period when the desire for innovation in all fields is still growing. In theoretical-experimental Scientific Research work, both theoretical and experimental results are achieved, and it is more useful to withstand more theoretical-experimental loads for a longer period of time. The occurrences in the production process of natural wool fiber technologists are a complex of physical and mechanical phenomena, which can be used only by the modern achievements of science and technology. In most cases, the parameter relationship with the factors influencing the technological process or the object can open a curve without any other things.展开更多
The technique of atmospheric pressure plasma is of value in textile industry.In this paper,argon(Ar)and argon/oxygen(Ar/O2)atmospheric pressure plasma were used to treat wool and ramie fibers.The structures and proper...The technique of atmospheric pressure plasma is of value in textile industry.In this paper,argon(Ar)and argon/oxygen(Ar/O2)atmospheric pressure plasma were used to treat wool and ramie fibers.The structures and properties of treated fibers were investigated by means of SEM,XPS,single fiber tensile tester and so on.The results proved that the effects of plasma treatments depended on structural characteristics of fibers to a great extent,besides conditions of plasma treatment.By atmospheric pressure plasma treatment,wool fiber had significant changes in morphology structure,surface chemical component,mechanic properties and dyeability,while ramie fiber just showed a little change.In additional,Ar/O2 plasma showed more effective action than argon.And at the beginning of treatment,plasma brought about remarkable effects,which did not increase with prolonging of treat time.展开更多
This paper deals with graft copolymerization of acrylic acid (AA) onto Xinjiang fine wool.fiber in aqueous medium initiated by gamma rays. Graft copolymerization was carried out by themutual irradiation method in limi...This paper deals with graft copolymerization of acrylic acid (AA) onto Xinjiang fine wool.fiber in aqueous medium initiated by gamma rays. Graft copolymerization was carried out by themutual irradiation method in limited air. Percent grafting and percent efficiency have been deter-mined as a function of total dose, dose rate, concentration of monomer, wool weight and reactiontemperature. Graft copolymers are characterized with infrared (IR) spectroscopy, scanning elec-tron microscopy (SEM), and X--ray diffractometer. Properties of the grafts were studied, and compared with the virgin fiber.展开更多
This study describes the characteristics of mineral wool and its applications,and also introduces the traditional process of mineral wool made from molten blast furnace （BF） slag. Compared with high energy consumpti...This study describes the characteristics of mineral wool and its applications,and also introduces the traditional process of mineral wool made from molten blast furnace （BF） slag. Compared with high energy consumption of the traditional process,the production of mineral wool by using molten BF slag will be able to take full advantage of the sensible heat of molten slag, and also reduce production costs. However, there are also further issues to resolve such as how to obtain the required amount of molten BF slag and how to make it homogeneous. Based on the physical and chemical properties of the molten BF slag,the investigation into the relationship between temperature and viscosity under different acidity coefficients of the slag and silicon mixture was conducted. Combined with the crystallization and phase diagram of slag wool, its heat resistance, water resistance, durability and corrosion resistance were analyzed. Finally, trends of the technology development are proposed.展开更多
Plasma etching technique used in the modification of fibres,yarns and fabrics of wool is re-ported.The experimental results show that the method is useful for improving wettability and re-ducing shrinkage of wool,it m...Plasma etching technique used in the modification of fibres,yarns and fabrics of wool is re-ported.The experimental results show that the method is useful for improving wettability and re-ducing shrinkage of wool,it may be used to increase the strength of tops and yarns,and to enhancethe hand and colour of the final products.In addition,the characteristic features of the plasmamodified wool and discussions of possible mechanisms of the action are presented.展开更多
Present study deals with the biodegradable behavior of individual components and their preforms of nonwoven biocomposites developed from waste wool fibers including coring wool(CW),dorper wool(DW)and recycled polyeste...Present study deals with the biodegradable behavior of individual components and their preforms of nonwoven biocomposites developed from waste wool fibers including coring wool(CW),dorper wool(DW)and recycled polyester fibers(RPET).A respirometric technique was employed to estimate the production of CO_(2) during the biodegradation experiments under soil and aqueous media conditions.Functional groups of test samples before and after biodegradation were analyzed using Fourier transform infrared spectroscopy(FTIR).Leaching chemicals such as formaldehyde(hydrolyzed)and Chromium VI(Cr VI)was also measured.The CO_(2) emission in wool fibers CW and DW indicated 90%and 60%biodegradation in soil burial and aqueous media conditions respectively,for 100 days incubation.RPET fibers,20%and 10%biodegradation in soil burial and aqueous media conditions was measured respectively while the preforms of waste wool and RPET reflected 30%and 25%biodegradation in soil burial and aqueous media conditions,respectively.The degradation of end functional groups such as carbonyl(keto and ester),aldehyde and hydroxyl were also confirmed by FTIR.The DW and CW wool fibers showed higher Cr(VI)concentration as compared to the RPET.The released formaldehyde results showed higher concentration for RPET preforms as compared to waste wool preforms.These results suggest that waste wool preforms are extremely environment friendly as compared to RPET preforms.Thus,waste wool preforms it can be potentially utilized for preparing biocomposite materials and associated biobased products.展开更多
Using the forearm test, the prickle of 26 commercially available light-weight worsted woven wool fabrics and 7 other fiber fabrics were studied under (24±1)℃ temperature and (65±5)% RH conditions. The surfa...Using the forearm test, the prickle of 26 commercially available light-weight worsted woven wool fabrics and 7 other fiber fabrics were studied under (24±1)℃ temperature and (65±5)% RH conditions. The surface fiber diameter of part of the wool fabrics was measured using a microscope. It was found that most of the light-weight worsted woven wool fabrics gave a prickle sensation under the above conditions. The prickle sensation was significantly correlated with the mean fiber diameter of the surface hairiness. It was also found that the prickle of the light-weight worsted woven wool fabrics was significantly correlated with the number of surface fibers which were coarser than 26 μm diameter.展开更多
文摘The molecular conformation and the microstructure of the slenderized wool fibers have been studied by the Raman spectroscopy. The typical bands analyzed in this paper include the amideⅠand amide Ⅲ regions, the CC skeletal vibration region, and the SS and CS bond vibration regions. The experimental results show that ⅰ) the Raman spectroscopy can reveal the secondary structural transformation from αhelical to βpleated sheet begin at the early stage of stretching; ⅱ) the stretching mechanism of wool fibers can be divided into two different mechanisms, i.e. the secondary structural transformation and the slippage of the polypeptide chain; and ⅲ) the stretching leads to the increasing of the amount of the disordered conformation and the decreasing of the amount of SS bonds.
文摘Science is the basis of the country’s development and wealth. In particular, it is necessary to effectively use advanced scientific developments and technical achievements in order to strengthen the economy in the period when the desire for innovation in all fields is still growing. In theoretical-experimental Scientific Research work, both theoretical and experimental results are achieved, and it is more useful to withstand more theoretical-experimental loads for a longer period of time. The occurrences in the production process of natural wool fiber technologists are a complex of physical and mechanical phenomena, which can be used only by the modern achievements of science and technology. In most cases, the parameter relationship with the factors influencing the technological process or the object can open a curve without any other things.
文摘The technique of atmospheric pressure plasma is of value in textile industry.In this paper,argon(Ar)and argon/oxygen(Ar/O2)atmospheric pressure plasma were used to treat wool and ramie fibers.The structures and properties of treated fibers were investigated by means of SEM,XPS,single fiber tensile tester and so on.The results proved that the effects of plasma treatments depended on structural characteristics of fibers to a great extent,besides conditions of plasma treatment.By atmospheric pressure plasma treatment,wool fiber had significant changes in morphology structure,surface chemical component,mechanic properties and dyeability,while ramie fiber just showed a little change.In additional,Ar/O2 plasma showed more effective action than argon.And at the beginning of treatment,plasma brought about remarkable effects,which did not increase with prolonging of treat time.
基金The project was supported by The National Natural Science Foundation of China.
文摘This paper deals with graft copolymerization of acrylic acid (AA) onto Xinjiang fine wool.fiber in aqueous medium initiated by gamma rays. Graft copolymerization was carried out by themutual irradiation method in limited air. Percent grafting and percent efficiency have been deter-mined as a function of total dose, dose rate, concentration of monomer, wool weight and reactiontemperature. Graft copolymers are characterized with infrared (IR) spectroscopy, scanning elec-tron microscopy (SEM), and X--ray diffractometer. Properties of the grafts were studied, and compared with the virgin fiber.
文摘This study describes the characteristics of mineral wool and its applications,and also introduces the traditional process of mineral wool made from molten blast furnace （BF） slag. Compared with high energy consumption of the traditional process,the production of mineral wool by using molten BF slag will be able to take full advantage of the sensible heat of molten slag, and also reduce production costs. However, there are also further issues to resolve such as how to obtain the required amount of molten BF slag and how to make it homogeneous. Based on the physical and chemical properties of the molten BF slag,the investigation into the relationship between temperature and viscosity under different acidity coefficients of the slag and silicon mixture was conducted. Combined with the crystallization and phase diagram of slag wool, its heat resistance, water resistance, durability and corrosion resistance were analyzed. Finally, trends of the technology development are proposed.
文摘Plasma etching technique used in the modification of fibres,yarns and fabrics of wool is re-ported.The experimental results show that the method is useful for improving wettability and re-ducing shrinkage of wool,it may be used to increase the strength of tops and yarns,and to enhancethe hand and colour of the final products.In addition,the characteristic features of the plasmamodified wool and discussions of possible mechanisms of the action are presented.
基金supported in part by the National Research Foundation of South Africa(Grant-specific unique reference numbers(UID)104840).
文摘Present study deals with the biodegradable behavior of individual components and their preforms of nonwoven biocomposites developed from waste wool fibers including coring wool(CW),dorper wool(DW)and recycled polyester fibers(RPET).A respirometric technique was employed to estimate the production of CO_(2) during the biodegradation experiments under soil and aqueous media conditions.Functional groups of test samples before and after biodegradation were analyzed using Fourier transform infrared spectroscopy(FTIR).Leaching chemicals such as formaldehyde(hydrolyzed)and Chromium VI(Cr VI)was also measured.The CO_(2) emission in wool fibers CW and DW indicated 90%and 60%biodegradation in soil burial and aqueous media conditions respectively,for 100 days incubation.RPET fibers,20%and 10%biodegradation in soil burial and aqueous media conditions was measured respectively while the preforms of waste wool and RPET reflected 30%and 25%biodegradation in soil burial and aqueous media conditions,respectively.The degradation of end functional groups such as carbonyl(keto and ester),aldehyde and hydroxyl were also confirmed by FTIR.The DW and CW wool fibers showed higher Cr(VI)concentration as compared to the RPET.The released formaldehyde results showed higher concentration for RPET preforms as compared to waste wool preforms.These results suggest that waste wool preforms are extremely environment friendly as compared to RPET preforms.Thus,waste wool preforms it can be potentially utilized for preparing biocomposite materials and associated biobased products.
文摘Using the forearm test, the prickle of 26 commercially available light-weight worsted woven wool fabrics and 7 other fiber fabrics were studied under (24±1)℃ temperature and (65±5)% RH conditions. The surface fiber diameter of part of the wool fabrics was measured using a microscope. It was found that most of the light-weight worsted woven wool fabrics gave a prickle sensation under the above conditions. The prickle sensation was significantly correlated with the mean fiber diameter of the surface hairiness. It was also found that the prickle of the light-weight worsted woven wool fabrics was significantly correlated with the number of surface fibers which were coarser than 26 μm diameter.
