Effects of Home Laundering on Electrical Resistance of Signal Transmission Lines on Colored E-Textiles

The aim of this work was to investigate the electrical resistance change of electro-textiles manufactured using cotton fabrics with stainless steel and silver plated PA yarns incorporation after being subjected to home laundering, i.e. detergent washing and silicone softening. Electrical resistances of conductive yams inside the fabric structure were compared and discussed statistically before and after washing and softener application. Greatest changes in electrical resistances were observed with samples including silver plated PA yams. After five washing cycles with detergent, silicone softening agent is removed from yarns by washing, and thus conductivity increases. Further washing of e-textiles with detergent for five more cycles causes decrease in conductivity, because of chemical effects of detergent and mechanical effects of washing process such as abrasion due to friction. Detergent which has negative reactive sites bonds with metal ions reduces conductivity.

In situ method for stress measurements in film-substrate electrodes during electrochemical processes:key role of softening and stiffening

Electrode stress is one of the main driving forces of electrochemical degradation,which is directly related to battery cycle life,thus attracting great interest.Herein,we propose an in situ method to measure bilayer stresses in film-substrate electrodes during electrochemical processes.This method consists of two parts:stress models featuring Li-dependent material modulus and in situ deformation measurements,through which electrode bilayer stresses evolution accompanied by Li-dependent material modulus can be quantitatively characterized.As application of the method,typical silicon-composite and carbon-composite film-substrate electrodes are selected for in situ mechanical measurements and experimental analysis is performed.Results show that silicon material and carbon material exhibit significant,continuous softening and stiffening,respectively.In two film-substrate electrodes,electrode material films experience compressive stress and current collector substrates undergo a tensile-to-compressive conversion across the thickness.Besides,moduli and stresses in both electrodes vary nonlinearly with capacity,presenting non-overlapping paths between lithiation and delithiation.Based on experimental data,we further demonstrate the key role of Li-dependent modulus on electrode stresses,finding that silicon material softening decreases and carbon material stiffening increases electrode stresses.The deficiencies of current stress measurement method based on Stoney equation and the applicability of our method are discussed.

Understanding Modulus Variation of the Active Layers of Silicon Composite Electrodes

The variation of the effective modulus of silicon composite electrodes,which is a fundamental feature to analyze the coupled mechanical–electrochemical behavior of Si-based electrodes in high-capacity lithium-ion batteries,remains qualitatively controversial.To clarify the contradictory experimental results,numerical modeling of a representative volume element with silicon particles,carbon-binder domains(CBDs),and pores has been performed for the lithiation process.The key parameters for modulus variation were identified and evaluated.A mesostructure change is proposed to be a crucial mechanism that affects the modulus variation,and silicon softening is another key mechanism.Silicon softening and the decreasing CBD volume fraction collectively result in a decrease in the effective modulus of the composite,whereas an increase in the silicon volume fraction along with a decrease in porosity has the opposite effect.The findings of this work provide an in-depth and fundamental understanding of the mechanical properties of silicon composite electrodes.