Effect of temperature, chloride ions and sulfide ions on the electrochemical properties of 316L stainless steel in simulated cooling water

The influence of temperature, chloride ions and sulfide ions on the anticorrosion behavior of 316L stainless steel in simulated cooling water was studied by electrochemical impedance spectroscopy and anodic polarization curves. The results show that the film resistance increases with the solution temperature but decreases after 8 days’ immersion, which indicates that the film formed at higher temperature has inferior anticorrosion behavior; Chloride ions and sulfide ions have remarkable effects on the electrochemical property of 316L stainless steel in simulated cooling water and the pitting potential declines with the concentration of chloride ions; the passivation current has no obvious effect; the rise of the concentration of sulfide ions obviously increases the passivation current, but the pitting potential changes little, which indicates that the two types of ions may have different effects on destructing passive film of stainless steel. The critical concentration of chloride ions causing anodic potential curve’s change in simulated cooling water is 250 mg/L for 316 L stainless. The effect of sulfide ions on the corrosion resistance behavior of stainless steel is increasing the passivation current density Ip. The addition of 6 mg/L sulfide ions to the solution makes Ip of 316 L increase by 0.5 times.

Numerical Simulation of the Influence of Water Flow on the Piers of a Bridge for Different Incidence Angles

A two-dimensional mathematical model is used to simulate the influence of water flow on the piers of a bridge for different incidence angles.In particular,a finite volume method is used to discretize the Navier-Stokes control equations and calculate the circumferential pressure coefficient distribution on the bridge piers’surface.The results show that the deflection of the flow is non-monotonic.It first increases and then decreases with an increase in the skew angle.

Corrosion behavior and electrochemical property of Q235A steel in treated water containing halide ions(F^-, Cl^-) from nonferrous industry

The corrosion behaviors and electrochemical properties of Q235 A steel in the treated water containing corrosive halide anions(F-, Cl-) have been investigated with corrosion tests of static coupon and dynamic coupon testing, electrochemical measurement of open-circuit potential and linear sweep voltammetry. The results reveal that the existence of F-and Cl-ions in the simulated treated water accelerate the corrosion rate of Q235 A steel. The corrosion rate reaches maximum with F-concentration of 50 mg/L, Cl-concentration of 200 mg/L, respectively. However, Q235 A steel would passivate when an applied potential is added to the system. Meanwhile, the initiating passive potential becomes positive with F-, Cl-concentration increasing. There is a little influence of F-, Cl-concentration on the initiating passivation current density. Therefore, it is necessary to control F-, Cl-concentration in the treated water when it is recycled by the pipelines made of Q235 A steel.

DYNAMICS MODEL AND SIMULATION OF FLAT VALVE SYSTEM OF INTERNAL COMBUSTION WATER PUMP

The dynamics differential equations are constructed, and the initial conditions are also given. Simulation shows the following conclusions： The water pressure in cylinder has great instantaneous pulsation and phase step when outlet valve or inlet valve opens, but is more gently in other time; The volume efficiency is influenced by the output pressure slightly, and decreases as the working rotational speed increases; When the inherent frequency of the valves is integer multiple of the working frequency, the volume efficiency of system will decrease evidently.

Asymmetry of the water flux induced by the deformation of a nanotube

The behavior of nano-confined water is expected to be fundamentally different from the behavior of bulk water.At the nanoscale,it is still unclear whether water flows more easily along the convergent direction or the divergent one,and whether a hourglass shape is more convenient than a funnel shape for water molecules to pass through a nanotube.Here,we present an approach to explore these questions by changing the deformation position of a carbon nanotube.The results of our molecular dynamics simulation indicate that the water flux through the nanotube changes significantly when the deformation position moves away from the middle region of the tube.Different from the macroscopic level,we find water flux asymmetry（water flows more easily along the convergent direction than along the divergent one）,which plays a key role in a nano water pump driven by a ratchet-like mechanism.We explore the mechanism and calculate the water flux by means of the Fokker-Planck equation and find that our theoretical results are well consistent with the simulation results.Furthermore,the simulation results demonstrate that the effect of deformation location on the water flux will be reduced when the diameter of the nanochannel increases.These findings are helpful for devising water transporters or filters based on carbon nanotubes and understanding the molecular mechanism of biological channels.

A Case Study on the Role of Water Vapor from Southwest China in Downstream Heavy Rainfall

Based on the observation data analysis and numerical simulation, the development of an eastwardmoving vortex generated in Southwest China during the period 25 27 June 2003 is studied. The water vapor budget analysis indicates that water vapor in the lower troposphere over Southwest China is transported downstream to the Yangtze and Huaihe River valleys by the southwesterly winds south of the vortex center. A potential vortieity （PV） budget analysis reveals that a positive feedback between latent heat release and low-level positive vortieity plays a vital role in the sudden development and eastward movement of the vortex. Numerical simulations are consistent with these results.

Simulation of water temperature distribution in Fenhe Reservoir

In order to evaluate the need of controlling the temperature of water discharged from the Fenhe Reservoir, the reservoir water temperature distribution was examined. A three-dimensional mathematical model was used to simulate the in-plane and vertical distribution of water temperature. The parameters of the model were calibrated with field data of the temperature distribution in the Fenhe Reservoir. The simulated temperature of discharged water is consistent with the measured data. The difference in temperature between the discharged water and the natural river channel is less than 3 ℃ under the current operating conditions. This will not significantly impact the environment of downstream areas.

Numerical Simulation and Dynamical Analysis for Low Salinity Water Lens in the Expansion Area of the Changjiang Diluted Water

The low salinity water lenses（LSWLes） in the expansion area of the Changjiang diluted water（CDW） exist in a certain period of time in some years. The impact of realistic river runoff, ocean currents and weather conditions need to be taken into account in the dynamical analysis of LSWL, which is in need of research. In this paper, the POM-σ-z model is used to set up the numerical model for the expansion of the CDW. Then LSWL in summer 1977 is simulated, and its dynamic mechanism driven by wind, tide, river runoff and the Taiwan Warm Current is also analyzed. The simulated results indicate that the isolated LSWL detaches itself from the CDW near the river mouth, and then moves towards the northeast region outside the Changjiang Estuary. Its maintaining period is from July 26 to August 11. Its formation and development is mainly driven by two factors. One is the strong southeasterly wind lasting for ten days. The other is the vertical tidal mixing during the transition from neap tide to spring tide.

Research on characteristics of water motion and influencing factors for the flexible air chamber jig body

The air bag deformation data were obtained by high-speed dynamic videos experiments. Based on gas–liquid flow VOF model, dynamic mesh technique and deformation data, numerical simulations for different structure models were achieved, and the law of water motion and influencing factors were analyzed.The results show that the flow in the length direction of the jig is smooth, and second pulsation appears in the separation time and forms the secondary separation. The installation position of screen and the number of air bags have a great influence on the uniformity of flow and velocity. The screen height cannot be too low to avoid forming the unstable flow. At the same time, the screen height cannot be too high, otherwise water velocity will be too small and was unable to provide enough power. At the height of 1.4m,velocity unevenness is minimum and the best uniform flow can be obtained. Compared with double air bags, there are the following features of single air bag: water flow is not smooth, the time achieving the maximum velocity is too long, maximum velocity is smaller, and overall effect is worse than double air bags.

Water abundance of mine floor limestone by simulation experiment

The water abundance of mine floor limestone needs to be solved urgently as the average depth of coal mining in China has increased gradually. A method is presented to discuss water abundance with the numerical and physical layered geoelectrical model being established in the half-space, full-space and full-space with tunnel, respectively. The parameters of water abundance are changed in this study, which includes water quantity, water content and volume of abnormity of water-containing abnormity. Results indicate that the different work fields have different macroscopic influences on the apparent resistivity,and the water abundance parameters of water-containing abnormity have quantitative relationship with the apparent resistivity mean in abnormal regions(three-dimensional space region). The quantitative relationships are shown as following: firstly, the amount of water injection has negative linear correlation with the apparent resistivity mean; secondly, when abnormity is unsaturated, there is a negative power function relationship between water content and apparent resistivity mean; thirdly, the volume of abnormity and apparent resistivity mean behave as a decreasing power function law.

Modelling of water quality of Minjiang estuary

In order to establish economic development region at Mawei districtwhich is nearby downstream of Minjiang river and to answer the question of impact of economic development on water quality of Minjiang estuary, the analyses of hydrologic and hydraulic characteristics of Mawei reach of Minjiang tidal river, a two-dimensional mathematical model has been established and simulation of water quality was studied. The results show that the flushing time of a conservative pollutant during dry and raining period are 12 and 7 days respectively from Mawei to Minjiang mouth, the decay rate constants of BOD and NH3-N are 0.1 to 0.4 and 0.18 to 0.45 d-1 respectively. The capacity of dilution and assimilation for pollutants is larger.

The water level simulation for crane habitat optimization in Xianghai Nature Reserve

The probability of crane living in reedy wetlands can reach 100%, at the same time, the area of reed, the water level and adjacent water area are main factors which control the crane's habitat selection. We all know that all these factors are spatially heterogeneous. For the Xianghai wetland safety and to protect the Xianghai wetland habitat of crane, this paper has mainly identified a solution to these problems. The wetland information is extracted from the TM images, which reflect the whole wetland landscape and are very important for both quantitative analysis of remote sensing observation of the earth system and positioning analysis in GIS database that is automatically extracted from DEM. The DEM for Xianghai characteristics of topography is created. On the basis of the GRID SUBMODULE, applying the GIS spatial overlay analysis, the relationship between the water level and the reed area below the water level and the rating distribution maps of reed area above water level is established. When the water level reaches the altitude of 165 m, the reed area, 981.2 ha is maximum, i.e., the water level of 165 m is the optimal.

K2_SPH Method and its Application for 2-D Water Wave Simulation

Smoothed Particle Hydrodynamics (SPH) is a Lagrangian meshless particle method. However, its low accuracy of kernel approximation when particles are distributed disorderly or located near the boundary is an obstacle standing in the way of its wide application. Adopting the Taylor series expansion method and solving the integral equation matrix, the second order kernel approximation method can be obtained, namely K2_SPH, which is discussed in this paper. This method is similar to the Finite Particle Method. With the improvement of kernel approximation, some numerical techniques should be adopted for different types of boundaries, such as a free surface boundary and solid boundary, which are two key numerical techniques of K2_SPH for water wave simulation. This paper gives some numerical results of two dimensional water wave simulations involving standing wave and sloshing tank problems by using K2_SPH. From the comparison of simulation results, the K2_SPH method is more reliable than standard SPH.

A BOD-DO coupling model for water quality simulation by artificial neural network

A one-dimensional BOD-DO coupling model for water quality simulation is presented, which adopts Streeter-Phelps equations and the theory of back-propagation artificial neural network. The water quality data of Yangtze River in the Chongqing region in the year of 1989 are divided into 5 groups and used in the learning and testing courses of this model. The result shows that such model is feasible for water quality simulation and is more accurate than traditional models.

Numerical simulation for the two-dimensional nonlinear shallow water waves

This study deals with the general numerical model to simulate the two-dimensional tidal flow, flooding wave (long wave) and shallow water waves (short wave). The foundational model is based on nonlinear Boussinesq equations. Numerical method for modelling the short waves is investigated in detail. The forces, such as Coriolis forces, wind stress, atmosphere and bottom friction, are considered. A two-dimensional implicit difference scheme of Boussinesq equations is proposed. The low-reflection outflow open boundary is suggested. By means of this model,both velocity fields of circulation current in a channel with step expansion and the wave diffraction behind a semi-infinite breakwater are computed, and the results are satisfactory.

Simulation of Water Quality of Neijiang River Based on RMA4 Model

Using the RMA4 water quality model to simulate the water quality of Neijiang river in Zhenjiang, the result showed that： in the dry season the ranges of the concentration of various pollutants simulation of Neijiang were BOD5 3.2-5.2 mg/L, CODMn 4.7-6.8 mg/L, NH3-N 0.46-1.8 mg/L, TP 0.23-0.48 mg/L, and in the rainy period, the ranges of the concentration of various pollutants simulation of Neijiang were BOD5 0.69-0.73 mg/L, CODM, 1.9-2.3 mg/L, NH3-N 0.25-0.38 mg/L, TP 0.14-0.17 mg/L.These simulated values were closed to the monitoring values of pollution concentrations of Neijiang, which indicated that RMA4 was certain practical in the river water quality simulation, and simulation results have a certain degree of reliability, and it provides a scientific planning and management method for the river pollution control.

MOLECULAR DYNAMICS SIMULATIONS OF FILLED AND EMPTY CAGE-LIKE WATER CLUSTERS IN LIQUID WATER AND THEIR SIGNIFICANCE TO GAS HYDRATE FORMATION MECHANISMS

Molecular dynamics simulations are performed to observe the evolutions of 512 and 51262 cage-like water clusters filled with or without a methane molecule immersed in bulk liquid water at 250 K and 230 K. The lifetimes of these clusters are calculated according to their Lindemann index δ (t) using the criteria of δ≥0.07. For both the filled and empty clusters, we find the dynamics of bulk water determines the lifetimes of cage-like water clusters, and that the lifetime of 512 62 cage-like cluster is the same as that of 512 cage-like cluster. Although the methane molecule indeed makes the filled cage-like cluster more stable than the empty one, the empty cage-like cluster still has chance to be long-lived compared with the filled clusters. These observations support the labile cluster hypothesis on the formation mechanisms of gas hydrates.

Simulation of Water Resources in Buerhatong River Basin

1∶250 000 contour was used to generate 0. 0012°（ 4. 32 s） of grid DEM of the basin,to simulate flow line of slope surface and gradient line,automatically draw valley line,and count catchment area at slope surface point. We organized data at the sections with 100 m of interval to simulate water system,establish coding system of river network,and build associated point with slope surface system. ＂ Hillside hydrology＂ theory simulated subsurface flow between surface water and groundwater,and used catchment water at slope surface point,gradient,valley line and depletion curve to study soil moisture distribution in the basin.

A New Simulation of Track Structure of Low-Energy Electrons in Liquid Water:Considering the Condensed-Phase Effect on Electron Elastic Scattering

A new Monte Carlo simulation of the track structure of low-energy electrons （〈10keV） in liquid water is presented. The feature of the simulation is taken into consideration of the condensed-phase effect of liquid water on electron elastic scattering with the use of the Champion model, while the dielectric response formalism incorporating the optical-data model developed by Emfietzoglou et al. is applied for calculating the electron inelastic scattering. The spatial distributions of energy deposition and inelastic scattering events of low-energy electrons with different primary energies in liquid water are calculated and compared with other theoretical evaluations. The present work shows that the condensed-phase effect of liquid water on electron elastic scattering may be of the influence on the fraction of absorbed energy and distribution of inelastic scattering events at lower primary energies, which also indicate potential effects on the DNA damage induced by low-energy electrons.