The extreme ultraviolet and soft x-ray sources are widely used in various domains. Suppressing higher order harmonics and improving spectral purity are significant. This paper describes a novel method of higher order ...The extreme ultraviolet and soft x-ray sources are widely used in various domains. Suppressing higher order harmonics and improving spectral purity are significant. This paper describes a novel method of higher order harmonics suppression with single order diffraction gratings in extreme ultraviolet and soft x-ray. The principle of harmonic suppression with single order diffraction grating is described, and an extreme ultraviolet and soft x-ray non-harmonics grating monochromator is designed based on the single order diffraction grating. The performance is simulated by an optical design software. The emergent beams of a monochromator with different gratings are measured by a transmission grating spectrometer. The results show that the single order diffraction grating can suppress higher order harmonics effectively, and it is expected to be widely used in synchrotron radiation, diagnostics of laser induced plasma, and astrophysics.展开更多
It is difficult to rapidly and on-line detect trace volatile organic compounds for miniature massspectrometry due to its limited sampling volume at slow pumping speed. In this paper, we developed anew radiofrequency f...It is difficult to rapidly and on-line detect trace volatile organic compounds for miniature massspectrometry due to its limited sampling volume at slow pumping speed. In this paper, we developed anew radiofrequency field enhanced chemical ionization source （RF-ECI） with vacuum ultraviolet （VUV）lamp by coupling radiofrequency electric field and direct-current field together. The experiment resultsshowed that the sensitivity of benzene, toluene, hydrogen sulfide and other compounds increased by 2-3orders of magnitude under the introduction of RF-ECI comparing to traditional single photon ionization（SPI）. At the same time, the reagent ion of O2＋ realized the charge transfer reaction chemical ionization,and the RF-ECI effectively expanded the detection range of the VUV lamp based SPI. The VUV lamp hasinherent advantages in the on-site analytical instrument for its small size and low power consumption,and the VUV lamp based RF-ECI miniature time-of-flight mass spectrometer （TOFMS） has a limit-of-detection for H2S as low as 0.0571 mg/m3, and it is expected to be used widely in the field of on-site rapidanalvsis.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFA0206004)the National Natural Science Foundation of China(Grant No.11375160)the National Science Instruments Major Project of China(Grant No.2012YQ130125)
文摘The extreme ultraviolet and soft x-ray sources are widely used in various domains. Suppressing higher order harmonics and improving spectral purity are significant. This paper describes a novel method of higher order harmonics suppression with single order diffraction gratings in extreme ultraviolet and soft x-ray. The principle of harmonic suppression with single order diffraction grating is described, and an extreme ultraviolet and soft x-ray non-harmonics grating monochromator is designed based on the single order diffraction grating. The performance is simulated by an optical design software. The emergent beams of a monochromator with different gratings are measured by a transmission grating spectrometer. The results show that the single order diffraction grating can suppress higher order harmonics effectively, and it is expected to be widely used in synchrotron radiation, diagnostics of laser induced plasma, and astrophysics.
基金financially supported by the National Natural Science Foundation of China(Nos.21375129 and 21675155)
文摘It is difficult to rapidly and on-line detect trace volatile organic compounds for miniature massspectrometry due to its limited sampling volume at slow pumping speed. In this paper, we developed anew radiofrequency field enhanced chemical ionization source （RF-ECI） with vacuum ultraviolet （VUV）lamp by coupling radiofrequency electric field and direct-current field together. The experiment resultsshowed that the sensitivity of benzene, toluene, hydrogen sulfide and other compounds increased by 2-3orders of magnitude under the introduction of RF-ECI comparing to traditional single photon ionization（SPI）. At the same time, the reagent ion of O2＋ realized the charge transfer reaction chemical ionization,and the RF-ECI effectively expanded the detection range of the VUV lamp based SPI. The VUV lamp hasinherent advantages in the on-site analytical instrument for its small size and low power consumption,and the VUV lamp based RF-ECI miniature time-of-flight mass spectrometer （TOFMS） has a limit-of-detection for H2S as low as 0.0571 mg/m3, and it is expected to be used widely in the field of on-site rapidanalvsis.
