The crystal structure of potential active 4-benzoyl-1,5-diphenyl-1H*-pyrazole-3-carbonitrile (C23H15N3O) (I) has been determined from single crystal X-ray diffraction data. Also IR, Uv-vis and NMR spectral data were d...The crystal structure of potential active 4-benzoyl-1,5-diphenyl-1H*-pyrazole-3-carbonitrile (C23H15N3O) (I) has been determined from single crystal X-ray diffraction data. Also IR, Uv-vis and NMR spectral data were determined. The title compound crystallizes in the monoclinic space group P* 21/c, with a* = 9.3167(2), b* = 20.6677(3), c* = 10.6143(3) ?, β* = 112.665(3)°, V* = 1886.00(8) ?3, Dcalc* = 1.23g cm-3, Z* = 4. In the structure, intermolecular H*-bonds lead to the formation of a centrosymmetric dimmer of the molecule. Furthermore, the compound has a wide transmission window (300 to 1100 nm) with a transparency of nearly 100% and the UV cut-off wavelength occurs at 242 nm.展开更多
The effect of different initial microstructures deftned by γ’ precipitate morphology has been investigated at the creep/fatigue conditions of 900℃ and 500 MPa. The wave form of stress as a function of time for cycl...The effect of different initial microstructures deftned by γ’ precipitate morphology has been investigated at the creep/fatigue conditions of 900℃ and 500 MPa. The wave form of stress as a function of time for cyclic load was of trapezoidal shape with a hold time of 10s at the upper stress level. The TEM was employed to examine the deformation process in strengthened γ’ matrix in dependence of γ’ precipitate morphology. The fracture lifetime and cycle number up to fracture were the criteria to evaluate the additional cyclic component efFect on the course of展开更多
A new transition-metal-free protocol for the synthesis of polysubstituted 1,5-diketone derivatives from readily available starting materials has been developed.All the compounds were confirmed by HRMS,1H NMR and 13C N...A new transition-metal-free protocol for the synthesis of polysubstituted 1,5-diketone derivatives from readily available starting materials has been developed.All the compounds were confirmed by HRMS,1H NMR and 13C NMR,and the single crystal structure of compound 4 f was determined to be of triclinic system,space group P1 with a=8.6515(8),b=8.6694(10),c=12.4985(8)?,b=102.152(6)°,V=895.43(15)?3,Dc=1.625 g/cm3,Z=2,F(000)=436,m(MoKα)=1.807 mm-1,R=0.0342 and w R=0.0691.Furthermore,the result of antioxidation test demonstrated that compound 4 a exhibited better antioxidant activity than butylated hydroxytoluene and vitamin C by the ABTS+radical cation decolorization assay.In addition,we further studied the mechanism of the transition-metal-free catalytic multicomponent domino reaction.展开更多
基金Financial support for this study from the Research Center of Erciyes University and the Research Center of Atatiiric University is grateflilly acknowledged.
文摘The crystal structure of potential active 4-benzoyl-1,5-diphenyl-1H*-pyrazole-3-carbonitrile (C23H15N3O) (I) has been determined from single crystal X-ray diffraction data. Also IR, Uv-vis and NMR spectral data were determined. The title compound crystallizes in the monoclinic space group P* 21/c, with a* = 9.3167(2), b* = 20.6677(3), c* = 10.6143(3) ?, β* = 112.665(3)°, V* = 1886.00(8) ?3, Dcalc* = 1.23g cm-3, Z* = 4. In the structure, intermolecular H*-bonds lead to the formation of a centrosymmetric dimmer of the molecule. Furthermore, the compound has a wide transmission window (300 to 1100 nm) with a transparency of nearly 100% and the UV cut-off wavelength occurs at 242 nm.
文摘The effect of different initial microstructures deftned by γ’ precipitate morphology has been investigated at the creep/fatigue conditions of 900℃ and 500 MPa. The wave form of stress as a function of time for cyclic load was of trapezoidal shape with a hold time of 10s at the upper stress level. The TEM was employed to examine the deformation process in strengthened γ’ matrix in dependence of γ’ precipitate morphology. The fracture lifetime and cycle number up to fracture were the criteria to evaluate the additional cyclic component efFect on the course of
基金Supported by the Youth Promotion Fund of Guangxi(2019KY0386)Guangxi Science and Technology Base and Talents Program(AD19110109)Guangxi University of science and Technology Foundation(197309)。
文摘A new transition-metal-free protocol for the synthesis of polysubstituted 1,5-diketone derivatives from readily available starting materials has been developed.All the compounds were confirmed by HRMS,1H NMR and 13C NMR,and the single crystal structure of compound 4 f was determined to be of triclinic system,space group P1 with a=8.6515(8),b=8.6694(10),c=12.4985(8)?,b=102.152(6)°,V=895.43(15)?3,Dc=1.625 g/cm3,Z=2,F(000)=436,m(MoKα)=1.807 mm-1,R=0.0342 and w R=0.0691.Furthermore,the result of antioxidation test demonstrated that compound 4 a exhibited better antioxidant activity than butylated hydroxytoluene and vitamin C by the ABTS+radical cation decolorization assay.In addition,we further studied the mechanism of the transition-metal-free catalytic multicomponent domino reaction.
