Determination of Structure and Polarity of Si C Single Crystal by X-Ray Diffraction Technique

Structure and polarity of the Si C single crystal have been analyzed with the four- circle X- ray diffraction method by a double- crystal diffractom eter.The hexagonal{ 10 15 } pole figure shows that this Si C sam ple has a6 H modification.The difference between the integrated intensities m easured byω scan in the triple- axis diffraction set- up finds some convincing evidence that the surface is either a Si- terminated face or C- terminated face.The experi- mental ratios of| F( 0 0 0 L) | 2 / | F( 0 0 0 L) | 2 are in good agreem entwith the calculated ones after the dispersion cor- rections to the atomic scattering factors( L=6 ,12 and18,respectively) .Thus,this m easurem ent technique is con- venient for the application of the materials with remarkable surface polarity.

Deep-subwavelength single grooves prepared by femtosecond laser direct writing on Si

It is well known that femtosecond laser pulses can easily spontaneously induce deep-subwavelength periodic surface structures on transparent dielectrics but not on non-transparent semiconductors.Nevertheless,in this study,we demonstrate that using high-numerical-aperture 800 nm femtosecond laser direct writing with controlled pulse energy and scanning speed in the near-damage-threshold regime,polarization-dependent deep-subwavelength single grooves with linewidths of~180 nm can be controllably prepared on Si.Generally,the single-groove linewidth increases slightly with increase in the pulse energy and decrease in the scanning speed,whereas the single-groove depth significantly increases from~300 nm to~600 nm with decrease in the scanning speed,or even to over 1μm with multi-processing,indicating the characteristics of transverse clamping and longitudinal growth of such deep-subwavelength single grooves.Energy dispersive spectroscopy composition analysis of the near-groove region confirms that single-groove formation tends to be an ultrafast,non-thermal ablation process,and the oxidized deposits near the grooves are easy to clean up.Furthermore,the results,showing both the strong dependence of groove orientation on laser polarization and the occurrence of double-groove structures due to the interference of pre-formed orthogonal grooves,indicate that the extraordinary field enhancement of strong polarization sensitivity in the deep-subwavelength groove plays an important role in single-groove growth with high stability and collimation.

Molten salt as ultrastrong polar solvent enables the most straightforward pyrolysis towards highly efficient and stable single-atom electrocatalyst

Currently,pyrolysis as the most widely used method still has some key issues not well resolved for synthesis of carbon-supported single-atom catalysts(C-SACs),e.g.,the sintering of metal atoms at high temperature as well as the high cost and complicated preparations of precursors.In this report,molten salts are demonstrated to be marvellous medium for preparation of C-SACs by pyrolysis of small molecular precursors(ionic liquid).The ultrastrong polarity on one hand establishes robust interaction with precursor and enables better carbonization,resulting in largely enhanced yield.On the other hand,the aggregation of metal atoms is effectively refrained while no nanoparticle or cluster is formed.By this strategy,a C-SAC with atomically dispersed Fe-N_(4) sites and a high specific area over 2000 m^(2) g^(-1) is obtained,which illustrates high ORR activity in both acid and alkaline media.Moreover,this SAC exhibits superior methanol tolerance and stability after acid soaking at 85℃ for 48 h.It is believed that the molten-salts-assisted pyrolysis can be developed into a routine strategy as it not only can largely simply the synthesis of C-SACs,but also can be extended to prepare other types of SACs.

Design and analysis of a novel single-mode single-polarization photonic crystal fibre based on polarization-dependent coupling and absorption effect

A novel single-mode single-polarization （SMSP） photonic crystal fibre has been proposed and analysed based on the polarization-dependent coupling and absorption effect via a full-vector finite element method with perfectly matched layers. The numerical results predict that very efficient SMSP operation can be achieved with both high bandwidth and high extinction ratio at low loss penalty. Effects of the fibre structural parameters on the SMSP bandwidth and extinction ratio have been explored, which will provide useful guide for the design and fabrication of the fibre. The results obtained will be instructive for the realization of new SMSP fibres with high performance.

Significant wave height estimation using azimuth cutoff of C-band RADARSAT-2 single-polarization SAR images

This paper proposes two simple models, look-up table（LUT） model and empirical model, to directly retrieve significant wave height（Hs） using synthetic aperture radar（SAR） azimuth cutoff（λc）. Both models aim at C-band VV, HH, VH, and HV single-polarization SAR images. The LUT model relates Hs to λc, while the empirical model relates Hs to both λc and SAR range-to-velocity（β）. The LUT model coefficients are derived by simulation under different sea states and observation conditions, which depend on incidence angle（θ）, wave direction（dw）, and βbut are independent of polarization. The empirical model coefficients are obtained by fitting the collocated data,which only depend on polarization. To fit empirical model coefficients and validate the two models, C-band RADARSAT-2 fine quad-polarization（VV＋HH＋VH＋HV） single-look complex（SLC） SAR images and collocated buoy data are collected. Retrieved Hs, using Yang model and the two models proposed in this paper from four kinds of polarization SAR data, are compared with buoy Hs. Results show that both LUT and empirical models have the capacity of retrieving Hs from C-band RADARSAT-2 co-polarization SAR data, while Yang model is not suitable for these kinds of SAR data. Moreover, the empirical model is also valid for cross-polarization SAR data showing clear ocean wave stripes.

Polarization Conversion of Single Photon via Scattering by a Λ System in a Semi-Infinite Waveguide

We theoretically investigate single-photon polarization conversion via scattering by an atom with Λ configuration coupled to a semi-infinite waveguide and discuss the two cases in which the Λ system is non-degenerated and degenerated. By applying the hard-wall boundary condition of the semi-infinite waveguide, it is found that singlephoton polarization conversion can be realized with unit probability for both cases under the ideal condition.Together with the polarization conversion, the frequency conversion of a single photon can also be realized with unit probability in the ideal case if the Λ system is not degenerated.

Noiseless linear amplification for the single-photon entanglement of arbitrary polarization–time-bin qudit

Single-photon entanglement(SPE) is an important source in quantum communication. In this paper, we put forward a single-photon-assisted noiseless linear amplification protocol to protect the SPE of an arbitrary polarization–time-bin qudit from the photon transmission loss caused by the practical channel noise. After the amplification, the fidelity of the SPE can be effectively increased. Meanwhile, the encoded polarization–time-bin features of the qudit can be well preserved. The protocol can be realized under the current experimental conditions. Moreover, the amplification protocol can be extended to resist complete photon loss and partial photon loss during the photon transmission. After the amplification, we can not only increase the fidelity of the target state, but also solve the decoherence problem simultaneously. Based on the above features, our amplification protocol may be useful in future quantum communication.

Wideband Tunable Frequency-Doubling Optoelectronic Oscillator Using a Polarization Modulator and an Optical Bandpass Filter

A wideband tunable frequency-doubling optoelectronic oscillator （FD-OEO） is proposed and experimentally demonstrated based on a polarization modulator and an optical bandpass filter （OBPF）. The central frequency of the correspondingly fundamental OEO could be adjusted by tuning the bandwidth and central frequency of the OBPF, which could also be regarded as a photonic-assisted tunable microwave filter. The frequency tuning range of the FD-OEO covers from 9.5 to 32.8？GHz, and the single sideband phase noise of the fundamental signal is lower than -100dBc/Hz at an offset of 10？kHz. Moreover, the frequency stability of the generated signal is investigated by measuring its Allan deviation. The Allan deviation of the generated fundamental signal at 10？GHz is 2.39×10^-9.

Relationship between Colored Microstructure under Polarized Light and Shape Recovery Characteristics on the Thermomechanical Cycled CuAlNi Single Crystals

The paper studied the relationship between microstructure and shape recovery characteristics by using colored microstructure analysis under polarized light on the thermomechanical cycled CuAlNi single crystals. The two-way shape memory effect in quenched thin bar resulted from the preferential formation/extinction of martensite variant due to the internal quench stress, and the variant was formed at an angle of about 45 deg. with the tension direction ([001] of the βphase). Initial thermomechanical cycling under relatively low stress single variant stress-induced martensite was formed at an angle of 45 deg. with the tension and its morphology was a lath of parallel twins. More than one group of variants were formed after several training cycles and such variants also caused tilting of some thermally formed accommodated martensite. By overheating the trained sample containing stabilized multi-variants of stress-induced martensite, very coarse martensite structure with a strong asymmetry was produced, which caused the reverse two-way shape memory effect.

A tunable comb filter using single-mode/multimode/polarization-maintaining-fiber-based Sagnac fiber loop

A novel tunable comb filter composed of a single-mode/multimode/polarization-maintaining-fiber-based Sagnac fiber loop is proposed and experimentally demonstrated. The filter tunability is achieved by rotating the polarization controller. The spectral shift is dependent on rotation direction and the position of the polarization controller. In addition, the adjustable range achieved by rotating the half-wave-plate polarization controller is twice higher than that of the quarter-wave-plate one.

Multicolor Circularly Polarized Luminescence of a Single-Component System Revealing Multiple Information Encryption

Metal-free materials with multicolor tunable circularly polarized luminescence(CPL)are attractive because of their potential applications in information storage and encryption.Here,we designed two enantiomers composed of chiral dialkyl glutamides and achiral vibration-induced emission(VIE)moiety,which can switch on CPL after a simple gelation process.It is noteworthy that the CPL colors vary in different solvents,and this is attributed to various self-assembly-induced microstructures,in which the VIE moiety is restrained to different degrees.Accordingly,a multidimensional code system composed of a quick response code,a ultraviolet(UV)light-activated color code,and a CPL information figure was constructed.To our satisfaction,the system possesses multiple information-storage functions.The orthogonal anticounterfeiting and CPLenhanced encryption functions also improve the system information encryption ability.In brief,this study provides a practical example of CPL applied to information security and an effective approach to obtain a single-component color-tunable CPL material with multiple information storage and encryption functions as well.

Hot-exciton effects on exciton diffusion and circular polarization dynamics in a single PbI_(2)nanoflake

As one of the emerging two-dimensional lead halide materials,lead iodide(PbI_(2))nanosheets have proven to possess strong application potential in the fields of high-energy radiation detection and highly efficient perovskite solar cells.However,the underlying photophysical properties such as hot-exciton-related carrier dynamics remain unclear for PbI_(2)nanosheets.Here,we report the exciton dynamics of a single PbI_(2)nanoflake prepared by an aqueous solution method.Through a three-dimensional(3D)diffusion model,we obtain the exciton annihilation radius and diffusion coefficient of a single PbI_(2)nanoflake under nonresonant and resonant excitation conditions of band-edge exciton state.As initial exciton densities increase,we find the carrier recombination mechanism for a single PbI_(2)nanoflake gradually changes from exciton-exciton annihilation to free-carrier recombination.Finally,we reveal the room-temperature circular polarization of a single PbI_(2)nanoflake is due to free-carrier recombination with a band-edge exciton dissociation time of~120 fs under the resonant excitation condition.

Efficient quantum private comparison protocol utilizing single photons and rotational encryption

As a branch of quantum secure multiparty computation,quantum private comparison is applied frequently in many fields,such as secret elections,private voting,and identification.A quantum private comparison protocol with higher efficiency and easier implementation is proposed in this paper.The private secrets are encoded as single polarized photons and then encrypted with a homomorphic rotational encryption method.Relying on this method and the circular transmission mode,we implement the multiplexing of photons,raising the efficiency of our protocol to 100%.Our protocol is easy to realize since only single photons,unitary operation,and single-particle measurement are introduced.Meanwhile,the analysis shows that our protocol is also correct and secure.

Surface-enhanced resonance Raman scattering spectroscopy of single R6G molecules

Surface-enhanced resonance Raman scattering （SERRS） of Rhodamine 6G （R6G） adsorbed on colloidal silver clusters has been studied. Based on the great enhancement of the Raman signal and the quench of the fluorescence, the SERRS spectra of R6G were recorded for the samples of dye colloidal solution with different concentrations. Spectral inhomogeneity behaviours from single molecules in the dried sample films were observed with complementary evidences, such as spectral polarization, spectral diffusion, intensity fluctuation of vibrational lines and even ＂breathing＂ of the molecules. Sequential spectra observed from a liquid sample with an average of 0.3 dye molecules in the probed volume exhibited the expected Poisson distribution for actually measuring 0, 1 or 2 molecules. Difference between the SERRS spectra of R6G excited by linearly and circularly polarized light were experimentally measured.

Structural analysis of tumor-relatedsingle amino acid mutations in human MxA protein

Background:Human myxovirus resistant protein A(MxA),encoded by the myxovirus resistance 1(Mx1) gene,is an interferon(IFN)-triggered dynamin-like multi-domain GTPase involved in innate immune responses against viral infections.Recent studies suggest that MxA is associated with several human cancers and may be a tumor suppressor and a promising biomarker for IFN therapy.Mxl gene mutations in the coding region for MxA have been discovered in many types of cancer,suggesting potential biological associations between mutations in MxA protein and corresponding cancers.In this study,we performed a systematic analysis based on the crystal structures of MxA and elucidated how these mutations specifically affect the structure and therefore the function of MxA protein.Methods:Cancer-associated Mxl mutations were collected and screened from the COSMIC database.Twenty-two unique mutations that cause single amino acid alterations in the MxA protein were chosen for the analysis.Amino acid sequence alignment was performed using Clustal W to check the conservation level of mutation sites in Mx proteins and dynamins.Structural analysis of the mutants was carried out with Coot.Structural models of selected mutants were generated by the SWISS-MODEL server for comparison with the corresponding non-mutated structures.All structural figures were generated using PyMOL.Results:We analyzed the conservation level of the single-point mutation sites and mapped them on different domains of MxA.Through individual structural analysis,we found that some mutations severely affect the stability and function of MxA either by disrupting the intraVinter-molecular interactions supported by the original residues or by incurring unfavorable configuration alterations,whereas other mutations lead to gentle or no interference to the protein stability and function because of positions or polarity features.The potential clinical value of the mutations that lead to drastic influence on MxA protein is also assessed.Conclusions:Among all of the reported tumor-associated single-point mutations,seven of them notably affect the structure and function of MxA and therefore deserve more attention with respect to potential clinical applications.Our research provides an example for systematic analysis and consequence evaluation of single-point mutations on a given cancer-related protein.

Morphologies and Structures of Perovskite Thin Film on Zn-face and O-face of ZnO Single Crystal

ZnO single crystal was used as the substrate to study the effect of ZnO crystal plane polarity on the morphology and structure of CH_3NH_3PbI_3（MAPbI_3） perovskite film and carrier transport properties,which is meaningful for improving ZnO-based perovskite solar cell. It is found that perovskite thin film has small grain size（about 190 nm） and high coverage rate on the O-face of ZnO single crystal,and the dominant exposed crystal plane of perovskite film is（110） plane. While the MAPbI_3 thin film has large grain size（about 1.03 μm） and low coverage rate on the Zn-face,and the（022） plane is dominantly exposed for the perovskite film. The injection of photogenerated electrons from MAPbI_3 film into the O-face of ZnO single crystal is faster and more effective than that to Zn-face. It is supposed that O-face is more suitable for ZnO single crystal based perovskite cell fabrication than Zn-face.

All-electric-controlled spin current switching in single-molecule magnet-tunnel junctions

A single-molecule magnet （SMM） coupled to two normal metallic electrodes can both switch spin-up and spin- down electronic currents within two different windows of SMM gate voltage. Such spin current switching in the SMM tunnel junction arises from spin-selected single electron resonant tunneling via the lowest unoccupied molecular orbit of the SMM. Since it is not magnetically controlled but all-electrically controlled, the proposed spin current switching effect may have potential applications in future spintronics.

极化调控PIN-PMN-PT铁电单晶压电性能的均匀性

弛豫铁电单晶具有优异的压电性能,在医学超声换能器、水声器件等领域有重要应用。坩埚下降法生长的弛豫铁电单晶不可避免地存在组分偏析,导致材料利用率极低。本工作测试了0.24PIN-0.46PMN-0.30PT铁电单晶沿生长方向压电系数(d_(33))和介电常数(ε_(33)^(T)/ε_(0))的变化,结果显示d_(33)和ε_(33)^(T)/ε_(0)沿着生长方向变化极大,能保持性能接近的区域不足20 mm。通过针对不同区域的极化设计,对铁电-铁电相变温度接近的区域进行极化调控,使超过60%晶体部分的d_(33)和ε_(33)^(T)/ε_(0)分别维持在(1500±140)pC·N-1和4900±350。为了验证极化调控后的晶体谐振区域是否一致,测试了两端区域的k_(33)振子的谐振谱,结果显示两者的机电耦合系数接近,谐振和反谐振的峰位置也接近,而且不存在额外的寄生振动,说明采用极化调控PIN-PMN-PT铁电单晶沿生长方向的均匀性是可行的。本工作为提高PIN-PMN-PT铁电单晶的利用率提供了一种参考方案。

基于多干扰机协同的极化SAR干扰方法

针对单极化干扰机生成的干扰会被极化合成孔径雷达(SAR)鉴别和对消的问题,本文提出了一种基于多干扰机协同的极化SAR干扰方法。该方法在不改变现有干扰机单极化发射结构的基础上,通过时序协同不同位置的多个单极化干扰机,实现对极化SAR的干扰。具体来说,根据极化SAR抗压制和欺骗干扰处理方式的不同,该方法利用不同位置的多个单极化干扰机同时发射,使极化SAR无法准确估计出干扰机发射天线极化比,从而无法对消压制干扰,实现压制干扰的目的;使用不同位置的多个单极化干扰机交替发射,有效破坏相邻两个接收脉冲之间的相关性,使极化SAR无法实现假目标对消,从而实现对极化SAR欺骗干扰的目的,并且多部单极化干扰机交替发射也能实现方位向间歇采样的干扰效果,增加欺骗干扰生成虚假目标的复杂性。由于实际应用中不需要改变现有单极化干扰机发射结构,该文所提方法为实现对极化SAR干扰带来了便利。并且该方法在生成压制和欺骗干扰时均使用模板调制干扰方式,通过简单的模板修改就能实现可控的压制和欺骗干扰效果。文中首先分析了极化SAR抗压制和欺骗干扰的方法,然后分别给出了多干扰机生成压制和欺骗干扰的时序协同方式,最后以模板调制干扰为基础具体分析了多干扰机协同生成干扰的方法,并分析了多干扰机的布局和干扰机数量选取准则。理论推导和仿真实验证明了本文方法能够实现对极化SAR的干扰。

极化方式对弛豫铁电单晶光学和电学性能的影响

针对传统弛豫铁电晶体透光率的问题,文中选择了三方相结构三元弛豫铁电单晶25PIN 44PMN 31PT,沿[001]方向对晶体进行了常温直流和交流极化,对比并分析了两种极化样品的透光率和介电压电性能。研究结果表明:交流极化后,样品透光率在可见光波段达到70%,室温下相对介电常数提高了18%,压电系数和逆压电系数分别提高了9.7%和11%。交流极化可以去除对光产生散射的71°畴壁,提高了材料透光率;交流极化样品中畴的极化旋转更加容易,因而具有更高的介电压电性能。