The polymeric Co(Ⅱ) complex[Co(Hdhpc)(py)]n(1)(py = pyridine,H3dhpc =2,6-dihydroxypyridine-4-carboxyl acid) was prepared and characterized.X-ray diffraction data revealed that the compound crystallizes in d...The polymeric Co(Ⅱ) complex[Co(Hdhpc)(py)]n(1)(py = pyridine,H3dhpc =2,6-dihydroxypyridine-4-carboxyl acid) was prepared and characterized.X-ray diffraction data revealed that the compound crystallizes in dimorphic 1α and 1β forms at room and low temperature,respectively.The former crystallizes in the orthorhombic crystal system,space group Pbcm with a =7.209(1),b = 14.834(3),c = 15.376(3) A°,V= 1644.3(5)A°3,Z = 4,C(16)H(13)CoN3O4,Mr = 370.22,Dc= 1.496 g/cm^3,F(000) = 756,μ = 1.068 mm^-1,R = 0.0633 and wR = 0.1192.While 1β is attributed to the monoclinic space group C2/c with a = 32.102(4),b = 7.022,c = 14.945(2)A°,β = 109.052(5)°,V= 3184.4(6) A°3,Z= 8,Dc= 1.544 g/cm^3,F(000) = 1512,μ = 1.103 mm^-1,R = 0.0428 and wR =0.0797.The conformation changes of pyridines between Co-citrazinate planes leading to a reversible single-crystal to single-crystal transformation.The variable temperature magnetic data indicate a weak ferrimagnetism.展开更多
Non-stoichiometric Ni50Mn27 Ga23 polycrystalline ribbons are prepared by melt-spinning technique. The magneticfield-induced strain (MFIS) of Ni-Mn-Ga bulk alloy prepared by bonding the melt-spun ribbons is obtained....Non-stoichiometric Ni50Mn27 Ga23 polycrystalline ribbons are prepared by melt-spinning technique. The magneticfield-induced strain (MFIS) of Ni-Mn-Ga bulk alloy prepared by bonding the melt-spun ribbons is obtained. The experimental results show that Ni50Mn27Ga23 bonded ribbons exhibit a typical thermal-elastic shape memory effect in the thickness direction. The martensitic transformation strain of bonded ribbons is an expansive strain of about 0.3% without the magnetic field and a contractive strain of about -0.46% at the magnetic field of 1 T. The field can not only enhance the value of the martensitic transformation strain of the bonded ribbons, but can also change the direction of the strain. The bonded ribbons alloy presents negative MFIS and obtains a larger value of the strain though influenced by the adhesive between the ribbons. Therefore, the preparation technique of the Ni-Mn-Ga bulk alloy by bonding melt-spun ribbons is helpful to get rid of the size restriction of the ribbon and to broaden the applications of the ribbons.展开更多
Recognized as one of the important active species involved in varicus ractions,singlet oxygen(^(1)O_(2))shows potential applications in chemical.blological,and environmental related fields.However,the con-trolled capt...Recognized as one of the important active species involved in varicus ractions,singlet oxygen(^(1)O_(2))shows potential applications in chemical.blological,and environmental related fields.However,the con-trolled capture and release of^(1)O_(2)are still facing huge challenges due to its short lifetime and high re-activity.Herein,a framework-interpenetration tuning strategy was applied on a metal-organic framework(MOF)that aiming to improve the capture and release rate of O.The porosity of the MOF was remark-ably enhanced with the structural evolution from seven-fold(termed NKM-181)to six-fold interpene-tration(termed NKM-182),and the active anthracene sites became much mare accessible.Such drastic process can be achieved as simple as exchanging the primitive MOF in selected solvent and occurred surprisingly as single-crystal to single-crystal transformation.Also,additionally owing to the unblocked regular channels,NKM-182 shown significantly improved^(1)O_(2)trapping and releasing rates compared to strates an unprecedented regulation of^(1)O_(2)capture and release that of in NKM-181.This work demon process,along with achieving the highest^(1)O_(2)capture and release rate among reported porous materi-als.furthermore.the obtalned endoperoxides with^(1)O_(2)loaded(termed EPO-NKM-181 and EPO-NKM-182)can be used as a high efficiency smart material for anti-fake application.展开更多
In the context of the highly desirable design and preparation of smart materials with adjustable properties based on photoreactive compounds,we report two unique photoreactive coordination polymers(CPs),{[Zn(4-Iba)_(2...In the context of the highly desirable design and preparation of smart materials with adjustable properties based on photoreactive compounds,we report two unique photoreactive coordination polymers(CPs),{[Zn(4-Iba)_(2)(4-tkpvb)]·H_()2O}_(n)(1,4-HIba=4-iodobenzoic acid,4-tkpvb=1,2,4,5-tetrakis(4-pyridylvinyl)benzene)and[Cd(1,4-bdc)(4-tkpvb)]_(n)(2,1,4-H_(2)bdc=1,4-benzenedicarboxylic acid).Depending on the metal ions and auxiliary carboxylate ligands used,the 4-tkpvb ligands in 1 and 2 adopt different mutual arrangements,which facilitate the photodimerization and photopolymerization reactions in single crystal to single crystal(SCSC)transformations.Upon UV light irradiation which results in the dimerization of the 4-tkpvb ligands,the one-dimensional(1D)zigzag chainsof 1 are transformed into a two-dimensional(2D)network of{[Zn(4-Iba)_(2)(bpbtpvcb)_(0.5)]·H_(2)O}_(n)(1a,bpbtpvcb=1,3-bis(4-pyridyl)-2,4-bis(2,4,5-tri(2-(4-pyridyl)vinyl)phenylcyclobutane).Similarly,in the crystals of 2,all 4-tkpvb ligands experience a photopolymerization reaction to form an unprecedented 1D linear organic polymer,poly-1,3-bis(4-pyridyl)-2,5-bis(2-(4-pyridyl)-vinyl)phenyl)cyclobutane(poly-bpbpvpcb).Furthermore,the 2D network of 2 is converted into a three-dimensional(3D)framework of[Cd_(n)(1,4-bdc)_(n)(poly-bpbpvpcb)](2a).This work not only offers a new protocol to selectively synthesize new supramolecular cyclic compounds,but also expands the application of photopolymerization to the synthesis of macromolecules.展开更多
A Brønsted acid-base bifunctional metal-organic framework(MOF)catalyst,PCN-700-AB[A=Brønsted acid site,TPDC-(COOH)_(2)[(1,1′∶4′,1″-terphenyl)-2,2″,4,4″-tetracarboxylic acid]and B=Brønsted basic si...A Brønsted acid-base bifunctional metal-organic framework(MOF)catalyst,PCN-700-AB[A=Brønsted acid site,TPDC-(COOH)_(2)[(1,1′∶4′,1″-terphenyl)-2,2″,4,4″-tetracarboxylic acid]and B=Brønsted basic site,BDC-NH_(2)],was designed precisely and synthesized successfully through sequential installation of Brønsted acid and base functionalities in a crystalline zirconium(Zr)-MOF.The installation underwent single-crystal-to-singlecrystal transformation throughout the process;hence,the structure of the bifunctional catalyst could be characterized accurately via single-crystal X-ray crystallography.The bifunctional MOF catalyst obtained exhibited excellent acid-base catalytic activity for a cascade of one-pot deacetalization-Knoevenagel condensation reaction.The work presented here could be considered as a promising solution to incorporate multifunctional components readily,especially the hostile aspects,into one MOF structure.展开更多
基金supported by the National Natural Science Foundation of China(No.21173074,J1210040 and J1103312)
文摘The polymeric Co(Ⅱ) complex[Co(Hdhpc)(py)]n(1)(py = pyridine,H3dhpc =2,6-dihydroxypyridine-4-carboxyl acid) was prepared and characterized.X-ray diffraction data revealed that the compound crystallizes in dimorphic 1α and 1β forms at room and low temperature,respectively.The former crystallizes in the orthorhombic crystal system,space group Pbcm with a =7.209(1),b = 14.834(3),c = 15.376(3) A°,V= 1644.3(5)A°3,Z = 4,C(16)H(13)CoN3O4,Mr = 370.22,Dc= 1.496 g/cm^3,F(000) = 756,μ = 1.068 mm^-1,R = 0.0633 and wR = 0.1192.While 1β is attributed to the monoclinic space group C2/c with a = 32.102(4),b = 7.022,c = 14.945(2)A°,β = 109.052(5)°,V= 3184.4(6) A°3,Z= 8,Dc= 1.544 g/cm^3,F(000) = 1512,μ = 1.103 mm^-1,R = 0.0428 and wR =0.0797.The conformation changes of pyridines between Co-citrazinate planes leading to a reversible single-crystal to single-crystal transformation.The variable temperature magnetic data indicate a weak ferrimagnetism.
文摘Non-stoichiometric Ni50Mn27 Ga23 polycrystalline ribbons are prepared by melt-spinning technique. The magneticfield-induced strain (MFIS) of Ni-Mn-Ga bulk alloy prepared by bonding the melt-spun ribbons is obtained. The experimental results show that Ni50Mn27Ga23 bonded ribbons exhibit a typical thermal-elastic shape memory effect in the thickness direction. The martensitic transformation strain of bonded ribbons is an expansive strain of about 0.3% without the magnetic field and a contractive strain of about -0.46% at the magnetic field of 1 T. The field can not only enhance the value of the martensitic transformation strain of the bonded ribbons, but can also change the direction of the strain. The bonded ribbons alloy presents negative MFIS and obtains a larger value of the strain though influenced by the adhesive between the ribbons. Therefore, the preparation technique of the Ni-Mn-Ga bulk alloy by bonding melt-spun ribbons is helpful to get rid of the size restriction of the ribbon and to broaden the applications of the ribbons.
基金the financial support of the National Natural Science Foundation of China(Nos.22035003 and 22201137)Nature Science Fund of Tianjin,China(No.19JCZDJC37200)+1 种基金Fundamental Research Funds for the Central Universities(No.63223020)the Haihe Laboratory of Sustainable Chemical Transformations(No.YYJC202101).
文摘Recognized as one of the important active species involved in varicus ractions,singlet oxygen(^(1)O_(2))shows potential applications in chemical.blological,and environmental related fields.However,the con-trolled capture and release of^(1)O_(2)are still facing huge challenges due to its short lifetime and high re-activity.Herein,a framework-interpenetration tuning strategy was applied on a metal-organic framework(MOF)that aiming to improve the capture and release rate of O.The porosity of the MOF was remark-ably enhanced with the structural evolution from seven-fold(termed NKM-181)to six-fold interpene-tration(termed NKM-182),and the active anthracene sites became much mare accessible.Such drastic process can be achieved as simple as exchanging the primitive MOF in selected solvent and occurred surprisingly as single-crystal to single-crystal transformation.Also,additionally owing to the unblocked regular channels,NKM-182 shown significantly improved^(1)O_(2)trapping and releasing rates compared to strates an unprecedented regulation of^(1)O_(2)capture and release that of in NKM-181.This work demon process,along with achieving the highest^(1)O_(2)capture and release rate among reported porous materi-als.furthermore.the obtalned endoperoxides with^(1)O_(2)loaded(termed EPO-NKM-181 and EPO-NKM-182)can be used as a high efficiency smart material for anti-fake application.
基金financially supported by the National Natural Science Foundation of China (NSFC No.21531006,21871196 and 21773163)the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry (No.KF2021005)+5 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Collaborative Innovation Center of Suzhou Nano Science and Technologythe Project of Scientific and Technologic Infrastructure of Suzhou(No.SZS201905)the Natural Science Research Program of Jiangsu Provincial Department of Education (No.20KJA150002)Hui-Chun Chin and Tsung-Dao Lee Chinese Undergraduate Research Endowmentthe Huaishang Talent Program of Huaian
文摘In the context of the highly desirable design and preparation of smart materials with adjustable properties based on photoreactive compounds,we report two unique photoreactive coordination polymers(CPs),{[Zn(4-Iba)_(2)(4-tkpvb)]·H_()2O}_(n)(1,4-HIba=4-iodobenzoic acid,4-tkpvb=1,2,4,5-tetrakis(4-pyridylvinyl)benzene)and[Cd(1,4-bdc)(4-tkpvb)]_(n)(2,1,4-H_(2)bdc=1,4-benzenedicarboxylic acid).Depending on the metal ions and auxiliary carboxylate ligands used,the 4-tkpvb ligands in 1 and 2 adopt different mutual arrangements,which facilitate the photodimerization and photopolymerization reactions in single crystal to single crystal(SCSC)transformations.Upon UV light irradiation which results in the dimerization of the 4-tkpvb ligands,the one-dimensional(1D)zigzag chainsof 1 are transformed into a two-dimensional(2D)network of{[Zn(4-Iba)_(2)(bpbtpvcb)_(0.5)]·H_(2)O}_(n)(1a,bpbtpvcb=1,3-bis(4-pyridyl)-2,4-bis(2,4,5-tri(2-(4-pyridyl)vinyl)phenylcyclobutane).Similarly,in the crystals of 2,all 4-tkpvb ligands experience a photopolymerization reaction to form an unprecedented 1D linear organic polymer,poly-1,3-bis(4-pyridyl)-2,5-bis(2-(4-pyridyl)-vinyl)phenyl)cyclobutane(poly-bpbpvpcb).Furthermore,the 2D network of 2 is converted into a three-dimensional(3D)framework of[Cd_(n)(1,4-bdc)_(n)(poly-bpbpvpcb)](2a).This work not only offers a new protocol to selectively synthesize new supramolecular cyclic compounds,but also expands the application of photopolymerization to the synthesis of macromolecules.
基金R.C.and T.L.gratefully acknowledge the financial support from the National Key Research and Development Program of China(grant no.2018YFA0208600)National Natural Science Foundation of China(grant no.21871267,21802142,and 51572260)+1 种基金Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000)Key Research Program of Frontier Sciences,CAS(grant no.QYZDJ-SSW-SLH045).
文摘A Brønsted acid-base bifunctional metal-organic framework(MOF)catalyst,PCN-700-AB[A=Brønsted acid site,TPDC-(COOH)_(2)[(1,1′∶4′,1″-terphenyl)-2,2″,4,4″-tetracarboxylic acid]and B=Brønsted basic site,BDC-NH_(2)],was designed precisely and synthesized successfully through sequential installation of Brønsted acid and base functionalities in a crystalline zirconium(Zr)-MOF.The installation underwent single-crystal-to-singlecrystal transformation throughout the process;hence,the structure of the bifunctional catalyst could be characterized accurately via single-crystal X-ray crystallography.The bifunctional MOF catalyst obtained exhibited excellent acid-base catalytic activity for a cascade of one-pot deacetalization-Knoevenagel condensation reaction.The work presented here could be considered as a promising solution to incorporate multifunctional components readily,especially the hostile aspects,into one MOF structure.