The effect of exchange-coupling interaction on the effective anisotropy and its varying tendency in nanocrystalline single-phase NdFeB permanent magnetic material have been investigated. The results show that the exch...The effect of exchange-coupling interaction on the effective anisotropy and its varying tendency in nanocrystalline single-phase NdFeB permanent magnetic material have been investigated. The results show that the exchange-coupling interaction between grains makes the effective anisotropy of material, Keff, decrease with the reduction of grain size. The variation of Keff is basically the same as that of coercivity. The decrease in effective anisotropy is the main reason of the reduction of coercivity for nanocrystalline single-phase NdFeB permanent magnetic material. In order to get high anisotropy and coercivity in nanocrystalline single-phase NdFeB permanent material, the grain size should be larger than 35 nm.展开更多
In this paper, the nanometer permanent magnetic BaFe12O19 powder was synthesized by a novel method of independent nucleation and crystallization steps and subsequent heat treatment,during the synthesis, Ba(NO3)2, Fe(N...In this paper, the nanometer permanent magnetic BaFe12O19 powder was synthesized by a novel method of independent nucleation and crystallization steps and subsequent heat treatment,during the synthesis, Ba(NO3)2, Fe(NO3)2 and NH4HCO3·NH2COONH4 were used as starting materials. The effect of crystallization process and heat treatment conditions on the particle size, microstructure and magnetic properties of powder was studied by using XRD, TEM and vibration sample magnetometometer techniques.XRD results showed that the hematite, α Fe2O3, was the main phase in the powder at heat treatment temperatures below 650℃ and its amount in the powder was decreased with increasing temperature and small amount of α Fe2O3 was still remained after being heated at 900℃ for 8hrs. BaFe12O19 was formed about 650℃ and its amount increased in the powder as temperature raised and the higher temperature was needed to attain considerable amount of BaFe12O19 and ideal nanometer BaFe12O19 particle in the powder. The temperature between 40℃～60℃ in the crystallization process was favor to the formation of good BaFe12O19 crystal and to the good magnetic properties of the powder. TEM showed that the particle size in the powder increased with the enhancement of the temperature and the powder crystallized at 40℃ and heated at 800℃ for 8hrs afterwards had a very homogenous particle size distribution, and that the powder heated at 900℃ for 8hrs with the same crystalline condition as the former had a typical hexagonal shape and a chain aggregation. Specific saturation and residential magnetizations and coercive force of the powder increased monotonically with the increase of temperature, and reached 39.86A·m2·kg-1, 23.96A·m2·kg-1, 480kA·m-1 at 900℃, respectively.展开更多
利用表面活性剂辅助高能球磨(SA-HEBM)分别制备了高性能的各向异性Sm2Co17纳米永磁粉末材料,然后对球磨产物进行超声波分散清洗。利用高速离心技术进行纳米颗粒分级,获得颗粒尺寸分布狭窄的纳米永磁颗粒,对所得粉末进行适当的快速热处...利用表面活性剂辅助高能球磨(SA-HEBM)分别制备了高性能的各向异性Sm2Co17纳米永磁粉末材料,然后对球磨产物进行超声波分散清洗。利用高速离心技术进行纳米颗粒分级,获得颗粒尺寸分布狭窄的纳米永磁颗粒,对所得粉末进行适当的快速热处理。分别采用扫描电镜、X射线衍射和振动样品磁强计分析、测试样品的显微形貌、相结构和室温磁性能。结果表明,粉末的厚度在80 nm左右,长度为亚微米级,具有高比表面积、强形状各向异性与磁各向异性;经过磁场取向后,Sm2Co17的易磁化轴和难磁化轴方向的室温矫顽力分别达到612.9 k A/m(7.7 k Oe)和278.6 k A/m(3.5 k Oe);表面活性剂在球磨过程中起到了重要作用。展开更多
运用1000kV超高压电子量微镜和Mossbauer谱仪结合磁测量,研究了含Nb钕铁硼永磁体的纳米微观结构与矫顽力机制模型。加入Nb,Ga等元素的NdFeB合金(3种化学元素以上组成Nd Fe B合金)的矫顽力变化机制用现有的成核硬化模型、界面局域钉扎、...运用1000kV超高压电子量微镜和Mossbauer谱仪结合磁测量,研究了含Nb钕铁硼永磁体的纳米微观结构与矫顽力机制模型。加入Nb,Ga等元素的NdFeB合金(3种化学元素以上组成Nd Fe B合金)的矫顽力变化机制用现有的成核硬化模型、界面局域钉扎、均匀钉札都不能解释,必须有一种新的矫顽力机制模型,这种新的模型提出的基础是畴壁受激活能作用而移动,当激活能足够大时,畴壁可克服阻力而脱出,从研究热涨落场和矫顽力关系引出研究三元以上NdFeB合金的理论,即"动态交叉,组合补益",要使这种动态交叉能补益必须去寻找Nb,Ga等元素加入量,文内提出以2%为宜。作者提出"晶粒细化局域钉札"模型可解释三元以上NdFeB的矫顽力变化机制。文内观察到的加Nb后出的Fe2Nb相(a=0.382nm,c=0.787nm)存在于Nd2Fe14B主相内,属Laves相。通过Mossbauer变研究得出:Nb进入e,c晶位,减少面各向异性,提高单轴各向异性,Nb主要在晶界,这是提高矫顽力原因之一。Nb和Ga以适量的添加即复合添加,可提高矫顽力,从而改善合金的热稳定性。展开更多
基金the National'863'Project of China(Grant No.2002AA324050)the National Natural Science Foundation of China(Grant Nos.9971026)the Nature Science Foundation of Shandong Province(Grant No.Y2000F10)
文摘The effect of exchange-coupling interaction on the effective anisotropy and its varying tendency in nanocrystalline single-phase NdFeB permanent magnetic material have been investigated. The results show that the exchange-coupling interaction between grains makes the effective anisotropy of material, Keff, decrease with the reduction of grain size. The variation of Keff is basically the same as that of coercivity. The decrease in effective anisotropy is the main reason of the reduction of coercivity for nanocrystalline single-phase NdFeB permanent magnetic material. In order to get high anisotropy and coercivity in nanocrystalline single-phase NdFeB permanent material, the grain size should be larger than 35 nm.
文摘In this paper, the nanometer permanent magnetic BaFe12O19 powder was synthesized by a novel method of independent nucleation and crystallization steps and subsequent heat treatment,during the synthesis, Ba(NO3)2, Fe(NO3)2 and NH4HCO3·NH2COONH4 were used as starting materials. The effect of crystallization process and heat treatment conditions on the particle size, microstructure and magnetic properties of powder was studied by using XRD, TEM and vibration sample magnetometometer techniques.XRD results showed that the hematite, α Fe2O3, was the main phase in the powder at heat treatment temperatures below 650℃ and its amount in the powder was decreased with increasing temperature and small amount of α Fe2O3 was still remained after being heated at 900℃ for 8hrs. BaFe12O19 was formed about 650℃ and its amount increased in the powder as temperature raised and the higher temperature was needed to attain considerable amount of BaFe12O19 and ideal nanometer BaFe12O19 particle in the powder. The temperature between 40℃～60℃ in the crystallization process was favor to the formation of good BaFe12O19 crystal and to the good magnetic properties of the powder. TEM showed that the particle size in the powder increased with the enhancement of the temperature and the powder crystallized at 40℃ and heated at 800℃ for 8hrs afterwards had a very homogenous particle size distribution, and that the powder heated at 900℃ for 8hrs with the same crystalline condition as the former had a typical hexagonal shape and a chain aggregation. Specific saturation and residential magnetizations and coercive force of the powder increased monotonically with the increase of temperature, and reached 39.86A·m2·kg-1, 23.96A·m2·kg-1, 480kA·m-1 at 900℃, respectively.
文摘利用表面活性剂辅助高能球磨(SA-HEBM)分别制备了高性能的各向异性Sm2Co17纳米永磁粉末材料,然后对球磨产物进行超声波分散清洗。利用高速离心技术进行纳米颗粒分级,获得颗粒尺寸分布狭窄的纳米永磁颗粒,对所得粉末进行适当的快速热处理。分别采用扫描电镜、X射线衍射和振动样品磁强计分析、测试样品的显微形貌、相结构和室温磁性能。结果表明,粉末的厚度在80 nm左右,长度为亚微米级,具有高比表面积、强形状各向异性与磁各向异性;经过磁场取向后,Sm2Co17的易磁化轴和难磁化轴方向的室温矫顽力分别达到612.9 k A/m(7.7 k Oe)和278.6 k A/m(3.5 k Oe);表面活性剂在球磨过程中起到了重要作用。
文摘运用1000kV超高压电子量微镜和Mossbauer谱仪结合磁测量,研究了含Nb钕铁硼永磁体的纳米微观结构与矫顽力机制模型。加入Nb,Ga等元素的NdFeB合金(3种化学元素以上组成Nd Fe B合金)的矫顽力变化机制用现有的成核硬化模型、界面局域钉扎、均匀钉札都不能解释,必须有一种新的矫顽力机制模型,这种新的模型提出的基础是畴壁受激活能作用而移动,当激活能足够大时,畴壁可克服阻力而脱出,从研究热涨落场和矫顽力关系引出研究三元以上NdFeB合金的理论,即"动态交叉,组合补益",要使这种动态交叉能补益必须去寻找Nb,Ga等元素加入量,文内提出以2%为宜。作者提出"晶粒细化局域钉札"模型可解释三元以上NdFeB的矫顽力变化机制。文内观察到的加Nb后出的Fe2Nb相(a=0.382nm,c=0.787nm)存在于Nd2Fe14B主相内,属Laves相。通过Mossbauer变研究得出:Nb进入e,c晶位,减少面各向异性,提高单轴各向异性,Nb主要在晶界,这是提高矫顽力原因之一。Nb和Ga以适量的添加即复合添加,可提高矫顽力,从而改善合金的热稳定性。
