3Y-TZP/3wt%Al_(2)O_(3) powder was coated with varying amounts of BN using the urea and borate reaction sintering method,and then multiphase ceramics were prepared by hot pressing sintering.The micro-topography and the...3Y-TZP/3wt%Al_(2)O_(3) powder was coated with varying amounts of BN using the urea and borate reaction sintering method,and then multiphase ceramics were prepared by hot pressing sintering.The micro-topography and the compositional analysis of synthesized ceramics were conducted through scanning electron microscopy,transmission electron microscopy and X-ray diffraction.A mechanical tester was used to analyze the Vickers hardness,fracture toughness,and bending strength of the synthesized ceramics.The results showed that the ceramic with a BN content of 12wt%showed the best processability,but had diminished mechanical properties(such as fracture toughness and bending strength).The ceramic with a BN content of 9wt%showed better processability than those with 3wt%and 6wt%BN.However,the fracture toughness was affected by the addition of 9wt%BN,making this ceramic only usable as a base material for a three-unit fixed bridge.In contrast,the ceramics with a BN content of 3wt%or 6wt%fulfilled the criteria for use in multi-unit restoration,but their low processability made them unsuitable for milling after sintering.展开更多
The preparation of LiNi_(0.8)Co_(0.2)O_2 was discussed by the multiply sintering method for solid reaction, in which the sintered material was smashed, ground and pelletted between two successive sintering steps. The...The preparation of LiNi_(0.8)Co_(0.2)O_2 was discussed by the multiply sintering method for solid reaction, in which the sintered material was smashed, ground and pelletted between two successive sintering steps. The optimum technological condition was obtained through orthogonal experiments by L_9(3~4) and DTA analysis. The result indicates that the factors of effecting the electrochemical properties of synthesized LiNi_(0.8)Co_(0.2)O_2 are molar ratio of Li/Ni/Co, oxygen pressure, homothermal time, the final sintering temperature in turn according to its importance. The oxygen pressure is reviewed independently and the technological condition is further optimized. With the same method, rare earth element Ce was studied as substitute element of Co and the cathode material of LiNi_(0.95)Ce_(0.05)O_2 with excellent electrochemical properties was prepared. The electrochemical testing results of LiNi_(0.8)Co_(0.2)O_2 and LiNi_(0.95)Ce_(0.05)O_2 experimental batteries show that discharge capacities of them reach 165 and 148 mAh·g^(-1) respectively and the persistence is more than 9 h at 3.7 V.展开更多
Nitrides MAX have attracted ever-growing interest owing to its unique metallic and ceramic characteristics and properties.Here,we report on the synthesis of highly purified Ti_(2)AlN and Ti_(4)AlN_(3) powders from Ti,...Nitrides MAX have attracted ever-growing interest owing to its unique metallic and ceramic characteristics and properties.Here,we report on the synthesis of highly purified Ti_(2)AlN and Ti_(4)AlN_(3) powders from Ti,Al and TiN powders by a facile atmosphere sintering method.The obtained nitrides show highly pure phase and excellent layered structure.Except for the composition difference of raw materials,both the nitrides can be sintered and obtained by same sintering temperature and holding time,which thus makes less processing time and less usage of synthesis parameters as compared to previously synthesis methods.To our knowledge,present work is one of the few reports on synthesis of Ti_(4)AlN_(3) and Ti_(2)AlN using atmosphere sintering method.Furthermore,the lattice changes of the layered structure of Ti_(2)AlX(X/C=N)were studied by changing the composition of X position from the synthesis of Ti_(2)AlCN and Ti_(2)AlC,and the optimal formulation and synthesis mechanism of Ti_(4)AlN_(3) were also studied.展开更多
There are many kinds and a large number of raw materials in the sintering material ground to be managed,while it is difficult to obtain the precise inventory values,which often leads to high cost.Furthermore,the exter...There are many kinds and a large number of raw materials in the sintering material ground to be managed,while it is difficult to obtain the precise inventory values,which often leads to high cost.Furthermore,the external factors of material ground are difficult to handle,such as weather variation,order fluctuation,measurement failure and so on.To solve such raw material management problems,a digital management system has been developed.First,the practical requirements and the raw material management processes are analyzed.Then,optimization and prediction methods are used to calculate the inventory according to the practical situation.With the help of practical technologies and production conditions,the developed system has been applied to a large-scale sintering material ground.The practical running results of the application demonstrate the validity of the proposed digital management system.展开更多
基金financially supported by the National Natural Science Foundation of China(No.81371183).
文摘3Y-TZP/3wt%Al_(2)O_(3) powder was coated with varying amounts of BN using the urea and borate reaction sintering method,and then multiphase ceramics were prepared by hot pressing sintering.The micro-topography and the compositional analysis of synthesized ceramics were conducted through scanning electron microscopy,transmission electron microscopy and X-ray diffraction.A mechanical tester was used to analyze the Vickers hardness,fracture toughness,and bending strength of the synthesized ceramics.The results showed that the ceramic with a BN content of 12wt%showed the best processability,but had diminished mechanical properties(such as fracture toughness and bending strength).The ceramic with a BN content of 9wt%showed better processability than those with 3wt%and 6wt%BN.However,the fracture toughness was affected by the addition of 9wt%BN,making this ceramic only usable as a base material for a three-unit fixed bridge.In contrast,the ceramics with a BN content of 3wt%or 6wt%fulfilled the criteria for use in multi-unit restoration,but their low processability made them unsuitable for milling after sintering.
文摘The preparation of LiNi_(0.8)Co_(0.2)O_2 was discussed by the multiply sintering method for solid reaction, in which the sintered material was smashed, ground and pelletted between two successive sintering steps. The optimum technological condition was obtained through orthogonal experiments by L_9(3~4) and DTA analysis. The result indicates that the factors of effecting the electrochemical properties of synthesized LiNi_(0.8)Co_(0.2)O_2 are molar ratio of Li/Ni/Co, oxygen pressure, homothermal time, the final sintering temperature in turn according to its importance. The oxygen pressure is reviewed independently and the technological condition is further optimized. With the same method, rare earth element Ce was studied as substitute element of Co and the cathode material of LiNi_(0.95)Ce_(0.05)O_2 with excellent electrochemical properties was prepared. The electrochemical testing results of LiNi_(0.8)Co_(0.2)O_2 and LiNi_(0.95)Ce_(0.05)O_2 experimental batteries show that discharge capacities of them reach 165 and 148 mAh·g^(-1) respectively and the persistence is more than 9 h at 3.7 V.
基金This work was supported by the National Natural Science Foundation of China(61774122)the Science and Technol-ogy Developing Project of Shaanxi Province(2015KW-001)the 111 Project of China(B14040).
文摘Nitrides MAX have attracted ever-growing interest owing to its unique metallic and ceramic characteristics and properties.Here,we report on the synthesis of highly purified Ti_(2)AlN and Ti_(4)AlN_(3) powders from Ti,Al and TiN powders by a facile atmosphere sintering method.The obtained nitrides show highly pure phase and excellent layered structure.Except for the composition difference of raw materials,both the nitrides can be sintered and obtained by same sintering temperature and holding time,which thus makes less processing time and less usage of synthesis parameters as compared to previously synthesis methods.To our knowledge,present work is one of the few reports on synthesis of Ti_(4)AlN_(3) and Ti_(2)AlN using atmosphere sintering method.Furthermore,the lattice changes of the layered structure of Ti_(2)AlX(X/C=N)were studied by changing the composition of X position from the synthesis of Ti_(2)AlCN and Ti_(2)AlC,and the optimal formulation and synthesis mechanism of Ti_(4)AlN_(3) were also studied.
基金supported by National High Technology Research and Development Program of China (863 Program)(No. 2012AA040307)
文摘There are many kinds and a large number of raw materials in the sintering material ground to be managed,while it is difficult to obtain the precise inventory values,which often leads to high cost.Furthermore,the external factors of material ground are difficult to handle,such as weather variation,order fluctuation,measurement failure and so on.To solve such raw material management problems,a digital management system has been developed.First,the practical requirements and the raw material management processes are analyzed.Then,optimization and prediction methods are used to calculate the inventory according to the practical situation.With the help of practical technologies and production conditions,the developed system has been applied to a large-scale sintering material ground.The practical running results of the application demonstrate the validity of the proposed digital management system.