The phosphorus slag（PS） can be used as a supplementary cementitious material due to its potential hydrating activity. However, its usage has been limited by its adverse effects, including prolonged setting and lower...The phosphorus slag（PS） can be used as a supplementary cementitious material due to its potential hydrating activity. However, its usage has been limited by its adverse effects, including prolonged setting and lowered early-stage strength. In this study, we achieved ultrafine granulation of PS using wetmilling（reducing d50 to as low as 2.02 μm） in order to increase its activity, and examined the physico-chemical properties of the resulting materials, including particle-size distribution, slurry pH, zeta potential, and activity index, as well as how their replacement level and granularity affect the setting time and mechanical performance of PS-cement mixture systems. The results suggested that as the granularity increases, there are significant boosts in the uniformity of particle sizes, slurry pH, and activity index, and the effects on cement paste, including setting times, and early-and late-stage strengths, are significantly mitigated. When d（50）=2.02 μm, the slurry becomes strongly alkaline（pH=12.16） compared to the initial d（50）=20.75 μm（pH=9.49）, and the activity is increased by 73%; when used at 40% replacement, the PS-cement mixture system can reach a 28 d compressive strength of 93.2 MPa, 36% higher than that of the pure cement control group.展开更多
A numerical simulation was performed to study the flow pattern,mixing time and open-eye slag produced by argon gas injection in an industrial scale steel ladle under non-isothermal conditions.The liquid steel remains ...A numerical simulation was performed to study the flow pattern,mixing time and open-eye slag produced by argon gas injection in an industrial scale steel ladle under non-isothermal conditions.The liquid steel remains 5min before the injection,and thermal stratification and convective flows were analyzed.Three different sequences in stages employing various argon-gas flow rates were simulated.In the first case,a sequence with the highest flow rates of argon was applied,while in the second and the third sequences,the intermediate and the lowest flow rates of argon gas were used,respectively.For determining the chemistry homogenization,the mixing time was computed and analyzed in all three cases.It was found that the cold steel is located near the walls while the steel with a high temperature is accumulated in the center of the ladle above the argon-gas tuyere.The higher and lower flows promote a faster chemistry homogenization owing to the secondary recirculations that are developed closer to the walls.The results from steel temperature drop show a good concordance with plant trial measurements.展开更多
基金Funded by National Natural Science Foundation of China(No.51372076)the Technology Innovation Major Project of Hubei Province(No.2017ACA178)the Science and Technology Support Program of Hubei Province(No.2015BCA244)
文摘The phosphorus slag（PS） can be used as a supplementary cementitious material due to its potential hydrating activity. However, its usage has been limited by its adverse effects, including prolonged setting and lowered early-stage strength. In this study, we achieved ultrafine granulation of PS using wetmilling（reducing d50 to as low as 2.02 μm） in order to increase its activity, and examined the physico-chemical properties of the resulting materials, including particle-size distribution, slurry pH, zeta potential, and activity index, as well as how their replacement level and granularity affect the setting time and mechanical performance of PS-cement mixture systems. The results suggested that as the granularity increases, there are significant boosts in the uniformity of particle sizes, slurry pH, and activity index, and the effects on cement paste, including setting times, and early-and late-stage strengths, are significantly mitigated. When d（50）=2.02 μm, the slurry becomes strongly alkaline（pH=12.16） compared to the initial d（50）=20.75 μm（pH=9.49）, and the activity is increased by 73%; when used at 40% replacement, the PS-cement mixture system can reach a 28 d compressive strength of 93.2 MPa, 36% higher than that of the pure cement control group.
文摘A numerical simulation was performed to study the flow pattern,mixing time and open-eye slag produced by argon gas injection in an industrial scale steel ladle under non-isothermal conditions.The liquid steel remains 5min before the injection,and thermal stratification and convective flows were analyzed.Three different sequences in stages employing various argon-gas flow rates were simulated.In the first case,a sequence with the highest flow rates of argon was applied,while in the second and the third sequences,the intermediate and the lowest flow rates of argon gas were used,respectively.For determining the chemistry homogenization,the mixing time was computed and analyzed in all three cases.It was found that the cold steel is located near the walls while the steel with a high temperature is accumulated in the center of the ladle above the argon-gas tuyere.The higher and lower flows promote a faster chemistry homogenization owing to the secondary recirculations that are developed closer to the walls.The results from steel temperature drop show a good concordance with plant trial measurements.
