The present study deals with the performance evaluation of the UASB reactor under varied organic loading rate(OLR) for the treatment of paper mill wastewater. The sludge granulation process started after 120 days from...The present study deals with the performance evaluation of the UASB reactor under varied organic loading rate(OLR) for the treatment of paper mill wastewater. The sludge granulation process started after 120 days from the start-up period. Sludge granules size was found to be 0 8 mm at OLR of 1 72 kgCOD/(m 3·d), which reached maximum size of about 1 0 to 1 2 mm at OLR of 2 1 kgCOD/(m 3·d). At the end of initial OLR of 1 0 kgCOD/(m 3·d) the VSS concentration was 12 86 gVSS/L, which got increased to 38 05 gVSS/L at the end of an OLR 2 1 kgCOD/(m 3·d). Most of the times VFA recorded were well within the limit of VFA reported in anaerobic fermentation process. Many times the pH observed was between 6 5 and 7 8, which is more favorable for any anaerobic process. It is also found that pH within the reactor increases along with the height of reactor. The total maximum biogas production was found to be 0 40 L/gCOD removals at OLR of 2 1 kgCOD/(m 3·d) and the maximum BOD removal at this stage was observed to be 90%.展开更多
An expanded granular sludge bed (EGSB) reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with c...An expanded granular sludge bed (EGSB) reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with continuous flow by adding proper quantity of nutritional trace elements. The results show that SLR was the key of steady operation of EGSB reactor. The increment of the granular sludge was influenced by volume loading rate (VLR), liquid up-flow velocity and sludge loading rate (SLR). Concentration of granular sludge increased rapidly when liquid up-flow velocity was over 0.94 m · h^-1 with SLR being at 1.0-2.0 d ^-1. With the propriety parameters: liquid up-flow velocity 2.52 m · h^-1, SLR 1.0-2.2 d^-1 and VLR 8.2-13.1 kg · m ^3 · d^-1, 23 days' continuous operation resulted in an increment by over 80% of granular sludge concentration in the EGSB reactor, plus good granular sludge property.展开更多
An anaerobic contact reactor (ACR) systemcomprising a continuous flow stirred tank reactor (CSTR)with settler to decouple the hydraulic retention time(HRT) from solids retention time (SRT) was developedfor fermentativ...An anaerobic contact reactor (ACR) systemcomprising a continuous flow stirred tank reactor (CSTR)with settler to decouple the hydraulic retention time(HRT) from solids retention time (SRT) was developedfor fermentative hydrogen production from dilutedmolasses by mixed microbial cultures. The ACR wasoperated at various volumetric loading rates (VLRs) of20-44 kgCOD·m^(-3)·d^(-1) with constant HRT of 6 h undermesophilic conditions of 35°C. The SRTwas maintained atabout 46-50 h in the system. At the initial VLR of20 kgCOD·m^(-3)·d^(-1), the hydrogen production rate droppedfrom 22.6 to 1.58 L·d^(-1) as the hydrogen was consumed bythe hydrogentrophic methanogen. After increasing theVLR to 28 kgCOD·m^(-3)·d^(-1) and discharging the sludge for6 consecutive times, the hydrogentrophic methanogenswere eliminated, and the hydrogen content reached 36.4%.As the VLR was increased to 44 kgCOD·m^(-3)·d^(-1), thehydrogen production rate and hydrogen yield increased to42.1 L·d^(-1) and 1.40 mol H2·molglucose-consumed^(-1),respectively. The results showed that a stable ethanoltypefermentation that favored hydrogen production inthe reactor was thus established with the sludgeloading rate (SLR) of 2.0-2.5 kgCOD·kgMLVSS-1·d^(-1).It was found that the ethanol increased more than otherliquid fermentation products, and the ethanol/acetic acid(mol/mol) ratio increased from 1.27 to 2.45 when the VLRincreased from 28 to 44 kgCOD·m^(-3)·d^(-1), whereas thehydrogen composition decreased from 40.4% to 36.4%.The results suggested that the anaerobic contact reactorwas a promising bioprocess for fermentative hydrogenproduction.展开更多
文摘The present study deals with the performance evaluation of the UASB reactor under varied organic loading rate(OLR) for the treatment of paper mill wastewater. The sludge granulation process started after 120 days from the start-up period. Sludge granules size was found to be 0 8 mm at OLR of 1 72 kgCOD/(m 3·d), which reached maximum size of about 1 0 to 1 2 mm at OLR of 2 1 kgCOD/(m 3·d). At the end of initial OLR of 1 0 kgCOD/(m 3·d) the VSS concentration was 12 86 gVSS/L, which got increased to 38 05 gVSS/L at the end of an OLR 2 1 kgCOD/(m 3·d). Most of the times VFA recorded were well within the limit of VFA reported in anaerobic fermentation process. Many times the pH observed was between 6 5 and 7 8, which is more favorable for any anaerobic process. It is also found that pH within the reactor increases along with the height of reactor. The total maximum biogas production was found to be 0 40 L/gCOD removals at OLR of 2 1 kgCOD/(m 3·d) and the maximum BOD removal at this stage was observed to be 90%.
基金Supported by Key Project of the Tenth Five-Year Plan of the Ministry of Science and Technology of China (02-2-2)
文摘An expanded granular sludge bed (EGSB) reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with continuous flow by adding proper quantity of nutritional trace elements. The results show that SLR was the key of steady operation of EGSB reactor. The increment of the granular sludge was influenced by volume loading rate (VLR), liquid up-flow velocity and sludge loading rate (SLR). Concentration of granular sludge increased rapidly when liquid up-flow velocity was over 0.94 m · h^-1 with SLR being at 1.0-2.0 d ^-1. With the propriety parameters: liquid up-flow velocity 2.52 m · h^-1, SLR 1.0-2.2 d^-1 and VLR 8.2-13.1 kg · m ^3 · d^-1, 23 days' continuous operation resulted in an increment by over 80% of granular sludge concentration in the EGSB reactor, plus good granular sludge property.
基金This work was financially supported by the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.2010DX06)National High Technology Research and Development Program of China(863 Program)(No.2006AA05Z109)Harbin Science and Technology Bureau(No.2009RFXXS004).
文摘An anaerobic contact reactor (ACR) systemcomprising a continuous flow stirred tank reactor (CSTR)with settler to decouple the hydraulic retention time(HRT) from solids retention time (SRT) was developedfor fermentative hydrogen production from dilutedmolasses by mixed microbial cultures. The ACR wasoperated at various volumetric loading rates (VLRs) of20-44 kgCOD·m^(-3)·d^(-1) with constant HRT of 6 h undermesophilic conditions of 35°C. The SRTwas maintained atabout 46-50 h in the system. At the initial VLR of20 kgCOD·m^(-3)·d^(-1), the hydrogen production rate droppedfrom 22.6 to 1.58 L·d^(-1) as the hydrogen was consumed bythe hydrogentrophic methanogen. After increasing theVLR to 28 kgCOD·m^(-3)·d^(-1) and discharging the sludge for6 consecutive times, the hydrogentrophic methanogenswere eliminated, and the hydrogen content reached 36.4%.As the VLR was increased to 44 kgCOD·m^(-3)·d^(-1), thehydrogen production rate and hydrogen yield increased to42.1 L·d^(-1) and 1.40 mol H2·molglucose-consumed^(-1),respectively. The results showed that a stable ethanoltypefermentation that favored hydrogen production inthe reactor was thus established with the sludgeloading rate (SLR) of 2.0-2.5 kgCOD·kgMLVSS-1·d^(-1).It was found that the ethanol increased more than otherliquid fermentation products, and the ethanol/acetic acid(mol/mol) ratio increased from 1.27 to 2.45 when the VLRincreased from 28 to 44 kgCOD·m^(-3)·d^(-1), whereas thehydrogen composition decreased from 40.4% to 36.4%.The results suggested that the anaerobic contact reactorwas a promising bioprocess for fermentative hydrogenproduction.