Two series of polyurethanes based on mixed polychloromethyl methyl siloxane and poly-tetramethylene oxide in different weight fractions were synthesized. The phase separation ofsamples was studied using DSC and dynami...Two series of polyurethanes based on mixed polychloromethyl methyl siloxane and poly-tetramethylene oxide in different weight fractions were synthesized. The phase separation ofsamples was studied using DSC and dynamic mechanical property analysis. The results showedthat the introduction of chloromethyl group into polysiloxane increased its polarity and henceimproved the miscibilities with polytetramethylene oxide and polyurethane hard segment.Particularly, in the case of N-methyldiethanolamine extended materials, the surface and tensileproperties of these samples can be adjusted by various ratios of two soft segments.展开更多
According to the tensile failure of rock bolt in weakly cemented soft rock, this paper presents a new segmented anchoring style in order to weaken the cumulative effect of anchoring force associated with the large def...According to the tensile failure of rock bolt in weakly cemented soft rock, this paper presents a new segmented anchoring style in order to weaken the cumulative effect of anchoring force associated with the large deformation. Firstly, a segmented mechanical model was established in which free and anchoring section of rock bolt were respectively arranged in different deformation zones. Then, stress and displacement in elastic non-anchoring zone, elastic anchoring zone, elastic sticking zone, softening sticking zone and broken zone were derived respectively based on neural theory and tri-linear strain softening constitutive model of soft rock. Results show that the anchoring effect can be characterized by a supporting parameter b. With its increase, the peak value of tangential stress gradually moves to the roadway wall, and the radial stress significantly increases, which means the decrease of equivalent plastic zone and improvement of confining effect provided by anchorage body. When b increases to 0.72, the equivalent plastic zone disappears, and stresses tend to be the elastic solutions. In addition, the anchoring effect on the displacement of surrounding rock can be quantified by a normalization factor δ.展开更多
Image segmentation remains one of the major challenges in image analysis.And soft image segmentation has been widely used due to its good effect.Fuzzy clustering algorithms are very popular in soft segmentation.A new ...Image segmentation remains one of the major challenges in image analysis.And soft image segmentation has been widely used due to its good effect.Fuzzy clustering algorithms are very popular in soft segmentation.A new soft image segmentation method based on center-free fuzzy clustering is proposed.The center-free fuzzy clustering is the modified version of the classical fuzzy C-means ( FCM ) clustering.Different from traditional fuzzy clustering , the center-free fuzzy clustering does not need to calculate the cluster center , so it can be applied to pairwise relational data.In the proposed method , the mean-shift method is chosen for initial segmentation firstly , then the center-free clustering is used to merge regions and the final segmented images are obtained at last.Experimental results show that the proposed method is better than other image segmentation methods based on traditional clustering.展开更多
A series of three cast polyurethane elastomers were prepared from 2,4-toluene diisocyanate (TDI) and 3,5-dimethyl-thioltoluenediamine (D MTDA) chain extender, with polyethylene adi-pate (PEA), polyoxytetramethylene gl...A series of three cast polyurethane elastomers were prepared from 2,4-toluene diisocyanate (TDI) and 3,5-dimethyl-thioltoluenediamine (D MTDA) chain extender, with polyethylene adi-pate (PEA), polyoxytetramethylene glycol (PTMG) and polycaprolactone (PCL) soft seg-ments. The polyol molecular weights em-ployed was 2000g/mol. The polyurethane elastomers were characterized by an elec-tronmechanical universal testing machine, an Akron abrasion loss tester, a LX-A Shore du-rometer, a rebound resilience equipment and a Dynamic- Mechanical analyzer. In addition, fractured surface of the polyurethane elas-tomers was investigated by a field emission scanning electron microscopy (SEM). The test results showed the PCL based elastomer ex-hibits the excellent tear and stress-strain properties that polyester based elastomers offer, while retaining superior compression set and resilience similar to polyether based elas-tomers. The static and dynamic properties of the PCL based elastomer were more suitable for dynamic applications. The SEM micro-graphs of all polyurethane samples indicated the existing of the microphase separation structure. Particles of the dispersed phase formed by the hard phase and crystalline part of the soft phase grows bigger with the in-creasing crystallinity of the soft segments. The hard domains are irregular shapes and with the sizes of a few micrometers.展开更多
文摘Two series of polyurethanes based on mixed polychloromethyl methyl siloxane and poly-tetramethylene oxide in different weight fractions were synthesized. The phase separation ofsamples was studied using DSC and dynamic mechanical property analysis. The results showedthat the introduction of chloromethyl group into polysiloxane increased its polarity and henceimproved the miscibilities with polytetramethylene oxide and polyurethane hard segment.Particularly, in the case of N-methyldiethanolamine extended materials, the surface and tensileproperties of these samples can be adjusted by various ratios of two soft segments.
基金Financial support for this work was provided by the Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents of China(No.2015RCJJ042)the National Natural Science Foundation of China(Nos.41472280,51274133)+1 种基金the Promotive Research Fund for Excellent Young and Middle-aged Scientisits of Shandong Province of China(No.BS2015SF005)the Opening Project Fund of Shandong Provincial Key Laboratory of Civil Engineering Disaster Prevention and Mitigation(No.CDPM2013KF05)
文摘According to the tensile failure of rock bolt in weakly cemented soft rock, this paper presents a new segmented anchoring style in order to weaken the cumulative effect of anchoring force associated with the large deformation. Firstly, a segmented mechanical model was established in which free and anchoring section of rock bolt were respectively arranged in different deformation zones. Then, stress and displacement in elastic non-anchoring zone, elastic anchoring zone, elastic sticking zone, softening sticking zone and broken zone were derived respectively based on neural theory and tri-linear strain softening constitutive model of soft rock. Results show that the anchoring effect can be characterized by a supporting parameter b. With its increase, the peak value of tangential stress gradually moves to the roadway wall, and the radial stress significantly increases, which means the decrease of equivalent plastic zone and improvement of confining effect provided by anchorage body. When b increases to 0.72, the equivalent plastic zone disappears, and stresses tend to be the elastic solutions. In addition, the anchoring effect on the displacement of surrounding rock can be quantified by a normalization factor δ.
基金Supported by the National Natural Science Foundation of China(61103058,61233011)
文摘Image segmentation remains one of the major challenges in image analysis.And soft image segmentation has been widely used due to its good effect.Fuzzy clustering algorithms are very popular in soft segmentation.A new soft image segmentation method based on center-free fuzzy clustering is proposed.The center-free fuzzy clustering is the modified version of the classical fuzzy C-means ( FCM ) clustering.Different from traditional fuzzy clustering , the center-free fuzzy clustering does not need to calculate the cluster center , so it can be applied to pairwise relational data.In the proposed method , the mean-shift method is chosen for initial segmentation firstly , then the center-free clustering is used to merge regions and the final segmented images are obtained at last.Experimental results show that the proposed method is better than other image segmentation methods based on traditional clustering.
文摘A series of three cast polyurethane elastomers were prepared from 2,4-toluene diisocyanate (TDI) and 3,5-dimethyl-thioltoluenediamine (D MTDA) chain extender, with polyethylene adi-pate (PEA), polyoxytetramethylene glycol (PTMG) and polycaprolactone (PCL) soft seg-ments. The polyol molecular weights em-ployed was 2000g/mol. The polyurethane elastomers were characterized by an elec-tronmechanical universal testing machine, an Akron abrasion loss tester, a LX-A Shore du-rometer, a rebound resilience equipment and a Dynamic- Mechanical analyzer. In addition, fractured surface of the polyurethane elas-tomers was investigated by a field emission scanning electron microscopy (SEM). The test results showed the PCL based elastomer ex-hibits the excellent tear and stress-strain properties that polyester based elastomers offer, while retaining superior compression set and resilience similar to polyether based elas-tomers. The static and dynamic properties of the PCL based elastomer were more suitable for dynamic applications. The SEM micro-graphs of all polyurethane samples indicated the existing of the microphase separation structure. Particles of the dispersed phase formed by the hard phase and crystalline part of the soft phase grows bigger with the in-creasing crystallinity of the soft segments. The hard domains are irregular shapes and with the sizes of a few micrometers.
