Moisture in coal seams changes gas adsorption capacity, induces coal deformation, and affects coal porosity. However, fewer studies have investigated the dynamic process of moisture loss. In this study, a fully couple...Moisture in coal seams changes gas adsorption capacity, induces coal deformation, and affects coal porosity. However, fewer studies have investigated the dynamic process of moisture loss. In this study, a fully coupled multi-physical model for coal deformation, gas flow and moisture loss was implemented. It validated the coal-gas-moisture interactions of the decay of gas adsorption capacity and the coal shrinkage.Subsequently, the proposed model was applied to a simulation of coal seam gas recovery from wet reservoir and solved using the finite method in COMSOL Multiphysics 3.5. Analyses of the component factors and the sensitive parameters of moisture loss on coal porosity and permeability were comprehensively studied at last. The results reveal that moisture loss enhances coal porosity and permeability. The decay of gas adsorption capacity decreases coal permeability while the coal shrinkage promotes it. The decrease of the adsorption decay coefficient and the increase of the initial density of saturated water vapor and water evaporation constant can enhance the permeability of wet coal seams.展开更多
The coal with low moisture during carbonization could not only increase the yield of coke,but also promote the coke quality and reduce the energy consumption.In this paper,the influence of the moisture in the blend co...The coal with low moisture during carbonization could not only increase the yield of coke,but also promote the coke quality and reduce the energy consumption.In this paper,the influence of the moisture in the blend coal(1.8%10.13%)on the product yields and coke quality during coal carbonization were investigated.The results show that the coke yield is increased from 75.90%to 77.16%,and the coke qualities such as coke strength after reaction with CO2(CSR),coke reactivity index(CRI),fragmentation index(M25)and abrasion index(M10))are also improved when the moisture of the blend coal decreases from 10.13%to 1.80%in a bench scale reactor.Due to the secondary reaction,tar become lighter when the moisture is decreased.In order to further prove the above results,the blend coal with 1.8%and 9%10%(common moisture used in coke plant)moisture is carbonized in a coke oven with 6 m height,the results show that CRI are 23.4%and 27.3%,CRS are 67.1%and 62.2%under 1.8%and 9%10%moisture of blend coal.Moreover,the variation of the moisture in blend coal has a limited influence on dust emission at the ascension pipe and the charging car.展开更多
In order to explore the spatial distribution and variation characteristics of soil moisture in coal mining subsidence area in Mu Us sandy Land,and provide theoretical basis for the restoration of the mining area,exper...In order to explore the spatial distribution and variation characteristics of soil moisture in coal mining subsidence area in Mu Us sandy Land,and provide theoretical basis for the restoration of the mining area,experiments based on a linear sampling and classic statistical and geostatistical methods were conducted. Spatial distribution characteristics and variation of soil moisture in the typical 0 to 100 cm dune area in the subsidence area and the non-subsidence area( control) were studied. The results showed that in the typical sand dune location of nonsubsidence area( control),the probability distribution curves of soil moisture changes in all layers along vertical and horizontal directions were all normal distribution,and it was consistent with the temporal and spatial variation characteristics of soil moisture in conventional dunes in Mu Us sandy land. By contrast,two years after the coal mine collapsed,the variations of soil moisture in different layers along vertical and horizontal directions were different,and soil moisture loss was more serious than that of control dune by nearly 10% to 30%,and the standard deviation varied from 0. 54 to 1. 05,increasing by 52. 08% compared with the non-subsidence area( control). The probability of positive and negative deviation greater than 1 was over 50%,and the coefficient of variation varied from 0. 14 to 0. 28,which was 80% higher than that of nonsubsidence area( control). After collapsing,the average level of soil moisture,standard deviation,variance and variation coefficient had greatly changed,and influence of coal mining subsidence on soil moisture was the most in the middle layer( 30-70 cm),and was not obvious in the surface( 0-20 cm) and lower layer( 80-100 cm). In coal mining subsidence area,the dispersion degree of soil moisture in different layers along the vertical and horizontal direction was greatly improved,which increased spatial variation of soil moisture.展开更多
A novel technique for the quick measurement moisture content of coal powder by microwave was studied. The effects of the various moisture contents on the measurement results were also discussed. The experimental resul...A novel technique for the quick measurement moisture content of coal powder by microwave was studied. The effects of the various moisture contents on the measurement results were also discussed. The experimental results show that the standard deviation is less than 0.36% when the moisture content of coal powder is 0.74%-16.90% and the standard deviation is less than 0.16% when the moisture content is 0.31%-1.49%. The experimental results indicate that a process of quick measurement moisture content of coal powder by microwave is practical.展开更多
The interactions between CO_(2) and coals during CO_(2)-ECBM(CO_(2) sequestration in deep coal seams with enhanced coal-bed methane recovery)could change pore morphology and chemistry property of coals,thereby affecti...The interactions between CO_(2) and coals during CO_(2)-ECBM(CO_(2) sequestration in deep coal seams with enhanced coal-bed methane recovery)could change pore morphology and chemistry property of coals,thereby affecting adsorption,diffusion and flow capability of CO_(2) and CH_(4) within coal reservoirs.To simulate CO_(2)-ECBM process more practically,the dynamic interactions of supercritical CO_(2)(sc CO_(2))and moisture-equilibrated coals were performed at temperature of 318.15 K,pressure of 12.00 MPa,and duration of 12.00 h.The impacts of the interactions on physicochemical properties of coals were investigated.Results indicate that sc CO_(2)/H_(2)O exposure shows minor effect on micropores of coals.However,the exposure significantly decreases the mesopore surface area of bituminous coals,while increases that of anthracites.The mesopore volume and the average mesopore diameter of all the coals after sc CO_(2)/H_(2)O exposure decrease.The multi-fractal analysis verifies that the sc CO_(2) exposure can enhance the pore connectivity of various rank coals.Apart from the pore morphology,the exposure of sc CO_(2)/H_(2)O also affects the oxygenic functional groups on coal surface.Particularly,the exposure of sc CO_(2)/H_(2)O reduces the content of CAO and C@O of coals.The content of COOH of low rank coals including Hehua-M2#coal,Zhongqiang-4#coal,Buliangou-9#coal and Tashan-5#coal decreases,while the high rank Laochang^(-1)1#coal and Kaiyuan-9#coal witness a growth in COOH.The content of total oxygenic functional groups of all coals after interaction with sc CO_(2)/H_(2)O decreases;on the contrary,that of CAC/CAH of all coals after sc CO_(2)/H_(2)O exposure increases.In summary,the interaction with sc CO_(2)/H_(2)O significantly changes the pore system and oxygenic functional groups of various rank coals,which needs further attention regarding CO_(2)-ECBM.展开更多
The effects of moisture content on the combustion characteristics and pore structure change of coal slime are studied in this paper.The effect of moisture content on the bed temperature change,combustion efficiency,an...The effects of moisture content on the combustion characteristics and pore structure change of coal slime are studied in this paper.The effect of moisture content on the bed temperature change,combustion efficiency,and NO_(x)and SO_(2)emission were obtained in a bench⁃scale fluidized bed reactor,revealing that the lowest bed temperature decreases with the increase in moisture content,but the effect on the highest bed temperature is not the same.Moreover,with the increase in moisture content,the observed degree of blackening of the flue gas increased,and more CO was produced,which in turn leads to a lower combustion efficiency of the coal slime.However,the presence of moisture plays a positive role in the reduction of NO_(x)and SO_(2).With the increase in moisture content,the amount of NO_(x)and SO_(2)produced tends to decrease.The effect of water on the combustion process of slime is mostly the impact of the severe vaporization process in the early stage to form a large water vapor channel,which is beneficial to the evaporation and loss of water,conducive to the reaction of water and coal combustion products,such as the formation of CO,reduction of NO_(x),SO_(2),etc.The large holes formed by the impact of water vapor decreased with the decrease of moisture content,and the nanoscale pores are mostly caused by the combustion process of volatilization and coke formation after the end of vaporization,and increase with the decrease of moisture content.展开更多
In China,the abrasion index and the free moisture are regarded as the criteria for determining whether the medium-speed pulverizer or the fan pulverizer could be selected.Based on comprehensive studies on foreign meth...In China,the abrasion index and the free moisture are regarded as the criteria for determining whether the medium-speed pulverizer or the fan pulverizer could be selected.Based on comprehensive studies on foreign methods for choosing the pulverizing system for lignite boilers,it is suggested that the particle size of coal,the drying time,the drying temperature and the humidity should be taken into account when measuring the free moisture of lignite,and the total moisture could also be the principle for type selection of pulverizer for lignite boilers.Furthermore,the determination of pulverized-coal moisture has great influence on the running of pulverizing systems.The actual moisture of certain pulverized coals is compared with that calculated with different methods and a feasible method for determining the moisture of the pulverized coal is suggested.展开更多
Mining operations can usually lead to environmental deteriorations. Underground mining activities could cause an extensive decrease in groundwater level and thus a dramatic variation in soil moisture content(SMC). I...Mining operations can usually lead to environmental deteriorations. Underground mining activities could cause an extensive decrease in groundwater level and thus a dramatic variation in soil moisture content(SMC). In this study, the spatial and temporal variations of SMC from 2001 to 2015 at two spatial scales(i.e., the Shendong coal mining area and the Daliuta Coal Mine) were analyzed using an improved thermal inertia model with a long-term series of Landsat TM/OLI(TM=Thematic Mapper and OLI=Operational Land Imager) data. Our results show that at large spatial scale(the Shendong coal mining area), underground mining activities had insignificant negative impacts on SMC and that at small spatial scale(the Daliuta Coal Mine), underground mining activities had significant negative impacts on SMC. Trend analysis of SMC demonstrated that areas with decreasing trend of SMC were mainly distributed in the mined area, indicating that underground mining is a primary cause for the drying trend in the mining region in this arid environment.展开更多
To solve the problem of water seepage of vertical feeding borehole for solid materials,we established the fluid-solid coupling dynamic model of groundwater flowing in rock mass adjacent to the vertical feeding borehol...To solve the problem of water seepage of vertical feeding borehole for solid materials,we established the fluid-solid coupling dynamic model of groundwater flowing in rock mass adjacent to the vertical feeding borehole.Combining with the engineering geological conditions,we built a numeral model to study the influence rule of the aquifer hydraulic pressure and seepage location of feeding borehole on the amount of seepage with fnite element numerical method.The results show that the nonlinear relationship is presented among the amount of seepage,the seepage location and aquifer hydraulic pressure.The higher the aquifer hydraulic pressure is,the closer the distance between seepage location and aquifer is,and the faster the harmful levels of aquifer will grow.In practice,we calculated the allowable seepage of feeding borehole by the optimum moisture content and natural moisture content of backflling materials,and then determined the protection zone of feeding borehole,so the moisture content of backflling materials can be controlled within the scope of optimum moisture content.展开更多
During the processes of methane adsorption and desorption,the internal structure of coal changes,accordingly leading to changes in electrical conductivity.In this paper,using low rank coal seams of the Yan'an Form...During the processes of methane adsorption and desorption,the internal structure of coal changes,accordingly leading to changes in electrical conductivity.In this paper,using low rank coal seams of the Yan'an Formation in the Dafbsi field as the research subject,the relationship between coal resistivity,methane adsorption quantity,and equilibrium pressure is analyzed through proximate analysis,mercury injection tests,low temperature liquid nitrogen adsorption tests,and coal resistivity measurements during methane adsorption and desorption.The results show that during the process of pressure rise and methane adsorption,the conductivity of coal increases,resulting from heat release from methane adsorption,coal matrix swelling and adsorbed water molecules replaced by methane,but the resistivity reduction gradually decreases.The relationship between coal resistivity and methane adsorption quantity and equilibrium pressure can be described by a quadratic function.During the processes of depressurization and desorption,the resistivity of coal rebounds slightly,due to decalescence of methane desorption,coal matrix shrinkage and water-gas displacement,and the relationship coincides with a linear function.Methane adsorption leads to irreversible changes in coal internal structure and enhances the coal conductivity,and resistivity can not be restored to the initial level even after methane desorption.The resistivity and reduction rate of durain are higher than those of vitrain,with relatively greater homogeneous pore throat structure and fewer charged particles in the double electric layer.In addition,moisture can enhance the conductivity of coal and makes it change more complexly during methane adsorption and desorption.展开更多
A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature(CPT) of different ranks of coal.The tests were carried out using a self-designed experimental system f...A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature(CPT) of different ranks of coal.The tests were carried out using a self-designed experimental system for coal self-heating.50 g(±0.01 g) of coal particles ranging from 0.18 mm to 0.38 mm in size were put into a pure copper reaction vessel attached to the center of a temperature programmed enclosure.The temperature program increased the temperature at a rate of 0.8℃/min.Dry air was permitted to flow into the coal reaction vessel at different rates.The surrounding temperature and the coal temperature were monitored by a temperature logger.The results indicate that CPT is affected by coal rank,moisture,sulfur, and the experimental conditions.Higher ranked coals show higher CPT values.A high moisture content causes a delay phenomenon during the self-heating of the coal.Drying at 40℃decreases the effects of moisture.The reactivity of sulfur components in the coal is low under dry and low-temperature conditions. These components form a film that covers the coal surface and slightly inhibits the self-heating of the coal. The flow rate of dry air,and the heating rate of the surroundings,also affect the self-heating of the coal.The most appropriate experimental conditions for coal samples of a given weight and particle size were determined through contrastive analysis.Based on this analysis we propose that CPTs be determined under the same,or nearly the same conditions,for evaluation of the spontaneous combustion of coal.展开更多
基金provided by the National Natural Science Foundation of China(No.51404250)the financial support from Creative Research and Development Group Program of Jiangsu Province(No.2014-27)the Natural Science Foundation of Jiangsu Province(No.BK20140189)
文摘Moisture in coal seams changes gas adsorption capacity, induces coal deformation, and affects coal porosity. However, fewer studies have investigated the dynamic process of moisture loss. In this study, a fully coupled multi-physical model for coal deformation, gas flow and moisture loss was implemented. It validated the coal-gas-moisture interactions of the decay of gas adsorption capacity and the coal shrinkage.Subsequently, the proposed model was applied to a simulation of coal seam gas recovery from wet reservoir and solved using the finite method in COMSOL Multiphysics 3.5. Analyses of the component factors and the sensitive parameters of moisture loss on coal porosity and permeability were comprehensively studied at last. The results reveal that moisture loss enhances coal porosity and permeability. The decay of gas adsorption capacity decreases coal permeability while the coal shrinkage promotes it. The decrease of the adsorption decay coefficient and the increase of the initial density of saturated water vapor and water evaporation constant can enhance the permeability of wet coal seams.
基金Project(51706160)supported by the National Natural Science Foundation of ChinaProject(T201906)supported by the Foundation for Outstanding Youth Innovative Research Groups of Higher Education Institution in Hubei Province,China
文摘The coal with low moisture during carbonization could not only increase the yield of coke,but also promote the coke quality and reduce the energy consumption.In this paper,the influence of the moisture in the blend coal(1.8%10.13%)on the product yields and coke quality during coal carbonization were investigated.The results show that the coke yield is increased from 75.90%to 77.16%,and the coke qualities such as coke strength after reaction with CO2(CSR),coke reactivity index(CRI),fragmentation index(M25)and abrasion index(M10))are also improved when the moisture of the blend coal decreases from 10.13%to 1.80%in a bench scale reactor.Due to the secondary reaction,tar become lighter when the moisture is decreased.In order to further prove the above results,the blend coal with 1.8%and 9%10%(common moisture used in coke plant)moisture is carbonized in a coke oven with 6 m height,the results show that CRI are 23.4%and 27.3%,CRS are 67.1%and 62.2%under 1.8%and 9%10%moisture of blend coal.Moreover,the variation of the moisture in blend coal has a limited influence on dust emission at the ascension pipe and the charging car.
基金Supported by National Natural Science Foundation of China(41661062)Shaanxi Provincial Science and Technology Research and Development Plan Project(2014KJXX-21)Shaanxi Provincial Natural Science Fund Project(2014jm5126)
文摘In order to explore the spatial distribution and variation characteristics of soil moisture in coal mining subsidence area in Mu Us sandy Land,and provide theoretical basis for the restoration of the mining area,experiments based on a linear sampling and classic statistical and geostatistical methods were conducted. Spatial distribution characteristics and variation of soil moisture in the typical 0 to 100 cm dune area in the subsidence area and the non-subsidence area( control) were studied. The results showed that in the typical sand dune location of nonsubsidence area( control),the probability distribution curves of soil moisture changes in all layers along vertical and horizontal directions were all normal distribution,and it was consistent with the temporal and spatial variation characteristics of soil moisture in conventional dunes in Mu Us sandy land. By contrast,two years after the coal mine collapsed,the variations of soil moisture in different layers along vertical and horizontal directions were different,and soil moisture loss was more serious than that of control dune by nearly 10% to 30%,and the standard deviation varied from 0. 54 to 1. 05,increasing by 52. 08% compared with the non-subsidence area( control). The probability of positive and negative deviation greater than 1 was over 50%,and the coefficient of variation varied from 0. 14 to 0. 28,which was 80% higher than that of nonsubsidence area( control). After collapsing,the average level of soil moisture,standard deviation,variance and variation coefficient had greatly changed,and influence of coal mining subsidence on soil moisture was the most in the middle layer( 30-70 cm),and was not obvious in the surface( 0-20 cm) and lower layer( 80-100 cm). In coal mining subsidence area,the dispersion degree of soil moisture in different layers along the vertical and horizontal direction was greatly improved,which increased spatial variation of soil moisture.
文摘A novel technique for the quick measurement moisture content of coal powder by microwave was studied. The effects of the various moisture contents on the measurement results were also discussed. The experimental results show that the standard deviation is less than 0.36% when the moisture content of coal powder is 0.74%-16.90% and the standard deviation is less than 0.16% when the moisture content is 0.31%-1.49%. The experimental results indicate that a process of quick measurement moisture content of coal powder by microwave is practical.
基金sponsored by the National Natural Science Foundation of China(41762013)the Open Foundation of Key Laboratory of Shale Oil and Gas Exploration&Production,SINOPEC(G5800-19-ZS-KFZY001)the National Major Project during the 13th Five-Year Plan Period(2016ZX05061)。
文摘The interactions between CO_(2) and coals during CO_(2)-ECBM(CO_(2) sequestration in deep coal seams with enhanced coal-bed methane recovery)could change pore morphology and chemistry property of coals,thereby affecting adsorption,diffusion and flow capability of CO_(2) and CH_(4) within coal reservoirs.To simulate CO_(2)-ECBM process more practically,the dynamic interactions of supercritical CO_(2)(sc CO_(2))and moisture-equilibrated coals were performed at temperature of 318.15 K,pressure of 12.00 MPa,and duration of 12.00 h.The impacts of the interactions on physicochemical properties of coals were investigated.Results indicate that sc CO_(2)/H_(2)O exposure shows minor effect on micropores of coals.However,the exposure significantly decreases the mesopore surface area of bituminous coals,while increases that of anthracites.The mesopore volume and the average mesopore diameter of all the coals after sc CO_(2)/H_(2)O exposure decrease.The multi-fractal analysis verifies that the sc CO_(2) exposure can enhance the pore connectivity of various rank coals.Apart from the pore morphology,the exposure of sc CO_(2)/H_(2)O also affects the oxygenic functional groups on coal surface.Particularly,the exposure of sc CO_(2)/H_(2)O reduces the content of CAO and C@O of coals.The content of COOH of low rank coals including Hehua-M2#coal,Zhongqiang-4#coal,Buliangou-9#coal and Tashan-5#coal decreases,while the high rank Laochang^(-1)1#coal and Kaiyuan-9#coal witness a growth in COOH.The content of total oxygenic functional groups of all coals after interaction with sc CO_(2)/H_(2)O decreases;on the contrary,that of CAC/CAH of all coals after sc CO_(2)/H_(2)O exposure increases.In summary,the interaction with sc CO_(2)/H_(2)O significantly changes the pore system and oxygenic functional groups of various rank coals,which needs further attention regarding CO_(2)-ECBM.
基金Sponsored by the Key Technologies Research and Development Program of China(Grant No.2016YFB0600203).
文摘The effects of moisture content on the combustion characteristics and pore structure change of coal slime are studied in this paper.The effect of moisture content on the bed temperature change,combustion efficiency,and NO_(x)and SO_(2)emission were obtained in a bench⁃scale fluidized bed reactor,revealing that the lowest bed temperature decreases with the increase in moisture content,but the effect on the highest bed temperature is not the same.Moreover,with the increase in moisture content,the observed degree of blackening of the flue gas increased,and more CO was produced,which in turn leads to a lower combustion efficiency of the coal slime.However,the presence of moisture plays a positive role in the reduction of NO_(x)and SO_(2).With the increase in moisture content,the amount of NO_(x)and SO_(2)produced tends to decrease.The effect of water on the combustion process of slime is mostly the impact of the severe vaporization process in the early stage to form a large water vapor channel,which is beneficial to the evaporation and loss of water,conducive to the reaction of water and coal combustion products,such as the formation of CO,reduction of NO_(x),SO_(2),etc.The large holes formed by the impact of water vapor decreased with the decrease of moisture content,and the nanoscale pores are mostly caused by the combustion process of volatilization and coke formation after the end of vaporization,and increase with the decrease of moisture content.
文摘In China,the abrasion index and the free moisture are regarded as the criteria for determining whether the medium-speed pulverizer or the fan pulverizer could be selected.Based on comprehensive studies on foreign methods for choosing the pulverizing system for lignite boilers,it is suggested that the particle size of coal,the drying time,the drying temperature and the humidity should be taken into account when measuring the free moisture of lignite,and the total moisture could also be the principle for type selection of pulverizer for lignite boilers.Furthermore,the determination of pulverized-coal moisture has great influence on the running of pulverizing systems.The actual moisture of certain pulverized coals is compared with that calculated with different methods and a feasible method for determining the moisture of the pulverized coal is suggested.
基金supported by the National Natural Science Foundation of China (U1361214)the National Key Research and Development Program of China (2016YFC0501107)
文摘Mining operations can usually lead to environmental deteriorations. Underground mining activities could cause an extensive decrease in groundwater level and thus a dramatic variation in soil moisture content(SMC). In this study, the spatial and temporal variations of SMC from 2001 to 2015 at two spatial scales(i.e., the Shendong coal mining area and the Daliuta Coal Mine) were analyzed using an improved thermal inertia model with a long-term series of Landsat TM/OLI(TM=Thematic Mapper and OLI=Operational Land Imager) data. Our results show that at large spatial scale(the Shendong coal mining area), underground mining activities had insignificant negative impacts on SMC and that at small spatial scale(the Daliuta Coal Mine), underground mining activities had significant negative impacts on SMC. Trend analysis of SMC demonstrated that areas with decreasing trend of SMC were mainly distributed in the mined area, indicating that underground mining is a primary cause for the drying trend in the mining region in this arid environment.
基金funded by the State Key Development Program for Basic Research of China(No.2013CB227900)the National High Technology Joint Research Program of China(No.2012BAB13B00)
文摘To solve the problem of water seepage of vertical feeding borehole for solid materials,we established the fluid-solid coupling dynamic model of groundwater flowing in rock mass adjacent to the vertical feeding borehole.Combining with the engineering geological conditions,we built a numeral model to study the influence rule of the aquifer hydraulic pressure and seepage location of feeding borehole on the amount of seepage with fnite element numerical method.The results show that the nonlinear relationship is presented among the amount of seepage,the seepage location and aquifer hydraulic pressure.The higher the aquifer hydraulic pressure is,the closer the distance between seepage location and aquifer is,and the faster the harmful levels of aquifer will grow.In practice,we calculated the allowable seepage of feeding borehole by the optimum moisture content and natural moisture content of backflling materials,and then determined the protection zone of feeding borehole,so the moisture content of backflling materials can be controlled within the scope of optimum moisture content.
基金financially supported by the Independent Projects of the Key Lab. of Coal Resources Exploration and Comprehensive Utilization, Ministry of Land and Resources of China (grants No. KF2019-2, ZKF2018-1, KF2018-4, ZP2018-2)the Major National Science and Technology Special Projects (grant No. 2016ZX05042004)+3 种基金the Projects Funded by China Postdoctoral Science Foundation (grant No. 2019M653873XB)the Natural Science Foundation Research Projects of Shaanxi Province (grant No. 2019JQ-245)the Doctoral Research Starting Foundation of Xi’an University of Science and Technology (grant No. 2016QDJ041)the Research Projects of the Geological Research Institute for Coal Green Mining of Xi’an University of Science and Technology (grant No. MTy2019-04)
文摘During the processes of methane adsorption and desorption,the internal structure of coal changes,accordingly leading to changes in electrical conductivity.In this paper,using low rank coal seams of the Yan'an Formation in the Dafbsi field as the research subject,the relationship between coal resistivity,methane adsorption quantity,and equilibrium pressure is analyzed through proximate analysis,mercury injection tests,low temperature liquid nitrogen adsorption tests,and coal resistivity measurements during methane adsorption and desorption.The results show that during the process of pressure rise and methane adsorption,the conductivity of coal increases,resulting from heat release from methane adsorption,coal matrix swelling and adsorbed water molecules replaced by methane,but the resistivity reduction gradually decreases.The relationship between coal resistivity and methane adsorption quantity and equilibrium pressure can be described by a quadratic function.During the processes of depressurization and desorption,the resistivity of coal rebounds slightly,due to decalescence of methane desorption,coal matrix shrinkage and water-gas displacement,and the relationship coincides with a linear function.Methane adsorption leads to irreversible changes in coal internal structure and enhances the coal conductivity,and resistivity can not be restored to the initial level even after methane desorption.The resistivity and reduction rate of durain are higher than those of vitrain,with relatively greater homogeneous pore throat structure and fewer charged particles in the double electric layer.In addition,moisture can enhance the conductivity of coal and makes it change more complexly during methane adsorption and desorption.
基金financial supports provided by the National Natural Science Foundation of China(Nos. 50927403 and 50674088)the Natural Science Foundation of Jiangsu Province(No.BK2009004)the Research Foundation of State Key Laboratory of Coal Resources and Safe Mining(No. SKLCRSM08X06)
文摘A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature(CPT) of different ranks of coal.The tests were carried out using a self-designed experimental system for coal self-heating.50 g(±0.01 g) of coal particles ranging from 0.18 mm to 0.38 mm in size were put into a pure copper reaction vessel attached to the center of a temperature programmed enclosure.The temperature program increased the temperature at a rate of 0.8℃/min.Dry air was permitted to flow into the coal reaction vessel at different rates.The surrounding temperature and the coal temperature were monitored by a temperature logger.The results indicate that CPT is affected by coal rank,moisture,sulfur, and the experimental conditions.Higher ranked coals show higher CPT values.A high moisture content causes a delay phenomenon during the self-heating of the coal.Drying at 40℃decreases the effects of moisture.The reactivity of sulfur components in the coal is low under dry and low-temperature conditions. These components form a film that covers the coal surface and slightly inhibits the self-heating of the coal. The flow rate of dry air,and the heating rate of the surroundings,also affect the self-heating of the coal.The most appropriate experimental conditions for coal samples of a given weight and particle size were determined through contrastive analysis.Based on this analysis we propose that CPTs be determined under the same,or nearly the same conditions,for evaluation of the spontaneous combustion of coal.