Effect of Submerged Arc Welding Flux Component on Softening Temperature

Based on simplex algorithm of optimal design, the multicomponent mixture regression model was used to investigate physical properties of submerged arc welding flux. The effect of complex interaction of seven components in agglomerated flux on softening temperature was analyzed. The results indicate that the interaction of MgO-TiO2-CaCOa-AI20a increases the softening temperature of flux, but the additions of CaF2 and ZrO2 can decrease the softening temperature.

Influence of RE on Ageing Precipitate Characteristics and Softening Resistance of Copper Alloys Contact Wire

The effect of RE （such as Ce, Y and mixed Ce ＋ Y, etc） on ageing precipitate, characteristics and softening resistance of Cu-Cr-Zr alloys contact wire used in electrical railway were investigated in this paper. The results show that the tested Cu-Cr-Zr alloy with trace RE addition could attain higher microhardness and lower electrical conductivity to some extent after being soluted at 950 ℃ for 1 h and aged at 480 ℃. The precipitation process of secondary phase could be accelerated by cold working before ageing treatment which resulted in ageing hardening. Aged at 480 ℃ after 60% cold working, the values of electrical conductivity and microhardness improved significantly compared with that without deformation. The mixed RE （Ce ＋ Y） improved the softening resistance substantially in these trace RE additions, which could increase the soften temperature by 45 ℃.

Influence of Cerium and Yttrium on Cu-Cr-Zr Alloys

Testing results shows that alloying with Ce and Y improves the hardness and softens temperature of cold worked Cu-Cr-Zr alloys obviously, while the conductivity was fluctuant with the variation of RE content. Observation and analysis indicate that micro-dosage RE elements helps to refine microstructure and morphology of Cu-Cr-Zr-RE alloys, suppress microstructure coarsening and improves homogeneous level of Cu-Cr-Zr alloys. Alloying with 0.01% Ce causes about 1% IACS increment of conductivity, and reduces about 2% ~ 3.5% IACS conductivity after alloying with 0.03% ~ 0.04% RE (Ce or Ce + Y) for Cu-Cr-Zr alloys. The microstructure of as-cast Cu-Cr-Zr alloy is refined after alloying with 0.01% Ce while the plasticity is improved slightly. Alloying with 0.01% ~ 0.04% RE improves the softening temperature of deformed Cu-Cr-Zr alloys about 20 ~ 40 K; hardness is also improved about 20 ~ 35 HV . Test data indicate that alloying with Ce + Y raises softening temperature and hardness of Cu-Cr-Zr alloys more notably than alloying with pure Ce.

Structure of Bi_2O_3-ZnO-B_2O_3 system low-melting sealing glass

Bi2O3-ZnO-B2O3 system glass is a kind of lead-free low melting sealing glasses. The structure of Bi2O3-ZnO-B2O3 system low-melting sealing glass was investigated by DSC, FT-IR, XRD and SEM. The results show that with the increase of B2O3 content, the transition temperature Tg and softening temperature Tf of Bi2O3-ZnO-B2O3 system low-melting sealing glasses increase, which leads to the liquid phase precipitation temperature increasing and promotes the structure stability in the glass. With increasing the heat treatment temperature, a large number of liquid phases appear in samples and the sinter efficiency of the samples increases. The FT-IR spectra of the glasses show the presence of some bands that are assigned to vibrations of Bi--O bond from [BO3] pyramidal and [BiO6] octahedral units and B--O from [BO3] and [BO4] units. With the decrease of B203 content, the crystallization tendency of the glass increases. In glass samples Bl and B〉 crystallization starts at 460 ℃ and 540 ℃, respectively. Both of them precipitate Bi24B2O39 phases.

Effects of various fillers on sintering, microstructures and properties of Ca-Ba-Al-B-Si-O glass/ceramic composites

Low-temperature sintering and properties of LTCC （low temperature co-fired ceramics） materials based on CaO-BaO-Al2O3-B2O3-SiO2 glass and various fillers such as Al2O3, silica glass, christobalite, AlN, ZrO2, MgO-SiO2, TiO2 were investigated. The results show that densification, crystallization, microstructures and dielectric properties of the composites are found to strongly depend on the type of filler. The densification process of glass/ceramic composites with various fillers is mainly from 600 ℃ to 925 ℃, and the initial compacting temperature of samples is 600 ℃. The initial rapid densification of samples starts at its glass softening temperature. LTCC compositions containing Al2O3, silica glass, AlN and MgO-SiO2 fillers start to have the crystallization peaks at 890, 903, 869 and 844 ℃, respectively. The crystallization peaks are believed as correlated to the crystallization of CaAl2SiO8, β-SiO2, Ca2Al2SiO7 and β-SiO2. The composite ceramic with Al2O3, silica glass and TiO2 ceramic have a better dense structure and better smooth fracture surface. Sample for Al2O3 has the lowest dielectric loss tanδ value of 0.00091, whereas the sample for MgO.SiO, has the highest dielectric loss tanδ value of 0.02576. The sample for TiO2 has the highest dielectric constant value of 14.46, whereas the sample for AIN has the lowest dielectric constant value of 4.61.