In recent years perovskite solar cells have attracted an increasing scientific and technological interest in the scientific community. It is important to know that the temperature is one of the factors which have a st...In recent years perovskite solar cells have attracted an increasing scientific and technological interest in the scientific community. It is important to know that the temperature is one of the factors which have a strong effect on the efficiency of perovskite solar cell. This study communicates a temperature analysis on the pho- tovoltaic parameters of CH3NH3Pbl3-based perovskite solar cell in a broad interval from 80 to 360 K. Strong temperature-dependent photovoltaic effects have been observed in the type of solar cell, which could be mainly attributed to CH3NH3PbI3, showing a ferroelectric-paraelectric phase transition at low temperature （T 〈 160 K）. An increase in temperature over the room temperature decreased the perovskite solar cell performance and reduced its efficiency from 16Z to 9%. The investigation with electronic impedance spectroscopy reveals that at low temperature （T 〈 120 K） the charge transport layer limits the device performance, while at high temperature （T 〉 200 K）, the interfacial charge recombination becomes the dominant factor.展开更多
The temperature of a solar cell subjected to the incident global solar radiation as a function of the local day time is determined. A heat balance equation is solved considering the heat losses due to convection and t...The temperature of a solar cell subjected to the incident global solar radiation as a function of the local day time is determined. A heat balance equation is solved considering the heat losses due to convection and thermal radiation. The cell efficiency is estimated as a measure of its performance. The results reveal that the temperature within the cell attains significant values. Nevertheless, the temperature dependence of its efficiency along the day time is not pronouncing. It slightly decreases with temperature.展开更多
基金supported by 973 Program of China (2014CB643506 and 2013CB922104)the NSFC (21173091 and 61205034)
文摘In recent years perovskite solar cells have attracted an increasing scientific and technological interest in the scientific community. It is important to know that the temperature is one of the factors which have a strong effect on the efficiency of perovskite solar cell. This study communicates a temperature analysis on the pho- tovoltaic parameters of CH3NH3Pbl3-based perovskite solar cell in a broad interval from 80 to 360 K. Strong temperature-dependent photovoltaic effects have been observed in the type of solar cell, which could be mainly attributed to CH3NH3PbI3, showing a ferroelectric-paraelectric phase transition at low temperature （T 〈 160 K）. An increase in temperature over the room temperature decreased the perovskite solar cell performance and reduced its efficiency from 16Z to 9%. The investigation with electronic impedance spectroscopy reveals that at low temperature （T 〈 120 K） the charge transport layer limits the device performance, while at high temperature （T 〉 200 K）, the interfacial charge recombination becomes the dominant factor.
文摘The temperature of a solar cell subjected to the incident global solar radiation as a function of the local day time is determined. A heat balance equation is solved considering the heat losses due to convection and thermal radiation. The cell efficiency is estimated as a measure of its performance. The results reveal that the temperature within the cell attains significant values. Nevertheless, the temperature dependence of its efficiency along the day time is not pronouncing. It slightly decreases with temperature.
