Ionic liquid (IL), [BMIM]Cl-water was applied in cellulose pretreatment process and the pretreated cellulose was used in subsequent polyethylene glycol liquefaction process as a new application method. Cellulose recov...Ionic liquid (IL), [BMIM]Cl-water was applied in cellulose pretreatment process and the pretreated cellulose was used in subsequent polyethylene glycol liquefaction process as a new application method. Cellulose recovery rate and molecular weight value of pretreated cellulose were investigated to understand the influence of IL-water mixtures by adding the different amount of catalysis on cellulose crystalline structure. Gel permeation chromatograph, X-ray diffraction, Fourier transform infrared spectrometer and thermo gravimetric/differential thermal analysis were used to clarify the changes of pretreated cellulose. The results showed that the pretreated cellulose was improved in crystalline structure, molecular weight distribution and thermal stability. The liquefied residues from untreated cellulose and pretreated cellulose were considered as a significant index to determine the effect of IL-water mixture on cellulose. It suggested that the lower molecular weight of cellulose was obtained, the crystalline structure was disrupted and less order was formed. The liquefied residues result suggested that the lower residues at the latter stages of the reaction from the pretreated cellulose were observed.展开更多
The viscosities for the selected CaO-MgO-SiO2 and CaO-MgO Al2 O3-SiO2 slags were measured by rota- ting cylinder method in a wide temperature range from 1608 K to 1 823 K. The effects of temperature, slag basicity and...The viscosities for the selected CaO-MgO-SiO2 and CaO-MgO Al2 O3-SiO2 slags were measured by rota- ting cylinder method in a wide temperature range from 1608 K to 1 823 K. The effects of temperature, slag basicity and Al2 O3 content were studied. The results indicated that the viscosity decreased with increasing the slag basicity at the same temperature. And the viscosities of the slag initially increased linearly with increasing Al2 O3 content in the slags and then decreased as the Al2 O3 content in the slags continued to increase. Al2 O3 addition has a more signifi- cant effect on the viscosity than slag basicity in the selected slags. Based on the experimental data and the fraction of solid phases calculated by the thermodynamic software, the effect of solid phases on slag viscosity was evaluated. The results indicated that the relationship between the relative viscosity and the volume fraction of solid phases esti- mated from the slag composition can be reasonable by allowing the inverse maximum fraction of solid particles to vary.展开更多
Flow characteristics of both oil and water in a horizontal pipe are the basic information for the design of crude oil transportation and production profile logging.The flow characteristics are more complicated when oi...Flow characteristics of both oil and water in a horizontal pipe are the basic information for the design of crude oil transportation and production profile logging.The flow characteristics are more complicated when oil or water carries sediment particles.In order to simulate the distribution of flow characteristic parameters of water-or oil-sediment mixture in a horizontal pipe,the governing equations and the boundary condition for the mixture phase of water-or oil-sediment were established by the mixture algebraic slip model (MASM) based on the Eulerian description method,and the numerical solution was obtained by the finite difference method and successive over relaxation (SOR).The simulation results indicated that the mainstream velocity moved downwards with increasing volume fraction of the particle phase and decreased with reducing pressure drop.The distributions of the volume fraction of the particle phase in the circular cross section were related to the mainstream velocity,and the volume fraction values increased downwards and sidewards with reducing mainstream velocity.Moreover the mainstream velocity of the oil-sediment mixture phase was larger than that of the water-sediment mixture phase.The mixture algebraic slip model could well simulate the flow characteristic parameters of the mixture phase with higher computing efficiency.展开更多
文摘Ionic liquid (IL), [BMIM]Cl-water was applied in cellulose pretreatment process and the pretreated cellulose was used in subsequent polyethylene glycol liquefaction process as a new application method. Cellulose recovery rate and molecular weight value of pretreated cellulose were investigated to understand the influence of IL-water mixtures by adding the different amount of catalysis on cellulose crystalline structure. Gel permeation chromatograph, X-ray diffraction, Fourier transform infrared spectrometer and thermo gravimetric/differential thermal analysis were used to clarify the changes of pretreated cellulose. The results showed that the pretreated cellulose was improved in crystalline structure, molecular weight distribution and thermal stability. The liquefied residues from untreated cellulose and pretreated cellulose were considered as a significant index to determine the effect of IL-water mixture on cellulose. It suggested that the lower molecular weight of cellulose was obtained, the crystalline structure was disrupted and less order was formed. The liquefied residues result suggested that the lower residues at the latter stages of the reaction from the pretreated cellulose were observed.
基金Item Sponsored by National Natural Science Foundation of China(50874072)Natural Science Foundation of Jiangsu Province of China(BK20130308)China Postdoctoral Science Foundation(2014M561710)
文摘The viscosities for the selected CaO-MgO-SiO2 and CaO-MgO Al2 O3-SiO2 slags were measured by rota- ting cylinder method in a wide temperature range from 1608 K to 1 823 K. The effects of temperature, slag basicity and Al2 O3 content were studied. The results indicated that the viscosity decreased with increasing the slag basicity at the same temperature. And the viscosities of the slag initially increased linearly with increasing Al2 O3 content in the slags and then decreased as the Al2 O3 content in the slags continued to increase. Al2 O3 addition has a more signifi- cant effect on the viscosity than slag basicity in the selected slags. Based on the experimental data and the fraction of solid phases calculated by the thermodynamic software, the effect of solid phases on slag viscosity was evaluated. The results indicated that the relationship between the relative viscosity and the volume fraction of solid phases esti- mated from the slag composition can be reasonable by allowing the inverse maximum fraction of solid particles to vary.
文摘Flow characteristics of both oil and water in a horizontal pipe are the basic information for the design of crude oil transportation and production profile logging.The flow characteristics are more complicated when oil or water carries sediment particles.In order to simulate the distribution of flow characteristic parameters of water-or oil-sediment mixture in a horizontal pipe,the governing equations and the boundary condition for the mixture phase of water-or oil-sediment were established by the mixture algebraic slip model (MASM) based on the Eulerian description method,and the numerical solution was obtained by the finite difference method and successive over relaxation (SOR).The simulation results indicated that the mainstream velocity moved downwards with increasing volume fraction of the particle phase and decreased with reducing pressure drop.The distributions of the volume fraction of the particle phase in the circular cross section were related to the mainstream velocity,and the volume fraction values increased downwards and sidewards with reducing mainstream velocity.Moreover the mainstream velocity of the oil-sediment mixture phase was larger than that of the water-sediment mixture phase.The mixture algebraic slip model could well simulate the flow characteristic parameters of the mixture phase with higher computing efficiency.
