NEW SOLID BASE DERIVED FROM AIPO4-5 SUPPORTED KF

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Mesoporogen-free synthesis of hierarchical sodalite as a solid base catalyst from sub-molten salt-activated aluminosilicate

A rapid and environmentally friendly approach to synthesize hierarchical sodalite from natural aluminosilicate mineral without the involvement of any mesoporogen or post-synthesis treatment was developed.This strategy involves three important steps:the first is the depolymerization of an aluminosilicate mineral into highly reactive silicon and aluminum species with ideal meso-scale structures through activation of a sub-molten salt.The second step is the hydrolysis and condensation of the activated aluminosilicate mineral into zeolitic precursors that also have a meso-scale structure.The third is the rapid zeolitization of the zeolitic precursors through the reversed crystal growth route at room temperature and ambient pressure to form hierarchical sodalite.The physicochemical properties of the as-synthesized sodalite were systematically characterized,and the formation mechanism of the hierarchical pore structure was discussed.When used as a solid base catalyst for Knoevenagel condensation,the as-synthesized sodalite and its potassium ion-exchanged product with hierarchical micro-meso-macroporous structure both exhibited high catalytic activity and product selectivity.

Development of solid base catalyst X/Y/MgO/-Al_(2)O_(3) for optimization of preparation of biodiesel from Jatropha curcas L.seed oil

The preparation and regeneration conditions of the identified catalyst X/Y/MgO/?-Al2O3 with high catalytic activity were studied and optimized. The biodiesel was prepared by transesterification of Jatropha curcas seed oil produced in Guizhou with methanol at its reflux temoerature in the presence of X/Y/MgO/?-Al2O3 . The pilot plant tests were carried out in a 100 L reaction vessel. Both average yield and fatty acid methyl esters (FAME) content reached more than 96.50% under the optimum reaction conditions of the pilot plant tests designed with an oil/methanol molar ratio of 1 : 10, catalyst concentration of 1.00%, and reaction time of 3 h at reflux temperature. In addition, analysis shows that the quality of biodiesel meets the standard EN 14214.

Primary amine-functionalized mesoporous phenolic resin as an effective and stable solid base catalyst for Knoevenagel reactions in water

A primary amine functionalized ordered mesoporous phenolic resin(NH2-MPR)was obtained by an evaporationinduced self-assembly method.The as-prepared NH2-MPR material possessed large surface area and ordered twodimensional hexagonal mesoporous structure.Also,the amine groups were well-dispersed in the mesoporous channels.It can act as an efficient solid base to promote Knoevenagel condensation of various aldehydes with ethyl cyanoacetate in water with high conversion and selectivity.This excellent performance was attributed ordered mesopores and hydrophobic pore surface,which resulted in the decreased the interference of water solvent and the increased active sites accessibility.Noted that it was comparable with homogenous base catalysts in the water-medium Knoevenagel condensation reaction,and it can be reused for at least five times without significant reduction in the catalytic efficiency.

Synthesis of dimethyl adipate from cyclopentanone and dimethyl carbonate over solid base catalysts

A facile route for the synthesis of dimethyl adipate (DAP) from cyclopentanone and dimethyl carbonate (DMC) in the presence of solid base catalysts has been developed.It was found that the intermediate carbomethoxycyclopentanone (CMCP) was produced from cyclopentanone with DMC in the first step,and then CMCP was further converted to DAP by reacting with a methoxide group.The role of the basic catalysts can be mainly ascribed to the activation of cyclopentanone via the abstraction of a proton in the α-position by base sites,and solid bases with moderate strength,such as MgO,favor the formation of DAP.

Transesterification of glyceryl tributyrate with methanol using strontium borate as the solid base catalyst

Four kinds of strontium borates were prepared and characterized by XRD,SEM,EDS,TG-DTA and Hammett titration method,and their catalytic activities were examined in the transesterification of glyceryl tributyrate with methanol for the first time.The separate effects of the molar ratio of methanol to oil,the reaction time,and reusability were investigated.In addition,the catalytic activities of Sr(OH)2and SrCO3were also examined for the comparison.The results showed that the basicity and catalytic activity of these catalysts were decreased as the following order:Sr(OH)2>SrB2O4·4H2O>SrB6O10·5H2O>SrB2O4>SrB6O10>SrCO3,and the reusability decreases as the following order:anhydrous strontium borates(SrB2O4,SrB6O10)>hydrated strontium borates(SrB2O4·4H2O,SrB6O10·5H2O)>Sr(OH)2.The results indicate that the SrB2O4·4H2O with regular morphology,which was obtained at low temperature by a simple preparation method,might be as one kind of good potential alkaline earth salts catalyst for transesterification.Moreover,the possible reaction mechanism is proposed and analyzed.

Wet carbon-based solid acid/NaNO_3 as a mild and efficient reagent for nitration of aromatic compound under solvent free conditions

Nitro aromatic compound can be obtained in high yields via nitration of aromatic compound with wet carbon-based solid acid and NaNO3 under solvent free oxidation at room temperature.

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

有基于碳的稳固的酸催化剂的同时的 transesterification 和酯化作用的动力学被学习。二稳固的酸催化剂被使碳化的蔬菜油沥青和石油沥青的 sulfonation 准备。这些催化剂根据元素的分析，酸味地点集中， Brunauer-Emmett-Teller (赌注) 表面区域和毛孔尺寸被描绘。有二催化剂的运动参数被决定，并且反应系统能被描述为假同类的催化反应。所有前面、反向的反应跟随第二顺序动力学。从运动方程的计算集中价值在对试验性的价值的好同意。

Acetalization of carbonyl compounds with 2,2,4-trimethyl-1,3-pentanedio catalyzed by novel carbon based solid acid catalyst

2 的合成，通过有 2 的 isobutyraldehyde 的 acetalization 的 4-diisopropyl-5,5-dimethyl-1,3-dioxane， 2，新奇的碳催化的 4-trimethyl-1,3-pentanediol (TMPD ) 基于酸首先被执行。高变换(≥98%) 和特定的选择用新奇的碳被获得基于酸，在它以后的保留的高活动它被再使用 5 次。而且，催化剂能被用来与优异产量催化不同的醛和酉同类的 acetalization 和 ketalization。几个产品的收益是超过 90% 。新奇异构的催化剂有高活动，在过程上面的惊人地简单的工作，非污染，和可重用性的明显的优点，它将极大地贡献绿过程的成功。

Effect of solid-solution temperature on the microstructure of Fe-Ni based high strength low thermal expansion (HSLTE) alloy

The influence of solid-solution temperature on the dissolution of carbide precipitates, the average grain size and the micro- hardness of the austenite matrix in an Fe-Ni based high strength low thermal expansion (HSLTE) alloy was investigated to obtain the proper temperature range of the solid-solution process. The XRD analysis, microstructure observations, and the theoretical calculations showed that the Mo-rich M2C-type precipitates in the Fe-Ni based HSLTE alloy dissolve completely at about 1100°C. The average grain size of the studied alloys increases from 14 to 46 μm in the temperature range of 1050 to 1200°C. The microhardness of the matrix decreases first for the sake of solid-solution treatment, but then increases later with increasing solution temperature because of the so- lution strengthening effect.

Wet carbon-based solid acid/potassium permanganate as an efficient heterogeneous reagents for oxidation of alcohols under mild conditions

湿基于碳的稳固的酸和钾高锰酸盐在异构的混合物为白酒的氧化被用作新试剂到他们的相应的醛和酉同类。实验以温和状况中等被做，在合适的时间的高收益被获得。

The Development of Gear Pump CAD/CAPP Based on Solid Works

Nowadays, many kinds of software, which have succes sf ully created the integration of CAD, CAPP and CAM, find their disadvantages in p ractical manufacturing. As a result, it is welcomed to develop small CAD/CAPP sy stems on a proper CAD platform, which aim at requirements of factories. Based on the one of the most popular three-dimensional design software SolidWorks, we successfully developed a set of gear pump CAD /CAPP software for Huaiyin Gene ral Factory of Mechanics. 1 The architecture and function of the software According to the need of the enterprises, the general structure of the software contain two subsystems, which are detailed as follows: · The gear pump CAD subsystem contains four main modules, including the optiona l design module of gear pump, module of part design, the module of entity modeli ng and the module of drawing which creates 2 D drawings of parts and assembly c orresponding 3 D modals. · The gear pump CAPP subsystem, which is a combination of creative mode and der ivate mode, also includes four modules, they are the module of access to feature s, the module of planning process route, the module of designing process sheets and the module of generating process documents. 2 The developing environment of the system Basing on Windows 98 and SolidWorks2001 platform, this system creates all functi ons by using Visual C++ 6.0 as developing tools. 3 The keys to the CAD/CAPP integration 3.1 The establishment of product information modal The information of parts is the basis of process planning. In this system, we us e feature modeling to describe the information of parts and assembly of gear pum p, and set up a fundamental basis for the whole system. The information module o f gear pump includes the information of both the assembly and the parts; the par t-describing module uses four-layer structure that is subassembly layer, part layer, feature layer and geometric layer. 3.2 The operation of the information on feature modeling After establishment of information mode of gear pump, the next key problem is ho w to transmit information of product to CAPP subsystem. In order to integrate pe rfectly, connecting CAD with CAPP directly can be a good method. In this system, all information of parts is store in the part drawing files, and the CAPP syste m can load these files to get information. The gear pumps, which are produced by Huaiyin General Factory of Mechanics, are usually belong to several similar typ es, and this means that most products possess large number of similar feature. T herefore, we can easily establish a specific feature for gear pump CAD/CAPP syst em. All parts are created by selecting these features and/or adding few special features. In the module of access to feature of CAPP subsystem, the main task is to find the features and the information will be easily got. 4 Conclusion This system successfully creates gear pump CAD/CAPP integration based on SolidWo rks. 3D CAD software provide more convenient platform for integration and will i nevitably become the mainstream of product design. By developing this system, we clearly realize the promising future of SolidWorks.

Biochar-based Solid Acids as Catalysts for Carbohydrate Hydrolysis: A Critical Review

Recently, increasing interest has been focused on the hydrolysis of carbohydrates to monosaccharides, among which, glucose and xylose as typical platform sugars can be used to produce chemicals and biofuels. As heterogeneous catalysts, solid acids have gained extensive attention for biomass biorefinery and could replace the conventional process owing to their excellent properties, including acceptable acidity and easy separation. In particular, biochar-based solid acids derived from biomass are promising for biomass conversion owing to the low-cost of feedstocks and the simple preparation procedure. Herein, we attempt to provide a critical overview of biochar-based solid acids for hydrolysis of carbohydrates into glucose and xylose. The preparation methods and properties of biochar-based catalysts as well as the influence of their properties on catalytic performance were discussed in detail. We also highlight the major challenges facing the use of biochar-based solid acids for carbohydrate hydrolysis.

Solid Solution Characteristics of Pb(B_(1/3)Nb_(2/3))O_(3)-based Composite Ceramics

The solid solution characteristics of Pb(B 1/3 Nb 2/3 )O 3 -based(B=Zn2+,Mg2+,Ni2+)composite ceramics prepared by two-phase mixed-sintering method were developed based on dielectric measurements. Results show that there are double dielectric peaks for PZN-based composite ceramic,implying two phases coexist.However single dielectric peak was presented in PMN-and PNN-based composite ceramics, respectively.It is indicated that obvious solid solution reaction exists during the sintering process of these two systems.The effects of B-site ion difference on the solid solution characteristics were discussed by crystal chemistry.SEM was employed to investigated the microstructures of composite ceramics.The influences of solid solution reaction on grain growth were discussed.

Abnormal mechanical property evolution induced by heat treatment for a semi-solid forming hypereutectic Al-Fe base alloy

In the present study, Al-5.5Fe-4Cu-2Zn-0.4Mg-0.5Mn al oy samples were prepared by electromagnetic stirring and semi-solid forming processing, and then the effects of T6 and T1 heat treatments on the microstructures and mechanical properties of the semi-solid forming samples were investigated. The results indicate that after semi-solid forming, the mechanical properties of the sample improved significantly compared to that of the merely electromagnetically stirred sample. The grains of semi-solid forming alloy became almost fine equiaxed; big long strip-shaped Al3 Fe phases became short rod-like morphology and distributed uniformly in the matrix. However, the mechanical properties of the T6-treated semi-solid forming sample decreased significantly instead of increasing and, with solution temperature rising, the tensile strength of the al oy decreased further. The results of EDS show that after high temperature solid-solution treatment, the Cu element in the semi-solid forming alloy sample is mainly concentrated at the boundaries of the Al3 Fe phases instead of being dissolved in the matrix. At the same time, the grains of the semi-solid forming sample grew slightly after solid-solution treatment. Therefore, the growth of the grains and the accumulation of Cu element at Al3 Fe phase boundaries during solution treatment of the semi-solid forming alloy were the main reasons for the mechanical properties decreasing after T6 treatment. The mechanical properties of the alloy were improved after T1 heat treatment due to aging strengthening phase being precipitated in the matrix.

Study of Bi_2O_3-based Rare Earth Solid Electrolyte Used in Fuel Cell

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煤电化基地大宗固废“三化”协同利用基础与技术

我国14个大型煤炭基地及89个大宗固体废弃物综合利用示范基地建设,标志着矿区大宗固废利用已被纳入全国战略发展布局。长期以来煤炭资源高强度的开发与利用,造成矿区浅埋煤层资源临近枯竭,煤电化基地大规模固废堆积及地表沉陷,已成为制约矿区绿色低碳、高质量发展的难题。大宗煤基固废协同利用与绿色充填是解放“三下一上”压煤,延长矿井服务年限,实现固废无害化、资源化、规模化“三化”利用的有效途径。基于产煤大省山西省、“华东能源粮仓”安徽两淮基地及宁东能源化工基地的煤基固废种类和产量,详细阐述了以煤矸石、粉煤灰、炉底渣、气化渣和脱硫石膏等为主要材料的煤基固废通过重金属吸附解吸和络合钝化技术实现无害化处置,列举煤基固废分类应用于低热值煤基固废发电、制备建筑材料如水泥、砖瓦等资源化利用途径,对比分析煤基固废采煤沉陷区复垦回填及井下充填规模化利用途径,突出煤基固废井下充填的优越性。基于煤电化基地深部煤炭资源,提出绿色充填开采理论与关键技术,包括深部煤矸石源头减量与采选充协同技术、充填材料高效制备与深部井下输送技术及煤基固废充填材料深部多场耦合机理,探究多源煤基固废从源头、过程到终端的深部充填开采全过程的技术原理与方法,以解决矿区深部井下充填的技术难题。根据宁东基地任家庄煤矿、山西省霍尔辛赫煤矿及淮北矿区地质条件和充填目的,分别提出超前钻孔注充低位充填方案、关键层非典型特征条件下多离层梯级注浆方案和煤基固废协同利用关键技术,综合矿山固废处置与利用、深部煤炭资源开发利用、地表沉陷控制、生态环境保护等优势,形成煤电化基地大宗固废协同利用与绿色开采模式,为煤炭开采高质量化和环境低损伤化提供参考。

Microstructure and properties of electronic packaging shell with high silicon carbide aluminum-base composites by semi-solid thixoforming

The electronic packaging shell with high silicon carbide aluminum-base composites was prepared by semi-solid thixoforming technique. The flow characteristic of the Si C particulate was analyzed. The microstructures of different parts of the shell were observed by scanning electron microscopy and optical microscopy, and the thermophysical and mechanical properties of the shell were tested. The results show that there exists the segregation phenomenon between the Si C particulate and the liquid phase during thixoforming, the liquid phase flows from the shell, and the Si C particles accumulate at the bottom of the shell. The volume fraction of Si C decreases gradually from the bottom to the walls. Accordingly, the thermal conductivities of bottom center and walls are 178 and 164 W·m-1·K-1, the coefficients of thermal expansion(CTE) are 8.2×10-6 and 12.6×10-6 K-1, respectively. The flexural strength decreases slightly from 437 to 347 MPa. The microstructures and properties of the shell show gradient distribution.

玻璃纤维改性煤基固废胶结充填材料性能研究

基于煤矸石、粉煤灰等煤基固废再生资源利用和胶结充填材料性能优化问题,研究了玻璃纤维掺量、长度和养护龄期对煤基固废胶结材料输送性能和力学性能的影响规律,探讨了玻璃纤维增强机理。实验结果表明:玻璃纤维改性煤基固废胶结材料坍落度随纤维长度和掺量的增大而减小,但均大于200 mm,满足输送性能要求;抗压强度和抗拉强度随纤维长度的增大呈先增高后降低,随纤维掺量的增加而增高的变化规律;当玻璃纤维长度为6 mm、掺量为0.3%时,质量分数为79%的煤基固废胶结材料的综合性能最佳;玻璃纤维改性煤基固废胶结材料水化反应后,生成的针状和团状产物填充了材料细小裂隙且附着于纤维表面,能够有效提高材料的力学性能。