Previous works have shown that the suction probe cannot be used to accurately measure the upward and downward particle fluxes independently. A new method using a single optical probe to measure the local solid flux is...Previous works have shown that the suction probe cannot be used to accurately measure the upward and downward particle fluxes independently. A new method using a single optical probe to measure the local solid flux is presented. The measurement of upward, downward and net solid fluxes was carried out in a cold model circulating fluidized bed (CFB) unit. The result shows that the profile of the net solid flux is in good agreement with the previous experimental data measured with a suction probe. The comparison between the average solid flux determined with the optical measuring system and the external solid flux was made, and the maximum deviationturned out to be 22%, with the average error being about 6.9%. These confirm that the optical fiber system can be successfully used to measure the upward, downward and net solid fluxes simultaneously by correctly processing the sampling signals obtained from the optical measuring system.展开更多
The gas-solid flow pattern in a rectangular cross-flow moving bed is simulated by the multiphase particle-in-cell(MP-PIC)model with the Barracuda software.The computed results are verified by the experimental data.In ...The gas-solid flow pattern in a rectangular cross-flow moving bed is simulated by the multiphase particle-in-cell(MP-PIC)model with the Barracuda software.The computed results are verified by the experimental data.In the bed,the actual solid flux generally equals the solid flow rates in the solid feed and discharge tubes.However,these two flow rates are greatly influenced by the air lock and the pressure drop in the solid feed and discharge tubes,namely,the negative and positive pressure gradients,respectively,rather than the traditional opinion that they are merely controlled by the valve openings.The pressure drops in these tubes are calculated by the proposed“common pressure pool with multiple outlets”(CPPMO)and the“common pressure pool”(CPP)methods.It is found that the local gas resistance dominates the pressure drop in the solid discharge tubes,while the gas frictional resistance determines the pressure drop in the solid feed tube.In addition,when the solid flow rate nearly tends to zero in the solid feed tube,the air lock forms.A solid flux equation is then given by considering both the air lock and the pressure drop factors in the cross-flow moving bed.展开更多
Municipal solid waste landfills emit nitrous oxide (N2O) gas. Assuming that the soil cover is the primary N2O source from landfills, this study tested, during a four-year project, the hypothesis that the proper use ...Municipal solid waste landfills emit nitrous oxide (N2O) gas. Assuming that the soil cover is the primary N2O source from landfills, this study tested, during a four-year project, the hypothesis that the proper use of chosen soils with fine texture minimizes N2O emissions. A full-scale sanitary landfill, a full-scale bioreactor landfill and a cell planted with Nerium indicum or Festuca arundinacea Schreb, at the Hangzhou Tianziling landfill in Hangzhou City were the test sites. The N2O emission rates from all test sites were considerably lower than those reported in the published reports. Specifically, the N2O emission rate was dependent on soil water content and nitrate concentrations in the cover soil. The effects of leachate recirculation and irrigation were minimal. Properly chosen cover soils applied to the landfills reduced N2O flux.展开更多
Analysis of the entrance and wall dynamics of a high-flux gas-solid riser was conducted using embedded solid concentration time series collected from a 76 mm internal diameter and 10 m high riser of a circulating flui...Analysis of the entrance and wall dynamics of a high-flux gas-solid riser was conducted using embedded solid concentration time series collected from a 76 mm internal diameter and 10 m high riser of a circulating fluidized bed (CFB) system. The riser was operated at 4.0 to 10.0 m/s air velocity and 50 to 550 kg/m2s solids flux of spent fluid catalytic cracking (FCC) catalyst particles with 67 μm mean diameter and density of 1500 kg/m3. Data were analyzed using prepared FORTRAN 2008 code to get correlation integral followed by determination of correlation dimensions with respect to the hyperspherical radius and their profiles, plots of which were studied. It was found that correlation dimension profiles at the centre have single peak with higher values than the wall region profiles. Towards the wall, these profiles have double or multiple peaks showing bifractal or multifractal flow behaviors. As the velocity increases the wall region profiles become random and irregular. Further it was found that, as the height increases the correlation dimension profiles shift towards higher hyperspherical radius at the centre and towards lower hyperspherical radius in the wall region at r/R = 0.81. The established method of mapping correlation dimension profiles in this study forms a suitable tool for analysis of high-flux riser dynamics compared to other analyses approaches. However, further analysis is recommended to other gas-solid CFB riser of different dimensions operated at high-flux conditions using the established method.展开更多
The gas-liquid-solid three-phase mixed flow is the most general in multiphase mixed transportation. It is significant to exactly solve the coupling hydraulic transient problems of this type of multiphase mixed flow in...The gas-liquid-solid three-phase mixed flow is the most general in multiphase mixed transportation. It is significant to exactly solve the coupling hydraulic transient problems of this type of multiphase mixed flow in pipelines. Presently, the method of characteristics is widely used to solve classical hydraulic transient problems. However, when it is used to solve coupling hydraulic transient problems, excessive interpolation errors may be introduced into the results due to unavoidable multiwave interpolated calculations. To deal with the problem, a finite difference scheme based on the Steger- Warming flux vector splitting is proposed. A flux vector splitting scheme is established for the coupling hydraulic transient model of gas-liquid-solid three-phase mixed flow in the pipelines. The flux subvectors are then discretized by the Lax-Wendroff central difference scheme and the Warming-Beam upwind difference scheme with second-order precision in both time and space. Under the Rankine-Hugoniot conditions and the corresponding boundary conditions, an effective solution to those points located at the boundaries is developed, which can avoid the problem beyond the calculation region directly induced by the second-order discrete technique. Numerical and experimental verifications indicate that the proposed scheme has several desirable advantages including high calculation precision, excellent shock wave capture capability without false numerical oscillation, low sensitivity to the Courant number, and good stability.展开更多
Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant...Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant. There is a limited information available in the literature regarding the effect of particle type,density, wettability and concentration on Sb. In this paper, computational fluid dynamics(CFD) simulations are performed to study the gas–liquid–solid three-phase flow dynamics in flotation column by employing the Eulerian–Eulerian formulation with k-e turbulence model. The model is developed by writing Fortran subroutine and incorporating then into the commercial CFD code AVL FIRE, v.2014.This paper studies the effects of superficial gas velocities and particle type, density, wettability and concentration on Sband bubble concentration in the flotation column. The model has been validated against published experimental data. It was found that the CFD model was able to predict, where the response variable as indicated by R-Square value of 0.98. These results suggest that the developed CFD model is reasonable to describe the flotation column reactor. From the CFD results, it is also found that Sb decreased with increasing solid concentration and hydrophobicity, but increased with increasing superficial gas velocity. For example, approximately 28% reduction in the surface area flux is observed when coal concentration is increased from 0 to 10%, by volume. While for the same solid concentration and gas flow rate, the bubble surface area flux is approximately increased by 7% in the presences of sphalerite.A possible explanation for this might be that increasing solid concentration and hydrophobicity promotes the bubble coalescence rate leading to the increase in bubble size. Also, it was found that the bubble concentration would decrease with addition of hydrophobic particle(i.e., coal). For instance, under the same operating conditions, approximately 23% reduction in the bubble concentration is predicted when the system was working with hydrophobic particles. The results presented are useful for understanding flow dynamics of three-phase system and provide a basis for further development of CFD model for flotation column.展开更多
The luminescence of EU^2+ in BaMgSiO4 with BaB2O4 as flux was studied. The emission spectrum of the phosphor consisted of two bands, peaking at about 398 nm and 515 nm, which were attributed to the emissions from dif...The luminescence of EU^2+ in BaMgSiO4 with BaB2O4 as flux was studied. The emission spectrum of the phosphor consisted of two bands, peaking at about 398 nm and 515 nm, which were attributed to the emissions from different Eu^2+ sites in the lattice. When the BaB2O4 flux was applied, the intensity of the 398 nm emission was not clearly affected, but the intensity of the 515 nm emission was enhanced by about ten times. Gaussian fitting showed that the emission band at around 515 nm could actually be resolved into two bands with peak wavelengths of 499 nm and 521 nm, respectively. The assignments of the emission bands to the cation sites were carried out according to the values of bond valence. The overlapping of the 398 nm emission band on the excitation band of 515 nm emission implied that energy transfer could occur from the luminescent center related to the 398 nm emission to the center related to the 515 nm emission, and the energy transfer process remarkably enhanced the intensity of the 515 nm emission band. The phosphor had strong excitation at around 350-400 nm and emitted a bright green luminescence. Thus it could have applications as a green component in solid-state lighting devices assembled by near-UV Light Emitting Diodes (LED) combined with tricolor phosphors.展开更多
A mathematical model of two-dimensional turbulent gas-particle two-phase flow based on the modified diffusion flux model (DFM) and a numerical simulation method to analyze the gas-particle flow structures are develope...A mathematical model of two-dimensional turbulent gas-particle two-phase flow based on the modified diffusion flux model (DFM) and a numerical simulation method to analyze the gas-particle flow structures are developed. The modified diffusion flux model, in which the acceleration due to various forces is taken into account for the calculation of the diffusion velocity of particles, is applicable to the analysis of multi-dimensional gas-particle two-phase turbulent flow. In order to verify its accuracy and efficiency, the numerical simulation by DFM is compared with experimental studies and the prediction by κ-ε-κp two-fluid model, which shows a reasonable agreement. It is confirmed that the modified diffusion flux model is suitable for simulating the multi-dimensional gas-particle two-phase flow.展开更多
The purpose of the present work is to derive some solutions for several solid angle cases via a fundamental formula which gives the solid angle for an isosceles triangle. From this formula the solid angle of pyramids ...The purpose of the present work is to derive some solutions for several solid angle cases via a fundamental formula which gives the solid angle for an isosceles triangle. From this formula the solid angle of pyramids is derived but, unlike other presentations, it is shown in a format similar to that of the well-known cone case. Besides the regular polygon cases (straight pyramids), solid angles of some other plane closed curves are calculated. The fundamental formula also leads to some interesting properties showing the not simple behavior of solid angles with the observer point on the curve itself, as it depends on how the observer arrived there. The question of the equi-Ω surfaces is also discussed and calculated in simple cases.展开更多
The interfacial status of the steel-aluminum solid to liquid bonding plates (their steel plate surfaces were or were not immersed in flux aqueous solution) were measured by using SEM (Scanning Electron Microscope) and...The interfacial status of the steel-aluminum solid to liquid bonding plates (their steel plate surfaces were or were not immersed in flux aqueous solution) were measured by using SEM (Scanning Electron Microscope) and X-ray diffraction . The results showed that the layer of flux (the minimum thickness was 15 μm on the steel plate surface) could protect the steel plate surface from oxidizing effectively at high temperature in solid to liquid bonding. The melt temperatUre of the flux should be lower than 580 ℃ so that it could be melted and removed completely. No. 1 flux (patent product made by the author) made up of halogeindes could also force liquid aluminum to infiltrate into steel plate surface and thus the interfacial shear strength of the bonding plate was rather large.展开更多
文摘Previous works have shown that the suction probe cannot be used to accurately measure the upward and downward particle fluxes independently. A new method using a single optical probe to measure the local solid flux is presented. The measurement of upward, downward and net solid fluxes was carried out in a cold model circulating fluidized bed (CFB) unit. The result shows that the profile of the net solid flux is in good agreement with the previous experimental data measured with a suction probe. The comparison between the average solid flux determined with the optical measuring system and the external solid flux was made, and the maximum deviationturned out to be 22%, with the average error being about 6.9%. These confirm that the optical fiber system can be successfully used to measure the upward, downward and net solid fluxes simultaneously by correctly processing the sampling signals obtained from the optical measuring system.
基金The authors gratefully acknowledge the financial support from the State Key Laboratory of Heavy Oil Processing(SKLOP201903002)the Natural Science Foundation of Hebei(B2017202185)the National Key Basic Research Development Program of China(973 Program)(No.2012CB215000)。
文摘The gas-solid flow pattern in a rectangular cross-flow moving bed is simulated by the multiphase particle-in-cell(MP-PIC)model with the Barracuda software.The computed results are verified by the experimental data.In the bed,the actual solid flux generally equals the solid flow rates in the solid feed and discharge tubes.However,these two flow rates are greatly influenced by the air lock and the pressure drop in the solid feed and discharge tubes,namely,the negative and positive pressure gradients,respectively,rather than the traditional opinion that they are merely controlled by the valve openings.The pressure drops in these tubes are calculated by the proposed“common pressure pool with multiple outlets”(CPPMO)and the“common pressure pool”(CPP)methods.It is found that the local gas resistance dominates the pressure drop in the solid discharge tubes,while the gas frictional resistance determines the pressure drop in the solid feed tube.In addition,when the solid flow rate nearly tends to zero in the solid feed tube,the air lock forms.A solid flux equation is then given by considering both the air lock and the pressure drop factors in the cross-flow moving bed.
基金This work was supported by the National Science and Technology Supporting Program of China (No. 2006BAJ04A06, 2006BAC06B05) ;the National Natural Science Foundation of China (No. 50538080).
文摘Municipal solid waste landfills emit nitrous oxide (N2O) gas. Assuming that the soil cover is the primary N2O source from landfills, this study tested, during a four-year project, the hypothesis that the proper use of chosen soils with fine texture minimizes N2O emissions. A full-scale sanitary landfill, a full-scale bioreactor landfill and a cell planted with Nerium indicum or Festuca arundinacea Schreb, at the Hangzhou Tianziling landfill in Hangzhou City were the test sites. The N2O emission rates from all test sites were considerably lower than those reported in the published reports. Specifically, the N2O emission rate was dependent on soil water content and nitrate concentrations in the cover soil. The effects of leachate recirculation and irrigation were minimal. Properly chosen cover soils applied to the landfills reduced N2O flux.
文摘Analysis of the entrance and wall dynamics of a high-flux gas-solid riser was conducted using embedded solid concentration time series collected from a 76 mm internal diameter and 10 m high riser of a circulating fluidized bed (CFB) system. The riser was operated at 4.0 to 10.0 m/s air velocity and 50 to 550 kg/m2s solids flux of spent fluid catalytic cracking (FCC) catalyst particles with 67 μm mean diameter and density of 1500 kg/m3. Data were analyzed using prepared FORTRAN 2008 code to get correlation integral followed by determination of correlation dimensions with respect to the hyperspherical radius and their profiles, plots of which were studied. It was found that correlation dimension profiles at the centre have single peak with higher values than the wall region profiles. Towards the wall, these profiles have double or multiple peaks showing bifractal or multifractal flow behaviors. As the velocity increases the wall region profiles become random and irregular. Further it was found that, as the height increases the correlation dimension profiles shift towards higher hyperspherical radius at the centre and towards lower hyperspherical radius in the wall region at r/R = 0.81. The established method of mapping correlation dimension profiles in this study forms a suitable tool for analysis of high-flux riser dynamics compared to other analyses approaches. However, further analysis is recommended to other gas-solid CFB riser of different dimensions operated at high-flux conditions using the established method.
基金supported by the Natural Science Foundation Project of CQ CSTC (No. 2010BB7421)
文摘The gas-liquid-solid three-phase mixed flow is the most general in multiphase mixed transportation. It is significant to exactly solve the coupling hydraulic transient problems of this type of multiphase mixed flow in pipelines. Presently, the method of characteristics is widely used to solve classical hydraulic transient problems. However, when it is used to solve coupling hydraulic transient problems, excessive interpolation errors may be introduced into the results due to unavoidable multiwave interpolated calculations. To deal with the problem, a finite difference scheme based on the Steger- Warming flux vector splitting is proposed. A flux vector splitting scheme is established for the coupling hydraulic transient model of gas-liquid-solid three-phase mixed flow in the pipelines. The flux subvectors are then discretized by the Lax-Wendroff central difference scheme and the Warming-Beam upwind difference scheme with second-order precision in both time and space. Under the Rankine-Hugoniot conditions and the corresponding boundary conditions, an effective solution to those points located at the boundaries is developed, which can avoid the problem beyond the calculation region directly induced by the second-order discrete technique. Numerical and experimental verifications indicate that the proposed scheme has several desirable advantages including high calculation precision, excellent shock wave capture capability without false numerical oscillation, low sensitivity to the Courant number, and good stability.
基金the Higher Committee for Education Development in Iraq (HCED) for their financial support
文摘Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant. There is a limited information available in the literature regarding the effect of particle type,density, wettability and concentration on Sb. In this paper, computational fluid dynamics(CFD) simulations are performed to study the gas–liquid–solid three-phase flow dynamics in flotation column by employing the Eulerian–Eulerian formulation with k-e turbulence model. The model is developed by writing Fortran subroutine and incorporating then into the commercial CFD code AVL FIRE, v.2014.This paper studies the effects of superficial gas velocities and particle type, density, wettability and concentration on Sband bubble concentration in the flotation column. The model has been validated against published experimental data. It was found that the CFD model was able to predict, where the response variable as indicated by R-Square value of 0.98. These results suggest that the developed CFD model is reasonable to describe the flotation column reactor. From the CFD results, it is also found that Sb decreased with increasing solid concentration and hydrophobicity, but increased with increasing superficial gas velocity. For example, approximately 28% reduction in the surface area flux is observed when coal concentration is increased from 0 to 10%, by volume. While for the same solid concentration and gas flow rate, the bubble surface area flux is approximately increased by 7% in the presences of sphalerite.A possible explanation for this might be that increasing solid concentration and hydrophobicity promotes the bubble coalescence rate leading to the increase in bubble size. Also, it was found that the bubble concentration would decrease with addition of hydrophobic particle(i.e., coal). For instance, under the same operating conditions, approximately 23% reduction in the bubble concentration is predicted when the system was working with hydrophobic particles. The results presented are useful for understanding flow dynamics of three-phase system and provide a basis for further development of CFD model for flotation column.
基金Project supported by the State Key Program for Basic Research of China (G1998061306)the National Natural Science Foundation of China (20071003, 20221101)the High Tech. Research of Zhejiang Province (2003C31029)
文摘The luminescence of EU^2+ in BaMgSiO4 with BaB2O4 as flux was studied. The emission spectrum of the phosphor consisted of two bands, peaking at about 398 nm and 515 nm, which were attributed to the emissions from different Eu^2+ sites in the lattice. When the BaB2O4 flux was applied, the intensity of the 398 nm emission was not clearly affected, but the intensity of the 515 nm emission was enhanced by about ten times. Gaussian fitting showed that the emission band at around 515 nm could actually be resolved into two bands with peak wavelengths of 499 nm and 521 nm, respectively. The assignments of the emission bands to the cation sites were carried out according to the values of bond valence. The overlapping of the 398 nm emission band on the excitation band of 515 nm emission implied that energy transfer could occur from the luminescent center related to the 398 nm emission to the center related to the 515 nm emission, and the energy transfer process remarkably enhanced the intensity of the 515 nm emission band. The phosphor had strong excitation at around 350-400 nm and emitted a bright green luminescence. Thus it could have applications as a green component in solid-state lighting devices assembled by near-UV Light Emitting Diodes (LED) combined with tricolor phosphors.
基金Special Funds for Major State Basic Research Projects of China(G1999022200)
文摘A mathematical model of two-dimensional turbulent gas-particle two-phase flow based on the modified diffusion flux model (DFM) and a numerical simulation method to analyze the gas-particle flow structures are developed. The modified diffusion flux model, in which the acceleration due to various forces is taken into account for the calculation of the diffusion velocity of particles, is applicable to the analysis of multi-dimensional gas-particle two-phase turbulent flow. In order to verify its accuracy and efficiency, the numerical simulation by DFM is compared with experimental studies and the prediction by κ-ε-κp two-fluid model, which shows a reasonable agreement. It is confirmed that the modified diffusion flux model is suitable for simulating the multi-dimensional gas-particle two-phase flow.
文摘The purpose of the present work is to derive some solutions for several solid angle cases via a fundamental formula which gives the solid angle for an isosceles triangle. From this formula the solid angle of pyramids is derived but, unlike other presentations, it is shown in a format similar to that of the well-known cone case. Besides the regular polygon cases (straight pyramids), solid angles of some other plane closed curves are calculated. The fundamental formula also leads to some interesting properties showing the not simple behavior of solid angles with the observer point on the curve itself, as it depends on how the observer arrived there. The question of the equi-Ω surfaces is also discussed and calculated in simple cases.
文摘The interfacial status of the steel-aluminum solid to liquid bonding plates (their steel plate surfaces were or were not immersed in flux aqueous solution) were measured by using SEM (Scanning Electron Microscope) and X-ray diffraction . The results showed that the layer of flux (the minimum thickness was 15 μm on the steel plate surface) could protect the steel plate surface from oxidizing effectively at high temperature in solid to liquid bonding. The melt temperatUre of the flux should be lower than 580 ℃ so that it could be melted and removed completely. No. 1 flux (patent product made by the author) made up of halogeindes could also force liquid aluminum to infiltrate into steel plate surface and thus the interfacial shear strength of the bonding plate was rather large.