The increasing application of near balanced drilling technology to low-pressure and depleted fractured reservoirs requires the use of low-density drilling fluids to avoid formation damage. Solidsfree oil-in-water （O/...The increasing application of near balanced drilling technology to low-pressure and depleted fractured reservoirs requires the use of low-density drilling fluids to avoid formation damage. Solidsfree oil-in-water （O/W） emulsion drilling fluid is one type of low-density drilling fluid suitable for depleted fractured reservoirs. In this paper, the solids-free O/W drilling fluid was developed and has been successfully used in the Bozhong 28-1 oil and gas field, by which lost circulation, a severe problem occurred previously when drilling into fractured reservoir beds, was controlled, thereby minimizing formation damage. The O/W emulsion drilling fluid was prepared by adding 20% （by volume） No. 5 mineral oil （with high flash point, as dispersed phase） into seawater （as continuous phase）. Surfactant HTO-1 （as a primary emulsifier） and non-ionic surfactant HTO-2 （as a secondary emulsifier） were added into the drilling fluid system to stabilize the emulsion; and YJD polymer was also added to seawater to improve the viscosity of the continuous phase （seawater）. The drilling fluid was characterized by high flash point, good thermal stability and high stability to crude oil contamination.展开更多
Nitro aromatic compound can be obtained in high yields via nitration of aromatic compound with wet carbon-based solid acid and NaNO_3 under solvent free oxidation at room temperature.
A solid phase radioimmunoassay for free triiodothyronine in serum was developed based on double-antibody coated tubes. The method was turned out to be reliable with good reproducibility, higher sensitivity and easy pe...A solid phase radioimmunoassay for free triiodothyronine in serum was developed based on double-antibody coated tubes. The method was turned out to be reliable with good reproducibility, higher sensitivity and easy performance. The measurable range of FT3 in serum was 1.2 to 38 pmol/L. The mean coefficients of variation within and between assays were 1.79%-3.18% and 4.72%-9.31%, respectively. The FT3 concentrations in euthyroid serum as determined by this method were 2.8 to 7.8pmol/L. The FT3 values determined by this new method correlated well with those measured by a commercial radioimmunoassay （r=0.853）.展开更多
This project is explaining a laboratory development of a solid free drilling fluid formula that could be potentially used in tight gas reservoirs. The configuration of the weak gel fluid WGL-1, which is resistant to h...This project is explaining a laboratory development of a solid free drilling fluid formula that could be potentially used in tight gas reservoirs. The configuration of the weak gel fluid WGL-1, which is resistant to high temperature and high salt, was tested, and concluded that its gelling properties, salt and temperature resistance, and environmental protection were all in line with industry requirements. The final drilling fluid formula was developed as: water + (0.3% ~ 0.5%) NaOH + 5% KCl + 2% WGL-1 + 5% NaCl + (1.0% ~ 2.0%) HBFR Anti-high temperature fluid loss agent + 2% Polyol + (1.5% ~ 2.0%) SDL-1 Lubricant + 0.4% A4O1. The performance of the liquid was tested for temperature resistance, inhibition, gas formation protection effect, plugging performance, and static settlement stability. It was concluded that the temperature resistance performance is satisfied at 150°C, and the cuttings recovery rate is as high as 96.78%. It has good performance in inhibiting water dispersion and swelling of cuttings. The permeability recovery value reaches 88.9%, which meets the requirements of gas formation protection. The SSSI value shows that its settlement stability is good;under high temperature and high pressure, its sealing performance is good. This drilling fluid system has achieved the expected results and laid a foundation for further promoting the development of solid-free drilling fluid systems. The future development direction of solid-free drilling fluids is pointed out, to the improvement of properties to be applied in high temperature environment and have high salt resistance capacity.展开更多
A β”/β-Al_2O_3 solid electrolyte was prepared and used in a Na conentration galvanic cell: (-)O_2(in Ar),SnO_2,Na_2SnO_3|β"/β-Al_2O_3]NaCrO_2,Cr_2O_3,O_2(in Ar)(+).The emf measurements were carried out in te...A β”/β-Al_2O_3 solid electrolyte was prepared and used in a Na conentration galvanic cell: (-)O_2(in Ar),SnO_2,Na_2SnO_3|β"/β-Al_2O_3]NaCrO_2,Cr_2O_3,O_2(in Ar)(+).The emf measurements were carried out in temperature range of 912—1223 K:E=652.1— 0.2092 T+2.3(mV).Using this equation and cited free energies of formation of NaCrO_2, Cr_2O_3 and SnO_2,the molar free energy of formation of Na_2 SnO_3 may be calculated by ΔG°=-1050+0.2544 T±5.4(kJ mol^(-1)).展开更多
This paper is concerned with the bifurcation analysis for a free boundary problem modeling the growth of solid tumor with inhibitors.In this problem,surface tension coefficient plays the role of bifurcation parameter,...This paper is concerned with the bifurcation analysis for a free boundary problem modeling the growth of solid tumor with inhibitors.In this problem,surface tension coefficient plays the role of bifurcation parameter,it is proved that there exists a sequence of the nonradially stationary solutions bifurcate from the radially symmetric stationary solutions.Our results indicate that the tumor grown in vivo may have various shapes.In particular,a tumor with an inhibitor is associated with the growth of protrusions.展开更多
In the present paper, the inelastic mean free path （IMFP） of incident electrons is calculated as a function of energy for silicon （Si）, oxides of silicon （SiO2）, SiO, and A1203 in bulk form by employing atomic/m...In the present paper, the inelastic mean free path （IMFP） of incident electrons is calculated as a function of energy for silicon （Si）, oxides of silicon （SiO2）, SiO, and A1203 in bulk form by employing atomic/molecular inelastic cross sections derived by using a semi-empirical quantum mechanical method developed earlier. A general agreement of the present results is found with most of the available data. It is of great importance that we have been able to estimate the minimum IMFP, which corresponds to the peak of inelastic interactions of incident electrons in each solid investigated. New results are presented for SiO, for which no comparison is available. The present work is important in view of the lack of experimental data on the IMFP in solids.展开更多
文摘The increasing application of near balanced drilling technology to low-pressure and depleted fractured reservoirs requires the use of low-density drilling fluids to avoid formation damage. Solidsfree oil-in-water （O/W） emulsion drilling fluid is one type of low-density drilling fluid suitable for depleted fractured reservoirs. In this paper, the solids-free O/W drilling fluid was developed and has been successfully used in the Bozhong 28-1 oil and gas field, by which lost circulation, a severe problem occurred previously when drilling into fractured reservoir beds, was controlled, thereby minimizing formation damage. The O/W emulsion drilling fluid was prepared by adding 20% （by volume） No. 5 mineral oil （with high flash point, as dispersed phase） into seawater （as continuous phase）. Surfactant HTO-1 （as a primary emulsifier） and non-ionic surfactant HTO-2 （as a secondary emulsifier） were added into the drilling fluid system to stabilize the emulsion; and YJD polymer was also added to seawater to improve the viscosity of the continuous phase （seawater）. The drilling fluid was characterized by high flash point, good thermal stability and high stability to crude oil contamination.
文摘Nitro aromatic compound can be obtained in high yields via nitration of aromatic compound with wet carbon-based solid acid and NaNO_3 under solvent free oxidation at room temperature.
文摘A solid phase radioimmunoassay for free triiodothyronine in serum was developed based on double-antibody coated tubes. The method was turned out to be reliable with good reproducibility, higher sensitivity and easy performance. The measurable range of FT3 in serum was 1.2 to 38 pmol/L. The mean coefficients of variation within and between assays were 1.79%-3.18% and 4.72%-9.31%, respectively. The FT3 concentrations in euthyroid serum as determined by this method were 2.8 to 7.8pmol/L. The FT3 values determined by this new method correlated well with those measured by a commercial radioimmunoassay （r=0.853）.
文摘This project is explaining a laboratory development of a solid free drilling fluid formula that could be potentially used in tight gas reservoirs. The configuration of the weak gel fluid WGL-1, which is resistant to high temperature and high salt, was tested, and concluded that its gelling properties, salt and temperature resistance, and environmental protection were all in line with industry requirements. The final drilling fluid formula was developed as: water + (0.3% ~ 0.5%) NaOH + 5% KCl + 2% WGL-1 + 5% NaCl + (1.0% ~ 2.0%) HBFR Anti-high temperature fluid loss agent + 2% Polyol + (1.5% ~ 2.0%) SDL-1 Lubricant + 0.4% A4O1. The performance of the liquid was tested for temperature resistance, inhibition, gas formation protection effect, plugging performance, and static settlement stability. It was concluded that the temperature resistance performance is satisfied at 150°C, and the cuttings recovery rate is as high as 96.78%. It has good performance in inhibiting water dispersion and swelling of cuttings. The permeability recovery value reaches 88.9%, which meets the requirements of gas formation protection. The SSSI value shows that its settlement stability is good;under high temperature and high pressure, its sealing performance is good. This drilling fluid system has achieved the expected results and laid a foundation for further promoting the development of solid-free drilling fluid systems. The future development direction of solid-free drilling fluids is pointed out, to the improvement of properties to be applied in high temperature environment and have high salt resistance capacity.
文摘A β”/β-Al_2O_3 solid electrolyte was prepared and used in a Na conentration galvanic cell: (-)O_2(in Ar),SnO_2,Na_2SnO_3|β"/β-Al_2O_3]NaCrO_2,Cr_2O_3,O_2(in Ar)(+).The emf measurements were carried out in temperature range of 912—1223 K:E=652.1— 0.2092 T+2.3(mV).Using this equation and cited free energies of formation of NaCrO_2, Cr_2O_3 and SnO_2,the molar free energy of formation of Na_2 SnO_3 may be calculated by ΔG°=-1050+0.2544 T±5.4(kJ mol^(-1)).
基金The NSF(11361029)of Chinathe NSF(20142BAB211001)of Jiangxi Province
文摘This paper is concerned with the bifurcation analysis for a free boundary problem modeling the growth of solid tumor with inhibitors.In this problem,surface tension coefficient plays the role of bifurcation parameter,it is proved that there exists a sequence of the nonradially stationary solutions bifurcate from the radially symmetric stationary solutions.Our results indicate that the tumor grown in vivo may have various shapes.In particular,a tumor with an inhibitor is associated with the growth of protrusions.
基金Project supported by the Indian Space Research Organization through Respond Project (Grant No.ISRO/RES/2/356/10-11)
文摘In the present paper, the inelastic mean free path （IMFP） of incident electrons is calculated as a function of energy for silicon （Si）, oxides of silicon （SiO2）, SiO, and A1203 in bulk form by employing atomic/molecular inelastic cross sections derived by using a semi-empirical quantum mechanical method developed earlier. A general agreement of the present results is found with most of the available data. It is of great importance that we have been able to estimate the minimum IMFP, which corresponds to the peak of inelastic interactions of incident electrons in each solid investigated. New results are presented for SiO, for which no comparison is available. The present work is important in view of the lack of experimental data on the IMFP in solids.
