Low-cost solid FeS lubricant as a possible alternative to MoS2 for producing Fe-based friction materials

Three reaction systems of MoS_2-Fe, FeS -Fe, and Fe S-Fe-Mo were designed to investigate the use of FeS as an alternative to MoS_2 for producing Fe-based friction materials. Samples were prepared by powder metallurgy, and their phase compositions, microstructures, mechanical properties, and friction performance were characterized. The results showed that MoS_2 reacts with the matrix to produce iron-sulfides and Mo when sintered at 1050°C. Iron-sulfides produced in the MoS_2-Fe system were distributed uniformly and continuously in the matrix, leading to optimal mechanical properties and the lowest coefficient of friction among the systems studied. The lubricity observed was hypothesized to originate from the iron-sulfides produced. The Fe S-Fe-Mo system showed a phase composition, porosity, and density similar to those of the MoS_2-Fe system, but an uneven distribution of iron-sulfides and Mo in this system resulted in less-optimal mechanical properties. Finally, the Fe S-Fe system showed the poorest mechanical properties among the systems studied because of the lack of Mo reinforcement. In friction tests, the formation of a sulfide layer contributed to a decrease in coefficient of friction（COF） in all of the samples.

Shot Peening and Solid Lubricating on Ti6 Al4 V Fretting Fatigue

The effects of three factors i.e. compressive residual stress, surface roughness and microstructure hardening in shot peened surface on fretting fatigue (FF) were evaluated. The results show that the residual stress and the surface roughness are predominant FF with the rectangular contact pad. Two kinds of commercial lubricants for post peening coating can not improve the FF resistance, since their processing reduce the compressive residual stress.

Phase Representation and Property Determination of Raw Materials of Solid Lubricant

The composition, microstructure, mechanical and frictional properties of PTFE and its fillers were represented and analyzed by XRD, SEM, DSC, XPS and large-scale polarizing microscope. The results show that PTFE has a flocculent structure with high melt temperature and decomposition temperature, big contact angle and crystallinity, and low surface hardness, compression strength, friction coefficient, wearing capacity and surface energy. Cooling rate influenced the friction coefficient and wear resistance. Graphite and molybdenum disulfide have a flake structure, and molybdenum disulfide has a big contact angle and low surface energy. Copper powder has a globular structure and its chief component is Cu-Pb alloy, and there is a loose layer on the surface. Carbon fiber has a rod structure and there are C=O and C-O-C polar groups on the skeleton surface. The decreasing order of water absorption capacity is graphite, carbon fiber, molybdenum disulfide, PTFE and copper powder.

Nano K_2Ti_4O_9 Whisker Enhanced Solid Lubrication Coating for Cutting Application

In order to decrease cutting fluid and improve environment, the cutting fluid was replaced by solid lubricant. Four kinds of solid lubricants were tested on a high temperature friction tester, from which nano K 2Ti 4O 9 whisker enhanced solid lubrication film was chosen. It was coated on the surface of cutters and tested on a CA6140 lathe. At the rate of 400r/min, the wear of the tool flank with solid lubrication film is 1/6 of that without the film, and it is even lower than that using cutting fluid. With the increase of cutting speed, the wear of the tool flank with solid lubrication film is still lower than that without film, but it is higher than that using cutting fluid. Surface analyses by AFM, SEM and EDX reveal that the solid lubrication film can prevent Fe element of chips from diffusing the cutter surface; adhesion of the cutter and chips is abated and the wear of the tool flank is obviously decreased.

Effect of Counterface Material on Friction and Wear Behavior of Ni-Cr-W-Al-Ti-MoS_2 Composites

Ni-Cr-W-Al-Ti-MoS2 self-lubricating composites were prepared through the powder metallurgy （P/M） method. Their friction properties were investigated by a pin-on-disk tribometer in the range from the room temperature to 600 ℃. Alumina, silicon nitride and nickel-iron-sulfide alloys were selected as the counterface materials. Results indicate that the lowest friction coefficients under 0.22 can be obtained at 600℃ when rubbed against alumina. When rubbed against nickel-iron-sulfide alloys, are presented the lowest wear rates in the magnitude of 10^-6 mm^3/N-m, one order of magnitude lower than those when rubbed against ceramics. In the case of three rubbing pairs, the wear rates of the composite containing MoS2 present themselves inversely proportional to friction coefficients. With alumina ceramics used as a counterface, transfer films and glaze layers will form on the contact surface playing a main role in lubrication at high temperatures. However, when silicon nitride and nickel-iron-sulfide alloy are used, the lubricating transfer films appear not to be prominent.

Influence of sulfides on the tribological properties of composites produced by pulse electric current sintering

Self-lubricating A1203-15wt% ZrO2 composites with sulfides, such as molybdenum disulfide （MoS2） and tungsten disulfide （WSz） serving as solid lubricants, were fabricated by using the pulse electric current sintering （PECS） technique. The coefficient of friction （COF） of the A1203-15wt% ZrO2 composite without/with sulfides was in the range of 0.37-0.48 and 0.27-0.49, respectively. As the amoant of sul- fides increased, the COF and the wear rate decreased. The reduction in COF and wear rate of the sulfide-containing composite is caused by a reduction in shear stresses between the specimen and the tribological medium due to the formation of a lubricating film resulting from the lamellar structure of sulfides located on the worn surface.

Experimental Study on Grinding Force of Electrostatic Coated Grinding Wheel

In order to deal with the hard machining of TC4 alloy,coated graphite on grinding wheel surface by electrostatic device is proposed in this paper.This paper mainly completed the design of graphite electrostatic spraying grinding wheel device,force experimental analysis of grinding TC4 alloy with coated graphite grinding wheel,and summary of the influence of different grinding speeds and grinding depths on grinding force and grinding force ratio.The experimental results show that the lubrication coating can reduce the grinding force and grinding force ratio in the process of grinding TC4 alloy with graphite powder-coated wheel under electrostatic field force,compared to dry grinding with the uncoated wheel.

Influence of structural depth of laser-patterned steel surfaces on the solid lubricity of carbon nanoparticle coatings

Carbon nanoparticle coatings on laser-patterned stainless-steel surfaces present a solid lubrication system where the pattern's recessions act as lubricant-retaining reservoirs.This study investigates the influence of the structural depth of line patterns coated with multi-walled carbon nanotubes(CNTs)and carbon onions(COs)on their respective potential to reduce friction and wear.Direct laser interference patterning(DLIP)with a pulse duration of 12 ps is used to create line patterns with three different structural depths at a periodicity of 3.5μm on AISI 304 steel platelets.Subsequently,electrophoretic deposition(EPD)is applied to form homogeneous carbon nanoparticle coatings on the patterned platelets.Tribological ball-on-disc experiments are conducted on the as-described surfaces with an alumina counter body at a load of 100 mN.The results show that the shallower the coated structure,the lower its coefficient of friction(COF),regardless of the particle type.Thereby,with a minimum of just below 0.20,CNTs reach lower COF values than COs over most of the testing period.The resulting wear tracks are characterized by scanning electron microscopy,transmission electron microscopy,and energy-dispersive X-ray spectroscopy.During friction testing,the CNTs remain in contact,and the immediate proximity,whereas the CO coating is largely removed.Regardless of structural depth,no oxidation occurs on CNT-coated surfaces,whereas minor oxidation is detected on CO-coated wear tracks.

Tribologically induced nanostructural evolution of carbon materials: A new perspective

Carbon-based solid lubricants are excellent options to reduce friction and wear,especially with the carbon capability to adopt different allotropes forms.On the macroscale,these materials are sheared on the contact along with debris and contaminants to form tribolayers that govern the tribosystem performance.Using a recently developed advanced Raman analysis on the tribolayers,it was possible to quantify the contactinduced defects in the crystalline structure of a wide range of allotropes of carbon-based solid lubricants,from graphite and carbide-derived carbon particles to multi-layer graphene and carbon nanotubes.In addition,these materials were tested under various dry sliding conditions,with different geometries,topographies,and solid-lubricant application strategies.Regardless of the initial tribosystem conditions and allotrope level of atomic ordering,there is a remarkable trend of increasing the point and line defects density until a specific saturation limit in the same order of magnitude for all the materials tested.

Investigation of tribological characteristics of nickel alloybased solid-lubricating composites at elevated temperatures under vacuum

The development of a high‐performance solid‐lubricating composite with excellent self‐lubricity over a broad temperature range in vacuum is significant to solve the frictional problems of spatial mechanisms.In this study,the vacuum tribological behaviors of nickel‐matrix/Ag/(Ca,Ba)F2/graphite(0–2 wt%)composites were studied from 25 to 800°C.The results show that the synergistic effects of solid lubricants can significantly improve the tribological properties of the composites in vacuum,with the graphite content contributing considerably.For 2 wt%graphite,a low friction coefficient(0.14–0.25)and the lowest wear rate((0.12–4.78)×10^(-5) mm^(3)∙N^(-1)∙m^(-1))were observed in vacuum over the entire testing temperature range.Moreover,the wear mechanisms were clarified via analysis of the chemical composition and morphologies of the sliding surfaces.

Graphite-based solid lubricant for high-temperature lubrication

High-temperature solid lubricants play a significant role in the hot metal forming process.However,preparing high-temperature solid lubricant is formidably challenging due to the stern working conditions.Here we successfully develop a new type of eco-friendly high-temperature graphite-based solid lubricant by using amorphous silica dioxide,aluminum dihydrogen phosphate,and solid lubricant graphite.The solid lubricating coating exhibits excellent tribological properties with a very low friction coefficient and good wear protection for workpiece at high temperature under the air atmosphere.An array of analytical techniques reveals the existence of solid lubricant graphite in the lubricating coating after the high-temperature friction test.A synergistic effect between the protective surface film and the solid lubricant graphite is proposed to account for such superior lubricating performance.This work highlights the synergistic effect between the protection layer and the lubricant graphite and further provides the insight in designing the high-temperature solid lubricant.

Improving surface integrity when drilling CFRPs and Ti-6Al-4V using sustainable lubricated liquid carbon dioxide

In the quest for decreasing fuel consumption and resulting gas emissions in the aeronautic sector,lightweight materials such as Carbon Fiber Reinforced Polymers(CFRPs)and Ti-6Al-4V alloys are being used.These materials,with excellent weight-to-strength ratios,are widely used for structural applications in aircraft manufacturing.To date,several studies have been published showing that the use of metalworking fluids(MWFs),special tool geometries,or advanced machining techniques is required to ensure a surface quality that meets aerospace component standards.Conventional MWFs pose a number of environmental and worker health hazards and also degrade the mechanical properties of CFRPs due to water absorption in the composite.Therefore,a transition to more environmentally friendly cooling/lubrication techniques that prevent moisture problems in the composite is needed.This research shows that lubricated LCO_(2) is a viable option to improve the quality of drilled CFRP and titanium aerospace components compared to dry machining,while maintaining clean work areas.The results show that the best combination of tool geometry and cooling conditions for machining both materials is drilling with Brad point drills and lubricated LCO_(2).Drilling under these conditions resulted in a 90%improvement in fiber pullout volume compared to dry machined CFRP holes.In addition,a 33% reduction in burr height and a 15% improvement in surface roughness were observed compared to dry drilling of titanium.

Cooling and lubrication techniques in grinding:A state-of-the-art review,applications,and sustainability assessment

Grinding technology is an essential manufacturing operation,in particular,when a component with a superfinishing and an ultra-resolution is yearned.Meeting the required strict quality checklist with maintaining a high level of productivity and sustainability is a substantive issue.The recent paper outlines the lubrication and cooling technologies and mediums that are used for grinding.Furthermore,it provides a basis for a critical assessment of the different lubrication/cooling techniques in terms of machining outputs,environmental impact,hygiene effect,etc.Meanwhile,the paper put light on the sustainability of different cooling/lubrication strategies.The sustainability of machining aims to get the product with the best accuracy and surface quality,minimum energy consumption,low environmental impact,reasonable economy,and minimum effect on worker’s health.The paper revealed that despite some cooling/lubrication mediums like mineral oils and semisynthetic,afford sufficient lubrication or cooling,they have a significant negative impact on the environment and public health.On the other hand,emulsions can overcome environmental problems but the economy and the energy consumption during grinding are still a matter of concern.Biodegradable and vegetable oils are considered eco-friendly oils,but they suffer from a lack of thermal stability which affects their ability of efficiently cooling.Using the cooling medium with the lowest amount can achieve the goal of the economy but it may be reflected negatively on the machinability.Furthermore,cryogenic lubrication doesn’t provide sufficient lubrication to reduce friction and hence energy consumption.The research described in the paper is such a comprehensive compilation of knowledge regarding the machinability and machining performance under different cooling and lubrication systems that it will aid the next generation of scientists in identifying current advancements as well as potential future directions of research on ecological aspects of machining for sustainability.

Tribological Behavior of TiAl-Multilayer Graphene-Ag Composites at Different Temperatures and Sliding Speeds

Tribological behavior of TiAl-multilayer graphene-Ag composites （TMACs） prepared by spark plasma sin- tering against a Si3N4 ball was investigated on a ball-on-disk high-temperature tribometer at different test temperatures and sliding speeds in this study. The test results showed that TMACs had the lower friction coefficient and less wear rate at 450 ℃-0.25 m/s, which was attributed to the formation of the high-strength and intact tribofilms on worn surface. At 450 ℃-0.25 m/s, during the sliding process, multilayer graphene （MLG） was ground out to form the high-strength skeletons on the wom surface of TMACs. Ag was migrated from the worn surface and combined with the MLG skeleton to form the high-strength and intact tribofilms. The high-strength and intact tribofilms were beneficial to lowering the friction coefficient for the lubricating effect of Ag and decreasing wear rate for the enhancing effect of MLG skeleton.

Tribological properties of M0S_(2) coating for ultra-long wear-life and low coefficient of friction combined with additive g-C3N4 in air

The solid lubricant M0S_(2) demonstrates excellent lubricating properties,but it spontaneously oxidizes and absorbs moisture in air,and thus results in poor wear resistance and short wear-life.In this study,the additive g-C_(3)N_(4)(CN)was successfully combined with M0S_(2) via hydrothermal synthesis as a solid lubricant for the first time.Meanwhile,a low friction coefficient(COF,y=0.031)and ultra-long wear-life of CN/M0S_(2) compared to pure M0S_(2) in air were demonstrated.The functional groups and good crystallinity of the lubricant material were characterized via Fourier transform infrared(FTIR)spectroscopy and X-ray diffraction(XRD).The formed valence states in CN/M0S_(2) were analyzed via X-ray photoelectron spectroscopy(XPS).The characterized results of the scanning electron microscopy(SEM)and high-resolution transmission electron microscopy(HRTEM)show the morphology and interior crystal phase structure of CN/M0S_(2).From the cross-section analysis,the presence of iron oxide nanoparticles lubricating film is synergistic with CN/M0S_(2) film during the friction process,resulting in its ultra-long wear-life.In particular,the friction mechanism of interlayer sliding friction combined with energy storage friction was analyzed and proposed.

Influence of graphene nanoplatelets on mechanical properties and adhesive wear performance of epoxy-based composites

Epoxy resin is one of the most widely used thermoset polymers in high-performance composite materials for lightweight applications.However,epoxy has a high coefficient of friction,which limits its tribological applications.In this study,the effect was investigated of different weight fractions of solid lubricant graphene nanoplatelets(GNPs),ranging from 0 to 4.5 wt%,on mechanical and adhesive wear performance of epoxy.Adhesive wear tests covered mild and severe wear regimes.The correlation of tribological and mechanical properties was studied as well.Scanning electron microscopy(SEM)was used to observe the failure mechanisms for both tribological and mechanical samples after each test.The results revealed that the addition of GNPs to the epoxy improved its stiffness and hardness but reduced its fracture strength and toughness.Adhesive wear performance exhibited high efficiency with GNP additions and showed reductions in the specific wear rate,the coefficient of friction,and the induced interface temperature by 76%,37%,and 22%,respectively.A fatigue wear mechanism was predominant as the applied load increased.Most importantly,severe wear signs occurred when the interface temperature reached the heat distortion temperature of the epoxy.The tribological,and mechanical properties showed only a weak correlation to each other.The addition of GNPs to epoxy by less than 4.5 wt%was highly efficient to improve the wear performance while maintaining the fracture strength and toughness.Fourier transform infrared spectroscopy(FTIR)analysis shows no chemical interaction between the epoxy matrix with GNPs,which implies its physical interaction.

Tribological properties of transition metal di-chalcogenide based lubricant coatings

Transition metal di-chalcogenides MX2 （X= S, Se, Te; and M = W, Mo, Nb, Ta） are one kind of solid lubricant materials that have been widely used in industry. The lubricant properties of such lubricant coatings are dependent not only on microstructure, orientation, morphology, and composition of the coatings, but also on the substrate, the interface between substrate and lubricant coatings, and the specific application environment. In this review, the effects of parameters on tribological properties of such kind of lubricant coatings were summarized. By comparing advantages and disadvantages of those coatings, the special treatments such as doping, structural modulation and post-treatment were suggested, aiming to improve the tribologicai performance under severe test conditions （e.g. high temperature, oxidizing atmosphere or humid condition）.

Novel design and composition optimization of self-lubricating functionally graded cemented tungsten carbide cutting tool material for dry machining

The functionally graded cemented tungsten carbide (FGCC) is a suitable material choice for cutting tool applications due to balanced hardness and fracture toughness.The presence of cobalt and CaF2 composition gradient in FGCC may enhance mechanical as well as antifriction properties.Therefore,structural design of selflubricating FGCC was proposed using Power law composition gradient model and thermal residual stresses (TRSs) as a key parameter.Wherein,S.Suresh and A.Mortensen model was adopted for estimation of TRS,and optimum composition gradient was identified at Power law exponent n =2.The designed material displayed compressive and tensile TRS at surface and core respectively;subsequently fabricated by spark plasma sintering and characterized via scanning electron microscope (SEM),indentation method.The agreement between experimental and analytical values of TRS demonstrated the effectiveness of intended design model in the composition optimization of self-lubricating FGCC.This work will be helpful in implementation of dry machining for clean and green manufacturing.

Lubrication of dry sliding metallic contacts by chemically prepared functionalized graphitic nanoparticles

Understanding the mechanism of precision sliding contacts with thin, adherent solid nano lubricating particle films is important to improve friction and wear behavior and ensure mechanical devices have long service lifetimes. Herein, a facile and multistep approach for the preparation of graphene oxide (GO) is presented. Subsequently, surface modification of as-synthesized GO with octadecyl amine (ODA) is performed to prepare hydrophobic GO-ODA and with 6-amino-4-hydroxy-2-naphthalenesulfonic acid (ANS) to prepare amphoteric GO-ANS through a nucleophilic addition reaction. X-ray diffraction and ultraviolet-visible, Fourier transform infrared, and Raman spectroscopy provide significant information about the reduction of oxygen functionalities on GO and the introduction of new functionalities in GO-ODA and GO-ANS. The effects of particle functionalization for the improved control of particle adhesion to the tribocontact have been studied. Wettability and thermal stability were determined using the water contact angle, and atomic force microscopy and differential scanning calorimetry (DSC) were used to characterize particle adhesion to the tribocontact. The tribological performances of the particles have been investigated using macro- and micro-tribometry using pin/ball-on-disc contact geometries. The influence of particle functionalization on the contact pressure and sliding velocity was also studied under rotating and reciprocating tribo-contact in ambient conditions. With an increase in the contact pressure, the functionalized particles are pushed down into the contact, and they adhere to the substrate to form a continuous film that eventually reduces friction. Amphoteric GO-ANS provides the lowest and most steady coefficient of friction (COF) under all tested conditions along with low wear depth and minimal plastic deformation. This is because particles with superior wetting and thermal properties can have better adherence to and stability on the surface. GO-ANS has a superior ability to adhere on the track to form a thicker and more continuous film at the interface, which is investigated by field emission scanning electron microscopy, energy dispersive spectroscopy, and Raman analysis.

Tribological behavior of magnetron sputtering CrMoN/MoS_2 composite coatings

CrMoN composite coatings were deposited on the surface of the stainless steel by magnetron sputtering, then were treated by low temperature ion sulfuration. FESEM equipped with EDX was adopted to analyze the morphologies and compositions of the surface, cross-section and worn scar of the sulfuration layer. The valence states of the film surface were detected by XPS. The nano-hardness and nano-modulus of the layer were measured by a nano tester. The results of the friction and wear show that the CrMoN/MoS2 composite coating is a kind of ideal solid lubrication layer and possess an excellent antifriction and wear-resistance.