Preparation and Mechanical Properties of Solid-phase Grafting Nanocomposites of PVC/Graft Copolymers/MMT

In order to improve the mechanical properties of PVC, by solid-phase grafting reaction, grafting on and nano-modifying the PVC process synchronously, acrylic monomers not only graft on PVC, but also are intercalated into the layers of MMT in the heating process. Blending PVC and the MMT-PVC grafting copolymers , we can get nanocomposites of PVC/ grafters/ MMT, and the mechanical performance of the material is improved.

Comparison of selective flocculation of low grade goethitic iron ore fines using natural and synthetic polymers and a graft copolymer

This study aims to beneficiate low grade goethitic iron ore fines using a selective flocculation process. Selective flocculation studies were conducted using different polymers such as starch amylopectin(AP), poly acrylic acid(PAA), and a graft copolymer(AP-g-PAA). The obtained results were analyzed; they indicate the enhancement of the iron ore grade from 58.49% to 67.52% using AP-g-PAA with a recovery of 95.08%. In addition, 64.45% Fe with a recovery of 88.79% was obtained using AP. Similarly, using PAA, the grade increased to 63.46% Fe with a recovery of 82.10%. The findings are also supported by characterizing concentrates using X-ray diffraction(XRD) and electron probe microanalysis(EPMA) techniques.

SYNTHESIS AND CHARACTERIZATION OF AMPHIPHILIC GRAFT COPOLYMER CONTAINING MICROPHASE SEPARATED AND LONG POLY(ETHYLENE OXIDE) SIDE CHAIN STRUCTURES

Acryloyl terminated Poly (ethyleneoxide)macromonomers (PEO-A) with different PEO chain lengths have been prepared by deactivation of PEO alkoxide with acryloyl chloride. A new kind of amphiphilic polystyrene-g-poly (ethylene oxide)graft copolymer containing both microphase separated and PEO side chain structures has been synthesized from radical copolymerization of PEO-A macromonomer with styrene. After careful purification by a newly-developed method called 'selective dissolution', the well-defined structure of the purified copolymers was confirmed by IR, ~1H-NMR and GPC. Various experimental parameters controlling the copolymerization were studied in detail. The results indicated that the feed ratio of styrene to macromonomer(S/M) was the most important determining factor for the composition of the copolymers. A detailed 'comb- model' was proposed to describe the molecular structure of the graft copolymers. Finally, this amphiphilic graft copolymers may readily form microphase separated structures as clearly indicated by transmission electron microscopy.

SYNTHESIS AND CHARACTERIZATION OF GRAFT COPOLYMERS BASED ON POLY(p-PHENYLENE TEREPHTHALAMIDE) BACKBONE AND WELL-DEFINED POLYSTYRENE SIDE CHAINS

A novel dualfunctional monomer, 2-（2＇,2＇,6＇,6＇-tetramethyl-piperidinyl-1＇-oxy）methylbenzene-1,4-dioyl chloride hydrochloride, with two acid chloride groups for step-growth polymerization and a nitroxide group for the mediation of living radical polymerization was synthesized. It was first copolymerized with terephthaloyl chloride and p- phenylenediamine at a feed molar ratio of 1：3：4 in N-methyl-2-pyrrolidone containing 10 wt% calcium chloride at -10℃ to yield a poly（p-phenylene terephthalamide） based macroinitiator, which initiated radical polymerization of styrene at 125℃ to obtain a series of poly（p-phenylene terephthalamide）-g-polystyrenes. A combinatory analysis of proton nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, elementary analysis, thermogravimetry and gel permeation chromatography indicated that the macroinitiator induced the radical polymerization of styrene to proceed in a well- controlled way. The molecular weight of side-chains increased with an increase of monomer conversion, and the molecular weight distribution index remained lower than 1.5. The graft copolymers showed a remarkably improved solubility in N- methyl-2-pyrrolidone and much depressed crystallinity in bulk.

Surface Photografting of Novel Sulfobetaine Copolymers on Silica

A couple of novel sulfobetaine copolymer is developed via Michael-type addition reaction. The comonomers, diamines and maleimide react via Michael reaction through UV irradiation using AIBN as photoinitiator producing polyamine chain. Further, sulfobetaine copolymers were obtained on treatment of the polyamine with sulfopropylating agent, 1,3-propane sultone. These novel sulfobetaine polymers were grafted on silica surface to produce responsive biocompatible surface. This easy straightforward, catalyst free facile protocol for synthesis of polymer grafted surface is useful for developing biomedical devices. Additionally, both the copolymers show fluorescence characteristics.

Synthesis and Characterization of Degraded Gelatin Grafted Poly(ε-caprolactone) Copolymers

Hydrophilic degraded gelatin was modified with hydrophobic poly(ε-caprolactone) (PCL) via a chemical grafting route.Firstly,PCL with one hydroxyl end group was prepared by the ring-opening polymerization of εcaprolactone (ε-CL) with tin (Ⅱ) 2-ethylhexanoate as catalyst and n-butyl alcohol as initiator.Secondly,the PCL reacted with isophorone diisocyanate (IPDI) to prepare PCL with isocyanate functional group (PCL-NCO).Hydroxylamine was used to degrade gelatin by the cleavage between asparagine and glycine residues of gelatin.PCL-NCO reacted with the hydroxyl/amino groups of degraded gelatin in a homogeneous system and yielded the PCL modified gelatin copolymers.The gelatin grafted PCL copolymers were measured by means of XRD,FTIR,DSC and 1 H NMR.The results confirmed the conjugation of PCL onto gelatin chains.The PCL modified gelatin can be used as biomaterials owing to their biocompatibility and biodegradation.

Self-assembly of block copolymers grafted onto a flat substrate:Recent progress in theory and simulations

Block copolymers are a class of soft matter that self-assemble to form ordered morphologies on the scale of nanome- ters, making them ideal materials for various applications. These applications directly depend on the shape and size of the self-assembled morphologies, and hence, a high degree of control over the self-assembly is desired. Grafting block copolymer chains onto a substrate to form copolymer brushes is a versatile method to fabricate functional surfaces. Such surfaces demonstrate a response to their environment, i.e., they change their surface topography in response to different external conditions. Furthermore, such surfaces may possess nanoscale patterns, which are important for some applica- tions; however, such patterns may not form with spun-cast films under the same condition. In this review, we summarize the recent progress of the self-assembly of block copolymers grafted onto a flat substrate. We mainly concentrate on the self-assembled morphologies of end-grafted AB dibloek eopolymers, junction p0int-grafted AB diblock copolymers （i.e., Y-shaped brushes）, and end-grafted ABA triblock copolymers. Special emphasis is placed on theoretical and simulation progress.

SYNTHESIS AND CHARACTERIZATION OF REACTIVE GRAFT COPOLYMER PDMS-g-(PEO-OH)

A new reactive graft copolymer, poly (dimethyl siloxane)-graft-omega-hydroxyl-poly (ethylene oxide) (PDMS-g-(PEO-OH)), was synthesized by the hydrosilylation reaction of alpha, omega-bifunctional PEO macromonomer (CH2=CH-CH2-PEO-OH) with poly (hydromethylsiloxane) (PHMS). The obtained copolymer, exhibited the expected comblike structure as indicated by the result of detailed characterization and the needed reactivity as demonstrated by the result of esterification between PDMS-g-(PEO-OH) and aminoacetic acid. This reactive graft copolymer is expected to be very useful in the preparation of new bioactive polymer materials.

STUDY ON DYNAMIC MECHANICAL BEHAVIOUR OF POLY BUTYLACRYLATE GRAFT VINYL CHLORIDE COPOLYMERS

Dynamic mechanical behaviours of PVC ho-mopolymer. poly butylacryiate (PBA ) graft vinylchloride copolymers and blend of PVC and ACR have been investigated. The results reveal that there is semicompatible nature in the two phases in these materials,that the compatibility of the two phases decrease, -with the increase of crosslinking density of PBA backbone in graft copolyers. For different copolymer types-PB A graft copolymers had better compatibility of the two phases compared ivith the graft copolymers 晈ith core/shell backbone poly-

CHARACTERIZATION OF AMPHIPHILIC AND MICROPHASE SEPARATED GRAFT COPOLYMERS Ⅱ SURFACE CHARACTERIZATION AND IN VITRO BLOOD-COMPATIBILITY ASSESSMENT OF POLYSTYRENE-GRAFT-ω-STEARYLPOLY (ETHYLENE OXIDE)

This paper reported the research results concerning the surface characterization ofpolystyrene-graft-w-stearyl poly(ethylene oxide) (PS-g-SPEO) by means of XPS,contactangle measurement and TEM, and its in vitro blood compatibility assessment by measuringthe plasma recalcification time (RT) and partial thromboplastin time (PTT). The XPSresults demonstrated that the surface and bulk composition of the PS-g-SPEO graftcopolymers differ remarkably from each other,and that SPEO component was constantlyenriched at the copolymer/air interface. Contact angle studies indicated that the surfacewater wettability can be adjusted effectively by changing the composition of the copolymer.PS-g-SPEO graft copolymers can undergo microphase separation as clearly illustrated byTEM photographs. The relationship between the surface properties of PS-g-SPEO graftcopolymer and its blood compatibility was also discussed.

SYNTHESIS OF AN AMPHIPHILIC PPESK-g-P(PEGMA)GRAFT COPOLYMER VIA ATRP AND ITS USE IN BLEND MODIFICATION OF PPESK MEMBRANES

Preparation of an amphiphilic graft copolymer having poly(phthalazinone ether sulfone ketone)(PPESK) as main chains was carried out by atom transfer radical polymerization(ATRP).The precursor,chloromethylated PPESK (CMPPESK),was prepared by using chioromethylether as chloromethylation agent.Then,poly(ethylene glycol) methyl ether methacrylate(PEGMA) was used as monomer to synthesize PPESK-g-P(PEGMA) by ATRP method under the catalysis of a cuprous chloride/2,2'-bipyridyl system.PPESK/PPESK-g-P(PEGMA) blend m...

Synthesis, Purification and Characterization of Amphiphilic and Microphase Separated Graft Copolymer Polystyrene-g-Poly(ethylene oxide)

The present paper covers the poly (ethylene oxide) macromer with vinyl benzyl terminal group (PEO-VB) prepared by deactivation of the alkoxide function of mono-functional 'living' PEO chains with vinyl benzyl chloride (VBC). The obtained macromers were subjected to careful purification and detailed characterization. A new kind of amphiphilic polystyrene-g-poly(ethylene oxide) (PS-g-PEO) with both mi-crophase separated and PEO side chains was synthesized from radical copolymerization of PEO-VB macromer with styrene monomer. An improved purification method, referred as 'selective dissolvation', was established for the isolation of graft copolymers from the grafting products, and the purity and yield of the purified copolymers were satisfactory. The well-defined structure of the purified copolymers was confirmed by IR, 1H NMR and GPC. The bulk composition of the graft copolymers was determined by a well-established first derivative UV spectrometry. Various experimental parameters controlling the copolymerization were also studied. The results indicate that the feed ratio of macromer to styrene (M/S) was the most important factor in determining the composition of the copolymers. Thus a series of PS-g-PEO with a wide range of bulk compositions were obtained simply by adjusting the value of M/S. As clearly indicated by transmission electron microscopy, this amphiphilic graft copolymers may readily form microphase separated structures.

Grafting Maleic Anhydride onto Carbon Fiber via a Solid-phase Grafting Method

By combining the strong and light carbon fibers （CFs） with polymers, composite materials with extraordinary mechanical properties are achieved. However, the mechanical properties of the as-prepared CF-reinforced polymer composites can not satisfy the applications in certain fields, especially for the poor interactions between CFs and the polymers. To enhance the mechanical properties of composite materials, a solid phase grafting method has been developed to improve the adhesion forces between CFs and the polymer, by modifying the surfaces of CFs. The effects of the reaction temperature, reaction time, as well as the dosage of the initiator and maleic anhydride （MAH） on the grafting efficiency have been investigated systematically. The structure and the surface chemistry of functionalized CFs have been characterized by Fourier Transform Infrared （FT-IR）, Scanning Electron Microscope （SEM）, X-ray Photoelectron Spectroscopy （XPS）, Thermogravimetric （TG）, and contact angle test. All of these results demonstrate that MAH is grafted onto the surface of CFs successfully by the solid phase grafting method. The MAH grafted CFs significantly improve its wettability, which further improves the interfacial adhesion between CFs and the polymeric matrix. The optimal reaction conditions are determined, such as the MAH/CF molar ratio, the dosage of initiator, the reaction temperature and the reaction time to be 3/1, 2%, 90℃ and 4 h, respectively. These attractive interracial characteristics of modified CFs suggest that the method proposed herein is a novel and efficient approach to develop CF-reinforced polymer composites with outstanding mechanical properties for cutting-edge industrial applications.

Design and comparative in-vitro and in-vivo evaluation of starch-acrylate graft copolymer based salbutamol sulphate sustained release tablets

The present work deals with the development of controlled release tablets of salbutamol sulphate(SS)using graft copolymers of methyl methacrylate(St-g-PMMA and Ast-g-PMMA)on starch and acetylated starch.Formulations were evaluated for physical characteristics like hardness,friability,drug release,drug content and weight variations,which fulfilled all the official requirements of tablet dosage form.The release rates from formulated matrix tablets were studied at SGF(pH 1.2)followed by SIF(pH 6.8).Drug release from the graft copolymer based tablets was found to be sustained upto the 14 h with>75%drug release.The in-vitro release study showed that the graft copolymer based matrix formulations(F3&F4)exhibited highest correlation value(r2)for higuchi kinetic model and Korsmeyer's model with n values between 0.61 and 0.67 proved that release mechanisms were governed by both diffusion and erosion mechanism.There was no significant difference in the pharmacokinetic parameters(tmax,Cmax,AUC,Ke,and t1/2)of the graft copolymers matrices and HPMC K100M matrix tablets,indicating their comparable sustained release effect.The potential of graft copolymers to sustain the drug release is well supported by in-vivo pharmacokinetic studies and their adequate physicochemical properties make them promising excipients for controlled drug delivery system.

The Optimized Synthesis of Starch-g-Lactic Acid Copolymer with High Grafting Degree Catalyzed by Sulfuric Acid

The starch-g-lactic acid copolymer was synthesized with catalysis of sulfuric acid by onestep process, and the structure of starch-g-lactic acid copolymer was characterized by means of IR, 13C-NMR, HMBC, XRD, and SEM. The experimental results show that the maximum grafting degree of starch can reach 75% when the starch-g-lactic acid copolymer is activated at 80 ℃ for 2 h and reacted with lactic acid at 90 ℃ for 4 h in vacuum.

CHARACTERIZATION OF RADIATION GRAFT COPOLYMER OF INORGANIC COMPOUND ONTO ALKENE

In this paper, the radiation graft copolymer of MgO, SiO2 and-Y- molecularsieve onto organic compounds, such as methacrylate, styrene and acrylonitrile obtained by per-rndiation method were characterized by X- ray diffraction, pyrolysis gas chromatography, GPC and X-ray photoelectron spectroscopy.

SYNTHESIS OF A COMB GRAFT COPOLYMER VIA RING OPENING METATHESIS POLYMERIZATION CATALYZED BY SUPPORTED RHUTHENIUM CARBENE COMPLEX

Chloromethyl-2-norbornene was synthesized via Diels-Alder reaction of cyclopentadiene and allyl chloride using a polymer supported boron trifluoride as the catalyst, and was then lithiated and used to initiate a living anionic polymerization of styrene to prepare a macromonome, 5-polystyryl-2-norbornene NBPS. Comb graft copolymer PNBgPS was synthesized via ring opening metathesis polymerization of the macromonomer under the catalysis of ruthenium carbene complex RuCl2(PPh3)2(=CCHtBu) and its polymer supported correspondent. Experimental results showed that the behavior of both the supported boron and supported ruthenium catalysts are superior to their unsupported counterparts. The possible promotion mechanism of the tailor-made supports is discussed.

Surface Graft Copolymerization of Acrylic Acid onto Corona Treated Cotton Fabric

Acrylic acid was grafted onto the surface of cotton fabric after being short time treated by corona-discharge inair in the presence of initiator.The means of gas-phaseSO2 derivatization was used along with ESCA to deter-mine corona-discharge-induced-hydroperoxidegroups on the surface.The content of hydroperoxideshows a maxmium value at 15 sec.of corona-dischargetime.Effect of corona treatment time and various con-centration initlator on graft yield was studied.The addit-ion of initiator increases the graft yield.Acceleratedgraft with an increase in the concentration of Mohr’s saltshows that peroxide groups on the corona treated cottonfabric initiate graft copolymerization.

An Approach to the Flame Retardancy of EVA Copolymer by Plasma Treatmentc2

An attempt was made in the paper aiming at imparting flame retardancy to polymers by plasma grafting technique Based on EVA copolymers with different VA contents the author tried to use the Ar plasma followed by grafting with/without subsequent saponification and metal ion exchange expediting the charring of polymers upon heationg Characterization of the flammability of the plasma treated EVA copolymers grafted with acrylic monomers(MAA,AA and AAm)indicates that this approach turns out to be a promising way and worthy doing whatever in research and/or applications

Synthesis and characterization of star-comb styrene/butadiene copolymer

A novel star-comb styrene/butadiene copolymer（SC-SBC） was synthesized by anionic polymerization and grafting reaction with epoxidized star liquid polybutadiene（ESPB） as coupling agent.The overall shape of the star-comb macromolecules can be altered by changing the molecular weight and number of the side chain.The molecular parameters and mechanical properties of the SC-SBC resins were investigated.The notched izod impact strength of the SC-SBC resins are excellent and reach as high as to 239 J/m.