Oxidation Kinetics of Aluminum Powders in a Gas Fluidized Bed Reactor in the Potential Application of Surge Arresting Materials

In this technical paper, the oxidation mechanism and kinetics of aluminum powders are discussed in great details. The potential applications of spherical aluminum powders after oxidation to be part of the surging arresting materials are discussed. Theoretical calculations of oxidation of spherical aluminum powders in a typical gas fluidization bed are demonstrated. Computer software written by the author is used to carry out the basic calculations of important parameters of a gas fluidization bed at different temperatures. A mathematical model of the dynamic system in a gas fluidization bed is developed and the analytical solution is obtained. The mathematical model can be used to estimate aluminum oxide thickness at a defined temperature. The mathematical model created in this study is evaluated and confirmed consistently with the experimental results on a gas fluidization bed. Detail technical discussion of the oxidation mechanism of aluminum is carried out. The mathematical deviations of the mathematical modeling have demonstrated in great details. This mathematical model developed in this study and validated with experimental results can bring a great value for the quantitative analysis of a gas fluidization bed in general from a theoretical point of view. It can be applied for the oxidation not only for aluminum spherical powders, but also for other spherical metal powders. The mathematical model developed can further enhance the applications of gas fluidization technology. In addition to the development of mathematical modeling of a gas fluidization bed reactor, the formation of oxide film through diffusion on both planar and spherical aluminum surfaces is analyzed through a thorough mathematical deviation using diffusion theory and Laplace transformation. The dominant defects and their impact to oxidation of aluminum are also discussed in detail. The well-controlled oxidation film on spherical metal powders such as aluminum and other metal spherical powders can potentially become an important part of switch devices of surge arresting materials, in general.

Molecular Dynamics, Physical Properties, Diffusion Coefficients and Activation Energy of the Lithium Oxide (Li-O) and Sodium Oxide (Na-O) Electrolyte (Cathode)

This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied a gap-free model using molecular dynamics. Physical quantities such as volume and pressure of the Na-O and Li-O systems exhibit similar behaviors around the thermodynamic ensembles NPT and NVE. However, for the Na2O system, at a minimum temperature value, we observe a range of total energy values;in contrast, for the Li2O system, a minimum energy corresponds to a range of temperatures. Finally, for physicochemical properties, we studied the diffusion coefficient and activation energy of lithium and potassium oxides around their melting temperatures. The order of magnitude of the diffusion coefficients is given by the relation Dli-O >DNa-O for the multiplicity 8*8*8, while for the activation energy, the order is well reversed EaNa-O > EaLi-O.

Regularization Method to the Parameter Identification of Interfacial Heat Transfer Coefficient and Properties during Casting Solidification

The accurate material physical properties, initial and boundary conditions are indispensable to the numerical simulation in the casting process, and they are related to the simulation accuracy directly. The inverse heat conduction method can be used to identify the mentioned above parameters based on the temperature measurement data. This paper presented a new inverse method according to Tikhonov regularization theory. A regularization functional was established and the regularization parameter was deduced, the Newton-Raphson iteration method was used to solve the equations. One detailed case was solved to identify the thermal conductivity and specific heat of sand mold and interfacial heat transfer coefficient (IHTC) at the meantime. This indicates that the regularization method is very efficient in decreasing the sensitivity to the temperature measurement data, overcoming the ill-posedness of the inverse heat conduction problem (IHCP) and improving the stability and accuracy of the results. As a general inverse method, it can be used to identify not only the material physical properties but also the initial and boundary conditions' parameters.

Distributed Lagrange Multiplier/Fictitious Domain Finite Element Method for a Transient Stokes Interface Problem with Jump Coefficients

The distributed Lagrange multiplier/fictitious domain(DLM/FD)-mixed finite element method is developed and analyzed in this paper for a transient Stokes interface problem with jump coefficients.The semi-and fully discrete DLM/FD-mixed finite element scheme are developed for the first time for this problem with a moving interface,where the arbitrary Lagrangian-Eulerian(ALE)technique is employed to deal with the moving and immersed subdomain.Stability and optimal convergence properties are obtained for both schemes.Numerical experiments are carried out for different scenarios of jump coefficients,and all theoretical results are validated.

变系数三阶周期边值问题的正解(英文)

研究了变系数非线性三阶周期边值问题的正解.非线性项可以关于空间变元奇异.利用适当的变换此问题被转换为一个Hammerstein积分方程,利用锥上的Guo-Krasno-selski不动点定理获得了1～2个正解的存在性.

Determination of Natural Logarithm of Diffusion Coefficient and Activation Energy of Thin Layer Drying Process of Ginger Rhizome Slices

This study is an extension of the previous work done with ARS-680 Environmental Chamber. Drying is a complex operation that demands much energy and time. Drying is essentially important for preservation of ginger rhizome. Drying of ginger was modeled, and then the effective diffusion coefficient and activation energy were determined. For this purpose, the experiments were done at six levels of varied temperatures: 10°C, 20°C, 30°C, 40°C, 50°C and 60°C. The values of effective diffusion coefficients obtained in this work for the variously treated ginger rhizomes closely agreed with the average effective diffusion coefficients of other notable authors who determined the drying kinetics and convective heat transfer coefficients of ginger slices.

基于实验的数值反演的滚动轮胎稳态温度场的有限元分析

根据轮胎温度场的单向解耦分析思想,形成了一个基于ABAQUS程序的轮胎稳态温度场的分析方法,单向解耦过程分为变形、损耗、热传导三个分析过程。变形分析中,采用了平衡态的超弹性材料模型;损耗分析中,依据变形分析获得的应力应变场,结合材料粘性损耗特性来获得损耗能量;热传导分析中,依据实测的轮胎胎侧温度场,提出了一种基于实验的数值反演方法来确定胎侧的对流热边界条件。由于轮胎胎侧的形状和结构细节,其对流热边界不同于旋转平圆盘的对流热边界,本文的数值反演方法避免了实测胎侧对流热交换系数的困难。

Combined value of apparent diffusion coefficient-standardized uptake value max in evaluation of post-treated locally advanced rectal cancer

AIM:To assess the clinical diagnostic value of functional imaging,combining quantitative parameters of apparent diffusion coefficient(ADC) and standardized uptake value(SUV)max,before and after chemo-radiation therapy,in prediction of tumor response of patients with rectal cancer,related to tumor regression grade at histology.METHODS:A total of 31 patients with biopsy proven diagnosis of rectal carcinoma were enrolled in our study.All patients underwent a whole body ^(18)FDG positron emission tomography(PET)/computed tomography(CT) scan and a pelvic magnetic resonance(MR)examination including diffusion weighted(DW) imaging for staging(PET1,RM1) and after completion(6.6 wk)of neoadjuvant treatment(PET2,RM2).Subsequently all patients underwent total mesorectal excision and the histological results were compared with imaging findings.The MR scanning,performed on 1.5 T magnet(Philips,Achieva),included T2-weighted multiplanar imaging and in addition DW images with b-value of 0 and 1000 mm^2/s.On PET/CT the SUVmax of the rectal lesion were calculated in PET1 and PET2.The percentage decrease of SUVmax(△SUV) and ADC(△ADC) values from baseline to presurgical scan were assessed and correlated with pathologic response classified as tumor regression grade(Mandard's criteria;TRG1 = complete regression,TRG5 = no regression).RESULTS:After completion of therapy,all the patients were submitted to surgery.According to the Mandard's criteria,22 tumors showed complete(TRG1) or subtotal regression(TRG2) and were classified as responders;9tumors were classified as non responders(TRG3,4 and5).Considering all patients the mean values of SUVmax in PET 1 was higher than the mean value of SUVmax in PET 2(P < 0.001),whereas the mean ADC values was lower in RM1 than RM2(P < 0.001),with a △SUV and △ADC respectively of 60.2%and 66.8%.The best predictors for TRG response were SUV2(threshold of4.4) and ADC2(1.29 × 10^(-3) mm^2/s) with high sensitivity and specificity.Combining in a single analysis both the obtained median value,the positive predictive value,in predicting the different group category response in related to TRG system,presented R^2 of 0.95.CONCLUSION:The functional imaging combining ADC and SUVmax in a single analysis permits to detect changes in cellular tissue structures useful for the assessment of tumour response after the neoadjuvant therapy in rectal cancer,increasing the sensitivity in correct depiction of treatment response than either method alone.

Advantages of rapid solidification over casting of Mg-0.4Zn-1Y alloy

The Mg-Y-Zn magnesium alloy system is commonly recognized for its remarkable combination of high strength and ductility,achieved even with minimal amounts of alloying elements.This exceptional performance is attributed to its unique microstructure,which includes Long-Period Stacking Ordered(LPSO)phases or the distinctive microstructure derived from the LPSO phase,referred to as the Mille-Feuille structure(MFS).This study systematically compares the traditional ingot metallurgy method with the rapid solidification technique,coupled with diverse heat treatments and extrusion processes.Microscopic analyses reveal variations in the presence of LPSO phases,Mille-Feuille structure,and grain size,leading to divergent mechanical and corrosion properties.The rapid solidification approach stands out,ensuring superior mechanical properties alongside a reasonable corrosion rate.

数学模型在二元复配杀螨剂最优配比筛选中的应用

采用共毒系数法对复配剂的最优配比进行筛选可能会造成真正最优配比的漏筛,且工作量很大,具有局限性。以朱砂叶螨为试虫,分别对甲氰菊酯、阿维菌素、氯氰菊酯、三氯杀螨醇、氧化乐果、甲氰·阿维、氯氰·三杀和氧乐·甲氰进行毒力测定并对复配剂共毒系数Y进行计算。将甲氰菊酯、氯氰菊酯和氧化乐果在各自复配剂有效成分中的质量分数k进行反正弦转换(X=arcsin(k)1/2),通过SPSS软件拟合k反正弦转换值与共毒系数的数学模型。甲氰·阿维、氯氰·三杀和氧乐·甲氰的数学模型为Y1=-30179.08+769.24X1-4.8472X21;Y2=-251.53+32.34X2-0.6858X22;Y3=-7066.96+266.06X3-2.4267X23。对上述的3个方程进行求导可得:Y1′=769.24-9.6944X1;Y2′=32.34-1.3716X2;Y3′=266.06-4.8534X3。令Y′=0,则有X1=79.34;X2=23.58;X3=54.82。将X1、X2和X3值分别代入各自的方程可以求得甲氰·阿维、氯氰·三杀和氧乐·甲氰复配剂的最大共毒系数分别为340.09、129.71和225.65,将X1、X2和X3值代入X=arcsin(K)1/2中可以求得各单剂在复配剂有效成分中的质量分数k值,根据k值可以求得:甲氰菊酯和阿维菌素的最优配比为28∶1;辛硫磷和啶虫脒的最优配比为1∶5.25;三唑磷和杀虫单最优配比为2∶1。

Lunar In Situ Large-Scale Construction:Quantitative Evaluation of Regolith Solidification Techniques

Lunar habitat construction is crucial for successful lunar exploration missions.Due to the limitations of transportation conditions,extensive global research has been conducted on lunar in situ material processing techniques in recent years.The aim of this paper is to provide a comprehensive review,precise classification,and quantitative evaluation of these approaches,focusing specifically on four main approaches:reaction solidification(RS),sintering/melting(SM),bonding solidification(BS),and confinement formation(CF).Eight key indicators have been identified for the construction of low-cost and highperformance systems to assess the feasibility of these methods:in situ material ratio,curing temperature,curing time,implementation conditions,compressive strength,tensile strength,curing dimensions,and environmental adaptability.The scoring thresholds are determined by comparing the construction requirements with the actual capabilities.Among the evaluated methods,regolith bagging has emerged as a promising option due to its high in situ material ratio,low time requirement,lack of hightemperature requirements,and minimal shortcomings,with only the compressive strength falling below the neutral score.The compressive strength still maintains a value of 2–3 MPa.The proposed construction scheme utilizing regolith bags offers numerous advantages,including rapid and large-scale construction,ensured tensile strength,and reduced reliance on equipment and energy.In this study,guidelines for evaluating regolith solidification techniques are provided,and directions for improvement are offered.The proposed lunar habitat design based on regolith bags is a practical reference for future research.

Molecular Dynamics, Diffusion Coefficients and Activation Energy of the Electrolyte (Anode) in Lithium (Li and Li+), Sodium (Na and Na+) and Potassium (K and K+)

This work is a simulation modelling with the LAMMPS calculation code of an electrode based on alkali metals (lithium, sodium and potassium) using the MEAM potential. For different multiplicities, two models were studied;with and without gap. In this work, we present the structural, physical and chemical properties of the lithium, sodium and potassium electrodes. For the structural properties, the cohesive energy and the mesh parameters were calculated, revealing that, whatever the chemical element selected, the compact hexagonal hcp structure is the most stable, followed by the face-centred cubic CFC structure, and finally the BCC structure. The most stable structure is lithium, with a cohesion energy of -6570 eV, and the lowest bcc-hcp transition energy of -0.553 eV/atom, followed by sodium. For physical properties, kinetic and potential energies were calculated for each of the sectioned chemical elements, with lithium achieving the highest value. Finally, for the chemical properties, we studied the diffusion coefficient and the activation energy. Only potassium followed an opposite order to the other two, with the quantities with lacunae being greater than those without lacunae, whatever the multiplicity. The order of magnitude of the diffusion coefficients is given by the relationship DLi > DNa > Dk for the multiplicity 6*6*6, while for the activation energy the order is reversed.

Determination of Potential Runoff Coefficient Using GIS and Remote Sensing

Flash floods in arid environments are a major hazard feature to human and to the infrastructure. Shortage of accurate environmental data is main reason for inaccurate prediction of flash flooding characteristics. The curve number (CN) is a hydrologic number used to describe the storm water runoff potential for drainage area. This study introduces an approach to determine runoff coefficient in Jeddah, Saudi Arabia using remote sensing and GIS. Remote sensing and geographic information system techniques were used to obtain and prepare input data for hydrologic model. The land cover map was derived using maximum likelihood classification of a SPOT image. The soil properties (texture and permeability) were derived using the soil maps published my ministry of water and agriculture in Saudi Arabia. These soil parameters were used to classify the soil map into hydrological soil groups (HSG). Using the derived information within the hydrological modelling system, the runoff depth was predicted for an assumed severe storm scenario. The advantages of the proposed approach are simplicity, less input data, one software used for all steps, and its ability to be applied for any site. The results show that the runoff depth is directly proportional to runoff coefficient and the total volume of runoff is more than 136 million cubic meters for a rainfall of 103.6 mm.

Application of Equality Test of Coefficients of Variation to the Heteroskedasticity Test

The presence of heteroskedasticity in a considered regression model may bias the standard deviations of parameters obtained by the Ordinary Least Square (OLS) method. In this case, several hypothesis tests on the model under consideration may be biased, for example, CHOW’s coefficient stability test (or structural change test), Student’s t-test and Fisher’s F-test. Most of the heteroscedasticity tests in the literature are based on the comparison of variances. Despite the multiplication of equality tests of coefficients of variation (CVs) that have appeared in the literature, to our knowledge, the first and only use of the coefficient of variation in the detection of heteroskedasticity was offered by Li and Yao in 2017. Thus, this paper offers an approach to determine the existence of heteroskedasticity by a test of equality of coefficients of variation. We verify by a Monte Carlo robustness and performance test that our method seems even better than some tests in the literature. The results of this study contribute to the exploitation of the statistical measurement of CV dispersion. They help technicians economists to better verify their hypotheses before making a scientific decision when making a necessary forecast, in order to contribute effectively to the economic and sustainable development of a company or enterprise.

Adaptive Random Effects/Coefficients Modeling

Adaptive fractional polynomial modeling of general correlated outcomes is formulated to address nonlinearity in means, variances/dispersions, and correlations. Means and variances/dispersions are modeled using generalized linear models in fixed effects/coefficients. Correlations are modeled using random effects/coefficients. Nonlinearity is addressed using power transforms of primary (untransformed) predictors. Parameter estimation is based on extended linear mixed modeling generalizing both generalized estimating equations and linear mixed modeling. Models are evaluated using likelihood cross-validation (LCV) scores and are generated adaptively using a heuristic search controlled by LCV scores. Cases covered include linear, Poisson, logistic, exponential, and discrete regression of correlated continuous, count/rate, dichotomous, positive continuous, and discrete numeric outcomes treated as normally, Poisson, Bernoulli, exponentially, and discrete numerically distributed, respectively. Example analyses are also generated for these five cases to compare adaptive random effects/coefficients modeling of correlated outcomes to previously developed adaptive modeling based on directly specified covariance structures. Adaptive random effects/coefficients modeling substantially outperforms direct covariance modeling in the linear, exponential, and discrete regression example analyses. It generates equivalent results in the logistic regression example analyses and it is substantially outperformed in the Poisson regression case. Random effects/coefficients modeling of correlated outcomes can provide substantial improvements in model selection compared to directly specified covariance modeling. However, directly specified covariance modeling can generate competitive or substantially better results in some cases while usually requiring less computation time.

Identification of the Diffusion Coefficients of Pollutants ( N O 3 - and Mn2+) through the Walls of Concrete Tank and Vulnerability of the Stored Water Quality

The populations of urban centers in Congo-Brazzaville have decided to develop various methods of water storage (concrete or masonry underground tanks) for domestic use, due to shortages in the distribution of water through the public network. However, questions remain as to the physico-chemical quality of the water stored in these tanks, when these structures are built in wet and relatively polluted areas. This paper presents a model of pollutant diffusion through the cementitious matrix (concrete) of tank walls simulated at a buried reservoir. The results of the experimental and numerical simulations show that certain concrete parameters, such as porosity, permeability and diffusivity, have a significant influence on the transfer of pollutants through the concrete walls, thus altering the physico-chemical quality of the stored water. The numerical models (1D) used to predict pollutant transfer and the quality of the stored water are consistent with those of the optimal control for identifying the diffusion coefficient. Major ion concentrations appear to be correlated with system porosity and diffusion coefficient. Nevertheless, the identification of the diffusion coefficient from the optimal control method, based on an explicit numerical resolution of a finite volume PDE for the approximation of the experiment, is not consistent with that of the optimal control method.

水平井射孔完井表皮系数分解计算方法

近井地带的表皮系数是评价油气井产能和完井效率的重要参数。由不稳定试井法确定的表皮系数,是一个既包括钻井液、完井液对近井地带储层污染与堵塞的影响,又包括钻井、完井的不完善和增产措施影响的总表皮系数,不能评价某一施工环节的好坏。针对完井施工过程中如何计算各表皮系数以引导完井现场施工的问题,提出了一种新的分解计算水平井表皮系数的方法,即:将水平井总表皮系数分解为打开程度表皮系数Spt、射孔总表皮系数Spf、钻井污染表皮系数Sd方法,并反推出各分项表皮系数的计算方法。它无需压力恢复曲线或压降曲线,仅利用DST数据即可计算。通过DST测试资料预测油井各施工环节的污染情况,以便选择最佳的钻井、完井方法以及优化完井参数并用于指导初期增产施工。

矿渣MTC固化体开裂的本质原因分析

矿渣MTC固化体高温下易开裂问题一直限制着矿渣MTC技术的推广应用,文章对影响固化体开裂的宏观因素:温度、压力、浆体pH值等进行了实验研究分析。通过X射线衍射、扫描电镜等分析手段找到了固化体开裂的本质原因在于高温条件下矿渣水化反应速度加快,其玻璃体分相结构中富钙相的分解速度加快,体系中Ca(OH)2 增加较多,而富硅相解体反应的变化幅度不大,体系中SiO2 则相对较少,反映在固化体局部区域中,C-S-H凝胶体不仅C/S增大且分布不均匀且由于该部分水化产物呈球形和蜂窝形,胶结时接触面积少,形成的凝胶体胶结差,不稳定,易发生晶形转变,宏观上表现为固化体容易形成裂纹。

Adhesion coefficient of automobile tire and road surface

The adhesion coefficient of automobile tire and road surface was analyzed and the formula about it was derived.Some suggestions about highway construction,driving safety of the drivers and the judgment of the traffic accidents were presented.The results show that the adhesion coefficient is a function with the extreme value.If there is atmospheric pressure in the tire,the load of the vehicle and the degree of the coarse on the road surface is not selected properly,it will reach the least and affect the safety of the running automobile.

Volume-averaged modeling of multiphase solidification with equiaxed crystal sedimentation in a steel ingot

Macrosegregation is a critical factor that limits the mechanical properties of materials.The impact of equiaxed crystal sedimentation on macrosegregation has been extensively studied,as it plays a significant role in determining the distribution of alloying elements and impurities within a material.To improve macrosegregation in steel connecting shafts,a multiphase solidification model that couples melt flow,heat transfer,microstructure evolution,and solute transport was established based on the volume-averaged Eulerian-Eulerian approach.In this model,the effects of liquid phase,equiaxed crystals,columnar dendrites,and columnar-to-equiaxed transition(CET)during solidification and evolution of microstructure can be considered simultaneously.The sedimentation of equiaxed crystals contributes to negative macrosegregation,where regions between columnar dendrites and equiaxed crystals undergo significant A-type positive macrosegregation due to the CET.Additionally,noticeable positive macrosegregation occurs in the area of final solidification in the ingot.The improvement in macrosegregation is beneficial for enhancing the mechanical properties of connecting shafts.To mitigate the thermal convection of molten steel resulting from excessive superheating,reducing the superheating during casting without employing external fields or altering the design of the ingot mold is indeed an effective approach to control macrosegregation.