As the structure of electrical double layer(EDL)is crucial for the transport properties of ions in micro/nanochannels,to demonstrate the effects of the ion-ion correlations on EDL structures in mixture electrolyte sol...As the structure of electrical double layer(EDL)is crucial for the transport properties of ions in micro/nanochannels,to demonstrate the effects of the ion-ion correlations on EDL structures in mixture electrolyte solutions,the interaction forces between two mica surfaces immersed in different volume fractions of LaCl3/KCl and LaCl3/MgCl2 mixture solutions with a total ionic strength of 10^-4 mol/L were measured using a surface forces apparatus(SFA).The results reveal that the surface charge of mica surfaces can be inversed at a critical concentration of La^3+ions in electrolyte solutions,due to the correlations between La^3+ions.The addition of monovalent has negligible effects on ion-ion correlations,while the charge inversion was slightly suppressed by introducing the divalent ions.The mechanism of charge inversion in mixture electrolyte solutions was analyzed based on the strongly correlated liquid(SCL)theory.These findings provide implications for understanding the effects of ion-ion correlations on EDL structures,surface charge properties,and ion transportation.展开更多
Weight lost method was used to comparatively study the corrosion behavior of four different metals under the dosage of chlorine dioxide, chlorine and their mixture respectively. The experimental results indicated that...Weight lost method was used to comparatively study the corrosion behavior of four different metals under the dosage of chlorine dioxide, chlorine and their mixture respectively. The experimental results indicated that chlorine causes the most serious corrosion of carbon steel, and the higher the concentration of chlorine, the more serious the corrosion. On the contrary, metals corrosion is the least serious in the case of chlorine dioxide. The results further revealed that chlorine dioxide is the most effective water treatment reagent, making it the best choice to use extensively in circulated cooling water disinfection and corrosion control.展开更多
基金The National Natural Science Foundation of China(No.51605090)the Natural Science Foundation of Jiangsu Province(No.BK20160776,BK20160670)Research Foundation of Nanjing Institute of Technology(No.YKJ201502)。
文摘As the structure of electrical double layer(EDL)is crucial for the transport properties of ions in micro/nanochannels,to demonstrate the effects of the ion-ion correlations on EDL structures in mixture electrolyte solutions,the interaction forces between two mica surfaces immersed in different volume fractions of LaCl3/KCl and LaCl3/MgCl2 mixture solutions with a total ionic strength of 10^-4 mol/L were measured using a surface forces apparatus(SFA).The results reveal that the surface charge of mica surfaces can be inversed at a critical concentration of La^3+ions in electrolyte solutions,due to the correlations between La^3+ions.The addition of monovalent has negligible effects on ion-ion correlations,while the charge inversion was slightly suppressed by introducing the divalent ions.The mechanism of charge inversion in mixture electrolyte solutions was analyzed based on the strongly correlated liquid(SCL)theory.These findings provide implications for understanding the effects of ion-ion correlations on EDL structures,surface charge properties,and ion transportation.
文摘Weight lost method was used to comparatively study the corrosion behavior of four different metals under the dosage of chlorine dioxide, chlorine and their mixture respectively. The experimental results indicated that chlorine causes the most serious corrosion of carbon steel, and the higher the concentration of chlorine, the more serious the corrosion. On the contrary, metals corrosion is the least serious in the case of chlorine dioxide. The results further revealed that chlorine dioxide is the most effective water treatment reagent, making it the best choice to use extensively in circulated cooling water disinfection and corrosion control.
