An accurate numerical simulation for wave equations is essential for understanding of wave propagation in the earth's interior as well as full waveform inversion and reverse time migration. However, due to computa...An accurate numerical simulation for wave equations is essential for understanding of wave propagation in the earth's interior as well as full waveform inversion and reverse time migration. However, due to computational cost and hardware capability limitations, numerical simulations are often performed within a finite domain. Thus, an adequate absorbing boundary condition (ABC) is indispensable for obtaining accurate numerical simulation results. In this study, we develop a hybrid ABC based on a transmitting boundary, which is referred to as THABC, to eliminate artificial boundary reflections in 3D second-order fractional viscoacoustic numerical simulations. Furthermore, we propose an adaptive weighted coefficient to reconcile the transmitting and viscoacoustic wavefields in THABC. Through several numerical examples, we determine that the proposed THABC approach is characterized by the following benefits. First, with the same number of absorbing layers, THABC exhibits a better ability in eliminating boundary reflection than traditional ABC schemes. Second, THABC is more effective in computation, since it only requires the wavefields at the current and last time steps to solve the transmitting formula within the absorbing layers. Benefiting from a simple but effective combination between the transmitting equation and the second-order wave equation, our scheme performs well in the 3D fractional Laplacian viscoacoustic numerical simulation.展开更多
Objective:To build the database of the absorbed fractions(AFs)and specific absorbed fractions(SAFs),in order to accurately assess the internal radiation dose in non-human biota.Methods:A voxel-based Portunus haanii ph...Objective:To build the database of the absorbed fractions(AFs)and specific absorbed fractions(SAFs),in order to accurately assess the internal radiation dose in non-human biota.Methods:A voxel-based Portunus haanii phantom was established based on the computed tomography(CT)images.A set of AFs and SAFs were calculated with Monte Carlo toolkit Geant4 for the emission of monoenergetic photons and electrons with energies ranging from 10 keV to 5 MeV.Results:The mass of the voxel-based Portunus haanii phantom(392.2 g)was in agreement with the actual mass(389.2 g),indicating the reliability of the phantom.The calculated AFs and SAFs,based on the voxel-based Portunus haanii phantom,provided precise and reliable data for conducting internal radiation dose calculations specifically tailored to the Chinese Red Swimming Crab(Portunus haanii).The results indicated that the self-AFs and self-SAFs were affected by both the radiation energy and the mass of the source/target organ.Moreover,the AFs and SAFs for cross irradiation,were not only dependent on the energy and the mass of the target organ,but also on the relative position of the source and target organs.Conclusion:These results serve as a valuable resource for accurately evaluating the internal radiation exposure of this species.展开更多
With XAD-series and ion exchange resins, dissolved organic matter (DOM) from Lake Hongfeng in Southwestern China Plateau was isolated into 6 fractions, i.e., humic acid (HA), fulvic acid (FA), hydrophobic neutra...With XAD-series and ion exchange resins, dissolved organic matter (DOM) from Lake Hongfeng in Southwestern China Plateau was isolated into 6 fractions, i.e., humic acid (HA), fulvic acid (FA), hydrophobic neutrals (HON), hydrophilic acids (HIA), hydrophilic bases (HIB) and hydrophilic neutrals (HIN). Those fractions were characterized by high performance size exclusion chromatography, fluorescence spectroscopy and UV absorbance. Among the 6 fractions, FA was predominant and accounted for 51% of the total DOM. The weight-average (Mw) and number-averaged (Mn) molecular weight of these fractions ranged from 1688 to 2355 Da and from 1338 to 1928 Da, respectively. A strong correlation was observed between specific UV absorbance at 280 nm, E2/E3 (absorbance at 250 nm to 365 nm), and the molecular weight for DOM fractions. UV-Vis fulvic-like fluorescence peaks were found in all fractions. Proteinlike fluorescence peaks existed in HON may indicate that microbial activity was severely in Lake Hongfeng. There was a significant relationship between fluorescence intensities and specific UV absorbance at 254 nm for those DOM fractions, suggesting their similar luminescence characteristics. The values of fluorescence index (f450/500) indicated that hydrophobic fractions may derive from terrestrial sources, and the hydrophilic fractions from microbial and terrestrial origins. Those results suggest that there were inter-relationships between molecular weight, fluorescence and absorbance characteristics, and also subtle consistencies between the hydrophilic and hydrophobic properties and the sources for these 6 fractions from Lake Hongfeng.展开更多
Thirteen fractions from the pathogenic plant fungus Setosphaeria turcica race 1 were separated and collected using high performance liquid chromatography (HPLC). Their toxic activities were assayed through leaf punc...Thirteen fractions from the pathogenic plant fungus Setosphaeria turcica race 1 were separated and collected using high performance liquid chromatography (HPLC). Their toxic activities were assayed through leaf puncturing on corn differentials (OH43, OH43Ht1, OH43Ht2, and OH43HtN), and the results revealed that eight fractions were toxic and fraction 6 was specifically toxic to OH43Ht1, which could be taken as a gene-selective toxin fraction. Fraction 6 was finely purified via HPLC and condensed by freeze desiccation. Its chemical structure was analyzed with EI-MS, IR, HMBC, ^1H-NMR, and two-dimensional NMR. The results suggested that fraction 6 contained an unsaturated double bond, carbonyl and methylene groups with molecular weight of 142.展开更多
Several task-specific ionic liquids(TSILs) with weak alkalinity have been designed based on tetraalkyl-ammonium cation and L-alanine anion([N<sub>2222</sub>][L-Ala]) for the CO<sub>2</sub> ab...Several task-specific ionic liquids(TSILs) with weak alkalinity have been designed based on tetraalkyl-ammonium cation and L-alanine anion([N<sub>2222</sub>][L-Ala]) for the CO<sub>2</sub> absorption.[N<sub>2222</sub>][L-Ala]has been chosen as a green and efficient activator for methyldiethanolamine(MDEA).The densities,viscosities and absorption properties of the equimolar[N<sub>2222</sub>][L-Ala]-MDEA blended absorbents were investigated.Low viscosity and density values support the idea that blended absorbents are preferred in the industrial applications.[N<sub>2222</sub>][L-Ala]-MDEA behave similarly to the aqueous counterparts but offer more advantages,such as large absorption capacities,fast absorption rate and relatively low damage to the environment.展开更多
The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of ...The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of <2μm clay size fraction isolated from 13 source rock cores collected from Dongying depression.Rock-Eval pyrolysis and N2 adsorption experiment were employed to probe the characteristics of OM and SSA(denoted SBET)in samples before and after OM extraction using trichloromethane.The results indicate that various kinds of OM occurrence coexist in clay size fraction and their contributions to hydrocarbon are different in each period of OM evolution.The occurrence and amount of OM affect the S BET of clay size fraction,and a nonlinear negative correlation between total organic carbon(TOC)and S BET can be recognized.The soluble OM(chloroform extract "A"),mainly stored in the pore space of clay size fraction,shows a negative correlation in amount with S BET.Our data also indicate that free hydrocarbon(S1)was stored mainly in the pore space and/or the surface of clay size fraction,whereas pyrolysis hydrocarbon(S2)was mingled mainly with clay minerals.Therefore,to understand various OM occurrences and their relationship with SBET in the clay size fraction is significant in the study of generation,accumulation,and migration of hydrocarbon in muddy source rock.展开更多
Aims accurate remote estimation of the fraction of absorbed photosynthetically active radiation(fAPAR)is essential for the light use efficiency(LUE)models.Currently,one challenge for the LUE models is lack of knowledg...Aims accurate remote estimation of the fraction of absorbed photosynthetically active radiation(fAPAR)is essential for the light use efficiency(LUE)models.Currently,one challenge for the LUE models is lack of knowledge about the relationship between fAPAR and the normalized difference vegetation index(NDVI).Few studies have tested this relationship against field measurements and evaluated the accuracy of the remote estimation method.this study aimed to reveal the empirical relationship between NDVI and fAPAR and to improve algorithms for remote estimation of fAPAR.Methods to investigate the method of remote estimation of fAPAR seasonal dynamics,the CASA(Carnegie-ames-stanford approach)model and spectral vegetation indices(VIs)were used for in situ measure-ments of spectral reflectance and fAPAR during the growing season of a maize canopy in Northeast China.Important Findingsthe results showed that the fAPAR increased rapidly with the day of year during the vegetative stage,it remained relatively stable at the stage of reproduction,and finally decreased slowly during the senescence stage.In addition,fAPAR green[fAPAR_(green)=fAPAR_(green) -fAPAR_(green) LAI_(max))]showed clearer seasonal trends than fAPAR.the NDVI,red-edge NDVI,wide dynamic range vegetation index,red-edge position(REP)and REP with sentinel-2 bands derived from hyperspectral remote sensing data were all significantly positively related to fAPAR green during the entire growing season.In a comparison of the predictive performance of VIs for the whole growing season,REP was the most appropriate spectral index,and can be recommended for monitoring seasonal dynamics of fAPAR in a maize canopy.展开更多
基金National Natural Science Foundation of China under Grant Nos.41930431 and 41974116Natural Science Foundation of Heilongjiang Province No.YQ2021D008CNPC Innovation Found No.2021DQ02-0302 for supporting this work.
文摘An accurate numerical simulation for wave equations is essential for understanding of wave propagation in the earth's interior as well as full waveform inversion and reverse time migration. However, due to computational cost and hardware capability limitations, numerical simulations are often performed within a finite domain. Thus, an adequate absorbing boundary condition (ABC) is indispensable for obtaining accurate numerical simulation results. In this study, we develop a hybrid ABC based on a transmitting boundary, which is referred to as THABC, to eliminate artificial boundary reflections in 3D second-order fractional viscoacoustic numerical simulations. Furthermore, we propose an adaptive weighted coefficient to reconcile the transmitting and viscoacoustic wavefields in THABC. Through several numerical examples, we determine that the proposed THABC approach is characterized by the following benefits. First, with the same number of absorbing layers, THABC exhibits a better ability in eliminating boundary reflection than traditional ABC schemes. Second, THABC is more effective in computation, since it only requires the wavefields at the current and last time steps to solve the transmitting formula within the absorbing layers. Benefiting from a simple but effective combination between the transmitting equation and the second-order wave equation, our scheme performs well in the 3D fractional Laplacian viscoacoustic numerical simulation.
基金funded by National Natural Science Foundation of China(11905106)the Fundamental Research Funds for the Central Universities(30921013110)+1 种基金Provincial Ecological Environment Research Project of Jiangsu(2022017)the Graduate student scientific research innovation projects in Jiangsu province(SJCX22_0118),China.
文摘Objective:To build the database of the absorbed fractions(AFs)and specific absorbed fractions(SAFs),in order to accurately assess the internal radiation dose in non-human biota.Methods:A voxel-based Portunus haanii phantom was established based on the computed tomography(CT)images.A set of AFs and SAFs were calculated with Monte Carlo toolkit Geant4 for the emission of monoenergetic photons and electrons with energies ranging from 10 keV to 5 MeV.Results:The mass of the voxel-based Portunus haanii phantom(392.2 g)was in agreement with the actual mass(389.2 g),indicating the reliability of the phantom.The calculated AFs and SAFs,based on the voxel-based Portunus haanii phantom,provided precise and reliable data for conducting internal radiation dose calculations specifically tailored to the Chinese Red Swimming Crab(Portunus haanii).The results indicated that the self-AFs and self-SAFs were affected by both the radiation energy and the mass of the source/target organ.Moreover,the AFs and SAFs for cross irradiation,were not only dependent on the energy and the mass of the target organ,but also on the relative position of the source and target organs.Conclusion:These results serve as a valuable resource for accurately evaluating the internal radiation exposure of this species.
基金supported by the China’s Na-tional Basic Research Program (No. 2008CB418200)the National Knowledge Innovation Program of Chinese Academy of Sciences (No. kzcx2-yw-102)the Nation-al Natural Science Foundation of China (No. U0833603,40873079, 40703022).
文摘With XAD-series and ion exchange resins, dissolved organic matter (DOM) from Lake Hongfeng in Southwestern China Plateau was isolated into 6 fractions, i.e., humic acid (HA), fulvic acid (FA), hydrophobic neutrals (HON), hydrophilic acids (HIA), hydrophilic bases (HIB) and hydrophilic neutrals (HIN). Those fractions were characterized by high performance size exclusion chromatography, fluorescence spectroscopy and UV absorbance. Among the 6 fractions, FA was predominant and accounted for 51% of the total DOM. The weight-average (Mw) and number-averaged (Mn) molecular weight of these fractions ranged from 1688 to 2355 Da and from 1338 to 1928 Da, respectively. A strong correlation was observed between specific UV absorbance at 280 nm, E2/E3 (absorbance at 250 nm to 365 nm), and the molecular weight for DOM fractions. UV-Vis fulvic-like fluorescence peaks were found in all fractions. Proteinlike fluorescence peaks existed in HON may indicate that microbial activity was severely in Lake Hongfeng. There was a significant relationship between fluorescence intensities and specific UV absorbance at 254 nm for those DOM fractions, suggesting their similar luminescence characteristics. The values of fluorescence index (f450/500) indicated that hydrophobic fractions may derive from terrestrial sources, and the hydrophilic fractions from microbial and terrestrial origins. Those results suggest that there were inter-relationships between molecular weight, fluorescence and absorbance characteristics, and also subtle consistencies between the hydrophilic and hydrophobic properties and the sources for these 6 fractions from Lake Hongfeng.
基金supported by National Excellent Teacher's Plan,Ministry of Education,China and Natural Science Foundation of Hebei Province,China(302318).
文摘Thirteen fractions from the pathogenic plant fungus Setosphaeria turcica race 1 were separated and collected using high performance liquid chromatography (HPLC). Their toxic activities were assayed through leaf puncturing on corn differentials (OH43, OH43Ht1, OH43Ht2, and OH43HtN), and the results revealed that eight fractions were toxic and fraction 6 was specifically toxic to OH43Ht1, which could be taken as a gene-selective toxin fraction. Fraction 6 was finely purified via HPLC and condensed by freeze desiccation. Its chemical structure was analyzed with EI-MS, IR, HMBC, ^1H-NMR, and two-dimensional NMR. The results suggested that fraction 6 contained an unsaturated double bond, carbonyl and methylene groups with molecular weight of 142.
基金supported by the National Natural Science Foundation (21076101)Technological Support Project of Jiangsu Province(SBE 201000600)
文摘Several task-specific ionic liquids(TSILs) with weak alkalinity have been designed based on tetraalkyl-ammonium cation and L-alanine anion([N<sub>2222</sub>][L-Ala]) for the CO<sub>2</sub> absorption.[N<sub>2222</sub>][L-Ala]has been chosen as a green and efficient activator for methyldiethanolamine(MDEA).The densities,viscosities and absorption properties of the equimolar[N<sub>2222</sub>][L-Ala]-MDEA blended absorbents were investigated.Low viscosity and density values support the idea that blended absorbents are preferred in the industrial applications.[N<sub>2222</sub>][L-Ala]-MDEA behave similarly to the aqueous counterparts but offer more advantages,such as large absorption capacities,fast absorption rate and relatively low damage to the environment.
基金supported by National Natural Science Foundation of China (Grant No. 41072089)National Oil and Gas Special Fund (Grant No.2011ZX05006-001)Program of the State Key Laboratory of Oil-gas of Petroleum University (Beijing) (Grant No. P08026)
文摘The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of <2μm clay size fraction isolated from 13 source rock cores collected from Dongying depression.Rock-Eval pyrolysis and N2 adsorption experiment were employed to probe the characteristics of OM and SSA(denoted SBET)in samples before and after OM extraction using trichloromethane.The results indicate that various kinds of OM occurrence coexist in clay size fraction and their contributions to hydrocarbon are different in each period of OM evolution.The occurrence and amount of OM affect the S BET of clay size fraction,and a nonlinear negative correlation between total organic carbon(TOC)and S BET can be recognized.The soluble OM(chloroform extract "A"),mainly stored in the pore space of clay size fraction,shows a negative correlation in amount with S BET.Our data also indicate that free hydrocarbon(S1)was stored mainly in the pore space and/or the surface of clay size fraction,whereas pyrolysis hydrocarbon(S2)was mingled mainly with clay minerals.Therefore,to understand various OM occurrences and their relationship with SBET in the clay size fraction is significant in the study of generation,accumulation,and migration of hydrocarbon in muddy source rock.
基金National Natural Science Foundation of China(41330531)the R&D Special Fund for Public Welfare Industry(Meteorology)Project(GYHY201106027)the State Key Development Program of Basic Research(2010CB951303).
文摘Aims accurate remote estimation of the fraction of absorbed photosynthetically active radiation(fAPAR)is essential for the light use efficiency(LUE)models.Currently,one challenge for the LUE models is lack of knowledge about the relationship between fAPAR and the normalized difference vegetation index(NDVI).Few studies have tested this relationship against field measurements and evaluated the accuracy of the remote estimation method.this study aimed to reveal the empirical relationship between NDVI and fAPAR and to improve algorithms for remote estimation of fAPAR.Methods to investigate the method of remote estimation of fAPAR seasonal dynamics,the CASA(Carnegie-ames-stanford approach)model and spectral vegetation indices(VIs)were used for in situ measure-ments of spectral reflectance and fAPAR during the growing season of a maize canopy in Northeast China.Important Findingsthe results showed that the fAPAR increased rapidly with the day of year during the vegetative stage,it remained relatively stable at the stage of reproduction,and finally decreased slowly during the senescence stage.In addition,fAPAR green[fAPAR_(green)=fAPAR_(green) -fAPAR_(green) LAI_(max))]showed clearer seasonal trends than fAPAR.the NDVI,red-edge NDVI,wide dynamic range vegetation index,red-edge position(REP)and REP with sentinel-2 bands derived from hyperspectral remote sensing data were all significantly positively related to fAPAR green during the entire growing season.In a comparison of the predictive performance of VIs for the whole growing season,REP was the most appropriate spectral index,and can be recommended for monitoring seasonal dynamics of fAPAR in a maize canopy.