Balmer H_α,H_β and H_γ Spectral Lines Intensities in High-Power RF Hydrogen Plasmas

Hα（Balmer-alpha）, Hβ （Balmer-beta） and Hγ （Balmer-gamma） spectral line inten- sities in atomic hydrogen plasma are investigated by using a high-power RF source. The intensities of the Hα, Hβ and Hγ spectral lines are detected by increasing the input power （0-6 kW） of ICPs （inductively coupled plasmas）. With the increase of net input power, the intensity of Hα im- proves rapidly （0-2 kW）, and then reaches its dynamic equilibrium; the intensities of Hβ can be divided into three processes： obvious increase （0-2 kW）, rapid increase （2-4 kW）, almost constant （4-6 kW）; while the intensities of Hγ increase very slowly. The energy levels of the excited hydro- gen atoms and the splitting energy levels produced by an obvious Stark effect play an important role in the results.

Extreme ultraviolet and soft x-ray spectral lines in Rb ⅩⅩⅨ

An extensive theoretical set of atomic data for Rb XXIX in a wide range with L-shell electron excitations to the M-shell has been reported. We have computed energy levels for the lowest 113 fine structure levels of Rb XXIX. The fully relativistic multiconfigurational Dirac-Fock method （MCDF） within the framework of Dirac-Coulomb Hamiltonian taking quantum electrodynamics （QED） and Breit corrections into account has been adopted for calculations. Radiative data are reported for electric dipole （El）, magnetic dipole （MI）, electric quadrupole （E2）, and magnetic quadrupole （M2） transitions from the ground level, although calculations have been performed for a much larger number of levels. To assess the accuracy of results, we performed analogous calculations using flexible atomic code （FAC）. Comparisons are made with existing available results and a good agreement has been achieved. Most of the wavelengths calculated lie in the soft x-ray （SXR） region. Lifetimes for all 113 levels have also been provided for the first time. Additionally, we have provided the spectra for allowed transitions from n = 2 to n = 3 within the x-ray region and also compared our SXR photon wavelengths with experimentally recognized wavelengths. We hope that our results will be beneficial in fusion plasma research and astrophysical applications.

Saturated absorption spectrum of cesium micrometric-thin cell with suppressed crossover spectral lines

Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimentally study the saturated absorption spectra using a 100-μm cesium MC,where the pump and probe beams are linearly polarized with mutually perpendicular polarizations,and the magnetic field is along the pump beam.Because of the distinctive thin chamber of the MC,crossover spectral lines in saturated absorption spectra are largely suppressed leading to clear splittings of hyperfine Zeeman transitions in experiments,and the effect of spatial magnetic field gradient is expected to be reduced.A calculation method is proposed to achieve good agreements between theoretical calculations and experimental results.This method successfully explains the suppression of crossover lines in MCs,as well as the effects of magnetic field direction,propagation and polarization directions of the pump/probe beam on saturated absorption spectrum.The saturated absorption spectrum with suppressed crossover lines is used for laser frequency stabilization,which may provide the potential value of MCs for high spatial resolution strong-field magnetometry with high sensitivity.

Effect of Characteristic Spectral Lines on Rock Identification of LIBS

The LIBS （Laser induced-breakdown spectroscopy） combined with BPNN （Back propagation neural network） was applied in rock sorting and distinguishing for 26 rock samples of 6 types. According to contents of major elements in samples, we selected lines of Si, Al, Fe, K, Ca, Mg, Na, Ti and Mn. These lines of 9 elements composed three characteristic spectral models which were the WSLM （Wide spectral line model）, the PM （Peak model） and the PRM （Peak ratio model）. The first and the second characteristic spectral model were divided into 9 kinds, as follows： the characteristic spectrum with 1 element, the characteristic spectrum with 2 elements, we can deduce the rest from this and the last one has 9 elements. The third model was divided into 8 kinds which were using AI as reference element. We analysed spectrums of the three models by BPNN. Experimental results shown that whether sorting or distinguishing these samples, identification accuracies of the PM were more than that of the PRM overall, the same as the WSLM did to the PM. While the selected number of elements was 5, 6 or 7, the identification accuracy of the WSLM could reach more than 90%. Continuing to add the number of elements to improve identification accuracy was not very obvious.

Intensities and shifts of Lyman and Balmer lines of hydrogen-like ions in high density plasmas

The spectral line intensities and line shifts of Lyman and Balmer series for transitions up to n=5 of hydrogen-like ion are studied in plasmas with densities and temperatures in the ranges n_(c)~10^(18)-10^(21)cm^(-3),T_(e)=0.3e1.2 eV respectively.The screened potential used to describe the interaction between charged particles includes the electron exchange-correlation and finite-temperature gradient effects and is valid for both weakly and strongly coupled plasmas.The dependencies of alpha,beta and gamma line shifts of Lyman and Balmer series on plasma density(for fixed temperature)and temperature(for fixed density)are investigated.The results for the H_(a)line shifts are compared with the available high-density experimental data.

Degenerate cascade fluorescence: Optical spectral-line narrowing via a single microwave cavity

For a three-level atom, two nondegenerate(even microwave and optical) electric dipole transitions are usually allowed;for either of these, the fluorescence spectra are well-described in terms of spontaneous transitions from a triplet of dressed sublevels to an adjacent lower-lying triplet. When the three dressed sublevels are equally spaced from each other, a remarkable feature known as degenerate cascade fluorescence takes place, which displays a five-peaked structure. We show that a single cavity can make all the spectral lines extremely narrow, whether they arise from cavity-coupled or cavity-free transitions. This effect is based on intrinsic cascade lasing feedback and makes it possible to use a single microwave cavity(even a bad cavity) to narrow the spectral lines in the optical frequency regime.

Humidity-Induced Spectral Shift in a Cross-DispersionEchelle Spectrometer and Its Theoretical Investigation

The relationship between ambient relative humidity H and the position shift of a spectral line was investigated both experimentally and theoretically.An echelle-based ICP emission spectrometer equipped with a CID detector was used for experimental verification of the derived model.The shift of a spectral line is quantitatively described by two defined spectral shift functions: Δλx(x,λ,H)(in the x direction of the CID detector) and Δλy(y,λ,H)(in the y direction of the CID detector).Experimental results indicate that Δλx(x,λ,H) does not change with a variation in ambient relative humidity, but Δλy(y,λ,H) does.A spectral shift equation,i.e.an empirical second-order polynomial equation,can be used to describe the relationship between Δλy(y,λ,H) and H.Based on the classical dipole model,classical mechanics and electrodynamics the empirical spectral-shift equation involving Δλy(y,λ,H) and H was theoretically deduced.The theoretical result is in good agreement with the experimental findings.The theoretical results indicate that the coefficients of the empirical spectral-shift equation are related to the basic physical parameters of materials and the geometric configuration of the echelle CID ICP-AES,and also provide physical meaning to the coefficients of the empirical shift equation obtained experimentally.

Stark-Broadened Profiles of the Spectral Line P_α in He Ⅱ Ions

We report a systematic method to perform calculations of spectral line broadening parameters in plasmas. This method is applied to calculate Stark-broadening line profiles of Pα（n = 4 → n = 3） transitions under certain specific plasma conditions, by treating this case as an example. In the framework of the fully relativistic Dirac R- matrix theory, we calculate the electron-impact broadening operators, which are assumed to be diagonal matrix to simplify the situation. The electric microfield distribution function is calculated by retaining Hooper＇s formalism. The dipole matrix elements and atomic structure parameters used in these calculations have been obtained from atomic structure GRASP code. Based on this required data, we calculate the Stark-broadened line profiles of the Paschen spectral lines in He Ⅱ ions in a systematic manner. Overall, there is a very good agreement between our calculated Stark-broadened line profiles and other line Our reported spectral line-broadening data have real also play a fundamental role in plasma modeling. broadening numerical simulation codes （Sire U and MELS）. applications in plasma spectroscopy, plasma diagnosis and

Gridless Variational Bayesian Inference of Line Spectral from Quantized Samples

Efficient estimation of line spectral from quantized samples is of significant importance in information theory and signal processing,e.g.,channel estimation in energy efficient massive MIMO systems and direction of arrival estimation.The goal of this paper is to recover the line spectral as well as its corresponding parameters including the model order,frequencies and amplitudes from heavily quantized samples.To this end,we propose an efficient gridless Bayesian algorithm named VALSE-EP,which is a combination of the high resolution and low complexity gridless variational line spectral estimation(VALSE)and expectation propagation(EP).The basic idea of VALSE-EP is to iteratively approximate the challenging quantized model of line spectral estimation as a sequence of simple pseudo unquantized models,where VALSE is applied.Moreover,to obtain a benchmark of the performance of the proposed algorithm,the Cram′er Rao bound(CRB)is derived.Finally,numerical experiments on both synthetic and real data are performed,demonstrating the near CRB performance of the proposed VALSE-EP for line spectral estimation from quantized samples.

High-level Stark Effect and Spectrum of Spherical Nanometer System

In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.

Plasma Formed in Argon,Acid Nitric and Water Used in Industrial ICP Torches

Inductively coupled plasmas （ICPs） are used in spectrochemical analyses. The introduction of the sample by means of an aerosol are widely used. The introduction and the total evaporation of the aerosol is required in order to obtain a good repeatability and reproducibility of analyses. To check whether the vaporization of the aerosol droplets inside the plasma is completed, a solution could be used to compare the experimental results of the emission spectral lines with theoretical results. An accurate calculation code to obtain monatomic spectral lines intensities is therefore required, which is the purpose of the present paper. The mixtures of argon, water and nitric acid are widely used in spectrochemical analyses with ICPs. With these mixtures, we calculate the composition, thermodynamic functions and monatomic spectral lines intensities of the plasma at thermodynamic equilibrium and at atmospheric pressure. To obtain a self sufficient paper and also to allow other researchers to compare their results, all required data and a robust accurate algorithm, which is simple and easy to compute, are given.

R-branch high-lying transition emission spectra of SbNa molecule

The calculation results of the R-branch transition emission spectra of(0–0) band of the A21 → X21 transition system of Sb Na molecule are presented in this paper. These R-branch high-lying transitional emission spectral lines are predicted by using the difference converging method(DCM). Our results show excellent agreement between DCM spectral lines and the experimental values, and the deviations are controlled within 0.0224 cm-1. What is more, based on the principle of over-determined linear equations, the prediction error is quantified in this work, which provides reliable theoretical support for our predicted DCM calculations. This work provides a lot of useful information for understanding the microstructure of Sb Na molecule.

Balmer-alpha and Balmer-beta Stark line intensity profiles for high-power hydrogen inductively coupled plasmas

We compare Balmer-alpha （Ha） and Balmer-beta （Hβ） emissions from high-power （1.0-6.0 kW） hydrogen inductively coupled plasmas （ICPs）, and propose region Ⅰ （0.0-2.0 kW）, region Ⅱ （2.0-5.0 kW）, and region Ⅲ （5.0-6.0 kW）. In region Ⅰ, both Ha emission intensity （la） and Hβ emission intensity （1β） increase with radio frequency （RF） power, which is explained by the corona model and Boltzmann＇s law, etc. However, in region II, la almost remains constant while 1β rapidly achieves its maximum value. In region Ⅲ, 1α slightly increases with RF power, while 1β decreases with RF power, which deviates significantly from the theoretical explanation for the Ha and Hβ emissions in region I. It is suggested that two strong electric fields are generated in high-power （2.0-6.0 kW） hydrogen ICPs： one is due to the external electric field of high-power RF discharge, and the other one is due to the micro electric field of the ions and electrons around the exited state hydrogen atoms in ICPs. Therefore, the strong Stark effect can play an important role in explaining the experimental results.

Calculation of the Voigt Function in the Region of Very Small Values of the Parameter a Where the Calculation Is Notoriously Difficult

The Voigt function is the convolution of a Lorentzian and a Guaussian density. The computation of these functions is required in several problems arising in a variety of physicochemical subjects;such as nuclear reactors, atmospheric transmittance and spectroscopy. In this work we suggest using a new formula for the calculation of the Voigt function. Our formula is a new integral representation for the Voigt function that gives the perfect results for the Voigt function calculation and is easily calculable. We give also a comparison between our results of calculation of Voigt function for the very small values of the parameter a, where the calculation is notoriously difficult, with those of the various algorithms of other authors.

Electron Spin and Proton Spin in the Hydrogen and Hydrogen-Like Atomic Systems

The mechanical angular momentum and magnetic moment of the electron and proton spin have been calculated semiclassically with the aid of the uncertainty principle for energy and time. The spin effects of both kinds of the elementary particles can be expressed in terms of similar formulae. The quantization of the spin motion has been done on the basis of the old quantum theory. It gives a quantum number n = 1/2 as the index of the spin state acceptable for both the electron and proton particle. In effect of the spin existence the electron motion in the hydrogen atom can be represented as a drift motion accomplished in a combined electric and magnetic field. More than 18,000 spin oscillations accompany one drift circulation performed along the lowest orbit of the Bohr atom. The semiclassical theory developed in the paper has been applied to calculate the doublet separation of the experimentally well-examined D line entering the spectrum of the sodium atom. This separation is found to be much similar to that obtained according to the relativistic old quantum theory.

Absorption linewidth inversion with wavelength modulation spectroscopy

For absorption linewidth inversion with wavelength modulation spectroscopy（WMS）, an optimized WMS spectral line fitting method was demonstrated to infer absorption linewidth effectively, and the analytical expressions for relationships between Lorentzian linewidth and the separations of first harmonic peak-to-valley and second harmonic zero-crossing were deduced. The transition of CO_2 centered at 4991.25 cm^（-1） was used to verify the optimized spectral fitting method and the analytical expressions. Results showed that the optimized spectra fitting method was able to infer absorption accurately and compute more than 10 times faster than the commonly used numerical fitting procedure. The second harmonic zero-crossing separation method calculated an even 6 orders faster than the spectra fitting without losing any accuracy for Lorentzian dominated cases. Additionally, linewidth calculated through second harmonic zero-crossing was preferred for much smaller error than the first harmonic peak-to-valley separation method. The presented analytical expressions can also be used in on-line optical sensing applications, electron paramagnetic resonance, and further theoretical characterization of absorption lineshape.

Optical Emission Spectroscopic Studies of ICP Ar Plasma

The ion line of 434.8 nm and atom line of 419.8 nm of Ar plasma produced by an inductively coupled plasma （ICP） were measured by optical emission spectroscopy and the influences from the working gas pressure, radio-frequency （RF） power and different positions in the discharge chamber on the line intensities were investigated in this study. It was found that the intensity of Ar atom line increased firstly and then saturated with the increase of the pressure. The line intensity of Ar^＋, on the other hand, reached a maximum value and then decreased along with the pressure. The intensity of the line in an RF discharge also demonstrated a jumping mode and a hysteresis phenomenon with the RF power. When the RF power increased to 400 W, the discharge jumped from the E-mode to the H-mode where the line intensity of Ar atom demonstrated a sudden increase, while the intensity of Ar^＋ ion only changed slightly. If the RF power decreased from a high value, e.g., 1000 W, the discharge would jump from the H-mode back to the E-mode at a power of 300 W. At this time the intensities of Ar and Ar^＋ lines would also decrease sharply. It was also noticed in this paper that the intensity of the ion line depended on the detective location in the chamber, namely at the bottom of the chamber the line was more intense than that in the middle of the chamber, but less intense than at the top, which is considered to be related to the capacitance coupling ability of the ICP plasma in different discharge areas.

High-power and high optical conversion efficiency diode-end-pumped laser with multi-segmented Nd：YAG/Nd：YVO-4

A novel flat-flat resonator consisting of two crystals（Nd：YAG ＋ Nd：YVO4） is established for power scaling in a diode-end-pumped solid-state laser. We systematically compare laser characteristics between multi-segmented（Nd：YAG ＋ Nd：YVO4） and conventional composite（Nd：YAG ＋ Nd：YAG） crystals to demonstrate the feasibility of spectral line matching for output power scale-up in end-pumped lasers. A maximum continuous-wave output power of 79.2 W is reported at 1064 nm, with Mx2= 4.82, My2= 5.48, and a pumping power of 136 W in the multi-segmented crystals（Nd：YAG ＋ Nd：YVO4）. Compared to conventional composite crystals（Nd：YAG ＋ Nd：YAG）, the optical-optical conversion efficiency of multi-segmented crystals（Nd：YAG ＋ Nd：YVO4） from 808 nm to 1064 nm is enhanced from 30% to 58.8%,while the laser output sensitivity as affected by the diode-laser temperature is reduced from 55% to 9%.

Flavour and Colour of Quarks in Spin Topological Space

An assumption that all the six flavour quarks are attributed to be the components of a same, a common isospin multiplets space named STS is proposed. Base on Pauli Exclusion Principle, every quark is assigned to different flavour marks in STS. Every flavour quark possesses its own colour spectral line array specially appointed. The collection of colour spectral line arrays of the six flavour quarks constructs together the CSDF, Colour Spectrum Diagram of Flavour, further baryons and mesons could be constructed from CSDF. STS, Spin Topological Space is a math frame with infinite dimensional matrix representation for spin angular momentum. Flavours is an isospin angular momentum coupling phenomena of the three-colour-quarks.

Primary Study on Microarc Oxidation of AZ91D

The magnesium has some excellent properties such as ligh quality, high specific strength and stiffness, high damp and reeoverd easily compared with steel, aluminium, engineering plastic. So the application and exploitation of magnesium arose extensive attention of the public.