Based on the experimental data of KY 3F 10∶Tm 3+ reported by Diaf, K ushida′s spectral overlap model (SOM) of energy transfer between J-multipl ets was studied. Firstly, with the help of the Inokuti-Hirayama an...Based on the experimental data of KY 3F 10∶Tm 3+ reported by Diaf, K ushida′s spectral overlap model (SOM) of energy transfer between J-multipl ets was studied. Firstly, with the help of the Inokuti-Hirayama and Yokota-Tan imoto models, the luminescence decay curve of 3H 4 of Tm 3+ ion was fitted, and the fitted values of corresponding interaction parameters C D A of energy transfer and C DD of energy migration were obtained. Seco ndly, by compared with Kushida′s SOM in which the relevant Judd-Ofelt approxim ative transition rates are known, the average overlap integrals of S DD and S DA were obtained. For S DD, how to treat the contributi on of the electronic-dipole (ED) crystal field transition forbidden by C 4v site symmetry in the calculation of S DD was discussed. For S DA we suggested that, by including the contribution of the phonon sideba nds in the analysis of oscillator strength of transition, Kushida′s SOM of ED- ED resonant energy transfer rate can be extended to non-resonant phonon-assist ed D-A energy transfer. The strengths and widths of phonon sidebands in this ex ample were discussed, and the results were reasonably good.展开更多
The energy migration interaction parameter CDD in high concentration Nd3＋ doped YAG laser crystal was estimated using the Yokota-Tanimoto（Y-T） model and the spectral overlap model（SOM） of Kushida, respectively.Fi...The energy migration interaction parameter CDD in high concentration Nd3＋ doped YAG laser crystal was estimated using the Yokota-Tanimoto（Y-T） model and the spectral overlap model（SOM） of Kushida, respectively.Firstly, the experimental luminescence decay curves of 4F3/2 state of Nd3＋ ions in YAG laser crystal at room temperature for 2.0at.% and 3.0at.% Nd3＋ concentrations reported by Mao were fitted successfully using the Y-T model, and the parameter CDD was obtained to be 1.50×10-39 cm6/s.Secondly, the parameter CDD was directly calculated using the spectral overlap model（SOM） of Kushida;CDD was calculated to be 2.73×10-39 cm6/s.By comparing the energy migration interaction parameter CDD with the energy transfer interaction parameter CDA（1.794×10-40 cm6/s）, it was concluded that the energy migration rate between Nd3＋ ions in YAG laser crystal was about 11 times larger than the energy transfer rate, and that energy migration played a very important role in high concentration Nd3＋-doped YAG laser crystal.展开更多
文摘Based on the experimental data of KY 3F 10∶Tm 3+ reported by Diaf, K ushida′s spectral overlap model (SOM) of energy transfer between J-multipl ets was studied. Firstly, with the help of the Inokuti-Hirayama and Yokota-Tan imoto models, the luminescence decay curve of 3H 4 of Tm 3+ ion was fitted, and the fitted values of corresponding interaction parameters C D A of energy transfer and C DD of energy migration were obtained. Seco ndly, by compared with Kushida′s SOM in which the relevant Judd-Ofelt approxim ative transition rates are known, the average overlap integrals of S DD and S DA were obtained. For S DD, how to treat the contributi on of the electronic-dipole (ED) crystal field transition forbidden by C 4v site symmetry in the calculation of S DD was discussed. For S DA we suggested that, by including the contribution of the phonon sideba nds in the analysis of oscillator strength of transition, Kushida′s SOM of ED- ED resonant energy transfer rate can be extended to non-resonant phonon-assist ed D-A energy transfer. The strengths and widths of phonon sidebands in this ex ample were discussed, and the results were reasonably good.
基金supported by the Scientific Project of Jiangxi Education Department of China ([2007]330)Scientific Project of Jiujiang University (05KJ01)
文摘The energy migration interaction parameter CDD in high concentration Nd3＋ doped YAG laser crystal was estimated using the Yokota-Tanimoto（Y-T） model and the spectral overlap model（SOM） of Kushida, respectively.Firstly, the experimental luminescence decay curves of 4F3/2 state of Nd3＋ ions in YAG laser crystal at room temperature for 2.0at.% and 3.0at.% Nd3＋ concentrations reported by Mao were fitted successfully using the Y-T model, and the parameter CDD was obtained to be 1.50×10-39 cm6/s.Secondly, the parameter CDD was directly calculated using the spectral overlap model（SOM） of Kushida;CDD was calculated to be 2.73×10-39 cm6/s.By comparing the energy migration interaction parameter CDD with the energy transfer interaction parameter CDA（1.794×10-40 cm6/s）, it was concluded that the energy migration rate between Nd3＋ ions in YAG laser crystal was about 11 times larger than the energy transfer rate, and that energy migration played a very important role in high concentration Nd3＋-doped YAG laser crystal.
