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Spectral Parameters of Nd^(3+) Ion in Nd^(3+):NaGd(MoO_4)_2 Crystal 被引量:1
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作者 李修芝 王国富 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第4期392-394,共3页
The spectral parameters of Nd^3+ ions in Nd^3+-doped NaGd(MoO4)2 crystal have been investigated based on Judd-Ofelt theory and obtained as follows: The intensity parameters Ωeff are Ω2 = 24.77×10^20, Ω4 =... The spectral parameters of Nd^3+ ions in Nd^3+-doped NaGd(MoO4)2 crystal have been investigated based on Judd-Ofelt theory and obtained as follows: The intensity parameters Ωeff are Ω2 = 24.77×10^20, Ω4 = 7.31×10^-20 and Ω6 = 6.91×10^-20 cm^2. The radiative lifetime is 100 μs, and the quantum efficiency is 93.9%. The fluorescence branch ratios were calculated to be β1 = 0.441, β2 = 0.469,β3 = 0.086 and β4=0.004. 展开更多
关键词 spectral parameters Judd-Ofelt theory Nd^3+:NaGd(MoO4)2 solid-state laser materials
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Spectral Parameters of Nd^(3+) in the Nd^(3+):GdMgB_5O_(10) Crystal
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作者 FANJun-Mei LINZhou-Bin ZHANGLi-Zhen HUZu-Shu WANGGuo-Fu 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第4期419-423,共5页
The absorption and emission spectra of Nd3+:GdMgB5O10 crystal were inves- tigated. Based on Judd-Ofelt theory the three parameters of oscillator strength were obtained as follows: ?2 = 2.099×10-20 cm2, ?4 = 4.5... The absorption and emission spectra of Nd3+:GdMgB5O10 crystal were inves- tigated. Based on Judd-Ofelt theory the three parameters of oscillator strength were obtained as follows: ?2 = 2.099×10-20 cm2, ?4 = 4.599×10-20 cm2 and ?6 = 5.139×10-20 cm2. The fluorescence branch rations were also obtained: β1 = 0.424, β2 = 0.474, β3 = 0.094 and β4 = 0.005. The radiative lifetime is 416 μs and quantum efficiency ηc 9.13%. The emission cross section σp (1.06 μm) is 4.38×10-19 cm2. 展开更多
关键词 spectral parameters Nd3+:GdMgB5O10 crystal Judd-Ofelt theory
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Spectral Parameters of Nd^(3+) Ion in Nd^(3+):KLu(WO_4)_2 Crystal
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作者 TANGLi-Yong WANGGuo-Fu 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第4期383-386,共4页
The spectral parameters of Nd3+ ions in Nd3+:Klu(WO4)2 crystal were calculated based on Judd-Ofelt theory and obtained as follows: for the oscillator strengths ?λ: ?2 = 7.5029×10-20 cm2, ?4 = 7.1837×10-20... The spectral parameters of Nd3+ ions in Nd3+:Klu(WO4)2 crystal were calculated based on Judd-Ofelt theory and obtained as follows: for the oscillator strengths ?λ: ?2 = 7.5029×10-20 cm2, ?4 = 7.1837×10-20 cm2 and ?6 = 3.1189×10-20 cm2; the radiative lifetime is 123 μs; the quantum efficiency is equal to 64.55%; and β1 = 0.5498, β2 = 0.3943, β3 = 0.0551 and β4 = 0.0027 for the fluorescence branch ratios. 展开更多
关键词 spectral parameters Nd3+:KLu(WO4)2 crystal Judd-Ofelt theory
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Hamiltonian Theory for the DNLS Equation with a Squared Spectral Parameter
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作者 Jin Zhang Tian Yan Hao Cai 《Wuhan University Journal of Natural Sciences》 CAS 2010年第4期315-319,共5页
With a special gauge transformation,the Lax pair of the derivative nonlinear Shcrdinger (DNLS) equation turns to depend on the squared parameter λ = k2instead of the usual spec-tral parameter k. By introducing a new ... With a special gauge transformation,the Lax pair of the derivative nonlinear Shcrdinger (DNLS) equation turns to depend on the squared parameter λ = k2instead of the usual spec-tral parameter k. By introducing a new direct product of Jost solu-tions,the complete Hamiltonian theory of the DNLS equation is constructed on the basis of the squared spectral parameter,which shows that the integrability completeness is still preserved. This result will be beneficial to the further study of the DNLS equation,such as the direct perturbation method. 展开更多
关键词 DNLS equation Hamiltonian theory squared spectral parameter inverse scattering transform PERTURBATION
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Spectral Parameter Study on Tm^(3+) in Na_5Tm(WO_4)_4 Crystal
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作者 姚连增 张海峰 《Journal of Rare Earths》 SCIE EI CAS CSCD 1997年第3期2-6,共5页
On the basis of the obtained intensity parameters Ω λ(λ =2,4,6) of Tm 3+ in the Na 5Tm(WO 4) 4 crystal, we performed calculations on the radiative transition probability, radiative lifetime, branching ... On the basis of the obtained intensity parameters Ω λ(λ =2,4,6) of Tm 3+ in the Na 5Tm(WO 4) 4 crystal, we performed calculations on the radiative transition probability, radiative lifetime, branching ratios and stimulated emission integrated cross sections between the two excited J manifolds of Tm 3+ , and discussed potentiality for the usage of this crystal as a laser material. 展开更多
关键词 Rare earths Na 5Tm(WO 4) 4 crystal Judd Ofelt theory Radiative transition probability Stimulated emission integrated cross section spectral parameters
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参数化S谱幅值调制及轴承故障诊断应用
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作者 姜祖华 张坤 +1 位作者 杨欢 胥永刚 《西安交通大学学报》 EI CAS CSCD 北大核心 2024年第3期117-128,共12页
针对传统谱幅值调制方法易受噪声影响的问题,利用参数化S变换得到信号在时频域中的幅值,提出了一种参数化S谱幅值调制方法。该方法首先使用参数化S变换将信号转换到时频域并得到幅值和相位,然后将不同权重赋予时频域中的幅值以改变不同... 针对传统谱幅值调制方法易受噪声影响的问题,利用参数化S变换得到信号在时频域中的幅值,提出了一种参数化S谱幅值调制方法。该方法首先使用参数化S变换将信号转换到时频域并得到幅值和相位,然后将不同权重赋予时频域中的幅值以改变不同能量频率成分在信号中的占比,最后将调制后的幅值与原相位结合,使用参数化S逆变换重构一系列修正信号并计算其平方包络谱以提取故障特征。仿真和实验结果表明,该方法获得的幅值信息相比传统谱幅值调制方法更加准确和全面,对强噪声环境更具鲁棒性,能够有效实现滚动轴承的外圈、内圈和复合故障诊断。将所提方法与传统谱幅值调制方法和快速谱峭度方法进行对比,证明了参数化S谱幅值调制既能检测强噪声环境下的轴承故障信息,又能同时提取多种故障分量,在滚动轴承的故障特征提取中更具优越性。 展开更多
关键词 滚动轴承 故障诊断 谱幅值调制 参数化S谱幅值调制
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Statistical Characteristics of Raindrop Size Distribution in the South China Monsoon Region(Guangdong Province) 被引量:1
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作者 陈超 张阿思 +3 位作者 吴乃庚 刘显通 孙晓光 王洪 《Journal of Tropical Meteorology》 SCIE 2023年第1期55-67,共13页
While heavy rainfall frequently takes place in southern China during summer monsoon seasons,quantitative precipitation forecast skills are relatively poor.Therefore,detailed knowledge about the raindrop size distribut... While heavy rainfall frequently takes place in southern China during summer monsoon seasons,quantitative precipitation forecast skills are relatively poor.Therefore,detailed knowledge about the raindrop size distribution(DSD)is useful in improving the quantitative precipitation estimation and forecast.Based on the data during 2018-2022 from 86stations in a ground-based optical disdrometer measurement network,the characteristics of the DSD in Guangdong province are investigated in terms of the particle size distribution(N(D)),mass-weighted mean diameter(Dm) and other integral DSD parameters such as radar reflectivity(Z),rainfall rate(R) and liquid water content(LWC).In addition,the effects of geographical locations,weather systems(tropical cyclones,frontal systems and the summer monsoon) and precipitation types on DSD characteristics are also considered.The results are shown as follows.1) Convective precipitation has a broader N(D) and larger mean particle diameter than the stratiform precipitation,and the DSD observations in Guangdong are consistent with the three-parameter gamma distribution.The relationships between the Z and R for stratiform and convective precipitation are also derived for the province,i.e.,Z=332.34 R1.32and Z=366.26R1.42which is distinctly different from that of the Next-generation Weather Radar(NEXRAD) Z-R relationship in United States.2) In the rainy season(April-September),the Dm, R and LWC are larger than those in the dry season(OctoberMarch).Moreover the above parameters are larger,especially in mid-May,which is the onset of the South China Sea summer monsoon.3) The spatial analysis of DSD shows that the coastal station observations indicate a smaller Dmand a larger normalized intercept parameter(log10Nw),suggestive of maritime-like rainfall.Dmis larger and log10Nwis smaller in the inland area,suggestive of continental-like rainfall.4) Affected by such weather systems as the tropical cyclone,frontal system and summer monsoon,the DSD shows characteristics with distinct differences.Furthermore,frontal system rainfall tends to present a continental-like rainfall,tropical cyclone rainfall tends to have a maritime-like rainfall,and summer monsoon rainfall characteristic are between maritime-and continental-like cluster(raindrop concentration and diameter are higher than continental cluster and maritime cluster,respectively.) 展开更多
关键词 raindrop size distribution spectral parameters Z-R relationship weather types
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Pr(Ⅲ) and Nd(Ⅲ) Absorption Spectroscopic Probe to Investigate Interaction with Lysozyme (HEW) 被引量:1
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作者 Jignasu P.Mehta Prashant N.Bhatt Sudhindra N. Misra 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第6期648-652,共5页
Pr( Ⅲ ) and Nd( Ⅲ ) can be utilized as absorption spectroscopic probes to investigate the interaction of biomolecules like Lysozyme (HEW) with Ca( Ⅱ ) in-vitro ; the most abundant metal ion in the human bod... Pr( Ⅲ ) and Nd( Ⅲ ) can be utilized as absorption spectroscopic probes to investigate the interaction of biomolecules like Lysozyme (HEW) with Ca( Ⅱ ) in-vitro ; the most abundant metal ion in the human body system. The spectroscopic techniques involving comparative absorption, absorption difference, and quantitative intensity analysis using 4f-4f transitions are utilized for changes in the inner sphere coordination pattern of Pr( Ⅲ ) and Nd(Ⅲ ) in solution as well as in solid state. The present study deals with an important biomolecule in human metabolism, that is, Lysozyme (HEW). The absorption er-Condon the probab spectral parameters such as the oscillator strength (P), the Judd-Ofelt (Tλ) intensity parameters, and the Slatinter electronic parameters are calculated using chi square methods. The obtained results are used to determine le geometry of the complex in the solution, the nature of the bond between Pr(Ⅲ)/Nd(Ⅲ) with lysozyme, and the inner sphere coordination environment of f-f transitions. The results obtained from various experimental conditions are utilized to investigate the coordination changes in the Pr(Ⅲ)/Nd(Ⅲ) complexes caused by different coordinating sites of lysozyme, normalized bite, denticity, the solvent nature, the coordination number, the nature of bond and other parameters to mimic the interaction of the Ca( Ⅱ ) ion with such biomolecule. 展开更多
关键词 absorption spectra Pr(Ⅲ) Nd(Ⅲ) Lysozyme (HEW) spectral parameters rare earths
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Optical-transition Probability of Tm^(3+) Ions in Tm^(3+)/Er^(3+):YVO_4 Crystal 被引量:1
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作者 张莉珍 王国富 Taiju Tsuboi 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2004年第4期381-385,共5页
The polarized absorption spectra of Tm3+/Er3+:YVO4 crystal were measured at room temperature. Based on the Judd-Ofelt theory, the spectral parameters were obtained: the intensity parameters Wl of Tm3+ in Tm/Er:YVO4 cr... The polarized absorption spectra of Tm3+/Er3+:YVO4 crystal were measured at room temperature. Based on the Judd-Ofelt theory, the spectral parameters were obtained: the intensity parameters Wl of Tm3+ in Tm/Er:YVO4 crystal: W2 = 10.69×10-20, W4 = 0.604×10-20, W6 = 2.05×10-20 cm2 for the (100) face and W2 = 10.43×10-20, W4 = 0.13×10-20, W6 = 1.83×10-20 cm2 for the (001) face. Based on these values, the oscillator strength, radioactive lifetime and fluorescence branch ratio were calculated for Tm3+ in Tm/Er:YVO4 crystal. 展开更多
关键词 spectral parameters Tm^(3+)/Er^(3+):YVO_4 crystal Judd-Ofelt theory
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基于地物波谱形态参数化的高光谱图像分类方法研究 被引量:1
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作者 谢凯 《湖北大学学报(自然科学版)》 CAS 2015年第2期116-121,142,共7页
利用语素向量的形态描述方法实现地物波谱形态的参数化,以不同地物具有不同波谱曲线为地物分类准则,在MATLAB设计中,实现一种带通配符的地物波谱曲线形态差异遥感图像分类程序,应用此程序对高光谱遥感图像所得的分类结果与其他分类方法... 利用语素向量的形态描述方法实现地物波谱形态的参数化,以不同地物具有不同波谱曲线为地物分类准则,在MATLAB设计中,实现一种带通配符的地物波谱曲线形态差异遥感图像分类程序,应用此程序对高光谱遥感图像所得的分类结果与其他分类方法所得的分类结果进行对比.结果说明,此方法可以将地物波谱的波形信息最大限度地保留并利用,进一步解决遥感影像分类中"光谱值"相似及现有的光谱匹配方法受类内差异变化影响大的问题,运用Kappa系数的精度评价证明此方法对高光谱遥感图像的分类优于SVM分类方法. 展开更多
关键词 波谱形态参数化 MATLAB 高光谱遥感图像分类
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Asymptotic Formulas of the Solutions and the Trace Formulas for the Polynomial Pencil of the Sturm-Liouville Operators
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作者 A. Adiloglu Nabiev 《Applied Mathematics》 2016年第18期2411-2417,共7页
This work studies the asymptotic formulas for the solutions of the Sturm-Liouville equation with the polynomial dependence in the spectral parameter. Using these asymptotic formulas it is proved some trace formulas fo... This work studies the asymptotic formulas for the solutions of the Sturm-Liouville equation with the polynomial dependence in the spectral parameter. Using these asymptotic formulas it is proved some trace formulas for the eigenvalues of a simple boundary problem generated in a finite interval by the considered Sturm-Liouville equation. 展开更多
关键词 Sturm-Liouville Equation Asymptotic Formulas for Solutions spectral parameter EIGENVALUE Boundary Value Problem Trace Formula Fractional Integrals and Derivatives
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显式云物理方案的研究进展 被引量:14
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作者 史月琴 楼小凤 《气象科技》 2006年第5期513-520,共8页
回顾了近年来显式云物理方案的研究进展。显式云方案主要有体积水方法和详细微物理方法(分档法)。体积水方法有单参数和双参数两种谱描述方法,根据模式预报变量和物理过程的不同,可以分为暖云方案、简单冰相方案和复杂冰相方案。详细的... 回顾了近年来显式云物理方案的研究进展。显式云方案主要有体积水方法和详细微物理方法(分档法)。体积水方法有单参数和双参数两种谱描述方法,根据模式预报变量和物理过程的不同,可以分为暖云方案、简单冰相方案和复杂冰相方案。详细的微物理方法由于预报变量繁多、计算量巨大而一般多应用于研究工作。不同的模式,有不同的显式云方案,并不是粒子分类越复杂模拟效果就越好,需要根据研究的重点、计算资源的许可选择使用不同的物理方案。物理过程参数化需要建立在理论和实验研究的基础上,因此应加强这方面的理论和实验研究,使物理参数化具有更坚实的物理基础。 展开更多
关键词 显式云物理方案 体积水方法 分档法 物理过程参数化
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重力波阻参数化方案及其预报试验 被引量:1
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作者 江野 陈嘉滨 《高原气象》 CSCD 北大核心 1992年第2期152-160,共9页
本文在中国科学院大气物理研究所二室自行设计的9层谱模式中,引入ECMWF的地形重力波阻参数化方案,取截断波数为21,进行了冬、夏两个例子的试验计算,分析讨论了重力波阻参数化对纬向平均西风剖面、纬向平均温度剖面、动能变化和预报评分... 本文在中国科学院大气物理研究所二室自行设计的9层谱模式中,引入ECMWF的地形重力波阻参数化方案,取截断波数为21,进行了冬、夏两个例子的试验计算,分析讨论了重力波阻参数化对纬向平均西风剖面、纬向平均温度剖面、动能变化和预报评分的作用。结果表明重力波阻参数化方案的引入是成功的。 展开更多
关键词 重力波阻 参数化 谱模式 预报
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全球地震面波相速度的微分性质及其波谱特征
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作者 唐娉 张禹慎 《CT理论与应用研究(中英文)》 1998年第3期1-6,共6页
本文从理论上揭示了全球地震面波相速度球谐展开的振幅谱特征与横向非均匀结构微分性质的内在联系,对现今存在的两组不同的高阶振幅谱特征作了进一步的分析,并为选择更为合适的参数化方法或模型光滑度的限制条件提供了某种理论判据。
关键词 参数化 地震勘探 地震面波 微分性质 波相速度
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Impacts of Spectral Nudging on the Sensitivity of a Regional Climate Model to Convective Parameterizations in East Asia 被引量:2
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作者 宋寔 汤剑平 陈星 《Acta meteorologica Sinica》 SCIE 2011年第1期63-77,共15页
The sensitivity of a regional climate model (RCM) to cumulus parameterization (CUPA) schemes in modeling summer precipitation over East Asia has been investigated by using the fifth-generation Pennsylvania State U... The sensitivity of a regional climate model (RCM) to cumulus parameterization (CUPA) schemes in modeling summer precipitation over East Asia has been investigated by using the fifth-generation Pennsylvania State University-National Center for Atmospheric Research Mesoscale Model (PSU-NCAR MM5). The feasibility of physical ensemble and the effect of interior (spectral) nudging are also assessed. The RCM simulations are evaluated against the NCEP/NCAR reanalysis data and NCEP/CPC precipitation data for three summers (JJA) in 1991, 1998, and 2003. The results show that the RCM is highly sensitive to CUPA schemes. Different CUPA schemes cause distinctive characteristics in the modeling of JJA precipitation and the intraseasonal (daily) variability of regional precipitation. The sensitivity of the RCM simulations to the CUPA schemes is reduced by adopting the spectral nudging technique, which enables the RCM to reproduce more realistic large-scale circulations at the upper levels of the atmosphere as well as near the surface, and better precipitation simulation in the selected experiments. The ensemble simulations using different CUPA schemes show higher skills than individual members for both control runs and spectral nudging runs. The physical ensemble adopting the spectral nudging technique shows the highest downscaling skill in capturing the general circulation patterns for all experiments and improved temporal distributions of precipitation in some regions. 展开更多
关键词 regional climate model (RCM) cumulus parameterizations spectral nudging ENSEMBLE East Asian summer precipitation
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几何光学冠层反射建模中的光谱分量特征的参数化(英文) 被引量:1
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作者 倪文革 李小文 +1 位作者 CurtisE.Woodcock AlanStrahler 《遥感学报》 EI CSCD 1997年第S1期110-116,共7页
该文用几何光学与辐射传输混合模型研究不连续植被冠层的几何光学反射模型的四分量(承照树冠、承照地面、阴影树冠、阴影地面)的参数化。用一个修正的均匀介质层路径散射(反射与传输)参数的解析算法估计路径散射参数(反射与传输)... 该文用几何光学与辐射传输混合模型研究不连续植被冠层的几何光学反射模型的四分量(承照树冠、承照地面、阴影树冠、阴影地面)的参数化。用一个修正的均匀介质层路径散射(反射与传输)参数的解析算法估计路径散射参数(反射与传输),其中也考虑了冠层间隙的影响。光谱分量特征是不连续植被冠层的传输与反射,背景反照率,以直射光通量与天空漫射光通量比例的函数。光谱分量特征的模型与在美国缅因州Holand采集的针叶林数据吻合。基于LiStrahler几何光学相互遮蔽模型,用参数化的光谱分量特征对老松林和老云杉林的方向反射进行估计,其结果与在不同太阳与观测方向上的PARABOLA测量值匹配得很好。 展开更多
关键词 光谱分量参数化 GO模型
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谱元大气模式SEAM简介
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作者 赵加华 刘喜迎 姜皓严 《中国科技信息》 2012年第6期42-43,46,共3页
本文介绍了谱元大气模式SEAM的动力框架、模式物理过程和参数方案,指出了模式研究中有待进一步解决的问题。
关键词 SEAM 谱元模式 参数化
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一种求解分布控制问题的含参预处理最小残量法(英文)
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作者 朱聪宜 黄玉梅 《应用数学与计算数学学报》 2015年第4期395-403,共9页
近年来,提出了一些求解约束优化分布控制问题的方法,其中最常用的方法是先离散偏微分方程,然后求解离散得到的线性方程组.文献中提出了一些Krylov子空间预处理方法用来求解该线性方程组.通过分析张晓莹等提出的块对角预处理矩阵(Zhang X... 近年来,提出了一些求解约束优化分布控制问题的方法,其中最常用的方法是先离散偏微分方程,然后求解离散得到的线性方程组.文献中提出了一些Krylov子空间预处理方法用来求解该线性方程组.通过分析张晓莹等提出的块对角预处理矩阵(Zhang X Y,Yan H Y.Huang Y M.On preconditionedMINRES method for solving the distributed control problems.Commun Appl Math Comput,2014,28:128-132.),构造了一个含参数的块对角预处理线性方程组,并运用含参数预处理最小残量方法求解该线性方程组.预处理矩阵的谱分析表明当参数大于1时,含参预处理线性方程组的谱分布更加集中.数值实验结果验证了含参数的预处理最小残量方法对于求解分布式控制问题是有效的. 展开更多
关键词 预处理最小残量法 含参预处理矩阵 谱分布
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Non-destructive measurement of chlorophyll in tomato leaves using spectral transmittance 被引量:1
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作者 Wang Jianfeng He Dongxian +2 位作者 Song Jinxiu Dou Haijie Du Weifen 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2015年第5期73-78,共6页
In this study,spectral transmittances were measured in the wavelength range from 300 nm to 1100 nm of tomato leaves with different chlorophyll contents and compositions,and the correlations between the spectral transm... In this study,spectral transmittances were measured in the wavelength range from 300 nm to 1100 nm of tomato leaves with different chlorophyll contents and compositions,and the correlations between the spectral transmittances and the contents of chlorophyll a,chlorophyll b and total chlorophyll were analyzed.With the characteristic wavelengths of 560 nm,650 nm,720 nm and the reference wavelength of 940 nm,nine sets of characteristic spectral parameters were obtained.According to the results of correlation analysis and regression model exploration,characteristic spectral parameters of T940/T560,T940/T650 and log(T940/T560)among the nine sets of parameters were highly correlated to the estimated contents of chlorophyll a,chlorophyll b and total chlorophyll of tomato leaves.The relative errors of total chlorophyll and chlorophyll a/b ratio were(5.1±3.7)%and(4.9±4.3)%,respectively.Therefore,the above three characteristic spectral parameters could be applied in the rapid non-destructive estimation of the contents of chlorophyll a,chlorophyll b and total chlorophyll as well as chlorophyll a/b ratio of tomato leaves. 展开更多
关键词 CHLOROPHYLL characteristic wavelength characteristic spectral parameter spectral transmittance
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Characterization of optical transitions of Eu^(3+) in lanthanum oxychloride nanophosphor 被引量:1
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作者 A. Choubey S. Som +1 位作者 M. Biswas S.K. Sharma 《Journal of Rare Earths》 SCIE EI CAS CSCD 2011年第4期345-348,共4页
This paper presented the studies on the optical properties and calculation of spectral parameters of europium doped lanthanum oxychloride nanophosphor for their possible applications in optoelectronic devices. The com... This paper presented the studies on the optical properties and calculation of spectral parameters of europium doped lanthanum oxychloride nanophosphor for their possible applications in optoelectronic devices. The compound was doped with 0.1 mol% Eu3+ ions. The X-ray diffraction study of prepared sample suggested the tetragonal structure with particle size in the range of 18–21 nm. The photoluminescence (PL) emission spectra showed the bright emission in orange-red region from 580 to 630 nm. The most intense emission peak at 621 nm was due to transition 5D0→7F2 in energy levels of Eu3+ ions. The spectral parameters were calculated from the absorption and emission spectra using Judd-Ofelt intensity parameters. The calculated values of the oscillator strength corresponding to the three transitions 7F1→5D1, 7F1→5D2 and 7F0→5D2 observed at 535, 472 and 465 nm in absorption spectra were 0.30×10–6, 1.36×10–6 and 0.63×10–6, respectively. The value of transi- tion probability (A), stimulated emission cross-section ( ) and radiative lifetime (τrad) corresponding to 621 nm emission peak (transition 5D0→7F2) were 308 s–1, 1.22×10–21 cm2 and 3.24×10–3 s, respectively. 展开更多
关键词 X-ray diffraction optical absorption PHOTOLUMINESCENCE spectral parameters rare earths
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