Time series data correction for the Chang'E-1 gamma-ray spectrometer

The main goal of the gamma-ray spectrometer（GRS） onboard Chang＇E1（CE-1） is to acquire global maps of elemental abundances and their distributions on the moon,since such maps will significantly improve our understanding of lunar formation and evolution.To derive the elemental maps and enable research on lunar formation and evolution,raw data that are received directly from the spacecraft must be converted into time series corrected gamma-ray spectra.The data correction procedures for the CE-1 GRS time series data are thoroughly described.The processing procedures to create the time series gamma-ray spectra described here include channel processing,optimal data selection,energy calibration,gain correction,dead time correction,geometric correction,orbit altitude normalization,eliminating unusable data and galactic cosmic ray correction.Finally,descriptions are also given on data measurement uncertainties,which will help the interested scientists to understand and estimate various uncertainties associated with the above data processing.

Qualitative and quantitative analysis of atmospheric methanol using a continuous-wave terahertz spectrometer

We present a specific-window method to subtract the interference of water vapor on terahertz frequency-domain spectroscopy（THz-FDS） at ambient temperature and pressure. A continuous-wave spectrometer based on photomixing was utilized to obtain THz-FDS of methanol vapor in the range of 50–1200 GHz. The distinctly spaced absorption features in the neighborhood of atmospheric windows of transparency were selected to perform linear fitting versus the calculated absorption cross section and obtain the concentration of methanol. Furthermore, the gradually decreased methanol vapor was quantified to demonstrate the reliability of the method.

Radiofrequency field enhanced chemical ionization with vacuum ultraviolet lamp for miniature time-of-flight mass spectrometer

It is difficult to rapidly and on-line detect trace volatile organic compounds for miniature massspectrometry due to its limited sampling volume at slow pumping speed. In this paper, we developed anew radiofrequency field enhanced chemical ionization source （RF-ECI） with vacuum ultraviolet （VUV）lamp by coupling radiofrequency electric field and direct-current field together. The experiment resultsshowed that the sensitivity of benzene, toluene, hydrogen sulfide and other compounds increased by 2-3orders of magnitude under the introduction of RF-ECI comparing to traditional single photon ionization（SPI）. At the same time, the reagent ion of O2＋ realized the charge transfer reaction chemical ionization,and the RF-ECI effectively expanded the detection range of the VUV lamp based SPI. The VUV lamp hasinherent advantages in the on-site analytical instrument for its small size and low power consumption,and the VUV lamp based RF-ECI miniature time-of-flight mass spectrometer （TOFMS） has a limit-of-detection for H2S as low as 0.0571 mg/m3, and it is expected to be used widely in the field of on-site rapidanalvsis.