Spin Dependent Hopping in Ti Doped La_(0.67)Ca_(0.33)MnO_3

A systematic investigation of the magnetic and transport properties of Ti doped La_(0.67)Ca_(0.33)MnO_3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x=0.055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system.

Anisotropic Spin Cluster as a Qubit

We study an anisotropic spin cluster of 3 spin S=1/2 particles with antiferromagnetic exchange interactionwith non-uniform coupling constants.A time-dependent magnetic field is applied to control the time evolution of thecluster.It is well known that for an odd number of sites a spin cluster qubit can be defined in terms of the ground statedoublet.The universal one-qubit logic gate can be constructed from the time evolution operator of the non-autonomousmany-body system,and the six basic one-qubit gates can be realized by adjusting the applied time-dependent magneticfield.

Improvement on Electrical Properties and Magnetoresistance Induced by Pd or Ag Addition in Lao.67（Ca0.65Ba0.35）0.33MnO3 Manganites

Electrical properties and magnetoresistance have been studied in two series of xAg-La0.67（Ca0.65Ba0.35）0.33MnO3 and xPd-La0.67（Ca0.65Ba0.35）0.33MnO3 （abbreviated by xAg-LCBMO and xPd-LCBMO） composites. Both Pd and Ag addition induce a decrease in resistivity and an increase in temperature at which the resistivity reaches its maximum. This is mainly due to the improvement of grain boundaries caused by the segregation of good conductive metal grains on the grain boundaries/surfaces. In addition, both Pd and Ag addition induce a large enhancement of room temperature magnetoresistance （RTMR）. Note that 27% molar ratio of Ag addition induces a large RTMR of about 70%, about ten times larger than pure LCBMO, whereas 27% molar ratio Pd addition brings a much larger RTMR of about 170%. The large enhancements of MR can be attributed to the decrease in resistivity of the samples caused by the good conductive metal. On the other hand, the polarization of Pd atoms near the Mn ions on the grain surfaces/boundaries plays a very im-portant role in the increase in MR, which induces a large number of spin clusters in Pd-added samples.

Physical Realization of Quantum C-Not Gate

We investigate a Heisenberg spin cluster with two particles controlled by a time-dependent magnetic field. The system is controlled by tuning the amplitude, frequency, and interaction time of the three-step time-dependent magnetic field. Then we solve the time-dependent Schrodinger equation of the two-particle system, and obtain the time evolution operator. By the three-timestep interaction, the wavefunction evolves from the initial state to the final state, and the total evolution operator can be expressed as a product of the three evolution operators. By adjusting the physical parameters, the key two-qubit logic gate, the C-Not gate, can be realized physically.

Irreversible Colossal Magnetoresistance in La_(0.58)Dy_(0.09)Ca_(0.33)MnO_3

The representative sample La0.58Dy0.09Ca0.33MnO3 of Dy doped La0.67Ca0.33MnO3 rare-earth manganites was investigated. The most important effect of Dy doping is to introduce the magnetoimpurity and form the spin clusters which induce dramatically large CMR in La0.58Dy0.09Ca0.33MnO3. The fitting results of field-induced resistivity decrease to the Brillouin function indicate that the CMR is caused by the spin dependent hopping between spin clusters. It is the magnetic field that reduces the size of spin clusters and induces a field-induced irreversible CMR behaviour.

Ultrasonic absorption with infrared divergence in cluster spin glass

The infrared divergence response theory is applied to reorientational relaxation process of magnetic clusters in cluster spin glass(CoF2)0.5 (BaF2)0.2 (NaPO3)0.3 to study the behaviour of low temperature ultrasonic absorption in this system . Our calculation results showed that the reorientational relaxation process makes the main contributions to the magnetic part of the ultrasonic absorption for T < 4.0 K ; as for T > 4.0 K , the contributions of the internal process inside the clusters must be considered.

The hyperfine structure of electron spin resonance spectrum of tricobalt cluster radical anion CH_3CCo_3(CO)_9^-

CH_3CCo_3(CO)_9 was synthesized from the reaction between chloralose and Co_2(CO)_. The radical anion was generated by electrochemical reduction,and electron spin resonance spectra in THF were recorded by in situ electrolysis in the sample tube in the ESR cavity at 298 and 110K with the spectral data