[Objectives] This study was conducted to develop a polyurea elastomer which can be sprayed on the surface of expanded polystyrene (EPS) floating balls, so as to improve the surface strength and service life of the flo...[Objectives] This study was conducted to develop a polyurea elastomer which can be sprayed on the surface of expanded polystyrene (EPS) floating balls, so as to improve the surface strength and service life of the floating balls. [Methods] The effects of the types and amounts of isocyanate, chain extenders and polyether polyols on the gelation rate, adhesion and wear resistance of polyurea elastomer were investigated, and it was finally determined the preparation process of polyurea elastomer using liquid isophorone diisocyanate (IPDI) and amino-terminated polyether (D2000) as the main raw materials, dimethylthiotoluene diamine (E300) as the chain extender and silica as the wear resistance modifier through two-step solution polymerization of prepolymerization and chain extension. [Results] The physical properties and chemical resistance tests of spray polyurea elastomer showed that it had good physical properties and acid and alkali resistance, and could meet the requirements of spraying and protection of EPS floating ball surface in marine environment. [Conclusions] Polyurea elastomer coating can improve the aging resistance, wear resistance and acid and alkali resistance of EPS floating balls, and prevent them from being fragile and floating randomly to form marine floating garbage which results in "white pollution".展开更多
应用ANSYS/LS-DYNA有限元软件对三种防爆罐在1.2 kg TNT爆炸载荷作用下的动态响应过程进行数值模拟。研究了无夹层、聚脲弹性体夹层和橡胶夹层防爆罐的抗爆性能。分析了不同夹层对防爆罐整体变形的影响及聚脲弹性体和橡胶夹层的吸能特...应用ANSYS/LS-DYNA有限元软件对三种防爆罐在1.2 kg TNT爆炸载荷作用下的动态响应过程进行数值模拟。研究了无夹层、聚脲弹性体夹层和橡胶夹层防爆罐的抗爆性能。分析了不同夹层对防爆罐整体变形的影响及聚脲弹性体和橡胶夹层的吸能特性。通过聚脲弹性体夹层防爆罐在爆炸载荷作用下的变形试验研究,验证了数值计算结论的可靠性;结果表明,在相同爆炸载荷作用下,无论变形或能量吸收方面,聚脲弹性体夹层防爆罐都优于无夹层防爆罐和橡胶夹层防爆罐;冲击波在聚脲弹性体传播过程中衰减幅度最大。展开更多
基金Supported by Special Project for High-quality Development of Marine Services and Fishery in Fujian Province in 2023(FJHY-YYKJ-2023-1-3)。
文摘[Objectives] This study was conducted to develop a polyurea elastomer which can be sprayed on the surface of expanded polystyrene (EPS) floating balls, so as to improve the surface strength and service life of the floating balls. [Methods] The effects of the types and amounts of isocyanate, chain extenders and polyether polyols on the gelation rate, adhesion and wear resistance of polyurea elastomer were investigated, and it was finally determined the preparation process of polyurea elastomer using liquid isophorone diisocyanate (IPDI) and amino-terminated polyether (D2000) as the main raw materials, dimethylthiotoluene diamine (E300) as the chain extender and silica as the wear resistance modifier through two-step solution polymerization of prepolymerization and chain extension. [Results] The physical properties and chemical resistance tests of spray polyurea elastomer showed that it had good physical properties and acid and alkali resistance, and could meet the requirements of spraying and protection of EPS floating ball surface in marine environment. [Conclusions] Polyurea elastomer coating can improve the aging resistance, wear resistance and acid and alkali resistance of EPS floating balls, and prevent them from being fragile and floating randomly to form marine floating garbage which results in "white pollution".
文摘应用ANSYS/LS-DYNA有限元软件对三种防爆罐在1.2 kg TNT爆炸载荷作用下的动态响应过程进行数值模拟。研究了无夹层、聚脲弹性体夹层和橡胶夹层防爆罐的抗爆性能。分析了不同夹层对防爆罐整体变形的影响及聚脲弹性体和橡胶夹层的吸能特性。通过聚脲弹性体夹层防爆罐在爆炸载荷作用下的变形试验研究,验证了数值计算结论的可靠性;结果表明,在相同爆炸载荷作用下,无论变形或能量吸收方面,聚脲弹性体夹层防爆罐都优于无夹层防爆罐和橡胶夹层防爆罐;冲击波在聚脲弹性体传播过程中衰减幅度最大。
