A novel method for preparation of magnetic polymer microspheres by spraying suspension polymerization (SSP) was developed. Relatively uniform magnetic poly(methyl methacrylate) microspheres were prepared by the sprayi...A novel method for preparation of magnetic polymer microspheres by spraying suspension polymerization (SSP) was developed. Relatively uniform magnetic poly(methyl methacrylate) microspheres were prepared by the spraying suspension polymerization (SSP) using methyl methacrylate (MMA) as monomer, divinylbenzene (DVB) as cross-linking agent, benzoyl peroxide (BPO) as initiator and polyvinyl alcohol (PVA) as stabilizer in the presence of hydrophobic Fe3O4 magnetic fluid. The microspheres prepared were modified by surface chemical reaction. The magnetic properties and morphology of the microspheres were examined by SEM and VSM respectively. The active functional groups of microspheres were examined by infrared spectra. The results showed that microspheres with saturation magnetization of 16.8 emu/g showed distinct superparamagnetic characteristics and the magnetic microspheres with a size of 10 μm were relatively uniform.展开更多
基金This work was supported partly by National High Technology Researc and Development Program.Of China(Grant No.2002AA302211)the National Natural Science Foundation of China(Grant No.20206032).
文摘A novel method for preparation of magnetic polymer microspheres by spraying suspension polymerization (SSP) was developed. Relatively uniform magnetic poly(methyl methacrylate) microspheres were prepared by the spraying suspension polymerization (SSP) using methyl methacrylate (MMA) as monomer, divinylbenzene (DVB) as cross-linking agent, benzoyl peroxide (BPO) as initiator and polyvinyl alcohol (PVA) as stabilizer in the presence of hydrophobic Fe3O4 magnetic fluid. The microspheres prepared were modified by surface chemical reaction. The magnetic properties and morphology of the microspheres were examined by SEM and VSM respectively. The active functional groups of microspheres were examined by infrared spectra. The results showed that microspheres with saturation magnetization of 16.8 emu/g showed distinct superparamagnetic characteristics and the magnetic microspheres with a size of 10 μm were relatively uniform.
