In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube ...In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thor- oughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materi- als, and hold potential for enhancing their mechanical, chemical, optical and electronic properties.展开更多
Dynamic response of multispan viscoelastic thin beams subjected to a moving mass is studied by an efficient numerical method in some detail. To this end, the unknown parameters of the problem are discretized in spatia...Dynamic response of multispan viscoelastic thin beams subjected to a moving mass is studied by an efficient numerical method in some detail. To this end, the unknown parameters of the problem are discretized in spatial domain using generalized moving least square method (GMLSM) and then, discrete equations of motion based on Lagrange's equation are obtained. Maximum deflection and bending moments are considered as the important design parameters. The design parameter spectra in terms of mass weight and velocity of the moving mass are presented for multispan viscoelastic beams as well as various values of relaxation rate and beam span number. A reasonable good agreement is achieved between the results of the proposed solution and those obtained by other researchers. The results indicate that, although the load inertia effects in beams with higher span number would be intensified for higher levels of moving mass velocity, the maximum values of design parameters would increase either. Moreover, the possibility of mass separation is shown to be more critical as the span number of the beam increases. This fact also violates the linear relation between the mass weight of the moving load and the associated design parameters, especially for high moving mass velocities. However, as the relaxation rate of the beam material increases, the load inertia effects as well as the possibility of moving mass separation reduces.展开更多
For the accurate extraction of cavity decay time, a selection of data points is supplemented to the weighted least square method. We derive the expected precision, accuracy and computation cost of this improved method...For the accurate extraction of cavity decay time, a selection of data points is supplemented to the weighted least square method. We derive the expected precision, accuracy and computation cost of this improved method, and examine these performances by simulation. By comparing this method with the nonlinear least square fitting (NLSF) method and the linear regression of the sum (LRS) method in derivations and simulations, we find that this method can achieve the same or even better precision, comparable accuracy, and lower computation cost. We test this method by experimental decay signals. The results are in agreement with the ones obtained from the nonlinear least square fitting method.展开更多
In this paper,for an arbitrary prime p,the square mapping graph of M2(Zp;s) is investigated and the formula of the decomposition of the square mapping graph of M2(Zp;s) is established.
Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound w...Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound which were well known as reaction products of cyanate esters and epoxy resins, compounds with hybrid ring structure of cyanurate/isocyanurate were determined. Gibbs free energies of the compound having hybrid ring structure of cyanurate/isocyanurate with two isocyanurate moiety were found to be lower than that of the compound with cyanurate ring structure through calculations. Calculation data supported the existence of hybrid ring structure of cy-anurate/isocyanurate. It was revealed that isomerization from cyanurate to isocyanurate occurs via hybrid ring structure of cyanurate/isocyanurate in the reaction of aryl cyanurate and epoxy.展开更多
应用基于气相色谱-质谱联用(GC-MS)的代谢组学方法结合细胞周期实验,研究羽扇豆醇体外抑制人乳腺癌细胞MCF-7增殖的作用机理。代谢组学的研究结果表明:通过正交偏最小方差判别分析(OPLS-DA)可以很好地区分羽扇豆醇作用的MCF-7细胞代谢...应用基于气相色谱-质谱联用(GC-MS)的代谢组学方法结合细胞周期实验,研究羽扇豆醇体外抑制人乳腺癌细胞MCF-7增殖的作用机理。代谢组学的研究结果表明:通过正交偏最小方差判别分析(OPLS-DA)可以很好地区分羽扇豆醇作用的MCF-7细胞代谢谱与对照组细胞代谢谱,模型参数为:R2 Ycum=0.988,Q2 Ycum=0.964。VIP(variable importance in the projection)值大于1的差异代谢物进一步用t检验进行单位分析,选择t<0.05(VIP>1)的代谢物作为羽扇豆醇作用组的生物标志物,得到琥珀酸、磷酸、亮氨酸、异亮氨酸等11种代谢差异物。结合羽扇豆醇将细胞周期抑制在G1期这一现象,推测羽扇豆醇可能是主要抑制了三羧酸循环中的琥珀酰辅酶A的生成和底物磷酸化生成ATP的反应来抑制MCF-7细胞的增殖。本实验从代谢组学角度为乳腺癌抗肿瘤机制提供新的线索。展开更多
A novel approach to design Internal Model Controller(IMC)is proposed in this paper directly from measuredinput and output plant data,which are assumed to becontaminated by measurement noise.In order to avoidthe compli...A novel approach to design Internal Model Controller(IMC)is proposed in this paper directly from measuredinput and output plant data,which are assumed to becontaminated by measurement noise.In order to avoidthe complicated structure-identification problem inmost cases,two Finite Impulse Response(FIR)modelsare taken to represent the plant model and the internalmodel controller respectively.Taking account of mea-surement noise both in the plant input and its output,anESD based Total Least Squares(TLS)solution is appliedfor the unbiased identification of the plant model and itsinverse model,the latter constitutes the internal modelcontroller according to the principle that the internalmodel controller approximates the inverse dynamics ofthe plant model.Simulations are given for a testifica-tion.展开更多
A mixed-valent hexanuclear complex [Cu^ⅡCu^Ⅰ2(pbi)2Br2]2 (pbi = (2-(2-pyridyl)-benzimidazole) exhibiting a dimeric unit bridged by two Br atoms was synthesized by hydrothermal reaction Interestingly, there ex...A mixed-valent hexanuclear complex [Cu^ⅡCu^Ⅰ2(pbi)2Br2]2 (pbi = (2-(2-pyridyl)-benzimidazole) exhibiting a dimeric unit bridged by two Br atoms was synthesized by hydrothermal reaction Interestingly, there exist intramolecular and intermolecular n^zstacking interactions as well as metalaromatic ring interactions in the title complex. The crystal belongs to the monoclinic system, space group P1, with a = 7.1061(9), b = 12.1008(13), c = 14.0711(17) A, α=91.742(8),β=100.155(9), γ=90.486(7)°, V = 1190.3(2) A^3, Z = 2, C48H32Br4CucoNt2, Mr = 1477.74, Dc= 2.061 g/cm^3, F(000) = 718, μ(MoKα) = 6.039 mm^-1, the final R = 0.0481 and wR = 0.0974 for 3426 observed reflections (I 〉 2σ(I)).展开更多
A new Cu(Ⅱ) coordination polymer [Cu(inio)2(H2O)] (inio = isonicotinic acid N-oxide) with chemical formula C12H10CuN2O7 was prepared and its crystal structure has been determined by X-ray analysis. The complex crysta...A new Cu(Ⅱ) coordination polymer [Cu(inio)2(H2O)] (inio = isonicotinic acid N-oxide) with chemical formula C12H10CuN2O7 was prepared and its crystal structure has been determined by X-ray analysis. The complex crystallizes in the monoclinic system, space group C2/c with a = 12.455(3), b = 6.202(1), c = 16.555(3) ? b = 106.776(3), V = 1224.3(4) 3, Z = 4, Mr = 357.76, Dc =1.941 g/cm3, m(MoKa) = 1.827 mm-1, F(000) = 724, R = 0.0601 and wR = 0.1417 for 908 observed reflections (I > 2s(I)). The Cu(Ⅱ) atom is coordinated by an elongated square pyramid geometry. The deprotonated isonicotinic acid N-oxides form a double-bridge between each pair of Cu(Ⅱ) ions in trans form through two oxygen atoms from the carboxyl groups and two other oxygen atoms from the -NO groups, respectively, which leads to an infinite one dimensional chain. The two adjacent elongated Cu(Ⅱ) square pyramidal geometries are arranged in trans form in the same chain. The OH…O hydrogen bonds extend the chain structure into two-dimensional layers.展开更多
With the aid of the spectnnn techique, a new concept named-α-stabilizability (0≤α≤1) is intnxhged and its suffident and necessary canditions are also prvposed. Especially, it is identical with the asymptotically...With the aid of the spectnnn techique, a new concept named-α-stabilizability (0≤α≤1) is intnxhged and its suffident and necessary canditions are also prvposed. Especially, it is identical with the asymptotically mean square stabilizability when α = 1. As an application, the suboptimal state feedback H2/H∞ controller that satisfies the additional Spectrum canstmint via solving a convex optimization problem is delt with.展开更多
光腔衰荡方法是目前测量光学元件超高反射率(反射率>99.9%)的唯一方法。介绍了一种对光腔衰荡法中激光信号强度与时间关系的优化提取方法。设计了基于光腔衰荡法的光学元件超高反射比的测试系统,通过对采集的光腔衰荡曲线数据进行分...光腔衰荡方法是目前测量光学元件超高反射率(反射率>99.9%)的唯一方法。介绍了一种对光腔衰荡法中激光信号强度与时间关系的优化提取方法。设计了基于光腔衰荡法的光学元件超高反射比的测试系统,通过对采集的光腔衰荡曲线数据进行分段指数拟合,将光腔衰荡曲线数据分为5段,对每段指数拟合结果对应的R^(2)(R-square)和RMSE(root mean squared error)值进行对比分析,计算每段指数拟合的衰荡时间。实验结果表明:截取光腔衰荡曲线数据40%~60%部分拟合得到的结果最接近真实值,求得对应的腔镜的反射率为99.988 977%。最后通过与腔镜的自身反射率进行比较,表明该种数据拟合方法能有效地测量腔镜的反射率,并能减小实验数据本身带来的误差。展开更多
In this paper, we have proposed a metal-insulator-metal (MIM) pressure sensor which consists of two plasmonic waveguides and a double square ring resonator. The two square rings are connected via a rectangular patch...In this paper, we have proposed a metal-insulator-metal (MIM) pressure sensor which consists of two plasmonic waveguides and a double square ring resonator. The two square rings are connected via a rectangular patch located between the two of them. The surface plasmon polaritons (SPPs) can be transferred from a square ring to the other through this patch. The finite-difference time-domain method (FDTD) has been used to simulate the device. Applying a pressure on the structure, it deforms, and a red shift of 103 nm in the resonance wavelength has been calculated. The deformation is linearly proportional to the wavelength shift in a wide range of wavelength. The proposed optical plasmonic pressure sensor has a sensitivity of 16.5nm/MPa which makes it very suitable for using in biological and biomedical engineering.展开更多
基金supported by the National Natural Science Foundation of China (11272357 and 11102140)Doctoral Fund of Ministry of Education of China (200804251520 and 20110141120024)Natural Science Foundation of Shandong Province (ZR2009AQ006)
文摘In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thor- oughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materi- als, and hold potential for enhancing their mechanical, chemical, optical and electronic properties.
文摘Dynamic response of multispan viscoelastic thin beams subjected to a moving mass is studied by an efficient numerical method in some detail. To this end, the unknown parameters of the problem are discretized in spatial domain using generalized moving least square method (GMLSM) and then, discrete equations of motion based on Lagrange's equation are obtained. Maximum deflection and bending moments are considered as the important design parameters. The design parameter spectra in terms of mass weight and velocity of the moving mass are presented for multispan viscoelastic beams as well as various values of relaxation rate and beam span number. A reasonable good agreement is achieved between the results of the proposed solution and those obtained by other researchers. The results indicate that, although the load inertia effects in beams with higher span number would be intensified for higher levels of moving mass velocity, the maximum values of design parameters would increase either. Moreover, the possibility of mass separation is shown to be more critical as the span number of the beam increases. This fact also violates the linear relation between the mass weight of the moving load and the associated design parameters, especially for high moving mass velocities. However, as the relaxation rate of the beam material increases, the load inertia effects as well as the possibility of moving mass separation reduces.
基金supported by the Preeminent Youth Fund of Sichuan Province,China(Grant No.2012JQ0012)the National Natural Science Foundation of China(Grant Nos.11173008,10974202,and 60978049)the National Key Scientific and Research Equipment Development Project of China(Grant No.ZDYZ2013-2)
文摘For the accurate extraction of cavity decay time, a selection of data points is supplemented to the weighted least square method. We derive the expected precision, accuracy and computation cost of this improved method, and examine these performances by simulation. By comparing this method with the nonlinear least square fitting (NLSF) method and the linear regression of the sum (LRS) method in derivations and simulations, we find that this method can achieve the same or even better precision, comparable accuracy, and lower computation cost. We test this method by experimental decay signals. The results are in agreement with the ones obtained from the nonlinear least square fitting method.
基金This research was supported by the National Natural Science Foundation of Chin (11161006,11171142),the Guangxi Natural Science Foundation(2011GXNSFA018139)and Guangx“New Century 1000 Talents Project”.
文摘In this paper,for an arbitrary prime p,the square mapping graph of M2(Zp;s) is investigated and the formula of the decomposition of the square mapping graph of M2(Zp;s) is established.
文摘Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound which were well known as reaction products of cyanate esters and epoxy resins, compounds with hybrid ring structure of cyanurate/isocyanurate were determined. Gibbs free energies of the compound having hybrid ring structure of cyanurate/isocyanurate with two isocyanurate moiety were found to be lower than that of the compound with cyanurate ring structure through calculations. Calculation data supported the existence of hybrid ring structure of cy-anurate/isocyanurate. It was revealed that isomerization from cyanurate to isocyanurate occurs via hybrid ring structure of cyanurate/isocyanurate in the reaction of aryl cyanurate and epoxy.
文摘应用基于气相色谱-质谱联用(GC-MS)的代谢组学方法结合细胞周期实验,研究羽扇豆醇体外抑制人乳腺癌细胞MCF-7增殖的作用机理。代谢组学的研究结果表明:通过正交偏最小方差判别分析(OPLS-DA)可以很好地区分羽扇豆醇作用的MCF-7细胞代谢谱与对照组细胞代谢谱,模型参数为:R2 Ycum=0.988,Q2 Ycum=0.964。VIP(variable importance in the projection)值大于1的差异代谢物进一步用t检验进行单位分析,选择t<0.05(VIP>1)的代谢物作为羽扇豆醇作用组的生物标志物,得到琥珀酸、磷酸、亮氨酸、异亮氨酸等11种代谢差异物。结合羽扇豆醇将细胞周期抑制在G1期这一现象,推测羽扇豆醇可能是主要抑制了三羧酸循环中的琥珀酰辅酶A的生成和底物磷酸化生成ATP的反应来抑制MCF-7细胞的增殖。本实验从代谢组学角度为乳腺癌抗肿瘤机制提供新的线索。
文摘A novel approach to design Internal Model Controller(IMC)is proposed in this paper directly from measuredinput and output plant data,which are assumed to becontaminated by measurement noise.In order to avoidthe complicated structure-identification problem inmost cases,two Finite Impulse Response(FIR)modelsare taken to represent the plant model and the internalmodel controller respectively.Taking account of mea-surement noise both in the plant input and its output,anESD based Total Least Squares(TLS)solution is appliedfor the unbiased identification of the plant model and itsinverse model,the latter constitutes the internal modelcontroller according to the principle that the internalmodel controller approximates the inverse dynamics ofthe plant model.Simulations are given for a testifica-tion.
基金This work was supported by the 973 Program of the MOST (001CB108906), the NNSFC (90206040, 20425313, 20521101, 20333070, and 20303021), the NSF of Fujian Province (2005HZ01-1) and the Chinese Academy of Sciences
文摘A mixed-valent hexanuclear complex [Cu^ⅡCu^Ⅰ2(pbi)2Br2]2 (pbi = (2-(2-pyridyl)-benzimidazole) exhibiting a dimeric unit bridged by two Br atoms was synthesized by hydrothermal reaction Interestingly, there exist intramolecular and intermolecular n^zstacking interactions as well as metalaromatic ring interactions in the title complex. The crystal belongs to the monoclinic system, space group P1, with a = 7.1061(9), b = 12.1008(13), c = 14.0711(17) A, α=91.742(8),β=100.155(9), γ=90.486(7)°, V = 1190.3(2) A^3, Z = 2, C48H32Br4CucoNt2, Mr = 1477.74, Dc= 2.061 g/cm^3, F(000) = 718, μ(MoKα) = 6.039 mm^-1, the final R = 0.0481 and wR = 0.0974 for 3426 observed reflections (I 〉 2σ(I)).
基金the Natural Science Foundation of Xuzhou Normal University (01BXL009)
文摘A new Cu(Ⅱ) coordination polymer [Cu(inio)2(H2O)] (inio = isonicotinic acid N-oxide) with chemical formula C12H10CuN2O7 was prepared and its crystal structure has been determined by X-ray analysis. The complex crystallizes in the monoclinic system, space group C2/c with a = 12.455(3), b = 6.202(1), c = 16.555(3) ? b = 106.776(3), V = 1224.3(4) 3, Z = 4, Mr = 357.76, Dc =1.941 g/cm3, m(MoKa) = 1.827 mm-1, F(000) = 724, R = 0.0601 and wR = 0.1417 for 908 observed reflections (I > 2s(I)). The Cu(Ⅱ) atom is coordinated by an elongated square pyramid geometry. The deprotonated isonicotinic acid N-oxides form a double-bridge between each pair of Cu(Ⅱ) ions in trans form through two oxygen atoms from the carboxyl groups and two other oxygen atoms from the -NO groups, respectively, which leads to an infinite one dimensional chain. The two adjacent elongated Cu(Ⅱ) square pyramidal geometries are arranged in trans form in the same chain. The OH…O hydrogen bonds extend the chain structure into two-dimensional layers.
基金supported by the research project of “SDUST Spring Bud”(Grant No.2008AZZ090)the National Natural Science Foundation of China(Grant No.60874032)
文摘With the aid of the spectnnn techique, a new concept named-α-stabilizability (0≤α≤1) is intnxhged and its suffident and necessary canditions are also prvposed. Especially, it is identical with the asymptotically mean square stabilizability when α = 1. As an application, the suboptimal state feedback H2/H∞ controller that satisfies the additional Spectrum canstmint via solving a convex optimization problem is delt with.
文摘光腔衰荡方法是目前测量光学元件超高反射率(反射率>99.9%)的唯一方法。介绍了一种对光腔衰荡法中激光信号强度与时间关系的优化提取方法。设计了基于光腔衰荡法的光学元件超高反射比的测试系统,通过对采集的光腔衰荡曲线数据进行分段指数拟合,将光腔衰荡曲线数据分为5段,对每段指数拟合结果对应的R^(2)(R-square)和RMSE(root mean squared error)值进行对比分析,计算每段指数拟合的衰荡时间。实验结果表明:截取光腔衰荡曲线数据40%~60%部分拟合得到的结果最接近真实值,求得对应的腔镜的反射率为99.988 977%。最后通过与腔镜的自身反射率进行比较,表明该种数据拟合方法能有效地测量腔镜的反射率,并能减小实验数据本身带来的误差。
文摘In this paper, we have proposed a metal-insulator-metal (MIM) pressure sensor which consists of two plasmonic waveguides and a double square ring resonator. The two square rings are connected via a rectangular patch located between the two of them. The surface plasmon polaritons (SPPs) can be transferred from a square ring to the other through this patch. The finite-difference time-domain method (FDTD) has been used to simulate the device. Applying a pressure on the structure, it deforms, and a red shift of 103 nm in the resonance wavelength has been calculated. The deformation is linearly proportional to the wavelength shift in a wide range of wavelength. The proposed optical plasmonic pressure sensor has a sensitivity of 16.5nm/MPa which makes it very suitable for using in biological and biomedical engineering.