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Effect of external and internal cues on core muscle activation during the Sahrmann five-level core stability test
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作者 Skyla Stifter Jessie McCaffrey +2 位作者 Tyler Nichols Ayse Ozcan Edeer Justine Ward 《World Journal of Methodology》 2025年第1期95-104,共10页
BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of cor... BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of core muscle activation and a person's ability to stabilize the lumbopelvic complex.Preparatory cues and images can be used to increase the activation of these muscles.To attain optimal movement patterns,it will be necessary to determine what cueing will give the most effective results for core stability.AIM To investigate the effects of external and internal cues on core muscle activation during the Sahrmann five-level core stability test.METHODS Total 68 participants(21.83±3.47 years)were randomly allocated to an external(n=35)or internal cue group(n=33).Participants performed the Sahrmann fivelevel core stability test without a cue as baseline and the five-level stability exercises with an internal or external cue.External cue group received a pressure biofeedback unit(PBU),and the internal cue group received an audio cue.A Delsys Trigno^(TM)surface electromyography unit was used for muscle activation from the rectus abdominis,external oblique,and transverse abdominis/internal oblique muscles.RESULTS Linear mixed effects model analysis showed that cueing had a significant effect on core muscle activation(P=0.001);however,there was no significant difference between cue types(internal or external)(P=0.130).CONCLUSION Both external and internal cueing have significant effects on core muscle activation during the Sahrmann five-level core stability test and the PBU does not create higher muscle activation than internal cueing. 展开更多
关键词 External cue Internal cue Muscle activation Core muscles Lumbopelvic stability Pressure biofeedback unit
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Evaluation of slope stability through rock mass classification and kinematic analysis of some major slopes along NH-1A from Ramban to Banihal, North Western Himalayas 被引量:2
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作者 Amit Jaiswal A.K.Verma T.N.Singh 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第1期167-182,共16页
The network of Himalayan roadways and highways connects some remote regions of valleys or hill slopes,which is vital for India’s socio-economic growth.Due to natural and artificial factors,frequency of slope instabil... The network of Himalayan roadways and highways connects some remote regions of valleys or hill slopes,which is vital for India’s socio-economic growth.Due to natural and artificial factors,frequency of slope instabilities along the networks has been increasing over last few decades.Assessment of stability of natural and artificial slopes due to construction of these connecting road networks is significant in safely executing these roads throughout the year.Several rock mass classification methods are generally used to assess the strength and deformability of rock mass.This study assesses slope stability along the NH-1A of Ramban district of North Western Himalayas.Various structurally and non-structurally controlled rock mass classification systems have been applied to assess the stability conditions of 14 slopes.For evaluating the stability of these slopes,kinematic analysis was performed along with geological strength index(GSI),rock mass rating(RMR),continuous slope mass rating(CoSMR),slope mass rating(SMR),and Q-slope in the present study.The SMR gives three slopes as completely unstable while CoSMR suggests four slopes as completely unstable.The stability of all slopes was also analyzed using a design chart under dynamic and static conditions by slope stability rating(SSR)for the factor of safety(FoS)of 1.2 and 1 respectively.Q-slope with probability of failure(PoF)1%gives two slopes as stable slopes.Stable slope angle has been determined based on the Q-slope safe angle equation and SSR design chart based on the FoS.The value ranges given by different empirical classifications were RMR(37-74),GSI(27.3-58.5),SMR(11-59),and CoSMR(3.39-74.56).Good relationship was found among RMR&SSR and RMR&GSI with correlation coefficient(R 2)value of 0.815 and 0.6866,respectively.Lastly,a comparative stability of all these slopes based on the above classification has been performed to identify the most critical slope along this road. 展开更多
关键词 Rock mass classification Kinematic analysis Slope stability Himalayan road Static and dynamic conditions
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Probabilistic analysis of tunnel face seismic stability in layered rock masses using Polynomial Chaos Kriging metamodel 被引量:2
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作者 Jianhong Man Tingting Zhang +1 位作者 Hongwei Huang Daniel Dias 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第7期2678-2693,共16页
Face stability is an essential issue in tunnel design and construction.Layered rock masses are typical and ubiquitous;uncertainties in rock properties always exist.In view of this,a comprehensive method,which combines... Face stability is an essential issue in tunnel design and construction.Layered rock masses are typical and ubiquitous;uncertainties in rock properties always exist.In view of this,a comprehensive method,which combines the Upper bound Limit analysis of Tunnel face stability,the Polynomial Chaos Kriging,the Monte-Carlo Simulation and Analysis of Covariance method(ULT-PCK-MA),is proposed to investigate the seismic stability of tunnel faces.A two-dimensional analytical model of ULT is developed to evaluate the virtual support force based on the upper bound limit analysis.An efficient probabilistic analysis method PCK-MA based on the adaptive Polynomial Chaos Kriging metamodel is then implemented to investigate the parameter uncertainty effects.Ten input parameters,including geological strength indices,uniaxial compressive strengths and constants for three rock formations,and the horizontal seismic coefficients,are treated as random variables.The effects of these parameter uncertainties on the failure probability and sensitivity indices are discussed.In addition,the effects of weak layer position,the middle layer thickness and quality,the tunnel diameter,the parameters correlation,and the seismic loadings are investigated,respectively.The results show that the layer distributions significantly influence the tunnel face probabilistic stability,particularly when the weak rock is present in the bottom layer.The efficiency of the proposed ULT-PCK-MA is validated,which is expected to facilitate the engineering design and construction. 展开更多
关键词 Tunnel face stability Layered rock masses Polynomial Chaos Kriging(PCK) Sensitivity index Seismic loadings
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A Facile Li_(2)TiO_(3) Surface Modification to Improve the Structure Stability and Electrochemical Performance of Full Concentration Gradient Li-Rich Oxides 被引量:2
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作者 Naifang Hu Yuan Yang +5 位作者 Lin Li Yuhan Zhang Zhiwei Hu Lan Zhang Jun Ma Guanglei Cui 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期41-48,共8页
Full concentration gradient lithium-rich layered oxides are catching lots of interest as the next generation cathode for lithium-ion batteries due to their high discharge voltage,reduced voltage decay and enhanced rat... Full concentration gradient lithium-rich layered oxides are catching lots of interest as the next generation cathode for lithium-ion batteries due to their high discharge voltage,reduced voltage decay and enhanced rate performance,whereas the high lithium residues on its surface impairs the structure stability and long-term cycle performance.Herein,a facile multifunctional surface modification method is implemented to eliminate surface lithium residues of full concentration gradient lithium-rich layered oxides by a wet chemistry reaction with tetrabutyl titanate and the post-annealing process.It realizes not only a stable Li_(2)TiO_(3)coating layer with 3D diffusion channels for fast Li^(+)ions transfer,but also dopes partial Ti^(4+)ions into the sub-surface region of full concentration gradient lithium-rich layered oxides to further strengthen its crystal structure.Consequently,the modified full concentration gradient lithium-rich layered oxides exhibit improved structure stability,elevated thermal stability with decomposition temperature from 289.57℃to 321.72℃,and enhanced cycle performance(205.1 mAh g^(-1)after 150 cycles)with slowed voltage drop(1.67 mV per cycle).This work proposes a facile and integrated modification method to enhance the comprehensive performance of full concentration gradient lithium-rich layered oxides,which can facilitate its practical application for developing higher energy density lithium-ion batteries. 展开更多
关键词 full concentration gradient lithium-rich layered oxides structure stability surface modification
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Enhanced High-Temperature Cycling Stability of Garnet-Based All Solid-State Lithium Battery Using a Multi-Functional Catholyte Buffer Layer 被引量:1
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作者 Leqi Zhao Yijun Zhong +2 位作者 Chencheng Cao Tony Tang Zongping Shao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期59-73,共15页
The pursuit of safer and high-performance lithium-ion batteries(LIBs)has triggered extensive research activities on solid-state batteries,while challenges related to the unstable electrode-electrolyte interface hinder... The pursuit of safer and high-performance lithium-ion batteries(LIBs)has triggered extensive research activities on solid-state batteries,while challenges related to the unstable electrode-electrolyte interface hinder their practical implementation.Polymer has been used extensively to improve the cathode-electrolyte interface in garnet-based all-solid-state LIBs(ASSLBs),while it introduces new concerns about thermal stability.In this study,we propose the incorporation of a multi-functional flame-retardant triphenyl phos-phate additive into poly(ethylene oxide),acting as a thin buffer layer between LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cathode and garnet electro-lyte.Through electrochemical stability tests,cycling performance evaluations,interfacial thermal stability analysis and flammability tests,improved thermal stability(capacity retention of 98.5%after 100 cycles at 60℃,and 89.6%after 50 cycles at 80℃)and safety characteristics(safe and stable cycling up to 100℃)are demonstrated.Based on various materials characterizations,the mechanism for the improved thermal stability of the interface is proposed.The results highlight the potential of multi-functional flame-retardant additives to address the challenges associated with the electrode-electrolyte interface in ASSLBs at high temperature.Efficient thermal modification in ASSLBs operating at elevated temperatures is also essential for enabling large-scale energy storage with safety being the primary concern. 展开更多
关键词 Solid-state battery Cathode electrolyte interlayer Flame-retardant additive Cycling stability Interfacial stability
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Influence of variable viscosity and double diffusion on the convective stability of a nanofluid flow in an inclined porous channel 被引量:1
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作者 N.HUMNEKAR D.SRINIVASACHARYA 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第3期563-580,共18页
The influence of variable viscosity and double diffusion on the convective stability of a nanofluid flow in an inclined porous channel is investigated.The DarcyBrinkman model is used to characterize the fluid flow dyn... The influence of variable viscosity and double diffusion on the convective stability of a nanofluid flow in an inclined porous channel is investigated.The DarcyBrinkman model is used to characterize the fluid flow dynamics in porous materials.The analytical solutions are obtained for the unidirectional and completely developed flow.Based on a normal mode analysis,the generalized eigenvalue problem under a perturbed state is solved.The eigenvalue problem is then solved by the spectral method.Finally,the critical Rayleigh number with the corresponding wavenumber is evaluated at the assigned values of the other flow-governing parameters.The results show that increasing the Darcy number,the Lewis number,the Dufour parameter,or the Soret parameter increases the stability of the system,whereas increasing the inclination angle of the channel destabilizes the flow.Besides,the flow is the most unstable when the channel is vertically oriented. 展开更多
关键词 NANOFLUID inclined channel variable viscosity linear stability double dif-fusion porous medium
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Enhanced mechanical stability and corrosion resistance ofsuperhydrophobic coating reinforced with inorganic binder 被引量:1
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作者 ZHAO Li-xia LI Hong-yan +3 位作者 ZHOU Kun LIU Hai-xing WANG Jian ZHANG Bin-bin 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第10期3502-3516,共15页
The development of superhydrophobic materials has demonstrated significant potential in the realm ofcorrosion protection for aluminum alloy(Al alloy)surfaces.However,the limited mechanical stability ofsuperhydrophobic... The development of superhydrophobic materials has demonstrated significant potential in the realm ofcorrosion protection for aluminum alloy(Al alloy)surfaces.However,the limited mechanical stability ofsuperhydrophobic surfaces has impeded the rapid advancement in this field.In this research,we synthesized analuminum phosphate(AP)inorganic binder and combined it with hydrophobic fumed SiO_(2)(HF-SiO_(2))nanoparticles andpolydimethylsiloxane(PDMS)to develop a HF-SiO_(2)@PDMS@AP superhydrophobic composite coating with improvedmechanical stability on Al alloy substrates using a simple spray-coating technique.The findings indicate that the additionof the AP inorganic binder significantly enhanced the coating’s resistance to abrasion,maintaining its superhydrophobicproperties and micro-nano hierarchical structure even after being subjected to a sandpaper abrasion distance of 2000 cm.Electrochemical impedance spectroscopy(EIS)testing showed that the low-frequency modulus(|Z|0.01Hz)of theHF-SiO_(2)@PDMS@AP superhydrophobic coating increased by four orders of magnitude compared to the initial Al alloysubstrate,resulting in a substantial improvement in corrosion protection capacity.The impressive corrosion resistanceand mechanical stability exhibited by this coating have the potential to greatly expand the practical applications of suchmaterials for surface functional protection in marine and industrial environments. 展开更多
关键词 SUPERHYDROPHOBICITY ANTI-CORROSION stability SELF-CLEANING
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Gouge stability controlled by temperature elevation and obsidian addition in basaltic faults and implications for moonquakes 被引量:1
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作者 Shutian Cao Fengshou Zhang +4 位作者 Mengke An Derek Elsworth Manchao He Hai Liu Luanxiao Zhao 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1273-1282,共10页
Basalt is a major component of the earth and moon crust.Mineral composition and temperature influence frictional instability and thus the potential for seismicity on basaltic faults.We performed velocitystepping shear... Basalt is a major component of the earth and moon crust.Mineral composition and temperature influence frictional instability and thus the potential for seismicity on basaltic faults.We performed velocitystepping shear experiments on basalt gouges at a confining pressure of 100 MPa,temperatures in the range of 100-400℃ and with varied obsidian mass fractions of 0-100%under wet/dry conditions to investigate the frictional strength and stability of basaltic faults.We observe a transition from velocity-neutral to velocity-weakening behaviors with increasing obsidian content.The frictional stability response of the mixed obsidian/basalt gouges is characterized by a transition from velocitystrengthening to velocity-weakening at 200℃ and another transition to velocity-strengthening at temperatures>300℃.Conversely,frictional strengths of the obsidian-bearing gouges are insensitive to temperature and wet/dry conditions.These results suggest that obsidian content dominates the potential seismic response of basaltic faults with the effect of temperature controlling the range of seismogenic depths.Thus,shallow moonquakes tend to occur in the lower lunar crust due to the corresponding anticipated higher glass content and a projected temperature range conducive to velocity-weakening behavior.These observations contribute to a better understanding of the nucleation mechanism of shallow seismicity in basaltic faults. 展开更多
关键词 Fault stability Basaltic fault Temperature elevation Obsidian content Shallow moonquakes
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Mechanical Modeling and Analysis of Stability Deterioration of Production Well During Marine Hydrate Depressurization Production 被引量:1
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作者 SUN Huan-zhao CHANG Yuan-jiang +4 位作者 SUN Bao-jiang WANG Kang CHEN Guo-ming LI Hao DAI Yong-guo 《China Ocean Engineering》 SCIE EI CSCD 2024年第2期338-351,共14页
Different from oil and gas production,hydrate reservoirs are shallow and unconsolidated,whose mechanical properties deteriorate with hydrate decomposition.Therefore,the formations will undergo significant subsidence d... Different from oil and gas production,hydrate reservoirs are shallow and unconsolidated,whose mechanical properties deteriorate with hydrate decomposition.Therefore,the formations will undergo significant subsidence during depressurization,which will destroy the original force state of the production well.However,existing research on the stability of oil and gas production wells assumes the formation to be stable,and lacks consideration of the force exerted on the hydrate production well by formation subsidence caused by hydrate decomposition during production.To fill this gap,this paper proposes an analytical method for the dynamic evolution of the stability of hydrate production well considering the effects of hydrate decomposition.Based on the mechanical model of the production well,the basis for stability analysis has been proposed.A multi-field coupling model of the force state of the production well considering the effect of hydrate decomposition and formation subsidence is established,and a solver is developed.The analytical approach is verified by its good agreement with the results from the numerical method.A case study found that the decomposition of hydrate will increase the pulling-down force and reduce the supporting force,which is the main reason for the stability deterioration.The higher the initial hydrate saturation,the larger the reservoir thickness,and the lower the production pressure,the worse the stability or even instability.This work can provide a theoretical reference for the stability maintaining of the production well. 展开更多
关键词 natural gas hydrate production well depressurization production formation deformation stability deterioration
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Stability of the Stratification of Water Bodies in the North Passage of the Yangtze River Estuary Based on the EFDC Model 被引量:1
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作者 WU De’an LI Xin WANG Yigang 《Journal of Ocean University of China》 CAS CSCD 2024年第1期23-32,共10页
To study the stratified stability of a water column in the North Passage of the Yangtze River Estuary,a numerical model of the hydrodynamics of this estuary is established using the EFDC model.On the basis of EFDC res... To study the stratified stability of a water column in the North Passage of the Yangtze River Estuary,a numerical model of the hydrodynamics of this estuary is established using the EFDC model.On the basis of EFDC results,this paper derives and pro-vides the discriminative index of water body stability caused by salinity and analyzes the along-range variation in water body strati-fication stability in the North Passage of the Yangtze River Estuary and the periodic variation at a key location(bend area)based on the simulation results of the numerical model.This work shows that the water body in the bend area varies between mixed and strati-fied types,and the vertical average flow velocity has a good negative correlation with the differential velocity between the surface and bottom layers of the water body.The model simulation results validate the formulae for the stratified stability discriminant during spring tides. 展开更多
关键词 Yangtze Estuary North Passage EFDC model stratification stability salinity distribution
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Impact of spatially varying rock disturbance on rock slope stability 被引量:1
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作者 Dowon Park Radoslaw L.Michalowski 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第10期3907-3923,共17页
Degradation of rock mass produced by rock blasting,stress relief,and other causes is an important factor in the assessment of rock strength.Quantified as a disturbance factor,such degradation varies depending on blast... Degradation of rock mass produced by rock blasting,stress relief,and other causes is an important factor in the assessment of rock strength.Quantified as a disturbance factor,such degradation varies depending on blasting control,stress state and stress relief,and rock mass quality.This study focuses on the impact of disturbance on the safety of slopes.The disturbance in the rock mass is characterized by the geometry of the disturbed zone,its size,the magnitude,and the decaying rate with the distance away from the slope surface.A method accounting for decay of rock disturbance is presented.A study of the impact of rock disturbance characteristics on the quantitative stability measures of slopes was carried out.These characteristics included disturbed zone geometry,its thickness,the maximum magnitude of the disturbance factor,and the rate of disturbance decaying.The thickness of the disturbed zone and the maximum factor of disturbance were found to have the greatest impact.For example,the factor of safety for a 45slope in low-quality rock mass can decrease from 1.96 to 1.09 as the thickness of the disturbed zone increases from 1/4 of slope height H to the double of H and the maximum disturbance factor increases from 0.5 to 1.Uniform thickness of a disturbed zone was found to yield more conservative outcomes than the triangular zones did.The critical failure surfaces were found to be shallow for high rates of disturbance decay,and they were the deepest for spatially uniform disturbance factors. 展开更多
关键词 Disturbance decaying Blast damage Limit analysis Damage zone stability number
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Insights into ionic association boosting water oxidation activity and dynamic stability 被引量:1
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作者 Zanling Huang Shuqi Zhu +8 位作者 Yuan Duan Chaoran Pi Xuming Zhang Abebe Reda Woldu Jing-Xin Jian Paul K.Chu Qing-Xiao Tong Liangsheng Hu Xiangdong Yao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期99-109,I0004,共12页
There have been reports about Fe ions boosting oxygen evolution reaction(OER)activity of Ni-based catalysts in alkaline conditions,while the origin and reason for the enhancement remains elusive.Herein,we attempt to i... There have been reports about Fe ions boosting oxygen evolution reaction(OER)activity of Ni-based catalysts in alkaline conditions,while the origin and reason for the enhancement remains elusive.Herein,we attempt to identify the activity improvement and discover that Ni sites act as a host to attract Fe(Ⅲ)to form Fe(Ni)(Ⅲ)binary centres,which serve as the dynamic sites to promote OER activity and stability by cyclical formation of intermediates(Fe(Ⅲ)→Fe(Ni)(Ⅲ)→Fe(Ni)-OH→Fe(Ni)-O→Fe(Ni)OOH→Fe(Ⅲ))at the electrode/electrolyte interface to emit O_(2).Additionally,some ions(Co(Ⅱ),Ni(Ⅱ),and Cr(Ⅲ))can also be the active sites to catalyze the OER process on a variety of electrodes.The Fe(Ⅲ)-catalyzed overall water-splitting electrolyzer comprising bare Ni foam as the anode and Pt/Ni-Mo as the cathode demonstrates robust stability for 1600 h at 1000 mA cm^(-2)@~1.75 V.The results provide insights into the ioncatalyzed effects boosting OER performance. 展开更多
关键词 Oxygen evolution reaction Fe(Ⅲ)-catalysis Ni-Fe binary active centers Ion-catalyzed effects Robust stability
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Reliability analysis of slope stability by neural network,principal component analysis,and transfer learning techniques 被引量:1
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作者 Sheng Zhang Li Ding +3 位作者 Menglong Xie Xuzhen He Rui Yang Chenxi Tong 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第10期4034-4045,共12页
The prediction of slope stability is considered as one of the critical concerns in geotechnical engineering.Conventional stochastic analysis with spatially variable slopes is time-consuming and highly computation-dema... The prediction of slope stability is considered as one of the critical concerns in geotechnical engineering.Conventional stochastic analysis with spatially variable slopes is time-consuming and highly computation-demanding.To assess the slope stability problems with a more desirable computational effort,many machine learning(ML)algorithms have been proposed.However,most ML-based techniques require that the training data must be in the same feature space and have the same distribution,and the model may need to be rebuilt when the spatial distribution changes.This paper presents a new ML-based algorithm,which combines the principal component analysis(PCA)-based neural network(NN)and transfer learning(TL)techniques(i.e.PCAeNNeTL)to conduct the stability analysis of slopes with different spatial distributions.The Monte Carlo coupled with finite element simulation is first conducted for data acquisition considering the spatial variability of cohesive strength or friction angle of soils from eight slopes with the same geometry.The PCA method is incorporated into the neural network algorithm(i.e.PCA-NN)to increase the computational efficiency by reducing the input variables.It is found that the PCA-NN algorithm performs well in improving the prediction of slope stability for a given slope in terms of the computational accuracy and computational effort when compared with the other two algorithms(i.e.NN and decision trees,DT).Furthermore,the PCAeNNeTL algorithm shows great potential in assessing the stability of slope even with fewer training data. 展开更多
关键词 Slope stability analysis Monte Carlo simulation Neural network(NN) Transfer learning(TL)
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Effects of connected automated vehicle on stability and energy consumption of heterogeneous traffic flow system
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作者 申瑾 赵建东 +2 位作者 刘华清 姜锐 余智鑫 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期291-301,共11页
With the development of intelligent and interconnected traffic system,a convergence of traffic stream is anticipated in the foreseeable future,where both connected automated vehicle(CAV)and human driven vehicle(HDV)wi... With the development of intelligent and interconnected traffic system,a convergence of traffic stream is anticipated in the foreseeable future,where both connected automated vehicle(CAV)and human driven vehicle(HDV)will coexist.In order to examine the effect of CAV on the overall stability and energy consumption of such a heterogeneous traffic system,we first take into account the interrelated perception of distance and speed by CAV to establish a macroscopic dynamic model through utilizing the full velocity difference(FVD)model.Subsequently,adopting the linear stability theory,we propose the linear stability condition for the model through using the small perturbation method,and the validity of the heterogeneous model is verified by comparing with the FVD model.Through nonlinear theoretical analysis,we further derive the KdV-Burgers equation,which captures the propagation characteristics of traffic density waves.Finally,by numerical simulation experiments through utilizing a macroscopic model of heterogeneous traffic flow,the effect of CAV permeability on the stability of density wave in heterogeneous traffic flow and the energy consumption of the traffic system is investigated.Subsequent analysis reveals emergent traffic phenomena.The experimental findings demonstrate that as CAV permeability increases,the ability to dampen the propagation of fluctuations in heterogeneous traffic flow gradually intensifies when giving system perturbation,leading to enhanced stability of the traffic system.Furthermore,higher initial traffic density renders the traffic system more susceptible to congestion,resulting in local clustering effect and stop-and-go traffic phenomenon.Remarkably,the total energy consumption of the heterogeneous traffic system exhibits a gradual decline with CAV permeability increasing.Further evidence has demonstrated the positive influence of CAV on heterogeneous traffic flow.This research contributes to providing theoretical guidance for future CAV applications,aiming to enhance urban road traffic efficiency and alleviate congestion. 展开更多
关键词 heterogeneous traffic flow CAV linear stability nonlinear stability energy consumption
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O-doping strategy enabling enhanced chemical/electrochemical stability of Li_(3)InCl_(6) for superior solid-state battery performance
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作者 Qiyue Luo Chen Liu +7 位作者 Lin Li Ziling Jiang Jie Yang Shaoqing Chen Xia Chen Long Zhang Shijie Cheng Chuang Yu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第12期484-494,共11页
Solid-state electrolytes with high oxidation stability are crucial for achieving high power density allsolid-state lithium batteries.Halide electrolytes are promising candidates due to their outstanding compatibility ... Solid-state electrolytes with high oxidation stability are crucial for achieving high power density allsolid-state lithium batteries.Halide electrolytes are promising candidates due to their outstanding compatibility with cathode materials and high Li^(+)conductivity.However,the electrochemical stability of chloride electrolytes is still limited,leaving them unsuitable for ultrahigh voltage operation.Besides,chemical compatibility issue between sulfide and halide electrolytes affects the electrochemical performance of all-solid-state batteries.Herein,Li-ion conductor Li_(3+x)InCl_(6-x)O_(x) is designed to address these challenges.Li_(3.25)InCl_(5.75)O_(0.25)shows a Li-ion conductivity of 0.90 mS cm^(-1)at room temperature,a high onset oxidation voltage of 3.84 V,fewer by-products at ultrahigh operation voltage,and good chemical compatibility with Li_(5.5)PS_(4.5)Cl_(1.5).The Li_(3.25)InCl_(5.75)O_(0.25)@LiNi_(0.7)Co_(0.1)Mn_(0.2)O_(2)-Li_(3.25)InCl_(5.75)O_(0.25)-VGCF/Li_(3.25)InCl_(5.75)O_(0.25)/Li_(5.5)PS_(4.5)Cl_(1.5)/Li-In battery delivers good electrochemical performances at high operating voltage.This work provides a simple,economical,and effective strategy for designing high-voltage all-solid-state electrolytes. 展开更多
关键词 Li_(3)InCl_(6) O doping Wide electrochemical window Chemical stability Interfacial stability Superior electrochemical performance
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Confinement and synergy effects of supported-confined bimetal catalysts with superior stability and catalytic activity
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作者 Yujun Sheng Farah Hazmatulhaq +5 位作者 Abdullah Al Mahmud Mostafa S.Sayed Iftikhar Hussain Stefano Leoni Wail Al Zoubi Young Gun Ko 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第12期93-99,共7页
Bimetallic nanocrystals have attracted considerable attention because of their complicated systems,which are far superior to those of their individual constituents.A TiO_(2)-confined PtMnP bimetallic catalyst(PtMnP@Ti... Bimetallic nanocrystals have attracted considerable attention because of their complicated systems,which are far superior to those of their individual constituents.A TiO_(2)-confined PtMnP bimetallic catalyst(PtMnP@TiO_(2)) was prepared using an ultrasonic-assisted coincident strategy,which demonstrated exceptional catalytic activity in the universal hydrogen evolution reaction (HER).Owing to the bimetallic synergistic effect and TiO_(2) confinement,PtMnP@TiO_(x)showed ultrasmall metal nanoparticles (NPs),a higher active Pt^(0) content,adequate activation at the porous surface,and abundant acid sites.Simulations were performed to visualize the strain properties of Mn and Pt during the bending process and demonstrate the high activity of Pt.The Pt-Mn bimetallic catalysts were enriched with Pt NPs,convoyed by electron transfer from Mn to Pt.Briefly,PtMnP@TiO_(2) showed robust evolution reaction activities (an overpotential of 220 mV at a current density of 10 mA cm^(-2) and a Tafel slope of 186 mV dec^(-1))and the ability to contrast stated catalysts without ultrasonication-plasma.This protocol revealed that the geometrical and electronic effects of Pt and P surrounding the Mn species in PtMnP@TiO_(2) were crucial for increasing the catalytic activity (99%) and durability (over 20 cycles),which were far superior to those of other reported catalysts. 展开更多
关键词 SYNERGY BIMETAL Catalyst stability Activity
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Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability
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作者 Bingning Wang Xianzhe Wang +3 位作者 Song Yang Chao Yang Huiling Fan Ju Shangguan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第7期203-216,共14页
The removal of organic sulfur through catalytic hydrolysis is a significant area of research in the field of desulfurization.This review provides an overview of recent advancements in catalytic hydrolysis technology o... The removal of organic sulfur through catalytic hydrolysis is a significant area of research in the field of desulfurization.This review provides an overview of recent advancements in catalytic hydrolysis technology of organic sulfur,including the activity,stability,and atmosphere effects of hydrolysis catalysts.The emphasis is on strategies for enhancing hydrolysis activity and anti-oxygen poisoning property of catalysts.Surface modification,metal doping and nitrogen doping have been found to improve the activity of catalysts.Alkaline components modification is the most commonly used method,the formation of oxygen vacancies through metal doping and creation of nitrogen basic sites through nitrogen doping also contribute to the hydrolysis of organic sulfur.The strategies for anti-oxygen poisoning are discussed in a systematic manner.The structural regulation of catalysts is beneficial for the desorption and diffusion of hydrogen sulfide(H_(2)S),thereby effectively inhibiting its oxidation.Nitrogen doping and the addition of electronic promoters such as transition metals can protect active sites and decrease the number of active oxygen species.These methods have been proven to enhance the anti-poisoning performance of catalysts.Additionally,this article summarizes how different atmospheres affect the activity of hydrolysis catalysts.The objective of this review is to pave the way for the development of efficient,stable and widely used catalysts for organic sulfur hydrolysis. 展开更多
关键词 Organic sulfur HYDROLYSIS CATALYSTS ACTIVITY stability
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Interfacial modification using the cross-linkable tannic acid for highly-efficient perovskite solar cells with excellent stability
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作者 Xing Gao Lirong Rong +6 位作者 Fei Wu Yen-Hung Lin Ye Zeng Junhong Tan Rongxing He Cheng Zhong Linna Zhu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期236-244,共9页
Although the performance of perovskite solar cells(PSCs)has been dramatically increased in recent years,stability is still the main obstacle preventing the PSCs from being commercial.PSC device instability can be caus... Although the performance of perovskite solar cells(PSCs)has been dramatically increased in recent years,stability is still the main obstacle preventing the PSCs from being commercial.PSC device instability can be caused by a variety of reasons,including ions diffusion,surface and grain boundary defects,etc.In this work,the cross-linkable tannic acid(TA)is introduced to modify perovskite film through post-treatment method.The numerous organic functional groups(–OH and C=O)in TA can interact with the uncoordinated Pb^(2+)and I^(-)ions in perovskite,thus passivating defects and inhibiting ions diffusion.In addition,the formed TA network can absorb a small amount of the residual moisture inside the device to protect the perovskite layer.Furthermore,TA modification regulates the energy level of perovskite,and reduces interfacial charge recombination.Ultimately,following TA treatment,the device efficiency is increased significantly from 21.31%to 23.11%,with a decreased hysteresis effect.Notably,the treated device shows excellent air,thermal,and operational stability.In light of this,the readily available,inexpensive TA has the potential to operate as a multipurpose interfacial modifier to increase device efficiency while also enhancing device stability. 展开更多
关键词 Tannic acid Defect passivation lons diffusion HYDROPHILIC stability Perovskite solar cells
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Significantly enhanced thermal stability of HMX by phase-transition lysozyme coating
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作者 Jiahui Liu Congmei Lin +3 位作者 Jianhu Zhang Chengcheng Zeng Zhijian Yang Fude Nie 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第5期60-68,共9页
A new robust bio-inspired route by using lysozyme aqueous solution for surface modification on 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX)was described in this paper.HMX crystals were coated by in situ phase transitio... A new robust bio-inspired route by using lysozyme aqueous solution for surface modification on 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX)was described in this paper.HMX crystals were coated by in situ phase transition of lysozyme(PTL)molecules.The HMX decorated by PTL was characterized by SEM,XRD,FTIR and XPS,demonstrating a dense core-shell coating layer.The coverage of lysozyme on HMX crystal was calculated by the ratio of sulfur content.The surface coverage increased from 60.5% to 93.5% when the content of PTL was changed from 0.5 wt% to 2.0 wt%,indicating efficient coating.The thermal stability of HMX was investigated by in situ XRD and DSC.The thermal phase transition temperature of HMX(β to δ phase)was delayed by 42℃ with 2.0 wt% PTL coating,which prevented HMX from thermal damage and sensitivity by the effect of PTL coating.After heating at 215℃,large cracks appeared in the naked HMX crystal,while the PTL coated HMX still maintained intact,with the impact energy of HMX dropped dramatically from 5 J to 2 J.However,the impact energy of HMX with 1.0 wt% and 2.0 wt% coating content(HMX@PTL-1.0 and HMX@PTL-2.0)was unchanged(5 J).Present results potentially enable large-scale fabrication of polymorphic energetic materials with outstanding thermal stability by novel lysozyme coating. 展开更多
关键词 HMX LYSOZYME Phase transition Thermal stability Sensitivity
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Sodium Nitrate/Formamide Deep Eutectic Solvent as Flame-Retardant and Anticorrosive Electrolyte Enabling 2.6 V Safe Supercapacitors with Long Cyclic Stability
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作者 Huachao Yang Yiheng Qi +6 位作者 Zifan Wang Qinghu Pan Chuanzhi Zhang Jianhua Yan Kefa Cen Zheng Bo Kostya(Ken)Ostrikov 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期374-383,共10页
Safe operation of electrochemical capacitors(supercapacitors)is hindered by the flammability of commercial organic electrolytes.Non-flammable Water-in-Salt(WIS)electrolytes are promising alternatives;however,they are ... Safe operation of electrochemical capacitors(supercapacitors)is hindered by the flammability of commercial organic electrolytes.Non-flammable Water-in-Salt(WIS)electrolytes are promising alternatives;however,they are plagued by the limited operation voltage window(typically≤2.3 V)and inherent corrosion of current collectors.Herein,a novel deep eutectic solvent(DES)-based electrolyte which uses formamide(FMD)as hydrogen-bond donor and sodium nitrate(NaNO_(3))as hydrogen-bond acceptor is demonstrated.The electrolyte exhibits the wide electrochemical stability window(3.14 V),high electrical conductivity(14.01 mScm^(-1)),good flame-retardance,anticorrosive property,and ultralow cost(7%of the commercial electrolyte and 2%of WIS).Raman spectroscopy and Density Functional Theory calculations reveal that the hydrogen bonds between the FMD molecules and NO_(3)^(-)ions are primarily responsible for the superior stability and conductivity.The developed NaNO_(3)/FMD-based coin cell supercapacitor is among the best-performing state-of-art DES and WIS devices,evidenced by the high voltage window(2.6 V),outstanding energy and power densities(22.77 Wh kg^(-1)at 630 W kg^(-1)and 17.37 kW kg^(-1)at 12.55 Wh kg^(-1)),ultralong cyclic stability(86%after 30000 cycles),and negligible current collector corrosion.The NaNO_(3)/FMD industry adoption potential is demonstrated by fabricating 100 F pouch cell supercapacitors using commercial aluminum current collectors. 展开更多
关键词 cyclic stability deep eutectic solvents electrical conductivity electrochemical stability window SUPERCAPACITORS
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