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Stabilizing effect of plasma discharge on bubbling fluidized granular bed 被引量:1
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作者 胡茂彬 党赛超 +1 位作者 马强 夏维东 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第7期288-292,共5页
Fluidized beds have been widely used for processing granular materials. In this paper, we study the effect of plasma on the fluidization behavior of a bubbling fluidized bed with an atmospheric pressure plasma dischar... Fluidized beds have been widely used for processing granular materials. In this paper, we study the effect of plasma on the fluidization behavior of a bubbling fluidized bed with an atmospheric pressure plasma discharger. Experiment results show that the bubbling fluidized bed is stabilized with the discharge of plasma. When the discharge current reaches a minimum stabilization current Cms, air bubbles in the bed will disappear and the surface fluctuation is completely suppressed.A simplified model is proposed to consider the effect of electric Coulomb force generated by the plasma. It is found that the Coulomb force will propel the particles to move towards the void area, so that the bubbling fluidized bed is stabilized with a high enough plasma discharge. 展开更多
关键词 plasma fluidized bed granular matter stabilization effect
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Fullerene bisadduct stabilizers:The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin 被引量:1
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作者 Ling Liao Bo Jin +3 位作者 Zhi-cheng Guo Fei Xian Chen-jie Hou Ru-fang Peng 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2021年第6期1944-1953,共10页
To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose(NC)/nitroglycerine(NG),we synthesized N-(... To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose(NC)/nitroglycerine(NG),we synthesized N-(4-methoxy)phenylpyrrolidine-C_(60) and four different of bis(N-(4-methoxy)phenylpyrrolidine)-C_(60) compounds through Prato reaction.Their structures were characterized by UVevis,^(1)H NMR,^(13)C NMR,high-resolution mass spectroscopy,and single-crystal X-ray diffraction.Their stabilization effect to NC/NG were investigated using differential scanning calorimetry,methyl violet,vacuum stabilization effect,weight loss,and accelerating rate calorimeter tests.The results indicated these compounds had excellent stabilization effect to NC/NG.The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C_(60).Moreover,the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different,and its stabilization effect to NC is also different.The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows:e-edge>trans-2>cis-2>trans-3.Electron paramagnetic resonance(EPR)and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG.The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide,and their ability is better than that of the monoadduct and C_(60),which is consistent with the results of stabilization effect performance test. 展开更多
关键词 Fulleropyrrolidine bisadducts stabilization effect Nitrocellulose/nitroglycerine
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EFFECT OF HYDRATION ON THE THERMAL STABILITY OF ENZYME 被引量:1
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作者 Yun Na LIU Fu TAN Institute of Chemistry,Academia Sinica,Beijing 100080 《Chinese Chemical Letters》 SCIE CAS CSCD 1990年第3期283-284,共2页
The thermal stability of New Zealand culture rabbit muscle aldolase was investigated by differential scanning calorimetry in the water content range 0.23-3.70 g water per g protein.The experimental results showed that... The thermal stability of New Zealand culture rabbit muscle aldolase was investigated by differential scanning calorimetry in the water content range 0.23-3.70 g water per g protein.The experimental results showed that at water contents below 0.47g/g,an endothermic peak was observed and at water contents above 0.57g/g,an endothermic and an exothermic peak were both observed on DSC thermogram.Thermal denaturation result of the enzyme and the relationship between two transition temperatures and water contents were first reported in this paper.Up to now we have not seen any similar reports concerning the exothermic transition. 展开更多
关键词 429 effect OF HYDRATION ON THE THERMAL STABILITY OF ENZYME
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Effect of initial nickel particle size on stability of nickel catalysts for aqueous phase reforming 被引量:2
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作者 Tomas van Haasterecht Marten Swart +1 位作者 Krijn P.de Jong Johannes Hendrik Bitter 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第2期287-294,共8页
The deactivation behavior by crystallite growth of nickel nanoparticles on various supports(carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3) was investigated in the aqueous phase reforming of ethylene glyco... The deactivation behavior by crystallite growth of nickel nanoparticles on various supports(carbon nanofibers, zirconia, Si C, α-Al2O3 and γ-Al2O3) was investigated in the aqueous phase reforming of ethylene glycol. Supported Ni catalysts of ~10 wt% were prepared by impregnation of carbon nanofibers(CNF),Zr O2, SiC, γ-Al2O3 and α-Al2O3. The extent of the Ni nanoparticle growth on various support materials follows the order CNF ~ ZrO2〉 SiC 〉 γ-Al2O3〉〉 α-Al2O3 which sequence, however, was determined by the initial Ni particle size. Based on the observed nickel leaching and the specific growth characteristics; the particle size distribution and the effect of loading on the growth rate, Ostwald ripening is suggested to be the main mechanism contributing to nickel particle growth. Remarkably, initially smaller Ni particles(~12 nm) supported on α-Al2O3 were found to outgrow Ni particles with initially larger size(~20 nm). It is put forward that the higher susceptibility with respect to oxidation of the smaller Ni nanoparticles and differences in initial particle size distribution are responsible for this behavior. 展开更多
关键词 Aqueous phase reforming Particle growth Catalyst stability Ostwald ripening Leaching Nickel catalysts Particle size effect Support effect
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First-Principles Calculations of the Quantum Size Effects on the Stability and Reactivity of Ultrathin Ru (0001) Films
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作者 武明义 贾瑜 孙强 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第6期131-135,共5页
We carry out first-principles calculations of Ru(0001) films up to 30 monolayers (MLs) to study the quantum size effect (Q, SE) of Ru films for two cases: the freestanding Ru films and Ru films on Pt(111) sub... We carry out first-principles calculations of Ru(0001) films up to 30 monolayers (MLs) to study the quantum size effect (Q, SE) of Ru films for two cases: the freestanding Ru films and Ru films on Pt(111) substrates. Our studies show that the properties of these films (surface energy, work-function, charge density decay length in a vacuum and chemical reactivity) exhibit pronounced oscillatory behavior as a function of the film thickness, with an oscillation period of about four MLs for both cases due to the relationship of the match between the Fermi wave vector and the film thickness. Due to the localization of d-electron of Ru films, these quantum oscillations almost disappear when the thickness of the film is more than -20 ML for the free standing Ru films, while for the Ru films on Pt substrates the oscillations disappear quickly when the thickness of the film is beyond -13 ML. Our results reveal that the stability and reactivity of the Ru films could be tailored through Q, SE and the Ru bilayer grown on Pt substrates observed in the experiment is also related to the effect. 展开更多
关键词 First-Principles Calculations of the Quantum Size effects on the Stability and Reactivity of Ultrathin Ru Pt FILMS
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STUDY ON THE STABILITY AND STACKING INTERACTION EFFECT OF THE TERNARY M(Ⅱ)(ATP)AND PYRIDINE-LIKE LIGANDS
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作者 Bin SONG Jie ZHANG Fu Hai WU Liang Nian JI Biotechnology Research Center,Chemistry Department Zhongshan University,Guangzhou 510275 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第12期1097-1100,共4页
The stabilities of the complexes of three pyridine-like ligands with M(II)(ATP)^(2-) and M(II)(M=Ni,Co)were studied by spectrophotometry and by comparing the stability constants of the ternary complexes with these of ... The stabilities of the complexes of three pyridine-like ligands with M(II)(ATP)^(2-) and M(II)(M=Ni,Co)were studied by spectrophotometry and by comparing the stability constants of the ternary complexes with these of the binary complexes.A stacking interaction between the pyridine ring and the purine ring of ATP is indicated.The general existence of the stacking interaction encourages us to interpret the antitumor mechanism of a new class of antitumor drugs. 展开更多
关键词 ATP)AND PYRIDINE-LIKE LIGANDS STUDY ON THE STABILITY AND STACKING INTERACTION effect OF THE TERNARY M
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THE EFFECT OF ACID TREATMENT ON THE STABILITY OF POLYMORPHS IN BETA ZEOLITE
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作者 Jian Ping SHEN Jun MA +1 位作者 Jun GUO Da Zhen JINAG and En Ze MIN (Department of Chemistry, Jilin University,Changchun,130023)(Research Iustitute of Petroleum Processing, Beijing, 100080) 《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第12期1075-1078,共4页
The stability of beta zeollie in acid solution and the effect of acid treatment on the polymorphs in beta zeolite were studied. This zeolite is easily dealuminated by HCI treatment but its framework highly resistent t... The stability of beta zeollie in acid solution and the effect of acid treatment on the polymorphs in beta zeolite were studied. This zeolite is easily dealuminated by HCI treatment but its framework highly resistent to acidity.In β zeolite, polymorph A is less stable than polymorph B.The chirality of β zeolite can be modified by the method of acid treatment. 展开更多
关键词 ACID THE effect OF ACID TREATMENT ON THE STABILITY OF POLYMORPHS IN BETA ZEOLITE
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Site 0ccupancy of Alloying Elements and Their Effects on the D0_3 Phase Stability in Fe_3Al
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作者 Jun CAF Shaojun LIU Ying LOU and Benkuan usDepartment 0f Physics, Beijing N0rmal University, Beijing lO0875, ChinaSuqing D UANInstitute of Applied Physics and Computati0nal Mathematics, Beijing 100088, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1999年第4期339-341,共3页
The effects of ternary solutes Ti, Co, V, Cr, Ta, W and Mo on the D03 phase 5tability of Fe3Alintermetallics are investigated by tight-binding linear Muffin-tin orbitaI method. The predictedsite preference5 of these e... The effects of ternary solutes Ti, Co, V, Cr, Ta, W and Mo on the D03 phase 5tability of Fe3Alintermetallics are investigated by tight-binding linear Muffin-tin orbitaI method. The predictedsite preference5 of these elements in Fe3AI are in agreement with the experimental observations.The calculated Iocal magnetic moment of Fe3AI is identical to the experimentaI. ln addition, itis found that the D03 phase stability of Fe3AI doped with Ti, V, Co and Cr depends on 'energygap- of energy band near Fermi level. while the D03 phase stability of Fe3AI doped with Ta, Wand Mo may be affected by Madelung energy. 展开更多
关键词 Al FE Site 0ccupancy of Alloying Elements and Their effects on the D03 Phase Stability in Fe3Al
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Vinylogous Fluorine Stabilizing Effect Enables Rational Design of a Novel Donor-Acceptor Cyclopropane and Its Applications in[3+2]Cycloaddition Reaction and Ring-Opening Polymerization
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作者 Yue Li Dian-Feng Chen 《Chinese Journal of Chemistry》 SCIE CAS 2024年第22期2723-2727,共5页
Comprehensive Summary Discovery of unprecedented donor-acceptor patterns can essentially enrich the chemistry of donor-acceptor cyclopropanes.We herein introduce a concept of vinylogous fluorine stabilizing effect,whi... Comprehensive Summary Discovery of unprecedented donor-acceptor patterns can essentially enrich the chemistry of donor-acceptor cyclopropanes.We herein introduce a concept of vinylogous fluorine stabilizing effect,which guides rational design of a novel donor-acceptor cyclopropane employing gem-difluorovinyl group as the electron donor,namely dFVCP.Application of such dFVCPs in a[3+2]cycloaddition with aldehydes and a controlled ring-opening polymerization by a Mg(OTf)2/DIPEA/C(sp3)-H initiator system have been demonstrated,providing direct access to fluorine-containing tetrahydrofurans and all-carbon main-chain polymers. 展开更多
关键词 Donor-acceptor cyclopropane gem-Difluorovinyl group Vinylogous fluorine stabilizing effect [3+2]cycloaddition Ring-opening polymerization Strainedmolecules Monomers lonic polymerization
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Analysis of mechanical behavior of soft rocks and stability control in deep tunnels 被引量:5
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作者 Hui Zhou Chuanqing Zhang +2 位作者 Zhen Li Dawei Hu Jing Hou 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2014年第3期219-226,共8页
Due to the weakness in mechanical properties of chlorite schist and the high in situ stress in Jinping II hydropower station, the rock mass surrounding the diversion tunnels located in chlorite schist was observed wit... Due to the weakness in mechanical properties of chlorite schist and the high in situ stress in Jinping II hydropower station, the rock mass surrounding the diversion tunnels located in chlorite schist was observed with extremely large deformations. This may significantly increase the risk of tunnel instability during excavation. In order to assess the stability of the diversion tunnels laboratory tests were carried out in association with the petrophysical properties, mechanical behaviors and waterlweakening properties of chlorite schist. The continuous deformation of surrounding rock mass, the destruction of the support structure and a large-scale collapse induced by the weak chlorite schist and high in situ stress were analyzed. The distributions of compressive deformation in the excavation zone with large deformations were also studied. In this regard, two reinforcement schemes for the excavation of diversion tunnel bottom section were proposed accordingly. This study could offer theoretical basis for deed tunnel construction in similar geological condition~ 展开更多
关键词 Deep tunnel Soft rock Water-weakening effect Large deformation Stability
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ON A NEW 3D MODEL FOR INCOMPRESSIBLE EULER AND NAVIER-STOKES EQUATIONS
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作者 王术 《Acta Mathematica Scientia》 SCIE CSCD 2010年第6期2089-2102,共14页
In this paper, we investigate some new properties of the incompressible Euler and Navier-Stokes equations by studying a 3D model for axisymmetric 3D incompressible Euler and Navier-Stokes equations with swirl. The 3D ... In this paper, we investigate some new properties of the incompressible Euler and Navier-Stokes equations by studying a 3D model for axisymmetric 3D incompressible Euler and Navier-Stokes equations with swirl. The 3D model is derived by reformulating the axisymmetric 3D incompressible Euler and Navier-Stokes equations and then neglecting the convection term of the resulting equations. Some properties of this 3D model are reviewed. Finally, some potential features of the incompressible Euler and Navier-Stokes equations such as the stabilizing effect of the convection are presented. 展开更多
关键词 finite time singularities nonlinear nonlocal system stabilizing effect of con- vection incompressible Euler and Navier-Stokes equations
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GPU-based discrete element simulation on flow stability of flat-bottomed hopper 被引量:1
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作者 Li Peng Zheng Zou +2 位作者 Libo Zhang Qingshan Zhu Hongzhong Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第1期43-52,共10页
In this study, the flow stability of the flat-bottomed hopper was investigated via GPU-based discrete element method(DEM) simulation. With the material height inside the hopper reducing, the fluctuation of the flow ra... In this study, the flow stability of the flat-bottomed hopper was investigated via GPU-based discrete element method(DEM) simulation. With the material height inside the hopper reducing, the fluctuation of the flow rate indicates an unstable discharge. The flow regions of the unstable discharge were compared with that of the stable discharge, a key transformation zone, where the voidage showed the largest difference between unstable and stable discharge, was revealed. To identify the relevance of the key transformation zone and the hopper flow stability, the voidage variation of the key transformation zone with material height reducing was studied.A sharp increase in the voidage in the key transformation zone was considered to be the standard for judging the unstable hopper flow, and the ‘Top–Bottom effect' of the hopper was defined, which indicated the hopper flow was unstable when the hopper only had the top area and the bottom area, because the voidage of particles in the top area and the bottom area were both variables. 展开更多
关键词 Stability Discrete element method(DEM) Granular flow Top-Bottom effect Flow regions
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EFFECTIVE STABILITY FOR NEARLY INTEGRABLE MAPPINGS WITH INTERSECTION PROPERTY
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作者 Han Yuliang Cong Fuzhong 《Annals of Differential Equations》 2005年第3期294-299,共6页
We consider a nearly integrable mapping with a fixed twist frequency. Under the intersection property and Diophantine condition we prove that the mapping possesses effective stability. In particular, the mapping consi... We consider a nearly integrable mapping with a fixed twist frequency. Under the intersection property and Diophantine condition we prove that the mapping possesses effective stability. In particular, the mapping considered may have different dimensions of action-angle variables in our case. 展开更多
关键词 effective stability nearly integrable mapping intersection prooertv
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Numerical Simulation of Active Suppression of Rotating Stallin Axial Compression Systems 被引量:2
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作者 JunHu LeonhardFottner 《Journal of Thermal Science》 SCIE EI CAS CSCD 1996年第4期231-242,共12页
In the present paper, a theoretical model is proposed to analyze the transient behavior of suppression of rotating stall in axial compression systems through the use of an additional disturbance. The governing equatio... In the present paper, a theoretical model is proposed to analyze the transient behavior of suppression of rotating stall in axial compression systems through the use of an additional disturbance. The governing equations of the model are a set of simultaneous nonlinear first order partial differential equations,and for numerical calculations, a simple explicit time marching method can be used. The influence of system parameters on the suppression effectiveness and the interaction between rotating stall and surge have been discussed initially. The analysis of the influence of system parameters presents that both the B parameter and axisymmetric compressor characteristic have significant effect on the stabilization effectiveness of a control strategy. The effectiveness decreases as the value of B and the number of stages or stage loading of the compressor increase. It has been found that the onset flow rate of rotating stall and surge in a compression system may be different, and there is a strong interaction between these two kinds of instabilities. The onset flow rate of pure one dimensional surge depends on the value of B and axisymmetric compressor characteristic, besides the slope of the compressor characteristic.In some cases, when rotating stall which is the natural mode of instability in a compression system is suppressed, one dimensional surge can occur. It often limits the effectiveness of a control strategy to suppress rotating stall. But when surge is initiated by rotating stall, it is also possible to inhibit the occurrence of surge by suppressing rotating stall in a compression system. 展开更多
关键词 active suppression rotating stall SURGE stabilization effectiveness system
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