Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and...Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and its key controlling processes are not well understood,which limits our comprehension of the physiological mechanisms of various management practices.In this study,four forest management measures(no thinning:NT;understory removal:UR;light thinning:LT;and heavy thinning:HT)were carried out in Pinus massoniana plantations in a subtropical region of China.Photosynthetic capacity and needle stable carbon isotope composition(δ^(13)C)were measured to assess instantaneous water use efficiency(WUE_(inst))and long-term water use efficiency(WUE_(i)).Multiple regression models and structural equation modelling(SEM)identified the effects of soil properties and physiological performances on WUE_(inst)and WUE_(i).The results show that WUE_(inst)values among the four treatments were insignificant.However,compared with the NT stand(35.8μmol·mol^(-1)),WUE_(i)values significantly increased to 41.7μmol·mol^(-1)in the UR,50.1μmol·mol^(-1)in the LT and 46.6μmol·mol^(-1)in HT treatments,largely explained by photosynthetic capacity and soil water content.Understory removal did not change physiological performance(needle water potential and photosynthetic capacity).Thinning increased the net photosynthetic rate(A_n)but not stomatal conductance(g_s)or predawn needle water potential(ψ_(pd)),implying that the improvement in water use efficiency for thinned stands was largely driven by radiation interception than by soil water availability.In general,thinning may be an appropriate management measure to promote P.massoniana WUE to cope with seasonal droughts under future extreme climates.展开更多
On the basis of hydrochemical observation and experimental calculation, the features of stable carbon isotope geochemistry in the karst dynamic systems of the Guilin Karst Experimental Site, Huanglong Ravine and Wujia...On the basis of hydrochemical observation and experimental calculation, the features of stable carbon isotope geochemistry in the karst dynamic systems of the Guilin Karst Experimental Site, Huanglong Ravine and Wujiangdu Dam Site are summarized in this study. Furthermore, an attempt has been made to solve several geochemical problems, such as the origin of CO2 in the system, kinetic fractionation of carbon isotopes during calcite deposition, hydrochemistry and formation of tufa, and carbon-14 dating of tufa of hydrothermal origin. The results show that three kinds of karst dynamic system can be distinguished: (1) the shallow system, such as the Guilin Karst Experimental Site, in which soil CO2 provides the an active agent for karst processes; (2) the geothermal system, such as the Huanglong Ravine, in which metamorphic or/ and juvenile CO, is the source of activity for karst; (3) the anthropogenic system, such as the Wujiangdu Dam Site, in which the stable carbon isotope geochemical and hydrochemical features have been greatly affected by human activity.展开更多
Monitoring and sampling of main plants, soil CO2, soil water, bedrock, spring water, drip water and its corresponding speleothem were performed at four cave systems of Guizhou, Southwest China, from April 2003 to May ...Monitoring and sampling of main plants, soil CO2, soil water, bedrock, spring water, drip water and its corresponding speleothem were performed at four cave systems of Guizhou, Southwest China, from April 2003 to May 2004, in order to understand stable carbon isotope ratios variations of dissolved inorganic Carbon (DIC) in cave percolation waters (δ13CDIC) and their implications for paleoclimate. Stable carbon isotopic compositions and ions (Ca, Mg, Sr, SO4, CI etc.) were measured for all samples. The results indicate that there are significant differences among the δ13CDIC values from inter-cave, even inter-drip of intra-cave in the four caves. The δ13CDIC values from the Liangfeng Cave (LFC) is lightest among the four caves, where vegetation type overlying the cave is primary forest dominated by tall trees with lighter average δ13C value (-29.9‰). And there are remarkable differences in δ13CDIC values of different drip waters in the Qixing Cave (QXC) and Jiangjun Cave (JJC), up to 6.9‰ and 7.8‰, respectively. Further analyses show that the δ13CDIC values in cave drip waters are not only controlled by vegetation biomass overlying the cave, but also hydro-geochemical processes. Therefore, accurate interpreting of δ13C recorded in speleothems cannot be guaranteed if these effects of the above mentioned factors are not taken into consideration.展开更多
This study aims to quantify the effects of different pretreatment methods on the stable carbon isotope values of fatty acids in marine microalgae(Isochrysis zhanjiangenisis).To identify the effects of sample prepara...This study aims to quantify the effects of different pretreatment methods on the stable carbon isotope values of fatty acids in marine microalgae(Isochrysis zhanjiangenisis).To identify the effects of sample preparation on theδ^(13)C value and the fatty acid composition,we examined eight types of pretreatment methods including:(a) drying the sample followed by direct methyl esterification using HCl-CH3OH;(b) drying the sample followed by direct methyl esterification using H2SO4-CH3OH;(c) drying the sample by ultrasonic extraction and methylesterification using HCl-CH3OH;(d) drying the sample by ultrasonic extraction and methyl-esterification using H2SO4-CH3OH;(e) fresh sample followed by direct methyl-esterification using HCl-CH3OH;(f) fresh sample followed by direct methyl-esterification using H2SO4-CH3OH;(g) fresh sample with ultrasonic extraction followed by methyl-esterification using HCl-CH3OH,and(h) fresh sample with ultrasonic extraction followed by methylesterification using H2SO4-CH3 OH.The results show that the δ^(13)C values from Groups a-e,g and h fluctuated within 0.3‰,and the δ^(13)C values of Group f were approximately 0.7‰ lower than the other seven groups.Therefore,the different sample pretreatment methods used towards the extraction of fatty acids from marine microalgae may result in different results regarding the stable carbon isotope ratios,and if necessary a correction should be applied.展开更多
Stable isotopes of carbon and oxygen variations in foraminiferal shells have been widely used in paleo-environment studies.However,studies about the shells of benthic foraminifera in methanehydrate-bearing sediments a...Stable isotopes of carbon and oxygen variations in foraminiferal shells have been widely used in paleo-environment studies.However,studies about the shells of benthic foraminifera in methanehydrate-bearing sediments as reliable geochemical proxies to reconstruct the potential methane release events in the geologic past are rare.In this study,we present the stable carbon and oxygen isotopes of fossil benthic foraminifera including one epifaunal species(Cibicidoides wuellerstorfi)and two infaunal species(Bulimina mexicana and Uvigerina peregrina)from the Site U1447 of IODP 353 Expedition to trace methane events in the Andaman Sea,where one of the thickest and deepest gas hydrate stability zones was discovered.Theδ^(13)C values of benthic foraminifera show that there are eight distinct intervals with negative values in the last~10 Myr,interpreted as a record of long-term fluctuations in methane emission.Six of these methane events occurred during the glacial sea-level lowstands in the last~1.1 Myr.We,therefore,infer that the trigger mechanism for these events might be the hydrate destabilization caused by sea level fall.The methane events that occurred at~2.11 and~5.93 Ma are more likely related to the sudden changes in sedimentation,either slide events or marked variations in sedimentation rate.展开更多
Because of the unique geographical location and important ecological effect of the Qinling Mountains, reconstruction of its vegetation and climate needs comprehensive research. We need to consider a multiple-proxy app...Because of the unique geographical location and important ecological effect of the Qinling Mountains, reconstruction of its vegetation and climate needs comprehensive research. We need to consider a multiple-proxy approach to gain more information on recovering the paleovegetation and climate in the Qinling Mountains. Black carbon (BC) is produced by the incomplete combustion of vegetation and fossil fuels, and is a good proxy, recording paleoenvironmental information. However, in the Qinling Mountains, what are the characteristics of the BC, and whether BC stable carbon isotope (δ^13CBc) can be used as a new proxy to study ancient vegetation, still need further study. In order to establish a sound basis for studying paleoenvironmental by BC proxy in the Qinling Mountains, we carried out systematic and detailed study on modern process of BC on the northern slope of the mountains. We analyzed stable carbon isotopes and carbon concentration of organic carbon (% SOC, δ^13Csoc) and BC (%BC, δ^13CBc), and identified the pollen assemblages from systematically sampled surface soil. The results show that the calculated ratio of C4 plants in the vegetation (%C4) based on the δ13Csoc data reflects a similar distribution of C4 plants in the surface vegetation and the pollen assemblage. The δ^13Cac values have a strong positive correlation with δ13Csoc values, and their difference (△13CSOC-BC) is in the low range. These data indicate that δ^13CBC and δ^13CSOC have very similar characteristics. Surface soil δ13BC values can indicate surface vegetation as effectively as δ^13Csoc values, and the δ^13CBC proxy can be used effectively in paleovegetational research in the northern slope of Qinling Mountains.展开更多
The carbon isotope δ 13C value of dispersed organic matter in the Upper Triassic sediments in the Ordos basin is (-24.5 to -26.6) ×10^-3 with the carbon being derived from C3-1ike pleustons. The paleoclimate o...The carbon isotope δ 13C value of dispersed organic matter in the Upper Triassic sediments in the Ordos basin is (-24.5 to -26.6) ×10^-3 with the carbon being derived from C3-1ike pleustons. The paleoclimate of the Late Triassic, especially during the deposition of the Chang 7 member, was characterized by a hot and humid climate. It underwent four small climate cycles from humid and warm to humid and hot.展开更多
For researching the spatio-temporal variation of the stable isotopic composition of the riverine dissolved inorganic carbon(DIC),we had carried out a survey throughout the hydrologic year during which theδ^13CDIC o...For researching the spatio-temporal variation of the stable isotopic composition of the riverine dissolved inorganic carbon(DIC),we had carried out a survey throughout the hydrologic year during which theδ^13CDIC of the surface water and its physicochemical parameter were examined along the Xijiang River Inner Estuarine waterway from September 2006 to June 2007.There was a striking seasonal variation on the averageδ^13CDIC,as the averageδ^13CDIC in summer(-13.91‰)or autumn(-13.09‰)was much less than those in spring(-11.71‰)or winter(-12.26‰).The riverineδ13C DIC was controlled by decomposed condition of the riverine organic matter linking the seasonal variation of the physicochemical parameter in the surface water according to the correlation analysis which indicated notable relations betweenδ^13CDIC and water temperature(p=0.000;r=-0.569)or betweenδ^13CDIC and oxide-reduction potential(p=0.000;r=0.646).The striking positive correlation between δ^13CDIC and the sampling distance happened in the summer rainy season,while striking negative correlation happened in the spring dry season,indicating that river-sea interaction influenced water physicochemical parameters and controlled the riverine DIC property in the survey waterway.In view of the riverineδ^13CDIC decreasing for the decomposition of the terrestrial organic matter in the rainy season in summer and increasing for the briny invaded zone extending in the spring dry season along the waterway from the Makou gauging station to the Modaomen outlet,theδ^13CDIC spatio-temporal variation was closely related to the geographical environment of the Xijiang drainage basin.展开更多
Significantly high abundant methyl-Methyl Trimethyl Tridecyl Chromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of th...Significantly high abundant methyl-Methyl Trimethyl Tridecyl Chromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of these compounds is dominated by methyl-MTTC and dimethyl- MTTC series, which indicate diagenetic products of a hypersaline depositional environment in the early stage and show a low degree of methylation. The occurrence of significantly high abundant methyl-MTTC depends mainly on good preservation conditions with a strongly reductive, hypersaline and water-columned depositional environment and subsequent non-intensive diagenetic transformations. The stable carbon isotopic compositions of the methyl-MTTCs and dimethyl-MTTCs in two samples are far different from the stable carbon isotopic composition of C30 hopane of apparent bacteria biogenesis (up to 4.11‰ and 5.75‰, respectively). This obviously demonstrates that the methyl-MTTC and dimethyl-MTTCs cannot be of bacteria origin, which is different from the previous point of view about non-photosynthetic bacteria products or possible bacteria-reworked products. On the contrary, the stable carbon isotopic compositions of methyl-MTTC and dimethyl-MTTCs in the two samples were similar to that of the same carbon-numbered n-alkanes (nC27-nC28-nC29), which indicates that they share the same source origin. Especially in the crude oil from the Zhao61 well, stable carbon isotopic compositions are also similar to that of the same carbon-numbered steranes with ααα- 20R isomer (mostly less than 0.4‰). In consideration of the results of previous studies on saline lake ecological sedimentation, the authors hold that the methyl-MTTC and dimethyl-MTTCs in the saline lake sediments should be of algal biogenesis origin.展开更多
Tree radial growth can have significantly differ-ent responses to climate change depending on the environ-ment.To elucidate the effects of climate on radial growth and stable carbon isotope(δ^(13)C)fractionation of Q...Tree radial growth can have significantly differ-ent responses to climate change depending on the environ-ment.To elucidate the effects of climate on radial growth and stable carbon isotope(δ^(13)C)fractionation of Qing-hai spruce(Picea crassifolia),a widely distributed native conifer in northwestern China in different environments,we developed chronologies for tree-ring widths and δ^(13)C in trees on the southern and northern slopes of the Qilian Mountains,and analysed the relationship between these tree-ring variables and major climatic factors.Tree-ring widths were strongly influenced by climatic factors early in the growing season,and the radial growth in trees on the northern slopes was more sensitive to climate than in trees on the southern.Tree-ring δ^(13)C was more sensitive to climate than radial growth.δ^(13)C fractionation was mainly influenced by summer temperature and precipitation early in the growing season.Stomatal conductance more strongly limited stable carbon isotope fractionation in tree rings than photosynthetic rate did.The response between tree rings and climate in mountains gradually weakened as climate warmed.Changes in radial growth and stable carbon isotope fractionation of P.crassifolia in response to climate in the Qilian Mountains may be further complicated by continued climate change.展开更多
Distributions and sources of total organic carbon (TOC)in seabed sediments and their implications for hydrodynamics are analyzed, in the turbidity maximum of the Changjiang Estuary. Ecology ecoenvironmental effects ...Distributions and sources of total organic carbon (TOC)in seabed sediments and their implications for hydrodynamics are analyzed, in the turbidity maximum of the Changjiang Estuary. Ecology ecoenvironmental effects of estuary water on the continuously increasing terrigenous organic carbon from the Changjiang River are also explored through variations of organic carbon content and water quality indicators. Results show that, hydrodynamics exert important influences on distributions of organic carbon in the tur- bidity maximum of Changjiang Estuary. For their redistribution effect of terrigenous organic carbon within the moving layer in the whole region, variations from land to sea are not indicated by surficial and vertical average values of TOC and total nitrogen (TN) contents in core sediment, as well as organic stable carbon isotopes in surface sediments. However, on the long-time scale, the trend of terrigenous organic carbon decreasing from land to sea is still displayed by variations of stable carbon isotopic average values becoming heavier from land to sea. Previous studies have shown that high content of Chl a cannot appear in the Changjiang Estuary in despite of adequate nourishment supply, because photosynthesis of phytoplankton is constrained by high suspended sediment concentration(SSC). However, an area with a high content of Chl a occurs, which may be caused by resuspended benthic algae with bottom fine grain-size sediments. Tremendous pressures are imposed on the environment of Changjiang Estuary, because of uhrophication trends and special hydrodynamics. Phytoplankton bloom area tends to extend from the outer sea to the mouth of Changjiang River.展开更多
This work discussed the origins, alteration and accumulation processes of the oil and gas in the Kekeya gas condensate field based on molecular compositions, stable carbon isotopes, light hydrocarbons, diamondoid hydr...This work discussed the origins, alteration and accumulation processes of the oil and gas in the Kekeya gas condensate field based on molecular compositions, stable carbon isotopes, light hydrocarbons, diamondoid hydrocarbons and biomarker fingerprints. A comparison study is also made between the geochemical characteristics of the Kekeya hydrocarbons and typical marine and terrigenous hydrocarbons of the Tarim Basin. Natural gas from the Kekeya gas condensate field is derived from Middle–Lower Jurassic coal measures while the condensates are derived from Carboniferous–Permian marine source rocks with a higher maturity. In the study area, both natural gas and condensates have experienced severe water washing. A large amount of methane was dissolved into the water, resulting in a decrease in the dryness coefficient. Water washing also makes the carbon isotopic compositions of the natural gas more negative and partially reverse. Considering that the gas maturities are higher than once expected, gas generation intensity in the study area should be much stronger and the gas related to the Jurassic coal measures could promise a greater prospecting potential. As a result of evaporative fractionation, the Kekeya condensates are enriched in saturates and lack aromatics. Evaporative fractionation disguises the original terrigenous characteristics of the light hydrocarbons associated with the natural gas, making it appear marinesourced. Thus, alteration processes should be fully taken into consideration when gas–source correlations are carried out based on light hydrocarbons. With the condensates discovered in the study area all being "migration phase", the pre-salt Cretaceous and Jurassic reservoirs may promise great exploration potential for the "residual phase" hydrocarbons. This research not only is of significance for oil and gas exploration in the southwest Tarim Basin, but also sheds light on the oil/gas-source correlations in general.展开更多
Black carbon(BC)has received increasing attention in the last 20 years because it is not only an absorbent of toxic pollutants but also a greenhouse substance,preserving fire-history records,and more importantly,actin...Black carbon(BC)has received increasing attention in the last 20 years because it is not only an absorbent of toxic pollutants but also a greenhouse substance,preserving fire-history records,and more importantly,acting as an indicator of biogeochemical cycles and global changes.By adopting an improved chemothermal oxidation method(WXY),this study reconstructed the century-scale high-resolution records of BC deposition from two fine-grained sediment cores collected from the Yellow Sea Cold Water Mass in the South Yellow Sea.The BC records were divided into five stages,which exhibited specific sequences with three BC peaks at approximately 1891,1921,and 2007 AD,representing times at which the first heavy storms appeared just after the termination of long-term droughts.The significant correlation between the times of the BC peaks in the cores and heavy storms in the area of the Huanghe(Yellow)River demonstrated that BC peaks could result from markedly strengthened sedimentation due to surface runof f,which augmented the atmospheric deposition.Stable carbon isotope analysis indicated that the evident increase in carbon isotope ratios of BC in Stage 5 might have resulted from the input of weathered rock-derived graphitic carbon cardinally induced by the annual anthropogenic modulation of water-borne sediment in the Huanghe River since 2005 AD.Numerical calculations demonstrated that the input fraction of graphitic carbon was 22.97% for Stage 5,whereas no graphitic carbon entered during Stages 1 and 3.The obtained data provide new and important understanding of the source-sink history of BC in the Yellow Sea.展开更多
Despite the upsurge in hydrocarbon exploration in the Lake Albert Rift Basin(LARB)over the past three decades,systematic characterization of hydrocarbon compositions remains lacking,leading to uncertainties in source ...Despite the upsurge in hydrocarbon exploration in the Lake Albert Rift Basin(LARB)over the past three decades,systematic characterization of hydrocarbon compositions remains lacking,leading to uncertainties in source rock and oil generation determination.We characterized crude oil compositions and oil sand samples in the northern and southern subbasins of LARB.The relative abundance of normal and branched linear alkanes,hopanes,steranes,and aromatic hydrocarbon suggest that northern and southern hydrocarbons were deposited in anoxic to suboxic lacustrine environments and share similar biological source compositions(i.e.,a mixture of plants and aquatic algae and bacteria).Relative to southern samples,northern samples show more negative δ^(13)C values for oils,saturates and aromatics,indicating longer migration paths,and exhibit higher MPI-1,DNR-1 and 4-/1-MDBT ratios,indicating higher maturity.Between the two possible sets of source rocks(upper Miocene and Jurassic strata),the positive δ^(13)C values of saturated hydrocarbons(average=-20.5‰)suggest that the upper Miocene lacustrine shale is the most likely candidate.Oleanane index(<5% in our samples)does not exclude either source rock possibility,and C_(28)/C_(29) regular sterane(average=0.63)may be biased by high terrestrial inputs in a lacustrine setting.Together,our data show that northern and southern oils originate from the same source rocks but different oil kitchens.Given the similar geochemical characteristics of southern and northern oils,previous exploration successes in the northern subbasin likely suggest similar potential in the southern sector,while other elements influencing exploration success must be also evaluated.展开更多
Isotopic signature is a powerful tool to discriminate methane(CH_(4)) source types and constrain regional and global scale CH_(4) budgets.Peatlands on the Qinghai-Tibetan Plateau are poorly understood about the isotop...Isotopic signature is a powerful tool to discriminate methane(CH_(4)) source types and constrain regional and global scale CH_(4) budgets.Peatlands on the Qinghai-Tibetan Plateau are poorly understood about the isotopic signature of CH_(4) due to the limited experimental conditions.In this study,three campaigns of diurnal air samples spacing 2-3 h were taken from an alpine peatland on the eastern Qinghai-Tibetan Plateau to investigate its source signal characteristics.Both CH_(4) concentration and its stable carbon isotope(δ^(13)C-CH_(4)) were measured to derive the carbon isotopic signature of the CH_(4) source using the Keeling plot technique.Diurnal variation patterns in CH_(4) concentration and δ^(13)C-CH_(4) were observed during summertime,with depleted δ^(13)C-CH_(4) signals and high CH_(4) concentration appearing at nighttime.The δ^(13)C-CH4 signature during summer was calculated to be-71 % ± 1.3%,which falls within the range of other wetland studies and close to high-latitude peatlands.The boundary layer dynamic and CH_(4) source were supposed to influence the measured CH_(4) concentration and δ^(13)C-CH_(4.)Further investigations of CH_(4) isotopic signals into the nongrowing season are still needed to constrain the δ^(13)C-CH_(4) signature and its environmental controls in this region.展开更多
Based on long-term dynamic tracing of dissolved inorganic carbon(DIC)and stable carbon isotope(δ13CDIC)in produced water from 20 coalbed methane(CBM)wells in western Guizhou,the spatial-temporal dynamic variations of...Based on long-term dynamic tracing of dissolved inorganic carbon(DIC)and stable carbon isotope(δ13CDIC)in produced water from 20 coalbed methane(CBM)wells in western Guizhou,the spatial-temporal dynamic variations ofδ13CDIC of the GP well group produced in multi-layer commingled manner were analyzed,and the relationship between the value ofδ13CDIC and CBM productivity was examined.The produced water samples of typical wells in the GP well group were amplified and sequenced using 16S rDNA,and a geological response model ofδ13CDIC in produced water from CBM wells with multi-coal seams was put forward.The research shows that:δ13CDIC in produced water from medium-rank coal seams commonly show positive anomalies,the produced water contains more than 15 species of methanogens,and Methanobacterium is the dominant genus.The dominant methanogens sequence numbers in the produced water are positively correlated withδ13CDIC,and the positive anomaly of v is caused by reduction of methanogens,and especially hydrogenotrophic methanogens.Vertical segmentation of sedimentary facies and lithology in stratum with multi-coal seams will result in permeability and water cut segmentation,which will lead to the segmentation ofδ13CDIC and archaea community in produced water,so in the strata with better permeability and high water cut,theδ13CDIC of the produced water is abnormally enriched,and the dominant archaea is mainly Methanobacterium.In the strata with weak permeability and low water cut,theδ13CDIC of the produced water is small,and the microbial action is weak.The shallow layer close to the coal seam outcrop is likely to be affected by meteoric precipitation,so theδ13CDIC of the produced water is smaller.The geological response model ofδ13CDIC in produced water from multi-coal seams CBM wells in the medium-rank coal reveals the geological mechanism and microbial action mechanism of theδ13CDIC difference in the produced water from the multi-coal seams CBM wells.It also provides effective geochemical evidence for the superimposed fluid system controlled by sedimentary facies,and can also be used for the contribution analysis of the produced gas and water by the multi-layer CBM wells.展开更多
Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inle...Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition (δ^13C) values of the carbonate sediment (-1‰ to -2‰) have no relation to the oxygen isotope composition of the carbonate (δ^18O) values (-7‰ to -8‰), with both isotopes showing a low variability. The carbonate content is low (〈20%). Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ^13C values between approximately +0.5‰ and +3‰, and δ^18O values between -1‰ and -5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg-calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg-calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate.展开更多
The spatial distribution patterns of total organic carbon and total nitrogen show significant correlations with currents of the East China Sea Shelf. Corresponding to distributions of these currents, the study area co...The spatial distribution patterns of total organic carbon and total nitrogen show significant correlations with currents of the East China Sea Shelf. Corresponding to distributions of these currents, the study area could be divided into four different parts. Total organic carbon, total nitrogen, and organic carbon and nitrogen stable isotopes in sediments show linear correlations with mean grain size, respectively, thus "grain size effect" is an important factor that influences their distributions. C/N ratios can reflect source information of organic matter to a certain degree. In contrast, nitrogen stable isotope shows different spatial distribution patterns with C/N and organic carbon stable isotope, according to their relationships and regional distributions. The highest contribution (up to 50%) of terrestrial organic carbon appears near the Changjiang Estuary with isolines projecting towards northeast, indicating the influence of the Changjiang dilution water. Terrestrial particulate organic matter suffers from effects of diagenesis, benthos and incessant inputting of dead organic matter of plankton, after depositing in seabed. Therefore, the contribution of terrestrial organic carbon to particulate organic matter is obviously greater than that to organic matter in sediments in the same place.展开更多
Soils of the Chinese Loess Plateau(CLP)contain substantial amounts of soil inorganic carbon(SIC),as well as recent and ancient soil organic carbon(SOC).With the advent of the Anthropocene,human perturbation,including ...Soils of the Chinese Loess Plateau(CLP)contain substantial amounts of soil inorganic carbon(SIC),as well as recent and ancient soil organic carbon(SOC).With the advent of the Anthropocene,human perturbation,including excavation,has increased soil CO_(2) emission from the huge loess carbon pool.This study aims to determine the potential of loess CO_(2) emission induced by excavation.Soil CO_(2) were continuously monitored for seven years on a newly-excavated profile in the central CLP and the stable C isotope compositions of soil CO_(2) and SOC were used to identify their sources.The results showed that the soil CO_(2) concentrations ranged from 830μL·L^(-1) to 11190μL·L^(-1) with an annually reducing trend after excavation,indicating that the human excavation can induce CO_(2) production in loess profile.Theδ^(13) C of CO_(2) ranged from–21.27‰to–19.22‰(mean:–20.11‰),with positive deviation from top to bottom.The range of δ^(13)CSOC was–24.0‰to–21.1‰with an average of–23.1‰.Theδ^(13) C-CO_(2) in this study has a positive relationship with the reversed CO_(2) concentration,and it is calculated that 80.22%of the soil CO_(2) in this profile is from the microbial decomposition of SOC and 19.78%from the degasification during carbonate precipitation.We conclude that the human excavation can significantly enhance the decomposition of the ancient OC in loess during the first two years after perturbation,producing and releasing soil CO_(2) to atmosphere.展开更多
Early Eocene hyperthermals are geologically short-lived global warming events and represent fundamental perturbations to the global carbon cycle and the Earth’s ecosystem due to massive additions of isotopically ligh...Early Eocene hyperthermals are geologically short-lived global warming events and represent fundamental perturbations to the global carbon cycle and the Earth’s ecosystem due to massive additions of isotopically light carbon to the ocean-atmosphere system.They serve as ancient analogs for understanding how the oceanic carbonate system and surface-ocean ecosystem would respond to ongoing and future climate change.Here,we present a continuous carbonate record across the Eocene Thermal Maximum 2(ETM2 or H1,ca.54.1 Ma)and H2(ca.54 Ma)events from an expanded section at Ocean Drilling Program Site 1258 in tropical Atlantic.The abundant calcareous nannofossils and moderate carbonate content throughout the studied interval suggest this record was deposited above the calcite compensation depth(CCD),but below the lysocline and under the influence of terrestrial dilution.An Earth system model cGENIE is used to simulate the carbon cycle dynamics across the ETM2 and H2 to offer insights on the mechanism of the rapid warming and subsequent recovery in climate and ecosystem.The model suggests moderate changes in ocean pH(0.1–0.2 unit)for the two scenarios,biogenic methane from a rechargeable methane capacitor and organic matter oxidation from thawing of the permafrost.These pH changes are consistent with a recent independent pH estimate across the ETM2 using boron isotopes.The carbon emission flux during the ETM2 is at least an order of magnitude smaller than that during the Paleocene–Eocene Thermal Maximum(PETM)(0.015–0.05 Pg C yr^(-1)vs.0.3–1.7 Pg C yr^(-1)).The comparable pre-and post-event carbonate contents suggest the lysocline did not over deepen following the ETM2 at this tropical Atlantic site,indicating spatial heterogeneity in the carbonate system due to strong dilution influence from terrestrial weathering and riverine discharge at Site 1258.展开更多
基金supported by the National Key Research and Development Program of China(2016YFD0600201)the National Nonprofit Institute Research Grant of CAF(CAFYBB2017ZB003)+1 种基金the National Natural Science Foundation of China(3187071631670720)。
文摘Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and its key controlling processes are not well understood,which limits our comprehension of the physiological mechanisms of various management practices.In this study,four forest management measures(no thinning:NT;understory removal:UR;light thinning:LT;and heavy thinning:HT)were carried out in Pinus massoniana plantations in a subtropical region of China.Photosynthetic capacity and needle stable carbon isotope composition(δ^(13)C)were measured to assess instantaneous water use efficiency(WUE_(inst))and long-term water use efficiency(WUE_(i)).Multiple regression models and structural equation modelling(SEM)identified the effects of soil properties and physiological performances on WUE_(inst)and WUE_(i).The results show that WUE_(inst)values among the four treatments were insignificant.However,compared with the NT stand(35.8μmol·mol^(-1)),WUE_(i)values significantly increased to 41.7μmol·mol^(-1)in the UR,50.1μmol·mol^(-1)in the LT and 46.6μmol·mol^(-1)in HT treatments,largely explained by photosynthetic capacity and soil water content.Understory removal did not change physiological performance(needle water potential and photosynthetic capacity).Thinning increased the net photosynthetic rate(A_n)but not stomatal conductance(g_s)or predawn needle water potential(ψ_(pd)),implying that the improvement in water use efficiency for thinned stands was largely driven by radiation interception than by soil water availability.In general,thinning may be an appropriate management measure to promote P.massoniana WUE to cope with seasonal droughts under future extreme climates.
基金This research was supproted by IGCP Project 379, National Natural Science Foundation of China (No. 49632100) and the Ministry of Geology and Mineral Resources of China (No. 9501104, Karst Dynamics Laboratory)
文摘On the basis of hydrochemical observation and experimental calculation, the features of stable carbon isotope geochemistry in the karst dynamic systems of the Guilin Karst Experimental Site, Huanglong Ravine and Wujiangdu Dam Site are summarized in this study. Furthermore, an attempt has been made to solve several geochemical problems, such as the origin of CO2 in the system, kinetic fractionation of carbon isotopes during calcite deposition, hydrochemistry and formation of tufa, and carbon-14 dating of tufa of hydrothermal origin. The results show that three kinds of karst dynamic system can be distinguished: (1) the shallow system, such as the Guilin Karst Experimental Site, in which soil CO2 provides the an active agent for karst processes; (2) the geothermal system, such as the Huanglong Ravine, in which metamorphic or/ and juvenile CO, is the source of activity for karst; (3) the anthropogenic system, such as the Wujiangdu Dam Site, in which the stable carbon isotope geochemical and hydrochemical features have been greatly affected by human activity.
基金funded by National Key Basic Research Development Program (Grant No. 2013CB956700)Orientation Project of Knowledge Innovation Program of Chinese Academy of Sciences (Grant No. kzcx2-yw-306)National Natural Science Foundation of China (Grant Nos. 41003054 and 90202003)
文摘Monitoring and sampling of main plants, soil CO2, soil water, bedrock, spring water, drip water and its corresponding speleothem were performed at four cave systems of Guizhou, Southwest China, from April 2003 to May 2004, in order to understand stable carbon isotope ratios variations of dissolved inorganic Carbon (DIC) in cave percolation waters (δ13CDIC) and their implications for paleoclimate. Stable carbon isotopic compositions and ions (Ca, Mg, Sr, SO4, CI etc.) were measured for all samples. The results indicate that there are significant differences among the δ13CDIC values from inter-cave, even inter-drip of intra-cave in the four caves. The δ13CDIC values from the Liangfeng Cave (LFC) is lightest among the four caves, where vegetation type overlying the cave is primary forest dominated by tall trees with lighter average δ13C value (-29.9‰). And there are remarkable differences in δ13CDIC values of different drip waters in the Qixing Cave (QXC) and Jiangjun Cave (JJC), up to 6.9‰ and 7.8‰, respectively. Further analyses show that the δ13CDIC values in cave drip waters are not only controlled by vegetation biomass overlying the cave, but also hydro-geochemical processes. Therefore, accurate interpreting of δ13C recorded in speleothems cannot be guaranteed if these effects of the above mentioned factors are not taken into consideration.
基金The State Oceanic Public Welfare Project of China under contract Nos 2012418012-02 and 201305002
文摘This study aims to quantify the effects of different pretreatment methods on the stable carbon isotope values of fatty acids in marine microalgae(Isochrysis zhanjiangenisis).To identify the effects of sample preparation on theδ^(13)C value and the fatty acid composition,we examined eight types of pretreatment methods including:(a) drying the sample followed by direct methyl esterification using HCl-CH3OH;(b) drying the sample followed by direct methyl esterification using H2SO4-CH3OH;(c) drying the sample by ultrasonic extraction and methylesterification using HCl-CH3OH;(d) drying the sample by ultrasonic extraction and methyl-esterification using H2SO4-CH3OH;(e) fresh sample followed by direct methyl-esterification using HCl-CH3OH;(f) fresh sample followed by direct methyl-esterification using H2SO4-CH3OH;(g) fresh sample with ultrasonic extraction followed by methyl-esterification using HCl-CH3OH,and(h) fresh sample with ultrasonic extraction followed by methylesterification using H2SO4-CH3 OH.The results show that the δ^(13)C values from Groups a-e,g and h fluctuated within 0.3‰,and the δ^(13)C values of Group f were approximately 0.7‰ lower than the other seven groups.Therefore,the different sample pretreatment methods used towards the extraction of fatty acids from marine microalgae may result in different results regarding the stable carbon isotope ratios,and if necessary a correction should be applied.
基金supported by the National Key R&D Program of China(No.2018YFC031000404)the National Natural Science Foundation of China(No.42276068)State Key Laboratory of Marine Geology,Tongji University(No.MGK202206)。
文摘Stable isotopes of carbon and oxygen variations in foraminiferal shells have been widely used in paleo-environment studies.However,studies about the shells of benthic foraminifera in methanehydrate-bearing sediments as reliable geochemical proxies to reconstruct the potential methane release events in the geologic past are rare.In this study,we present the stable carbon and oxygen isotopes of fossil benthic foraminifera including one epifaunal species(Cibicidoides wuellerstorfi)and two infaunal species(Bulimina mexicana and Uvigerina peregrina)from the Site U1447 of IODP 353 Expedition to trace methane events in the Andaman Sea,where one of the thickest and deepest gas hydrate stability zones was discovered.Theδ^(13)C values of benthic foraminifera show that there are eight distinct intervals with negative values in the last~10 Myr,interpreted as a record of long-term fluctuations in methane emission.Six of these methane events occurred during the glacial sea-level lowstands in the last~1.1 Myr.We,therefore,infer that the trigger mechanism for these events might be the hydrate destabilization caused by sea level fall.The methane events that occurred at~2.11 and~5.93 Ma are more likely related to the sudden changes in sedimentation,either slide events or marked variations in sedimentation rate.
基金supported by the National Natural Science Foundation of China(41102106)
文摘Because of the unique geographical location and important ecological effect of the Qinling Mountains, reconstruction of its vegetation and climate needs comprehensive research. We need to consider a multiple-proxy approach to gain more information on recovering the paleovegetation and climate in the Qinling Mountains. Black carbon (BC) is produced by the incomplete combustion of vegetation and fossil fuels, and is a good proxy, recording paleoenvironmental information. However, in the Qinling Mountains, what are the characteristics of the BC, and whether BC stable carbon isotope (δ^13CBc) can be used as a new proxy to study ancient vegetation, still need further study. In order to establish a sound basis for studying paleoenvironmental by BC proxy in the Qinling Mountains, we carried out systematic and detailed study on modern process of BC on the northern slope of the mountains. We analyzed stable carbon isotopes and carbon concentration of organic carbon (% SOC, δ^13Csoc) and BC (%BC, δ^13CBc), and identified the pollen assemblages from systematically sampled surface soil. The results show that the calculated ratio of C4 plants in the vegetation (%C4) based on the δ13Csoc data reflects a similar distribution of C4 plants in the surface vegetation and the pollen assemblage. The δ^13Cac values have a strong positive correlation with δ13Csoc values, and their difference (△13CSOC-BC) is in the low range. These data indicate that δ^13CBC and δ^13CSOC have very similar characteristics. Surface soil δ13BC values can indicate surface vegetation as effectively as δ^13Csoc values, and the δ^13CBC proxy can be used effectively in paleovegetational research in the northern slope of Qinling Mountains.
文摘The carbon isotope δ 13C value of dispersed organic matter in the Upper Triassic sediments in the Ordos basin is (-24.5 to -26.6) ×10^-3 with the carbon being derived from C3-1ike pleustons. The paleoclimate of the Late Triassic, especially during the deposition of the Chang 7 member, was characterized by a hot and humid climate. It underwent four small climate cycles from humid and warm to humid and hot.
基金National Natural Science Foundation of China, No.40671027 No.40471120+2 种基金 Guangdong Provincial Natural Science Foundation, No.7003669 Specialized Research Fund for the Doctoral Program of Higher Education, No.20040558025 The Program for New Century Excellent Talents in University
文摘For researching the spatio-temporal variation of the stable isotopic composition of the riverine dissolved inorganic carbon(DIC),we had carried out a survey throughout the hydrologic year during which theδ^13CDIC of the surface water and its physicochemical parameter were examined along the Xijiang River Inner Estuarine waterway from September 2006 to June 2007.There was a striking seasonal variation on the averageδ^13CDIC,as the averageδ^13CDIC in summer(-13.91‰)or autumn(-13.09‰)was much less than those in spring(-11.71‰)or winter(-12.26‰).The riverineδ13C DIC was controlled by decomposed condition of the riverine organic matter linking the seasonal variation of the physicochemical parameter in the surface water according to the correlation analysis which indicated notable relations betweenδ^13CDIC and water temperature(p=0.000;r=-0.569)or betweenδ^13CDIC and oxide-reduction potential(p=0.000;r=0.646).The striking positive correlation between δ^13CDIC and the sampling distance happened in the summer rainy season,while striking negative correlation happened in the spring dry season,indicating that river-sea interaction influenced water physicochemical parameters and controlled the riverine DIC property in the survey waterway.In view of the riverineδ^13CDIC decreasing for the decomposition of the terrestrial organic matter in the rainy season in summer and increasing for the briny invaded zone extending in the spring dry season along the waterway from the Makou gauging station to the Modaomen outlet,theδ^13CDIC spatio-temporal variation was closely related to the geographical environment of the Xijiang drainage basin.
文摘Significantly high abundant methyl-Methyl Trimethyl Tridecyl Chromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of these compounds is dominated by methyl-MTTC and dimethyl- MTTC series, which indicate diagenetic products of a hypersaline depositional environment in the early stage and show a low degree of methylation. The occurrence of significantly high abundant methyl-MTTC depends mainly on good preservation conditions with a strongly reductive, hypersaline and water-columned depositional environment and subsequent non-intensive diagenetic transformations. The stable carbon isotopic compositions of the methyl-MTTCs and dimethyl-MTTCs in two samples are far different from the stable carbon isotopic composition of C30 hopane of apparent bacteria biogenesis (up to 4.11‰ and 5.75‰, respectively). This obviously demonstrates that the methyl-MTTC and dimethyl-MTTCs cannot be of bacteria origin, which is different from the previous point of view about non-photosynthetic bacteria products or possible bacteria-reworked products. On the contrary, the stable carbon isotopic compositions of methyl-MTTC and dimethyl-MTTCs in the two samples were similar to that of the same carbon-numbered n-alkanes (nC27-nC28-nC29), which indicates that they share the same source origin. Especially in the crude oil from the Zhao61 well, stable carbon isotopic compositions are also similar to that of the same carbon-numbered steranes with ααα- 20R isomer (mostly less than 0.4‰). In consideration of the results of previous studies on saline lake ecological sedimentation, the authors hold that the methyl-MTTC and dimethyl-MTTCs in the saline lake sediments should be of algal biogenesis origin.
基金supported by Basic Research Operating Expenses of the Central level Non-profit Research Institutes (IDM2022003)National Natural Science Foundation of China (42375054)+2 种基金Regional collaborative innovation project of Xinjiang (2021E01022,2022E01045)Young Meteorological Talent Program of China Meteorological Administration,Tianshan Talent Program of Xinjiang (2022TSYCCX0003)Youth Innovation Team of China Meteorological Administration (CMA2023QN08).
文摘Tree radial growth can have significantly differ-ent responses to climate change depending on the environ-ment.To elucidate the effects of climate on radial growth and stable carbon isotope(δ^(13)C)fractionation of Qing-hai spruce(Picea crassifolia),a widely distributed native conifer in northwestern China in different environments,we developed chronologies for tree-ring widths and δ^(13)C in trees on the southern and northern slopes of the Qilian Mountains,and analysed the relationship between these tree-ring variables and major climatic factors.Tree-ring widths were strongly influenced by climatic factors early in the growing season,and the radial growth in trees on the northern slopes was more sensitive to climate than in trees on the southern.Tree-ring δ^(13)C was more sensitive to climate than radial growth.δ^(13)C fractionation was mainly influenced by summer temperature and precipitation early in the growing season.Stomatal conductance more strongly limited stable carbon isotope fractionation in tree rings than photosynthetic rate did.The response between tree rings and climate in mountains gradually weakened as climate warmed.Changes in radial growth and stable carbon isotope fractionation of P.crassifolia in response to climate in the Qilian Mountains may be further complicated by continued climate change.
基金the National Key Basic Research Program of China under contract No.2002CB412401the National Natural Science Foundation of China under contract Nos40506022 and 40506013
文摘Distributions and sources of total organic carbon (TOC)in seabed sediments and their implications for hydrodynamics are analyzed, in the turbidity maximum of the Changjiang Estuary. Ecology ecoenvironmental effects of estuary water on the continuously increasing terrigenous organic carbon from the Changjiang River are also explored through variations of organic carbon content and water quality indicators. Results show that, hydrodynamics exert important influences on distributions of organic carbon in the tur- bidity maximum of Changjiang Estuary. For their redistribution effect of terrigenous organic carbon within the moving layer in the whole region, variations from land to sea are not indicated by surficial and vertical average values of TOC and total nitrogen (TN) contents in core sediment, as well as organic stable carbon isotopes in surface sediments. However, on the long-time scale, the trend of terrigenous organic carbon decreasing from land to sea is still displayed by variations of stable carbon isotopic average values becoming heavier from land to sea. Previous studies have shown that high content of Chl a cannot appear in the Changjiang Estuary in despite of adequate nourishment supply, because photosynthesis of phytoplankton is constrained by high suspended sediment concentration(SSC). However, an area with a high content of Chl a occurs, which may be caused by resuspended benthic algae with bottom fine grain-size sediments. Tremendous pressures are imposed on the environment of Changjiang Estuary, because of uhrophication trends and special hydrodynamics. Phytoplankton bloom area tends to extend from the outer sea to the mouth of Changjiang River.
基金funded by the National Natural Science Foundation of China (grant No.41503044)the Fundamental Research Program of PetroChina (grant No.2014B–0608)
文摘This work discussed the origins, alteration and accumulation processes of the oil and gas in the Kekeya gas condensate field based on molecular compositions, stable carbon isotopes, light hydrocarbons, diamondoid hydrocarbons and biomarker fingerprints. A comparison study is also made between the geochemical characteristics of the Kekeya hydrocarbons and typical marine and terrigenous hydrocarbons of the Tarim Basin. Natural gas from the Kekeya gas condensate field is derived from Middle–Lower Jurassic coal measures while the condensates are derived from Carboniferous–Permian marine source rocks with a higher maturity. In the study area, both natural gas and condensates have experienced severe water washing. A large amount of methane was dissolved into the water, resulting in a decrease in the dryness coefficient. Water washing also makes the carbon isotopic compositions of the natural gas more negative and partially reverse. Considering that the gas maturities are higher than once expected, gas generation intensity in the study area should be much stronger and the gas related to the Jurassic coal measures could promise a greater prospecting potential. As a result of evaporative fractionation, the Kekeya condensates are enriched in saturates and lack aromatics. Evaporative fractionation disguises the original terrigenous characteristics of the light hydrocarbons associated with the natural gas, making it appear marinesourced. Thus, alteration processes should be fully taken into consideration when gas–source correlations are carried out based on light hydrocarbons. With the condensates discovered in the study area all being "migration phase", the pre-salt Cretaceous and Jurassic reservoirs may promise great exploration potential for the "residual phase" hydrocarbons. This research not only is of significance for oil and gas exploration in the southwest Tarim Basin, but also sheds light on the oil/gas-source correlations in general.
基金Supported by the National Basic Research Program of China(973 Program)(No.2012CB956004)the Fundamental Research Funds for the Central Universities(No.16lgjc22)
文摘Black carbon(BC)has received increasing attention in the last 20 years because it is not only an absorbent of toxic pollutants but also a greenhouse substance,preserving fire-history records,and more importantly,acting as an indicator of biogeochemical cycles and global changes.By adopting an improved chemothermal oxidation method(WXY),this study reconstructed the century-scale high-resolution records of BC deposition from two fine-grained sediment cores collected from the Yellow Sea Cold Water Mass in the South Yellow Sea.The BC records were divided into five stages,which exhibited specific sequences with three BC peaks at approximately 1891,1921,and 2007 AD,representing times at which the first heavy storms appeared just after the termination of long-term droughts.The significant correlation between the times of the BC peaks in the cores and heavy storms in the area of the Huanghe(Yellow)River demonstrated that BC peaks could result from markedly strengthened sedimentation due to surface runof f,which augmented the atmospheric deposition.Stable carbon isotope analysis indicated that the evident increase in carbon isotope ratios of BC in Stage 5 might have resulted from the input of weathered rock-derived graphitic carbon cardinally induced by the annual anthropogenic modulation of water-borne sediment in the Huanghe River since 2005 AD.Numerical calculations demonstrated that the input fraction of graphitic carbon was 22.97% for Stage 5,whereas no graphitic carbon entered during Stages 1 and 3.The obtained data provide new and important understanding of the source-sink history of BC in the Yellow Sea.
基金funded by National Natural Science Foundation of China(Grant No.42072149)support of US National Science Foundation grant(Grant No.EAR-1255724)。
文摘Despite the upsurge in hydrocarbon exploration in the Lake Albert Rift Basin(LARB)over the past three decades,systematic characterization of hydrocarbon compositions remains lacking,leading to uncertainties in source rock and oil generation determination.We characterized crude oil compositions and oil sand samples in the northern and southern subbasins of LARB.The relative abundance of normal and branched linear alkanes,hopanes,steranes,and aromatic hydrocarbon suggest that northern and southern hydrocarbons were deposited in anoxic to suboxic lacustrine environments and share similar biological source compositions(i.e.,a mixture of plants and aquatic algae and bacteria).Relative to southern samples,northern samples show more negative δ^(13)C values for oils,saturates and aromatics,indicating longer migration paths,and exhibit higher MPI-1,DNR-1 and 4-/1-MDBT ratios,indicating higher maturity.Between the two possible sets of source rocks(upper Miocene and Jurassic strata),the positive δ^(13)C values of saturated hydrocarbons(average=-20.5‰)suggest that the upper Miocene lacustrine shale is the most likely candidate.Oleanane index(<5% in our samples)does not exclude either source rock possibility,and C_(28)/C_(29) regular sterane(average=0.63)may be biased by high terrestrial inputs in a lacustrine setting.Together,our data show that northern and southern oils originate from the same source rocks but different oil kitchens.Given the similar geochemical characteristics of southern and northern oils,previous exploration successes in the northern subbasin likely suggest similar potential in the southern sector,while other elements influencing exploration success must be also evaluated.
基金financially supported by the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No.XDB40010000)the National Natural Science Foundation of China (Grant Nos.41907288,41673119,and 41773140)+1 种基金the Science and Technology Foundation of Guizhou Province (Grant Nos.[2019]1317 and [2020]1Y193)supported by the“Light of West China”Program and the CAS Scholarship。
文摘Isotopic signature is a powerful tool to discriminate methane(CH_(4)) source types and constrain regional and global scale CH_(4) budgets.Peatlands on the Qinghai-Tibetan Plateau are poorly understood about the isotopic signature of CH_(4) due to the limited experimental conditions.In this study,three campaigns of diurnal air samples spacing 2-3 h were taken from an alpine peatland on the eastern Qinghai-Tibetan Plateau to investigate its source signal characteristics.Both CH_(4) concentration and its stable carbon isotope(δ^(13)C-CH_(4)) were measured to derive the carbon isotopic signature of the CH_(4) source using the Keeling plot technique.Diurnal variation patterns in CH_(4) concentration and δ^(13)C-CH_(4) were observed during summertime,with depleted δ^(13)C-CH_(4) signals and high CH_(4) concentration appearing at nighttime.The δ^(13)C-CH4 signature during summer was calculated to be-71 % ± 1.3%,which falls within the range of other wetland studies and close to high-latitude peatlands.The boundary layer dynamic and CH_(4) source were supposed to influence the measured CH_(4) concentration and δ^(13)C-CH_(4.)Further investigations of CH_(4) isotopic signals into the nongrowing season are still needed to constrain the δ^(13)C-CH_(4) signature and its environmental controls in this region.
基金Supported by the National Natural Science Foundation of China(41772155)the National Science and Technology Major Project of China(2016ZX05044-002)
文摘Based on long-term dynamic tracing of dissolved inorganic carbon(DIC)and stable carbon isotope(δ13CDIC)in produced water from 20 coalbed methane(CBM)wells in western Guizhou,the spatial-temporal dynamic variations ofδ13CDIC of the GP well group produced in multi-layer commingled manner were analyzed,and the relationship between the value ofδ13CDIC and CBM productivity was examined.The produced water samples of typical wells in the GP well group were amplified and sequenced using 16S rDNA,and a geological response model ofδ13CDIC in produced water from CBM wells with multi-coal seams was put forward.The research shows that:δ13CDIC in produced water from medium-rank coal seams commonly show positive anomalies,the produced water contains more than 15 species of methanogens,and Methanobacterium is the dominant genus.The dominant methanogens sequence numbers in the produced water are positively correlated withδ13CDIC,and the positive anomaly of v is caused by reduction of methanogens,and especially hydrogenotrophic methanogens.Vertical segmentation of sedimentary facies and lithology in stratum with multi-coal seams will result in permeability and water cut segmentation,which will lead to the segmentation ofδ13CDIC and archaea community in produced water,so in the strata with better permeability and high water cut,theδ13CDIC of the produced water is abnormally enriched,and the dominant archaea is mainly Methanobacterium.In the strata with weak permeability and low water cut,theδ13CDIC of the produced water is small,and the microbial action is weak.The shallow layer close to the coal seam outcrop is likely to be affected by meteoric precipitation,so theδ13CDIC of the produced water is smaller.The geological response model ofδ13CDIC in produced water from multi-coal seams CBM wells in the medium-rank coal reveals the geological mechanism and microbial action mechanism of theδ13CDIC difference in the produced water from the multi-coal seams CBM wells.It also provides effective geochemical evidence for the superimposed fluid system controlled by sedimentary facies,and can also be used for the contribution analysis of the produced gas and water by the multi-layer CBM wells.
基金funded by NSFC grants(no.:40773064,40331012,and 40041004).
文摘Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition (δ^13C) values of the carbonate sediment (-1‰ to -2‰) have no relation to the oxygen isotope composition of the carbonate (δ^18O) values (-7‰ to -8‰), with both isotopes showing a low variability. The carbonate content is low (〈20%). Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ^13C values between approximately +0.5‰ and +3‰, and δ^18O values between -1‰ and -5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg-calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg-calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate.
基金National Basic Research Program of China, No.2002CB412401 National Natural Science Foundation of China, No.40506022+1 种基金 No.40506013 Natural Science Foundation of Jiangsu Province, No.BK2006131
文摘The spatial distribution patterns of total organic carbon and total nitrogen show significant correlations with currents of the East China Sea Shelf. Corresponding to distributions of these currents, the study area could be divided into four different parts. Total organic carbon, total nitrogen, and organic carbon and nitrogen stable isotopes in sediments show linear correlations with mean grain size, respectively, thus "grain size effect" is an important factor that influences their distributions. C/N ratios can reflect source information of organic matter to a certain degree. In contrast, nitrogen stable isotope shows different spatial distribution patterns with C/N and organic carbon stable isotope, according to their relationships and regional distributions. The highest contribution (up to 50%) of terrestrial organic carbon appears near the Changjiang Estuary with isolines projecting towards northeast, indicating the influence of the Changjiang dilution water. Terrestrial particulate organic matter suffers from effects of diagenesis, benthos and incessant inputting of dead organic matter of plankton, after depositing in seabed. Therefore, the contribution of terrestrial organic carbon to particulate organic matter is obviously greater than that to organic matter in sediments in the same place.
基金funded by National Natural Science Foundation of China(Grant No.41877398)the Basic Science Research Fund from the Institute of Chinese Academy of Geological Sciences(Grant No.SK201911)the Belt and Road Fund on Water and Sustainability(U2019NKMS01)。
文摘Soils of the Chinese Loess Plateau(CLP)contain substantial amounts of soil inorganic carbon(SIC),as well as recent and ancient soil organic carbon(SOC).With the advent of the Anthropocene,human perturbation,including excavation,has increased soil CO_(2) emission from the huge loess carbon pool.This study aims to determine the potential of loess CO_(2) emission induced by excavation.Soil CO_(2) were continuously monitored for seven years on a newly-excavated profile in the central CLP and the stable C isotope compositions of soil CO_(2) and SOC were used to identify their sources.The results showed that the soil CO_(2) concentrations ranged from 830μL·L^(-1) to 11190μL·L^(-1) with an annually reducing trend after excavation,indicating that the human excavation can induce CO_(2) production in loess profile.Theδ^(13) C of CO_(2) ranged from–21.27‰to–19.22‰(mean:–20.11‰),with positive deviation from top to bottom.The range of δ^(13)CSOC was–24.0‰to–21.1‰with an average of–23.1‰.Theδ^(13) C-CO_(2) in this study has a positive relationship with the reversed CO_(2) concentration,and it is calculated that 80.22%of the soil CO_(2) in this profile is from the microbial decomposition of SOC and 19.78%from the degasification during carbonate precipitation.We conclude that the human excavation can significantly enhance the decomposition of the ancient OC in loess during the first two years after perturbation,producing and releasing soil CO_(2) to atmosphere.
基金This study was supported by the National Natural Science Foundation of China(Grant Nos.41976045&41888101)and the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)through a group research project(99147-42080024).Y.Cui is supported by the U.S.National Science Foundation award 1603051.Samples and core data were provided by ODP.ODP is sponsored by the U.S.National Science Foundation(NSF)and participating countries under management of Joint Oceanographic Institutions(JOI),Inc.
文摘Early Eocene hyperthermals are geologically short-lived global warming events and represent fundamental perturbations to the global carbon cycle and the Earth’s ecosystem due to massive additions of isotopically light carbon to the ocean-atmosphere system.They serve as ancient analogs for understanding how the oceanic carbonate system and surface-ocean ecosystem would respond to ongoing and future climate change.Here,we present a continuous carbonate record across the Eocene Thermal Maximum 2(ETM2 or H1,ca.54.1 Ma)and H2(ca.54 Ma)events from an expanded section at Ocean Drilling Program Site 1258 in tropical Atlantic.The abundant calcareous nannofossils and moderate carbonate content throughout the studied interval suggest this record was deposited above the calcite compensation depth(CCD),but below the lysocline and under the influence of terrestrial dilution.An Earth system model cGENIE is used to simulate the carbon cycle dynamics across the ETM2 and H2 to offer insights on the mechanism of the rapid warming and subsequent recovery in climate and ecosystem.The model suggests moderate changes in ocean pH(0.1–0.2 unit)for the two scenarios,biogenic methane from a rechargeable methane capacitor and organic matter oxidation from thawing of the permafrost.These pH changes are consistent with a recent independent pH estimate across the ETM2 using boron isotopes.The carbon emission flux during the ETM2 is at least an order of magnitude smaller than that during the Paleocene–Eocene Thermal Maximum(PETM)(0.015–0.05 Pg C yr^(-1)vs.0.3–1.7 Pg C yr^(-1)).The comparable pre-and post-event carbonate contents suggest the lysocline did not over deepen following the ETM2 at this tropical Atlantic site,indicating spatial heterogeneity in the carbonate system due to strong dilution influence from terrestrial weathering and riverine discharge at Site 1258.