Turbulence in the nocturnal boundary layer(NBL)is still not well characterized,especially over complex underlying surfaces.Herein,gradient tower data and eddy covariance data collected by the Beijing 325-m tower were ...Turbulence in the nocturnal boundary layer(NBL)is still not well characterized,especially over complex underlying surfaces.Herein,gradient tower data and eddy covariance data collected by the Beijing 325-m tower were used to better understand the differentiating characteristics of turbulence regimes and vertical turbulence structure of urban the NBL.As for heights above the urban canopy layer(UCL),the relationship between turbulence velocity scale(VTKE)and wind speed(V)was consistent with the“HOckey-Stick”(HOST)theory proposed for a relatively flat area.Four regimes have been identified according to urban nocturnal stable boundary layer.Regime 1 occurs where local shear plays a leading role for weak turbulence under the constraint that the wind speed V<VT(threshold wind speed).Regime 2 is determined by the existence of strong turbulence that occurs when V>VT and is mainly driven by bulk shear.Regime 3 is identified by the existence of moderate turbulence when upside-down turbulence sporadic bursts occur in the presence of otherwise weak turbulence.Regime 4 is identified as buoyancy turbulence,when V>VT,and the turbulence regime is affected by a combination of local wind shear,bulk shear and buoyancy turbulence.The turbulence activities demonstrated a weak thermal stratification dependency in regime 1,for which within the UCL,the turbulence intensity was strongly affected by local wind shear when V<VT.This study further showed typical examples of different stable boundary layers and the variations between turbulence regimes by analyzing the evolution of wind vectors.Partly because of the influence of large-scale motions,the power spectral density of vertical velocity for upsidedown structure showed an increase at low frequencies.The upside-down structures were also characterized by the highest frequency of the stable stratifications in the higher layer.展开更多
Shipborne observations obtained with the coherent Doppler lidar(CDL)and radiosonde during 2014 campaign were used to study the structure of marine boundary layer in the Yellow Sea.Vertical wind profiles corrected for ...Shipborne observations obtained with the coherent Doppler lidar(CDL)and radiosonde during 2014 campaign were used to study the structure of marine boundary layer in the Yellow Sea.Vertical wind profiles corrected for ship motion was used to derive higher-order statistics,showing that motion correction is required and significant for turbulence analysis.During a day with weak mesoscale activity,a complexed three-layer structure system was observed.The lowest layer showed a typical stable boundary layer structure feature.An aerosol layer with abrupt variation in wind speed and relative humidity always appeared at the middle layer,the formation of which may be due to Kelvin-Helmholz instability.The top layer encountered a dramatic change in wind direction,which may result from the warm advection from the Eurasian continent on the basis of backward trajectory analysis.Furthermore,the MABL height in stable regime was derived from potential temperature,CDL signal-to-noise ratio(SNR)and CDL vertical velocity variance,respectively.The stable boundary layer(SBL)height in SBL can be derived from the inversion layer of potential temperature profile,and the mixing height in SBL can be retrieved from the vertical velocity variance gradient method.Neither the SBL height nor the mixing height is in agreement with the height retrieved from CDL SNR gradient method because of different definition and criterion.One of the limitations of SNR gradient method for MABL retrieval is that it is easier to be affected by the lofted decoupled aerosol layer,where the retrieved result is less suitable.Finally,the higher-order vertical velocity statistics within the marine stable boundary layer were investigated and compared with the previous studies,and different turbulence mechanisms have an important effect on the statistics deviation.展开更多
Modified refractivity (M) profile is an important parameter to describe the atmospheric refraction environment,as well as a key factor in uniquely evaluating electromagnetic propagation effects.In order to improve the...Modified refractivity (M) profile is an important parameter to describe the atmospheric refraction environment,as well as a key factor in uniquely evaluating electromagnetic propagation effects.In order to improve the model-derived M profile in stable (especially very stable) conditions,three nonlinear similarity functions,namely BH91,CB05,SHEBA07,are introduced in this paper to improve the original Babin_V25 model,and the performances of these modified models are verified based on the hydrometeorological observations from tower platforms,which are finally compared with the original Babin_V25 model and Local_HYQ92 model.Results show that introducing nonlinear similarity functions can significantly improve the model-derived M profile;especially,the newly developed SHEBA07 functions manage to reduce the predicted root mean square (rms) differences of M and M slope (for both 0-5m and 5-40m) by 64.5%,16.6%,and 60.4%,respectively in stable conditions.Unfortunately,this improved method reacts little on the evaporation duct height;in contrast,Local_HYQ92 model is capable of reducing the predicted rms differences of M,M slope (for both 0-5m and 5-40m),and evaporation duct height by 76.7%,40.2%,83.7%,and 58.0% respectively.Finally,a new recommendation is made to apply Local_HYQ92 and Babin_SHEBA07 in very stable conditions considering that M slope is more important than evaporation duct height and absolute M value in uniquely determining electromagnetic propagation effects.展开更多
The construction method of continuous paving of the upper and lower base of the water stable macadam base can improve the construction efficiency,overcome the quality problems of the traditional layered paving of the ...The construction method of continuous paving of the upper and lower base of the water stable macadam base can improve the construction efficiency,overcome the quality problems of the traditional layered paving of the upper and lower base,such as untimely curing,slow construction,poor interlayer bonding,contraction joint and interlayer,so as to ensure the construction quality of the water stable macadam.It is also the promotion and application of new technology.展开更多
Lithium–sulfur(Li–S)battery as a high-energy density electrochemical energy storage system has attracted many researchers’attention.However,the shuttle effect of Li–S batteries and the challenges associated with l...Lithium–sulfur(Li–S)battery as a high-energy density electrochemical energy storage system has attracted many researchers’attention.However,the shuttle effect of Li–S batteries and the challenges associated with lithium metal anode caused poor cycle performance.In this work,the organosulfide poly(sulfur-1,3-diisopropenylbenzene)(PSD)was prepared as cathode material and additive of P(VDFHFP)polymer electrolyte(P(VDF-HFP)).It was verified that P(VDF-HFP)polymer electrolyte with 10%PSD(P(VDF-HFP)-10%PSD)showed a higher ionic conductivities than that of liquid electrolyte up to2.27×10-3 S cm-1 at room temperature.The quasi-solid-state Li-S batteries fabricated with organosulfide cathode material PSD and P(VDF-HFP)based functional polymer electrolyte delivered good cycling stability(780 m Ah g-1 after 200 th cycle at 0.1 C)and rate performance(613 m Ah g-1 at 1 C).The good cycling performance could be attributed to the synergistic effect of components,including the interaction between polysulfides and polymer main chain in the organosulfide cathode,the sustained organic/inorganic hybrid stable SEI layer formed by polymer electrolyte additive PSD,the improved cathode/electrolyte interface and the good affinity between P(VDF-HFP)based functional polymer electrolyte and Li metal surface.This strategy herein may provide a new route to fabricate high-performance Li–S batteries through the organosulfide cathode and functional polymer electrolyte.展开更多
In the stably stratified boundary layer,the vertical flux profiles for momentum and heat can be obtained from an atmospheric boundary layer model which includes parameterization of the long-wave radiation,In addi- tio...In the stably stratified boundary layer,the vertical flux profiles for momentum and heat can be obtained from an atmospheric boundary layer model which includes parameterization of the long-wave radiation,In addi- tion,the Monin-Obukhov similarity theory can be extended to the whole boundary layer by using the local tur- bulent scales L(z),U_*(z)and 0_*(z)in place of surface layer scales.The similarity predictions are in good agreement with observational data.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 42105093 and 41975018)the China Postdoctoral Science Foundation (Grant No. 2020M670420)the Special Research Assistant Project。
文摘Turbulence in the nocturnal boundary layer(NBL)is still not well characterized,especially over complex underlying surfaces.Herein,gradient tower data and eddy covariance data collected by the Beijing 325-m tower were used to better understand the differentiating characteristics of turbulence regimes and vertical turbulence structure of urban the NBL.As for heights above the urban canopy layer(UCL),the relationship between turbulence velocity scale(VTKE)and wind speed(V)was consistent with the“HOckey-Stick”(HOST)theory proposed for a relatively flat area.Four regimes have been identified according to urban nocturnal stable boundary layer.Regime 1 occurs where local shear plays a leading role for weak turbulence under the constraint that the wind speed V<VT(threshold wind speed).Regime 2 is determined by the existence of strong turbulence that occurs when V>VT and is mainly driven by bulk shear.Regime 3 is identified by the existence of moderate turbulence when upside-down turbulence sporadic bursts occur in the presence of otherwise weak turbulence.Regime 4 is identified as buoyancy turbulence,when V>VT,and the turbulence regime is affected by a combination of local wind shear,bulk shear and buoyancy turbulence.The turbulence activities demonstrated a weak thermal stratification dependency in regime 1,for which within the UCL,the turbulence intensity was strongly affected by local wind shear when V<VT.This study further showed typical examples of different stable boundary layers and the variations between turbulence regimes by analyzing the evolution of wind vectors.Partly because of the influence of large-scale motions,the power spectral density of vertical velocity for upsidedown structure showed an increase at low frequencies.The upside-down structures were also characterized by the highest frequency of the stable stratifications in the higher layer.
基金National High Technology R&D Program of China(No.2014AA09A511)National Natural Science Foundation of China(Nos.41471309+3 种基金4137501661975191)National Key R&D Program of China(No.2016YFC1400904)The first author is supported by China Scholarship Council (CSC number: 201706330031). The authors gratefully acknowledge the NOAA Air Resources Laboratory (ARL) for the provision of the HYSPLIT transport and dispersion model and ECMWF for providing reanalysis datasets the in this publication.
文摘Shipborne observations obtained with the coherent Doppler lidar(CDL)and radiosonde during 2014 campaign were used to study the structure of marine boundary layer in the Yellow Sea.Vertical wind profiles corrected for ship motion was used to derive higher-order statistics,showing that motion correction is required and significant for turbulence analysis.During a day with weak mesoscale activity,a complexed three-layer structure system was observed.The lowest layer showed a typical stable boundary layer structure feature.An aerosol layer with abrupt variation in wind speed and relative humidity always appeared at the middle layer,the formation of which may be due to Kelvin-Helmholz instability.The top layer encountered a dramatic change in wind direction,which may result from the warm advection from the Eurasian continent on the basis of backward trajectory analysis.Furthermore,the MABL height in stable regime was derived from potential temperature,CDL signal-to-noise ratio(SNR)and CDL vertical velocity variance,respectively.The stable boundary layer(SBL)height in SBL can be derived from the inversion layer of potential temperature profile,and the mixing height in SBL can be retrieved from the vertical velocity variance gradient method.Neither the SBL height nor the mixing height is in agreement with the height retrieved from CDL SNR gradient method because of different definition and criterion.One of the limitations of SNR gradient method for MABL retrieval is that it is easier to be affected by the lofted decoupled aerosol layer,where the retrieved result is less suitable.Finally,the higher-order vertical velocity statistics within the marine stable boundary layer were investigated and compared with the previous studies,and different turbulence mechanisms have an important effect on the statistics deviation.
基金Key project of the National Natural Science Foundation of China(4083095841005029)the "973" National Basis Research and Development Program of China (2009CB421502)
文摘Modified refractivity (M) profile is an important parameter to describe the atmospheric refraction environment,as well as a key factor in uniquely evaluating electromagnetic propagation effects.In order to improve the model-derived M profile in stable (especially very stable) conditions,three nonlinear similarity functions,namely BH91,CB05,SHEBA07,are introduced in this paper to improve the original Babin_V25 model,and the performances of these modified models are verified based on the hydrometeorological observations from tower platforms,which are finally compared with the original Babin_V25 model and Local_HYQ92 model.Results show that introducing nonlinear similarity functions can significantly improve the model-derived M profile;especially,the newly developed SHEBA07 functions manage to reduce the predicted root mean square (rms) differences of M and M slope (for both 0-5m and 5-40m) by 64.5%,16.6%,and 60.4%,respectively in stable conditions.Unfortunately,this improved method reacts little on the evaporation duct height;in contrast,Local_HYQ92 model is capable of reducing the predicted rms differences of M,M slope (for both 0-5m and 5-40m),and evaporation duct height by 76.7%,40.2%,83.7%,and 58.0% respectively.Finally,a new recommendation is made to apply Local_HYQ92 and Babin_SHEBA07 in very stable conditions considering that M slope is more important than evaporation duct height and absolute M value in uniquely determining electromagnetic propagation effects.
文摘The construction method of continuous paving of the upper and lower base of the water stable macadam base can improve the construction efficiency,overcome the quality problems of the traditional layered paving of the upper and lower base,such as untimely curing,slow construction,poor interlayer bonding,contraction joint and interlayer,so as to ensure the construction quality of the water stable macadam.It is also the promotion and application of new technology.
基金Financial supports from the National Natural Science Foundation of China(51532002 and 51872027)Beijing Natural Science Foundation(L172023)National Basic Research Program of China(2016YFA0202500,2017YFE0113500,and 2018YFB0104300)。
文摘Lithium–sulfur(Li–S)battery as a high-energy density electrochemical energy storage system has attracted many researchers’attention.However,the shuttle effect of Li–S batteries and the challenges associated with lithium metal anode caused poor cycle performance.In this work,the organosulfide poly(sulfur-1,3-diisopropenylbenzene)(PSD)was prepared as cathode material and additive of P(VDFHFP)polymer electrolyte(P(VDF-HFP)).It was verified that P(VDF-HFP)polymer electrolyte with 10%PSD(P(VDF-HFP)-10%PSD)showed a higher ionic conductivities than that of liquid electrolyte up to2.27×10-3 S cm-1 at room temperature.The quasi-solid-state Li-S batteries fabricated with organosulfide cathode material PSD and P(VDF-HFP)based functional polymer electrolyte delivered good cycling stability(780 m Ah g-1 after 200 th cycle at 0.1 C)and rate performance(613 m Ah g-1 at 1 C).The good cycling performance could be attributed to the synergistic effect of components,including the interaction between polysulfides and polymer main chain in the organosulfide cathode,the sustained organic/inorganic hybrid stable SEI layer formed by polymer electrolyte additive PSD,the improved cathode/electrolyte interface and the good affinity between P(VDF-HFP)based functional polymer electrolyte and Li metal surface.This strategy herein may provide a new route to fabricate high-performance Li–S batteries through the organosulfide cathode and functional polymer electrolyte.
文摘In the stably stratified boundary layer,the vertical flux profiles for momentum and heat can be obtained from an atmospheric boundary layer model which includes parameterization of the long-wave radiation,In addi- tion,the Monin-Obukhov similarity theory can be extended to the whole boundary layer by using the local tur- bulent scales L(z),U_*(z)and 0_*(z)in place of surface layer scales.The similarity predictions are in good agreement with observational data.