Base on the previous work in laboratory, a novel polyaniline doped with polydimethylsiloxane coating was developed on a stainless steel wire for solid phase microextraction（SPME） by electroplating method. This elect...Base on the previous work in laboratory, a novel polyaniline doped with polydimethylsiloxane coating was developed on a stainless steel wire for solid phase microextraction（SPME） by electroplating method. This electroplating method not only has advantages of ease preparation and simple equipments required, but also increases the lifetime of the SPME fiber. The composite fiber（polyaniline/ polydimethylsiloxane（PANI/PDMS）） was evaluated by analyzing n-tridecane, n-tetradecane and n-pentadecane in aqueous sample. The new fiber coating showed comprehensive abilities to extract alkanes compounds. The relative standard deviations were found to be 6.8%-10.33%.展开更多
One kind of quenched Cr12 steel dies for impacting stainless steel wire rope （SSWR） was treated by low temperature liquid sulfurization catalyzed with rare earths, in order to extend their service life for assuring ...One kind of quenched Cr12 steel dies for impacting stainless steel wire rope （SSWR） was treated by low temperature liquid sulfurization catalyzed with rare earths, in order to extend their service life for assuring the continuity of production line, and simultaneously improve the surface quality of SSWR obtained. After immerged into the melting sulphur containing 4 % （mass fraction） of LaF3 and 1% of CeCl3 at 463 K for 4 h, the sulfurized dies were very smooth and black, with little distortion and hardness loss. They exhibited a certain extent of corrosion-resistance in air due to the coexisting rare earths in the sulfurized layer. Optical observations showed that the sulfurized layer was uniform and had scale-like structure. The trail of machined SSWR indicated that the production capacity of sulfurized dies had been doubled and the replacing period on line was postponed. SEM morphology also proved that the wear extent of cavities on sulfurized dies decreased greatly and the surface quality of SSWR obtained was improved markedly.展开更多
Droplet impacting on the stainless steel wire mesh is very common in chemical devices,like a rotating packed bed.Surface wettability of wire mesh significantly affects the liquid flow pattern and liquid dispersion per...Droplet impacting on the stainless steel wire mesh is very common in chemical devices,like a rotating packed bed.Surface wettability of wire mesh significantly affects the liquid flow pattern and liquid dispersion performance.However,the effect of surface wettability on the impaction phenomena at microscale such as liquid film is still unknown.In this work,the dynamic behavior of liquid film on the surface of wire mesh was analyzed by computational fluid dynamics simulation.The dynamic behavior of liquid film on the surface of wire mesh can be divided into the following three steps:(1)spreading step;(2)shrinkage process;(3)stabilizing or disappearing step.Effects of surface wettability,as well as operating conditions,on wetting area and liquid film thickness were studied.Compared to the hydrophilic wire mesh,the final wetting area of hydrophobic wire mesh is zero in most cases.The average liquid film thickness on the surface of hydrophilic wire mesh is 30.02–77.29μm,and that of hydrophobic wire mesh is 41.76–237.37μm.This work provided a basic understanding of liquid film flow at microscale on the surface with various surface wettabilities,which can be guiding the packing optimization and design.展开更多
文摘Base on the previous work in laboratory, a novel polyaniline doped with polydimethylsiloxane coating was developed on a stainless steel wire for solid phase microextraction（SPME） by electroplating method. This electroplating method not only has advantages of ease preparation and simple equipments required, but also increases the lifetime of the SPME fiber. The composite fiber（polyaniline/ polydimethylsiloxane（PANI/PDMS）） was evaluated by analyzing n-tridecane, n-tetradecane and n-pentadecane in aqueous sample. The new fiber coating showed comprehensive abilities to extract alkanes compounds. The relative standard deviations were found to be 6.8%-10.33%.
基金Project supported by the Natural Science Fund of Jiangsu Province (BK2002062)Startup Fund of Hohai University(2084/40501107)
文摘One kind of quenched Cr12 steel dies for impacting stainless steel wire rope （SSWR） was treated by low temperature liquid sulfurization catalyzed with rare earths, in order to extend their service life for assuring the continuity of production line, and simultaneously improve the surface quality of SSWR obtained. After immerged into the melting sulphur containing 4 % （mass fraction） of LaF3 and 1% of CeCl3 at 463 K for 4 h, the sulfurized dies were very smooth and black, with little distortion and hardness loss. They exhibited a certain extent of corrosion-resistance in air due to the coexisting rare earths in the sulfurized layer. Optical observations showed that the sulfurized layer was uniform and had scale-like structure. The trail of machined SSWR indicated that the production capacity of sulfurized dies had been doubled and the replacing period on line was postponed. SEM morphology also proved that the wear extent of cavities on sulfurized dies decreased greatly and the surface quality of SSWR obtained was improved markedly.
基金This work was supported by the National Natural Science Foundation of China(Grant No.22022802).
文摘Droplet impacting on the stainless steel wire mesh is very common in chemical devices,like a rotating packed bed.Surface wettability of wire mesh significantly affects the liquid flow pattern and liquid dispersion performance.However,the effect of surface wettability on the impaction phenomena at microscale such as liquid film is still unknown.In this work,the dynamic behavior of liquid film on the surface of wire mesh was analyzed by computational fluid dynamics simulation.The dynamic behavior of liquid film on the surface of wire mesh can be divided into the following three steps:(1)spreading step;(2)shrinkage process;(3)stabilizing or disappearing step.Effects of surface wettability,as well as operating conditions,on wetting area and liquid film thickness were studied.Compared to the hydrophilic wire mesh,the final wetting area of hydrophobic wire mesh is zero in most cases.The average liquid film thickness on the surface of hydrophilic wire mesh is 30.02–77.29μm,and that of hydrophobic wire mesh is 41.76–237.37μm.This work provided a basic understanding of liquid film flow at microscale on the surface with various surface wettabilities,which can be guiding the packing optimization and design.
