This paper establishes a new model for calculation of the standard entropies of solid binary oxides as follows: S_(29)=27.07×Φ_1+1.120×Φ_2+n_1×k×Φ, -22.19 e.u (R=0.9960) We have invesigated 103 ...This paper establishes a new model for calculation of the standard entropies of solid binary oxides as follows: S_(29)=27.07×Φ_1+1.120×Φ_2+n_1×k×Φ, -22.19 e.u (R=0.9960) We have invesigated 103 binary oxides. and found good agreemenl between estimated and experimental entropies.展开更多
This paper presents a new model for the calculation of the standard entropies of solidcomplex silicates as follows.4. =53.63+9914-72.81 J/kmol (R=0.9915, Sd=5.39)Sixty complex silicates have been investigated, and go...This paper presents a new model for the calculation of the standard entropies of solidcomplex silicates as follows.4. =53.63+9914-72.81 J/kmol (R=0.9915, Sd=5.39)Sixty complex silicates have been investigated, and good agreement was found between theestimated and experimental entropy values.展开更多
文摘This paper establishes a new model for calculation of the standard entropies of solid binary oxides as follows: S_(29)=27.07×Φ_1+1.120×Φ_2+n_1×k×Φ, -22.19 e.u (R=0.9960) We have invesigated 103 binary oxides. and found good agreemenl between estimated and experimental entropies.
文摘This paper presents a new model for the calculation of the standard entropies of solidcomplex silicates as follows.4. =53.63+9914-72.81 J/kmol (R=0.9915, Sd=5.39)Sixty complex silicates have been investigated, and good agreement was found between theestimated and experimental entropy values.