Selective harmonic elimination pulse width modula-tion(SHEPWM)is a modulation strategy widely used for three-level wind power grid-connected converters.Its purpose is to eliminate specified sub-low frequency harmonics...Selective harmonic elimination pulse width modula-tion(SHEPWM)is a modulation strategy widely used for three-level wind power grid-connected converters.Its purpose is to eliminate specified sub-low frequency harmonics by controlling switching angle.Furthermore,it can reduce fluctuation of the microgrid system and improve system stability.Intelligent al-gorithms have been applied to the SHEPWM solution process to mitigate calculation complexity associated with the algebraic method,as well as the need to set the initial value.However,disorder of the optimization result causes difficulty in satisfying incremental constraint of the three-level NPC switching angles,and affects the success rate of the algorithm.To overcome this limitation,this paper proposes a fast SHEPWM strategy to optimize the result obtained by the intelligent algorithm.The SHEPWM can be realized by solving switching angles through a state equations-based mathematical model,which is constructed by using the initial variables randomly generated by the intelligent algorithm as the disturbance.This mathematical model improves the success rate of calculation by simplifying constraint representation of switching angles and solving the disorder problem of the optimization result.At the same time,a method based on the circle equation and the trigonometric function is applied to the initial variable assignment of the state equation,which further improves the speed and accuracy of the solution,realizes a more thorough filtering effect,and further reduces the impact of sub-low frequency harmonics on a wind power integrated system.Finally,simulation and experiment results have been used to prove the effectiveness of the proposed SHEPWM strategy when combined with intelligent algorithms.Index Terms-Wind power converter,adaptive genetic algorithm,selective harmonic elimination pulse-width modulation(SHEPWM),state equation,success rate.展开更多
Adopting the classical theory of hydrocodes,the constitutive relations of concretes are separated into an equation of state(EoS)which describes the volumetric behavior of concrete material and a strength model which d...Adopting the classical theory of hydrocodes,the constitutive relations of concretes are separated into an equation of state(EoS)which describes the volumetric behavior of concrete material and a strength model which depicts the shear properties of concrete.The experiments on the EoS of concrete is always challenging due to the technical difficulties and equipment limitations,especially for the specimen size effect on the EoS.Although some researchers investigate the shock properties of concretes by fly-plate impact tests,the specimens used in their tests are usually in one size.In this paper,the fly-plate impact tests on concrete specimens with different sizes are performed to investigate the size effect on the shock properties of concrete materials.The mechanical background of the size effect on the shock properties are revealed,which is related to the lateral rarefaction effect and the deviatoric stress produced in the specimen.According to the tests results,the modified EoS considering the size effect on the shock properties of concrete are proposed,which the bulk modulus of concrete is unpredicted by up to 20% if size effects are not accounted for.展开更多
Encouraged by the wide spectrum of novel applications of gas hydrates,e.g.,energy recovery,gas separation,gas storage,gas transportation,water desalination,and hydrogen hydrate as a green energy resource,as well as CO...Encouraged by the wide spectrum of novel applications of gas hydrates,e.g.,energy recovery,gas separation,gas storage,gas transportation,water desalination,and hydrogen hydrate as a green energy resource,as well as CO2 capturing,many scientists have focused their attention on investigating this important phenomenon.Of course,from an engineering viewpoint,the mathematical modeling of gas hydrates is of paramount importance,as anticipation of gas hydrate stability conditions is effective in the design and control of industrial processes.Overall,the thermodynamic modeling of gas hydrate can be tackled as an equilibration of three phases,i.e.,liquid,gas,and solid hydrate.The inseparable component in all hydrate systems,water,is highly polar and non-ideal,necessitating the use of more advanced equation of states(EoSs) that take into account more intermolecular forces for thermodynamic modeling of these systems.Motivated by the ever-increasing number of publications on this topic,this study aims to review the application of associating EoSs for the thermodynamic modeling of gas hydrates.Three most important hydrate-based models available in the literature including the van der Waals-Platteeuw(vdW-P) model,Chen-Guo model,and Klauda-Sandler model coupled with and SAFT EoSs were investigated and compared with cubic EoSs.It was concluded that the CPA and SAFT EoSs gave very accurate results for hydrate systems as they take into account the association interactions,which are very crucial in gas hydrate systems in which water,methanol,glycols,and other types of associating compounds are available.Moreover,it was concluded that the CPA EoS is easier to use than the SAFT-type EoSs and our suggestion for the gas hydrate systems is the CPA EoS.展开更多
With a new approach,the general current expressions of two typical second order catalytic reactions at microelectrodes are obtained.This allows the study of fast chemical reactions and systems where the reactants are ...With a new approach,the general current expressions of two typical second order catalytic reactions at microelectrodes are obtained.This allows the study of fast chemical reactions and systems where the reactants are present in similar concentrations.展开更多
The importance of equations of state (EOS) has brought about the proliferation of hundreds of EOS. Nearly all prevailing cubic EOS could be regarded as the results of reforming the original vdW EOS. However, the accur...The importance of equations of state (EOS) has brought about the proliferation of hundreds of EOS. Nearly all prevailing cubic EOS could be regarded as the results of reforming the original vdW EOS. However, the accuracy of the vdW EOS is so low. In view of this, a new general equation is proposed that could be used to value or compare vdW type of EOS, and consequently develop a better vdW type of EOS.展开更多
In the present work, effect of the attraction terms of four recently modified Peng-Robinson (MPR) equations of state on the prediction of solubility of caffeine, cholesterol, uracil and erythromycin was studied. The...In the present work, effect of the attraction terms of four recently modified Peng-Robinson (MPR) equations of state on the prediction of solubility of caffeine, cholesterol, uracil and erythromycin was studied. The attraction terms of two of these equations are linear relative to the acentric factor and for the other two are exponential. It is found that the later show less deviation. Also interaction parameters for the studied systems are obtained and the percentage of average absolute relative deviation (%AARD) in each calculation is displayed.展开更多
The equation of state of MgSiO3 perovskite under high pressure and high temperature is simulated using the molecular dynamics method. It was found that the molecular dynamics simulation is very successful in accuratel...The equation of state of MgSiO3 perovskite under high pressure and high temperature is simulated using the molecular dynamics method. It was found that the molecular dynamics simulation is very successful in accurately reproducing the measured molar volumes of MgSiO3 perovskite over a wide range of temperatures and pressures. The simulated equation of state of MgSiO3 perovskite matched experimental data at up to 140GPa at 300K, as well as the fitting data of others and results from the first-principles simulation based on the local density approximation. The simulated equations of state of MgSiO3 perovskite at higher temperatures and higher pressures also correspond to the other calculations. In addition, the volume compression data of MgSiO3 perovskite is simulated up to 120 GPa at 300, 900, 2000 and 3000 K, respectively.展开更多
Progress in hydrate thermodynamic study necessitates robust and fast models to be incorporated in reservoir simulation softwares. However, numerous models presented in the literature makes selection of the best,proper...Progress in hydrate thermodynamic study necessitates robust and fast models to be incorporated in reservoir simulation softwares. However, numerous models presented in the literature makes selection of the best,proper predictive model a cumbersome task. It is of industrial interest to make use of cubic equations of state(EOS) for modeling hydrate equilibria. In this regard, this study focuses on evaluation of three common EOSs including Peng–Robinson, Soave–Redlich–Kwong and Valderrama–Patel–Teja coupled with van der Waals and Platteeuw theory to predict hydrate P–T equilibrium of a real natural gas sample. Each EOS was accompanied with three mixing rules, including van der Waals(vd W),Avlonitis non-density dependent(ANDD) and general nonquadratic(GNQ). The prediction of cubic EOSs was in sufficient agreement with experimental data and with overall AARD% of less than unity. In addition, PR plus ANDD proved to be the most accurate model in this study for prediction of hydrate equilibria with AARD% of 0.166.It was observed that the accuracy of cubic EOSs studied in this paper depends on mixing rule coupled with them,especially at high-pressure conditions. Lastly, the present study does not include any adjustable parameter to be correlated with hydrate phase equilibrium data.展开更多
A new approach to the investigation of vdW type of equations of state (EOS) is developed by embedding a vapor pressure equation and a saturated liquid volume equation into vdW type EOS, which results in a new function...A new approach to the investigation of vdW type of equations of state (EOS) is developed by embedding a vapor pressure equation and a saturated liquid volume equation into vdW type EOS, which results in a new function AS(T). The AS(T) possesses the properties of an attractive parameter A(T), and if an EOS is accurate in the whole PVT space, then its numerical value equals A(T). As a useful tool for investigating EOS, the As(T) has been used to make comparisons among RKS, PRSVII, PT and ALS EOS, and to indicate where the shortcomings of the EOS are coming from. Based on the AS(T), a possible way to develop a real predictive equation of state is also suggested.展开更多
The equations of state(EOSs)of materials are the cornerstone of condensed matter physics,material science,and geophysics.However,acquiring an accurate EOS in diamond anvil cell(DAC)experiments continues to prove probl...The equations of state(EOSs)of materials are the cornerstone of condensed matter physics,material science,and geophysics.However,acquiring an accurate EOS in diamond anvil cell(DAC)experiments continues to prove problematic because the current lack of an accurate pressure scale with clarified sources of uncertainty makes it difficult to determine a precise pressure value at high pressure,and nonhydrostaticity affects both the volume and pressure determination.This study will discuss the advantages and drawbacks of various pressure scales,and propose an absolute pressure scale and correction methods for the effects of non-hydrostaticity.At the end of this paper,we analyze the accuracy of the determined EOS in the DAC experiments we can achieve to date.展开更多
In this paper, the LCVM mixing rule is extended to the multi-parameter equations of state by combining infi- nite-pressure and zero-pressure mixing rule models. The new LCVM-type mixing rule, coupled with Patel-Teja e...In this paper, the LCVM mixing rule is extended to the multi-parameter equations of state by combining infi- nite-pressure and zero-pressure mixing rule models. The new LCVM-type mixing rule, coupled with Patel-Teja equation of state (EOS) is applied for vapor-liquid equilibria of different polar and non-polar systems in which the NRTL activity coefficient model is used to calculate the excess Gibbs free energy. The tested results agree well with existing experimental data within a wide range of temperatures and pressures. In comparison with the Van der Waals mixing rule, the new mixing rule gives much better corre- lations for the vapor-liquid equilibria of non-polar and polar systems.展开更多
Supercritical CO_(2)(SCO_(2))Brayton cycle has received more and more attention in the field of power generation due to its high cycle efficiency and compact structure.SCO_(2) compressor is the core component of the c...Supercritical CO_(2)(SCO_(2))Brayton cycle has received more and more attention in the field of power generation due to its high cycle efficiency and compact structure.SCO_(2) compressor is the core component of the cycle,and the improvement of its performance is the key to improving the efficiency of the entire cycle.However,the operation of the SCO_(2) compressor near the critical point has brought many design and operation problems.Based on the Reynolds Averaged Navier-Stokes(RANS)model,the performance and flow field of SCO_(2) centrifugal compressors based on different CO_(2) working fluid models are numerically investigated in this paper.The stability and convergence of the compressor steady-state simulation are also discussed.The results show that the fluid based on the Span-Wanger(SW)equation can obtain a more ideal compressor performance curve and capture a more accurate flow field structure,while the CO_(2) ideal gas is not suitable for the calculation of SCO_(2) centrifugal compressors.But its flow field can be used as the initial flow field for numerical calculation of centrifugal compressor based on CO_(2) real gas.展开更多
In the U.S., the current Load and Resistance Factor Design (LRFD) Specifications for highway bridges is a reliability-based formulation that considers failure probabilities of bridge components due to the actions of...In the U.S., the current Load and Resistance Factor Design (LRFD) Specifications for highway bridges is a reliability-based formulation that considers failure probabilities of bridge components due to the actions of typical dead load and frequent vehicular loads. Various extreme load effects, such as earthquake and vessel collision, are on the same reliability-based platform. Since these extreme loads are time variables, combining them with not considered frequent. non- extreme loads is a significant challenge. The number of design limit state equations based on these failure probabilities can be unrealistically large and unnecessary from the view point of practical applications. Based on the opinion of AASHTO State Bridge Engineers, many load combinations are insignificant in their states. This paper describes the formulation of a criterion to include only the necessary load combinations to establish the design limit states. This criterion is established by examining the total failure probabilities for all possible time-invariant and time varying load combinations and breaking them down into partial terms. Then, important load combinations can be readily determined quantitatively,展开更多
The recent measurements of neutron skins via parity violation in electron scattering have extracted an abnormally thick neutron skin for 208 Pb,which has significant consequences in nuclear equation of state(EoS)and n...The recent measurements of neutron skins via parity violation in electron scattering have extracted an abnormally thick neutron skin for 208 Pb,which has significant consequences in nuclear equation of state(EoS)and neutron star observations.In this study,we perform optimizations of extended Skyrme forces in a consistent manner by including neutron skin thicknesses from PREX-Ⅱand CREX experiments and investigate nuclear EoSs and neutron stars in the GW170817 event By varying the fitting weights of neutron skins,several new Skyrme parameterizations are obtained.Our results show the competition in the fitting procedure to simultaneously describe neutron skins,other properties of finite nuclei,and neutron star observations.The prospects of resolving neutron skin issues are also discussed.展开更多
A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square ...A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.展开更多
2,4-dinitroanisole(DNAN)is a good replacement for 2,4,6-trinitrotoluene(TNT)in melt-cast explosives due to its superior insensitivity.With the increasing use of DNAN-based melt-cast explosives,the prediction of reacti...2,4-dinitroanisole(DNAN)is a good replacement for 2,4,6-trinitrotoluene(TNT)in melt-cast explosives due to its superior insensitivity.With the increasing use of DNAN-based melt-cast explosives,the prediction of reaction violence and hazard assessment of the explosives subjected to shock is of great significance.This study investigated the shock initiation characteristics for a DNAN-based melt-cast explosive,DHFA,using the one-dimensional Lagrangian apparatus.The embedded manganin gauges in the apparatus record the pressure histories at four Lagrangian positions and show that shock-todetonation transition in DHFA needs a high input shock pressure.The experimental data are analyzed to calibrate the Ignition and Growth model.The calibration is performed using an objective function based on both pressure history and the arrival time of shock.Good agreement between experimental and calculated pressure histories indicates the high accuracy of the calibrated parameters with the optimization method.展开更多
This study aims to discuss anisotropic solutions that are spherically symmetric in the quintessence field,which describe compact stellar objects in the modified Rastall teleparallel theory of gravity.To achieve this g...This study aims to discuss anisotropic solutions that are spherically symmetric in the quintessence field,which describe compact stellar objects in the modified Rastall teleparallel theory of gravity.To achieve this goal,the Krori and Barua arrangement for spherically symmetric components of the line element is incorporated.We explore the field equations by selecting appropriate off-diagonal tetrad fields.Born-Infeld function of torsion f(T)=β√λT+1-1 and power law form h(T)=δTn are used.The Born-Infeld gravity was the first modified teleparallel gravity to discuss inflation.We use the linear equation of state pr=ξρto separate the quintessence density.After obtaining the field equations,we investigate different physical parameters that demonstrate the stability and physical acceptability of the stellar models.We use observational data,such as the mass and radius of the compact star candidates PSRJ 1416-2230,Cen X-3,&4U 1820-30,to ensure the physical plausibility of our findings.展开更多
Compressed gas is usually used for the pressure compensation of the deep-sea pressure-maintaining sampler.The pressure and volume of the recovered fluid sample are highly related to the precharged gas. To better under...Compressed gas is usually used for the pressure compensation of the deep-sea pressure-maintaining sampler.The pressure and volume of the recovered fluid sample are highly related to the precharged gas. To better understand the behavior of the gas under high pressure, we present a new real gas state equation based on the compression factor Z which was derived from experimental data. Then theoretical calculation method of the pressure and volume of the sample was introduced based on this empirical gas state equation. Finally, the proposed calculation method was well verified by the high-pressure vessel experiment of the sampler under 115 MPa.展开更多
An analytical method is presented to fit parameters of Jones-Wilkins-Lee (JWL) equation of state (EOS) for the chemical process of aluminum-polytetrafluoroethylene ( AI/PTFE ) mixture. Subroutine codes for both ...An analytical method is presented to fit parameters of Jones-Wilkins-Lee (JWL) equation of state (EOS) for the chemical process of aluminum-polytetrafluoroethylene ( AI/PTFE ) mixture. Subroutine codes for both strength model and EOS were developed in explicit-FE code AUTODYN. Firstly, the shock Hugoniot data of reactive A1/PTFE mixture was analytically derived by implemen- ting this methodology. The JWL EOS was verified to fit shock Hugoniot data of both reacted and un- reacted A1/PTFE mixture, which gives reasonable results. Furthermore, to numerically ascertain the reaction phases of ignition and growth and quasi detonation of A1/PTFE mixture, characterized ex- periment was setup to validate the reaction phases and coefficients of JWL EOS for A1/PTFE mix- ture. From the test, a promising example of reactive mixture A1/PTFE is capable to enhance lethality of weapons, the status computation in clude quasi-detonation pressure and temperature of A1/PTFE mixture in different chemical reaction phases is validated.展开更多
Based on the Hugenholtz-Van Hove theorem six basic quantities of the EoS in isospin asymmetric nuclear matter are expressed in terms of the nucleon kinetic energy t(k),the isospin symmetric and asymmetric parts of the...Based on the Hugenholtz-Van Hove theorem six basic quantities of the EoS in isospin asymmetric nuclear matter are expressed in terms of the nucleon kinetic energy t(k),the isospin symmetric and asymmetric parts of the single-nucleon potentials U_(0)(ρ,k)and U_(sym,i)(ρ,k).The six basic quantities include the quadratic symmetry energy E_(sym,2)(ρ),the quartic symmetry energy E_(sym,4)(ρ),their corresponding density slopes L_(2)(ρ)and L_(4)(ρ),and the incompressibility coefficients K_(2)(ρ)and K_(4)(ρ).By using four types of well-known effective nucleon-nucleon interaction models,namely the BGBD,MDI,Skyrme,and Gogny forces,the density-and isospin-dependent properties of these basic quantities are systematically calculated and their values at the saturation density q_(0)are explicitly given.The contributions to these quantities from t(k)U_(0)(ρ,k),and U_(sym,i)(ρ,k)are also analyzed at the norma nuclear density q_(0).It is clearly shown that the first-order asymmetric term U_(sym,1)(ρ,k)(also known as the symmetry potential in the Lane potential)plays a vital role in determining the density dependence of the quadratic symmetry energy E_(sym,2)(ρ).It is also shown that the contributions from the high-order asymmetric parts of the single-nucleon potentials(U_(sym,i)(ρ,k)with i>1)cannot be neglected in the calculations of the other five basic quantities Moreover,by analyzing the properties of asymmetric nuclear matter at the exact saturation densityρ_(sat)(δ),the corresponding quadratic incompressibility coefficient is found to have a simple empirical relation K_(sat,2)=K_(2)(ρ_(0))-4.14L_(2)(ρ_(0))展开更多
基金supported in part by National Natural Science Foundation of China(52177193)Key Research and Development Program of Shaanxi Province(2022GY-182)+1 种基金China Scholarship Council(CSC)State Scholarship Fund International Clean Energy Talent Project(Grant No.[2018]5046,[2019]157)Open Research Fund of Jiangsu Collaborative Innovation Center for Smart Distribution Network,Nanjing Institute of Technology(XTCX202107).
文摘Selective harmonic elimination pulse width modula-tion(SHEPWM)is a modulation strategy widely used for three-level wind power grid-connected converters.Its purpose is to eliminate specified sub-low frequency harmonics by controlling switching angle.Furthermore,it can reduce fluctuation of the microgrid system and improve system stability.Intelligent al-gorithms have been applied to the SHEPWM solution process to mitigate calculation complexity associated with the algebraic method,as well as the need to set the initial value.However,disorder of the optimization result causes difficulty in satisfying incremental constraint of the three-level NPC switching angles,and affects the success rate of the algorithm.To overcome this limitation,this paper proposes a fast SHEPWM strategy to optimize the result obtained by the intelligent algorithm.The SHEPWM can be realized by solving switching angles through a state equations-based mathematical model,which is constructed by using the initial variables randomly generated by the intelligent algorithm as the disturbance.This mathematical model improves the success rate of calculation by simplifying constraint representation of switching angles and solving the disorder problem of the optimization result.At the same time,a method based on the circle equation and the trigonometric function is applied to the initial variable assignment of the state equation,which further improves the speed and accuracy of the solution,realizes a more thorough filtering effect,and further reduces the impact of sub-low frequency harmonics on a wind power integrated system.Finally,simulation and experiment results have been used to prove the effectiveness of the proposed SHEPWM strategy when combined with intelligent algorithms.Index Terms-Wind power converter,adaptive genetic algorithm,selective harmonic elimination pulse-width modulation(SHEPWM),state equation,success rate.
基金supported by the National Natural Science Foundation of China[Grant Nos.51938011 and 51908405]Australian Research Council。
文摘Adopting the classical theory of hydrocodes,the constitutive relations of concretes are separated into an equation of state(EoS)which describes the volumetric behavior of concrete material and a strength model which depicts the shear properties of concrete.The experiments on the EoS of concrete is always challenging due to the technical difficulties and equipment limitations,especially for the specimen size effect on the EoS.Although some researchers investigate the shock properties of concretes by fly-plate impact tests,the specimens used in their tests are usually in one size.In this paper,the fly-plate impact tests on concrete specimens with different sizes are performed to investigate the size effect on the shock properties of concrete materials.The mechanical background of the size effect on the shock properties are revealed,which is related to the lateral rarefaction effect and the deviatoric stress produced in the specimen.According to the tests results,the modified EoS considering the size effect on the shock properties of concrete are proposed,which the bulk modulus of concrete is unpredicted by up to 20% if size effects are not accounted for.
文摘Encouraged by the wide spectrum of novel applications of gas hydrates,e.g.,energy recovery,gas separation,gas storage,gas transportation,water desalination,and hydrogen hydrate as a green energy resource,as well as CO2 capturing,many scientists have focused their attention on investigating this important phenomenon.Of course,from an engineering viewpoint,the mathematical modeling of gas hydrates is of paramount importance,as anticipation of gas hydrate stability conditions is effective in the design and control of industrial processes.Overall,the thermodynamic modeling of gas hydrate can be tackled as an equilibration of three phases,i.e.,liquid,gas,and solid hydrate.The inseparable component in all hydrate systems,water,is highly polar and non-ideal,necessitating the use of more advanced equation of states(EoSs) that take into account more intermolecular forces for thermodynamic modeling of these systems.Motivated by the ever-increasing number of publications on this topic,this study aims to review the application of associating EoSs for the thermodynamic modeling of gas hydrates.Three most important hydrate-based models available in the literature including the van der Waals-Platteeuw(vdW-P) model,Chen-Guo model,and Klauda-Sandler model coupled with and SAFT EoSs were investigated and compared with cubic EoSs.It was concluded that the CPA and SAFT EoSs gave very accurate results for hydrate systems as they take into account the association interactions,which are very crucial in gas hydrate systems in which water,methanol,glycols,and other types of associating compounds are available.Moreover,it was concluded that the CPA EoS is easier to use than the SAFT-type EoSs and our suggestion for the gas hydrate systems is the CPA EoS.
文摘With a new approach,the general current expressions of two typical second order catalytic reactions at microelectrodes are obtained.This allows the study of fast chemical reactions and systems where the reactants are present in similar concentrations.
文摘The importance of equations of state (EOS) has brought about the proliferation of hundreds of EOS. Nearly all prevailing cubic EOS could be regarded as the results of reforming the original vdW EOS. However, the accuracy of the vdW EOS is so low. In view of this, a new general equation is proposed that could be used to value or compare vdW type of EOS, and consequently develop a better vdW type of EOS.
文摘In the present work, effect of the attraction terms of four recently modified Peng-Robinson (MPR) equations of state on the prediction of solubility of caffeine, cholesterol, uracil and erythromycin was studied. The attraction terms of two of these equations are linear relative to the acentric factor and for the other two are exponential. It is found that the later show less deviation. Also interaction parameters for the studied systems are obtained and the percentage of average absolute relative deviation (%AARD) in each calculation is displayed.
基金This work was supported by the National Natural Sci- ence Foundation of China, (NSFC No. 10274055), the Natural Science Foundation of Gansu Province of China (No. 3ZS051-A25-027) and the Natural Science Foundation of Education Department of Gansu Province of China (No. 0410-01).
文摘The equation of state of MgSiO3 perovskite under high pressure and high temperature is simulated using the molecular dynamics method. It was found that the molecular dynamics simulation is very successful in accurately reproducing the measured molar volumes of MgSiO3 perovskite over a wide range of temperatures and pressures. The simulated equation of state of MgSiO3 perovskite matched experimental data at up to 140GPa at 300K, as well as the fitting data of others and results from the first-principles simulation based on the local density approximation. The simulated equations of state of MgSiO3 perovskite at higher temperatures and higher pressures also correspond to the other calculations. In addition, the volume compression data of MgSiO3 perovskite is simulated up to 120 GPa at 300, 900, 2000 and 3000 K, respectively.
文摘Progress in hydrate thermodynamic study necessitates robust and fast models to be incorporated in reservoir simulation softwares. However, numerous models presented in the literature makes selection of the best,proper predictive model a cumbersome task. It is of industrial interest to make use of cubic equations of state(EOS) for modeling hydrate equilibria. In this regard, this study focuses on evaluation of three common EOSs including Peng–Robinson, Soave–Redlich–Kwong and Valderrama–Patel–Teja coupled with van der Waals and Platteeuw theory to predict hydrate P–T equilibrium of a real natural gas sample. Each EOS was accompanied with three mixing rules, including van der Waals(vd W),Avlonitis non-density dependent(ANDD) and general nonquadratic(GNQ). The prediction of cubic EOSs was in sufficient agreement with experimental data and with overall AARD% of less than unity. In addition, PR plus ANDD proved to be the most accurate model in this study for prediction of hydrate equilibria with AARD% of 0.166.It was observed that the accuracy of cubic EOSs studied in this paper depends on mixing rule coupled with them,especially at high-pressure conditions. Lastly, the present study does not include any adjustable parameter to be correlated with hydrate phase equilibrium data.
文摘A new approach to the investigation of vdW type of equations of state (EOS) is developed by embedding a vapor pressure equation and a saturated liquid volume equation into vdW type EOS, which results in a new function AS(T). The AS(T) possesses the properties of an attractive parameter A(T), and if an EOS is accurate in the whole PVT space, then its numerical value equals A(T). As a useful tool for investigating EOS, the As(T) has been used to make comparisons among RKS, PRSVII, PT and ALS EOS, and to indicate where the shortcomings of the EOS are coming from. Based on the AS(T), a possible way to develop a real predictive equation of state is also suggested.
基金supported by the National Natural Science Foundation of China under Grant No.11504354Research Foundation of National Key Laboratory of Shock Wave and Detonation Physics under Grants No.9140C6703010703 and 9140C6703010803.
文摘The equations of state(EOSs)of materials are the cornerstone of condensed matter physics,material science,and geophysics.However,acquiring an accurate EOS in diamond anvil cell(DAC)experiments continues to prove problematic because the current lack of an accurate pressure scale with clarified sources of uncertainty makes it difficult to determine a precise pressure value at high pressure,and nonhydrostaticity affects both the volume and pressure determination.This study will discuss the advantages and drawbacks of various pressure scales,and propose an absolute pressure scale and correction methods for the effects of non-hydrostaticity.At the end of this paper,we analyze the accuracy of the determined EOS in the DAC experiments we can achieve to date.
基金Project (No. 50276054) supported by the National Natural Science Foundation of China
文摘In this paper, the LCVM mixing rule is extended to the multi-parameter equations of state by combining infi- nite-pressure and zero-pressure mixing rule models. The new LCVM-type mixing rule, coupled with Patel-Teja equation of state (EOS) is applied for vapor-liquid equilibria of different polar and non-polar systems in which the NRTL activity coefficient model is used to calculate the excess Gibbs free energy. The tested results agree well with existing experimental data within a wide range of temperatures and pressures. In comparison with the Van der Waals mixing rule, the new mixing rule gives much better corre- lations for the vapor-liquid equilibria of non-polar and polar systems.
文摘Supercritical CO_(2)(SCO_(2))Brayton cycle has received more and more attention in the field of power generation due to its high cycle efficiency and compact structure.SCO_(2) compressor is the core component of the cycle,and the improvement of its performance is the key to improving the efficiency of the entire cycle.However,the operation of the SCO_(2) compressor near the critical point has brought many design and operation problems.Based on the Reynolds Averaged Navier-Stokes(RANS)model,the performance and flow field of SCO_(2) centrifugal compressors based on different CO_(2) working fluid models are numerically investigated in this paper.The stability and convergence of the compressor steady-state simulation are also discussed.The results show that the fluid based on the Span-Wanger(SW)equation can obtain a more ideal compressor performance curve and capture a more accurate flow field structure,while the CO_(2) ideal gas is not suitable for the calculation of SCO_(2) centrifugal compressors.But its flow field can be used as the initial flow field for numerical calculation of centrifugal compressor based on CO_(2) real gas.
基金Federal Highway Administration at the University at Buffalo under Contract No.DTFH61-08-C-00012
文摘In the U.S., the current Load and Resistance Factor Design (LRFD) Specifications for highway bridges is a reliability-based formulation that considers failure probabilities of bridge components due to the actions of typical dead load and frequent vehicular loads. Various extreme load effects, such as earthquake and vessel collision, are on the same reliability-based platform. Since these extreme loads are time variables, combining them with not considered frequent. non- extreme loads is a significant challenge. The number of design limit state equations based on these failure probabilities can be unrealistically large and unnecessary from the view point of practical applications. Based on the opinion of AASHTO State Bridge Engineers, many load combinations are insignificant in their states. This paper describes the formulation of a criterion to include only the necessary load combinations to establish the design limit states. This criterion is established by examining the total failure probabilities for all possible time-invariant and time varying load combinations and breaking them down into partial terms. Then, important load combinations can be readily determined quantitatively,
基金Supported by the National Key R&D Program of China(G2023YFA1606403,2023YFE0101500)the National Natural Science Foundation of China(12335007,11961141003)the funding support from the State Key Laboratory of Nuclear Physics and Technology,Peking University(NPT2023ZX01)。
文摘The recent measurements of neutron skins via parity violation in electron scattering have extracted an abnormally thick neutron skin for 208 Pb,which has significant consequences in nuclear equation of state(EoS)and neutron star observations.In this study,we perform optimizations of extended Skyrme forces in a consistent manner by including neutron skin thicknesses from PREX-Ⅱand CREX experiments and investigate nuclear EoSs and neutron stars in the GW170817 event By varying the fitting weights of neutron skins,several new Skyrme parameterizations are obtained.Our results show the competition in the fitting procedure to simultaneously describe neutron skins,other properties of finite nuclei,and neutron star observations.The prospects of resolving neutron skin issues are also discussed.
文摘A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.
基金Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology(Grant No.2021yjrc38)Anhui Provincial Natural Science Foundation(Grant No.2208085QA27)+1 种基金National Natural Science Foundation of China(Grant Nos.11972046,12002266)the authors would like to thank these foundations for financial support.
文摘2,4-dinitroanisole(DNAN)is a good replacement for 2,4,6-trinitrotoluene(TNT)in melt-cast explosives due to its superior insensitivity.With the increasing use of DNAN-based melt-cast explosives,the prediction of reaction violence and hazard assessment of the explosives subjected to shock is of great significance.This study investigated the shock initiation characteristics for a DNAN-based melt-cast explosive,DHFA,using the one-dimensional Lagrangian apparatus.The embedded manganin gauges in the apparatus record the pressure histories at four Lagrangian positions and show that shock-todetonation transition in DHFA needs a high input shock pressure.The experimental data are analyzed to calibrate the Ignition and Growth model.The calibration is performed using an objective function based on both pressure history and the arrival time of shock.Good agreement between experimental and calculated pressure histories indicates the high accuracy of the calibrated parameters with the optimization method.
基金funded by the National Natural Science Foundation of China (Grant No. 11975145)
文摘This study aims to discuss anisotropic solutions that are spherically symmetric in the quintessence field,which describe compact stellar objects in the modified Rastall teleparallel theory of gravity.To achieve this goal,the Krori and Barua arrangement for spherically symmetric components of the line element is incorporated.We explore the field equations by selecting appropriate off-diagonal tetrad fields.Born-Infeld function of torsion f(T)=β√λT+1-1 and power law form h(T)=δTn are used.The Born-Infeld gravity was the first modified teleparallel gravity to discuss inflation.We use the linear equation of state pr=ξρto separate the quintessence density.After obtaining the field equations,we investigate different physical parameters that demonstrate the stability and physical acceptability of the stellar models.We use observational data,such as the mass and radius of the compact star candidates PSRJ 1416-2230,Cen X-3,&4U 1820-30,to ensure the physical plausibility of our findings.
基金The National Key Research and Development Program of China under contract Nos 2018YFC0310600 and2016YFC0300500。
文摘Compressed gas is usually used for the pressure compensation of the deep-sea pressure-maintaining sampler.The pressure and volume of the recovered fluid sample are highly related to the precharged gas. To better understand the behavior of the gas under high pressure, we present a new real gas state equation based on the compression factor Z which was derived from experimental data. Then theoretical calculation method of the pressure and volume of the sample was introduced based on this empirical gas state equation. Finally, the proposed calculation method was well verified by the high-pressure vessel experiment of the sampler under 115 MPa.
基金Supported by Specialized Research Fund for the Doctoral Program of Higher Education(20091101120009)the Project of State Key Laboratory of Science and Technology(YBKT09-03)+1 种基金the National Natural Science Foundation of China(11032002)National Basic Research Program of China(2010CB832706)
文摘An analytical method is presented to fit parameters of Jones-Wilkins-Lee (JWL) equation of state (EOS) for the chemical process of aluminum-polytetrafluoroethylene ( AI/PTFE ) mixture. Subroutine codes for both strength model and EOS were developed in explicit-FE code AUTODYN. Firstly, the shock Hugoniot data of reactive A1/PTFE mixture was analytically derived by implemen- ting this methodology. The JWL EOS was verified to fit shock Hugoniot data of both reacted and un- reacted A1/PTFE mixture, which gives reasonable results. Furthermore, to numerically ascertain the reaction phases of ignition and growth and quasi detonation of A1/PTFE mixture, characterized ex- periment was setup to validate the reaction phases and coefficients of JWL EOS for A1/PTFE mix- ture. From the test, a promising example of reactive mixture A1/PTFE is capable to enhance lethality of weapons, the status computation in clude quasi-detonation pressure and temperature of A1/PTFE mixture in different chemical reaction phases is validated.
基金supported by the National Natural Science Foundation of China(No.11822503)。
文摘Based on the Hugenholtz-Van Hove theorem six basic quantities of the EoS in isospin asymmetric nuclear matter are expressed in terms of the nucleon kinetic energy t(k),the isospin symmetric and asymmetric parts of the single-nucleon potentials U_(0)(ρ,k)and U_(sym,i)(ρ,k).The six basic quantities include the quadratic symmetry energy E_(sym,2)(ρ),the quartic symmetry energy E_(sym,4)(ρ),their corresponding density slopes L_(2)(ρ)and L_(4)(ρ),and the incompressibility coefficients K_(2)(ρ)and K_(4)(ρ).By using four types of well-known effective nucleon-nucleon interaction models,namely the BGBD,MDI,Skyrme,and Gogny forces,the density-and isospin-dependent properties of these basic quantities are systematically calculated and their values at the saturation density q_(0)are explicitly given.The contributions to these quantities from t(k)U_(0)(ρ,k),and U_(sym,i)(ρ,k)are also analyzed at the norma nuclear density q_(0).It is clearly shown that the first-order asymmetric term U_(sym,1)(ρ,k)(also known as the symmetry potential in the Lane potential)plays a vital role in determining the density dependence of the quadratic symmetry energy E_(sym,2)(ρ).It is also shown that the contributions from the high-order asymmetric parts of the single-nucleon potentials(U_(sym,i)(ρ,k)with i>1)cannot be neglected in the calculations of the other five basic quantities Moreover,by analyzing the properties of asymmetric nuclear matter at the exact saturation densityρ_(sat)(δ),the corresponding quadratic incompressibility coefficient is found to have a simple empirical relation K_(sat,2)=K_(2)(ρ_(0))-4.14L_(2)(ρ_(0))