Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed

An environmentally friendly method for extracting sulfonamides（SAs） residues from animal feed was described and applied. The method used online microwave-assisted steam extraction coupled with solid phase extraction（MASE-SPE）, which was followed by the analysis using high performance liquid chromatography-mass spectro- metry（HPLC-MS/MS）. The SAs residues were extracted successively with water steam under microwave irradiation, and thus directly introduced into an SPE colunm containing cation-exchange resin. The SAs were then eluted with methanol-ammonia（90：10, volume ratio） from the SPE column and followed by HPLC-MS/IVIS. The limits of detec- tion（LODs） for the analytes ranged from 0.24 ng/g to 0.49 ng/g. The limits of quantification（LOQs） ranged from 0.82 ng/g to 1.63 ng/g. Average recoveries of SAs were 76.3%--92.1%. The developed method was a reliable and envi-ronmentally friendly alternative to previous methods with respect to time, solvent and labor consumption for the analysis of SAs in animal foodstuffs.

Performance evaluation of an improved biomass-fired cogeneration system simultaneously using extraction steam, cooling water, and feedwater for heating

An advanced cogeneration system based on biomass direct combustion was developed and its feasibility was demonstrated. In place of the traditional single heat source (extraction steam), the extraction steam from the turbine, the cooling water from the plant condenser, and the low-pressure feedwater from the feedwater preheating system were collectively used for producing district heat in the new scheme. Hence, a remarkable energy-saving effect could be achieved, improving the overall efficiency of the cogeneration system. The thermodynamic and economic performance of the novel system was examined when taking a 35 MW biomass-fired cogeneration unit for case study. Once the biomass feed rate and net thermal production remain constant, an increment of 1.36 MW can be expected in the net electric production, because of the recommended upgrading. Consequently, the total system efficiency and effective electrical efficiency augmented by 1.23 and 1.50 percentage points. The inherent mechanism of performance enhancement was investigated from the energy and exergy aspects. The economic study indicates that the dynamic payback period of the retrofitting project is merely 1.20 years, with a net present value of 5796.0 k$. In conclusion, the proposed concept is validated to be advantageous and profitable.

Flexible Operation Mode of Coal-fired Power Unit Coupling with Heat Storage of Extracted Reheat Steam

In order to provide more grid space for the renewable energy power,the traditional coal-fired power unit should be operated flexibility,especially achieved the deep peak shaving capacity.In this paper,a new scheme using the reheat steam extraction is proposed to further reduce the load far below 50%rated power.Two flexible operation modes of increasing power output mode and reducing fuel mode are proposed in heat discharging process.A 600 MW coal-fired power unit with 50%rated power is chosen as the research model.The results show that the power output is decreased from 300.03 MW to 210.07 MW when the extracted reheat steam flow rate is 270.70 t·h^(-1),which increases the deep peak shaving capacity by 15%rated power.The deep peak shaving time and the thermal efficiency are 7.63 h·d^(-1)and 36.91%respectively for the increasing power output mode,and they are 7.24 h·d^(-1)and 36.58%respectively for the reducing fuel mode.The increasing power output mode has the advantages of higher deep peak shaving time and the thermal efficiency,which is recommended as the preferred scheme for the flexible operation of the coal-fired power unit.

Energy-Saving Optimization Study on 700℃ Double Reheat Advanced Ultra-Supercritical Coal-Fired Power Generation System

700°C double reheat advanced ultra-supercritical power generation technology is one of the most important development directions for the efficient and clean utilization of coal.To solve the great exergy loss problem caused by the high superheat degrees of regenerative steam extractions in 700°C double reheat advanced ultra-supercritical power generation system,two optimization systems are proposed in this paper.System 1 is integrated with the back pressure extraction steam turbine,and system 2 is simultaneously integrated with both the outside steam cooler and back pressure extraction steam turbine.The system performance models are built by the Ebsilon Professional software.The performances of optimized systems are analyzed by the unit consumption method.The off-design performances of optimization systems are analyzed.The results show that:the standard power generation coal consumption rates of optimization systems 1 and 2 are decreased by 1.88 g·(kW·h)^(–1),2.97 g·(kW·h)^(–1)compared with that of the 700°C reference system;the average superheat degrees of regenerative steam extractions of optimized systems 1 and 2 are decreased by 122.2°C,140.7°C(100%turbine heat acceptance condition),respectively.The comparison results also show that the performance of the optimized system 2 is better than those of the optimized system 1 and the 700°C reference system.The power generation standard coal consumption rate and the power generation efficiency of the optimized system 2 are about 232.08 g·(kW·h)^(–1)and 52.96%(100%turbine heat acceptance condition),respectively.